Abstract:For the purpose of improve cutting property and anisotropy of steels imultaneously, the control of sulfidemorphologywas the key technique for producing free cutting steel.Effect of Mg addition and Ca addition on the composition and diameter of inclusion for the sulfur steel were studied. In the laboratory, the steel was melted by the vertical resistance furnace.One of the steels was treated by Mg, and the other steel was treated by Ca. The samples extracted from the liquid steel were polished and analyzed by scanning electron microscopy and energy dispersive spectrometer. The results show that the steel with Mg addition has tinier oxide inclusions than that with Ca addition. The tiny Mg-Al-O inclusions are the nucleus of MnS in the solidification process of liquid steel. The Mg of composite sulfide (Mg-Mn-S) surrounding oxide core derives from Mg diffusion of the oxide core. The Ca-Al-O oxide of Ca treated steel also could serve as the nucleus of MnS in solidification process of liquid steel. The Ca of composite sulfide (Ca-Mn-S) comes from Ca in the liquid steel. In addition,the mass percent of Ca in the oxide core increaseswith the diffusion of Ca in the composite sulfide.
收稿日期: 2017-04-14
出版日期: 2017-11-14
引用本文:
田 俊,王德永,屈天鹏,苏丽娟,鄂欣蕊. 钙、镁在含硫钢中硫化物变性过程中的作用[J]. 钢铁, 2017, 52(11): 27-31.
TIAN Jun,WANG De-yong,QU Tian-peng,SU Li-juan,E Xin-rui. Role and distinction of Ca and Mg to sulfide modification for sulfur steel. Iron and Steel, 2017, 52(11): 27-31.
J Maciejewski.The Effects of Sulfide Inclusions on Mechanical Properties and Failures of Steel Components[J].J Fail Anal and Preven, 2015, 15(2):169-178
[5]
J Maciejewski.The Effects of Sulfide Inclusions on Mechanical Properties and Failures of Steel Components[J].J Fail Anal and Preven, 2015, 15(2):169-178
[6]
C H Leung, L H Vanvlack.Solution and Precipitation Hardening in (Ca,Mn) Sulfides and Selenides[J].Metallurgical Transactions A, 1981, 12(6):987-991
[6]
C H Leung, L H Vanvlack.Solution and Precipitation Hardening in (Ca,Mn) Sulfides and Selenides[J].Metallurgical Transactions A, 1981, 12(6):987-991
[7]
F Matsuno, S C Nishikida, H Ikesaki.Mechanical properties of manganese sulphides in the temperature range between room temperature and 1000[J].Trans. ISIJ, 1985, 25(9):989-998
[7]
F Matsuno, S C Nishikida, H Ikesaki.Mechanical properties of manganese sulphides in the temperature range between room temperature and 1000[J].Trans. ISIJ, 1985, 25(9):989-998
[8]
K Cui, P Z Sun, X L Qiao, et al.free cutting prehardened plastic mould steel 5NiSCa[J].Die & Mould Tech., 1990, 2(5):487-494
[8]
K Cui, P Z Sun, X L Qiao, et al.free cutting prehardened plastic mould steel 5NiSCa[J].Die & Mould Tech., 1990, 2(5):487-494
T S Zhang, D Y Wang, C W Liu, et al.Modification of inclusions in liquid iron by Mg treatment[J].Journal of Iron and Steel Research, International, 2014, 21(Suppl):99-103
[10]
T S Zhang, D Y Wang, C W Liu, et al.Modification of inclusions in liquid iron by Mg treatment[J].Journal of Iron and Steel Research, International, 2014, 21(Suppl):99-103
[11]
J Fu, Y G Yu, A R Wang, et al.Inclusion Modification with Mg Treatment for 35CrNi3MoV Steel[J].J. Mater. Sci. Technol., 1998, 14(1):54-56
[11]
J Fu, Y G Yu, A R Wang, et al.Inclusion Modification with Mg Treatment for 35CrNi3MoV Steel[J].J. Mater. Sci. Technol., 1998, 14(1):54-56
[12]
N Tsunekage, H Tsubakino.Effects of sulfur content and sulfide-forming elements addition on impact properties of ferrite–pearlitic microalloyed steels[J].ISIJ Int., 2001, 41(5):498-505
[12]
N Tsunekage, H Tsubakino.Effects of sulfur content and sulfide-forming elements addition on impact properties of ferrite–pearlitic microalloyed steels[J].ISIJ Int., 2001, 41(5):498-505