Thermodynamic calculation on yield of shaft furnace as COG pyrolysised with O2
ZHOU Yu-lu1, JIANG Xin1, WANG Xiao-ai2, ZHENG Hai-yan1, LUO Guo-ping3, SHEN Feng-man1
1. School of Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China; 2. Technology Research Institute, HBIS Group, Shijiazhuang 050023, Hebei, China; 3. School of Materials and Metallurgy, Inner Mongolia of Science and Technolgoy, Baotou 014010, Nei Mongol, China
Abstract:The consumption of coke oven gas (COG) in the shaft furnace reduction process will affect the yield of metallic Fe. In order to better understand the relation between the COG consumption (pyrolysised with O2) and the yield of metallic Fe, the consumption of COG and the yield in shaft furnace process under ideal conditions were thermodynamically calculated. The calculation results show that, in the shaft furnace process, the COG consumption as a heat source is more than that as a reducing agent. There are two methods to supply the heat gap. The tendency of metallic Fe production is different from two different methods of heat compensation. In the case of directly supplying reformed COG, the yield of metallic Fe decreases with increasing formation temperature of metallic Fe. For a coke oven with a capacity of 120×104 t, as the formation temperature are 850 and 900 ℃, the corresponding annual yields of shaft furnace are 50.72×104 and 49.90×104 t/a. In the case of ZR technology followed by supplying extra COG, the yield of metallic Fe first increases and then decreases with increasing formation temperature of metallic Fe. For a coke oven with a capacity of 120×104 t, as the formation temperature are 845 and 900 ℃, the corresponding annual yields of shaft furnace are 56.69×104 t/a (maximum value) and 55.68×104 t/a. The findings from this work may provide guidelines for choosing optimal parameters for an actual shaft furnace process.
[1] 张福明,曹朝真,徐辉.气基竖炉直接还原技术的发展现状与展望[J].钢铁,2014,49(3):1.(ZHANG Fu-ming, CAO Chao-zhen, XU Hui. Current status and prospects of gas-based shaft furnace direct reduction technology[J]. Iron and Steel, 2014, 49(3): 1.) [2] 沈峰满,姜鑫,高强健,等.直接还原铁生产技术的现状及展望[J].钢铁,2017,52(1):7.(SHEN Feng-man, JIANG Xin, GAO Qiang-jian, et al. Situation and prospect on production technology of direct reduction iron[J]. Iron and Steel, 2017, 52(1): 7.) [3] 张建国.直接还原铁工艺技术的对比分析论述[J].资源再生,2018(2):57.(ZHANG Jian-guo. Comparison and analysis of direct reduction of iron technology[J]. Resource Recycling, 2018(2): 57.) [4] JIANG X, WANG L, SHEN F M, et al. Adiabatic carbon rate of alternative ironmaking processes to produce hot metal [J]. Steel Research International, 2014, 85(1): 35. [5] 徐宽. 气基直接还原竖炉内物料下行及还原气流场研究[D].秦皇岛:燕山大学,2017.(XU Kuan. Research on Particle Descending Velocity Distribution and Reducing Gas Flow Field in Gas-based Direct Reduction Shaft Furnace[D]. Qinhuangdao:Yanshan University, 2017.) [6] JIANG X, LIU S H, HUANG T Y, et al. Effects of reducing time on metallization degree of carbothermic reduction of tall pellets bed[J]. ISIJ International, 2016, 56(1): 88. [7] 何桂珍,都兴红,曲赫威,等.非高炉冶炼技术的发展现状与展望[J].矿产综合利用,2014(3):1.(HE Gui-zhen, DU Xing-hong, QU He-wei, et al. Present status and development perspective of non-blast furnace ironmaking technology [J].Multipurpose Utilization of Mineral Resources, 2014(3): 1.) [8] 应自伟,储满生,唐珏,等.非高炉炼铁工艺现状及未来适应性分析[J].河北冶金,2019(6):1.(YING Zi-wei, CHU Man-sheng, TANG Jue, et al. Current situation and future adaptability analysis of non-blast furnace ironmaking process[J]. Hebei Metallurgy, 2019(6): 1.) [9] JIANG X, WANG L, SHEN F M. Shaft furnace direct reduction technology—Midrex and energiron[J]. Advanced Materials Research, 2013, 805: 654. [10] 闫龙飞,师学峰,赵凯,等.高磷鲕状赤铁矿气基竖炉直接还原试验[J].钢铁,2018,53(2):14.(YAN Long-fei, SHI Xue-feng, ZHAO Kai, et al. Experiment on direct reduction of gas-based shaft furnace of high phosphorus oolitic hematite[J]. Iron and Steel, 2018, 53(2): 14.) [11] 朱仁良.未来炼铁技术发展方向探讨以及宝钢探索实践[J].钢铁,2020,55(8):2.(ZHU Ren-liang. Discussion on future development direction of ironmaking technology and exploratory practice of Baosteel[J]. Iron and Steel, 2020, 55(8):2.) [12] 张福明.首钢绿色低碳炼铁技术的发展与展望[J].钢铁,2020,55(8):11.(ZHANG Fu-ming. Development and prospect of green and low carbon ironmaking technologies in Shougang[J]. Iron and Steel, 2020, 55(8): 11.) [13] 王广,王静松,左海滨,等.高炉煤气循环耦合富氢对中国炼铁低碳发展的意义[J].中国冶金,2019,29(10):1.(WANG Guang, WANG Jing-song, ZUO Hai-bin, et al. Effect of blast furnace gas recycling with hydrogen injection on low carbon development of Chinese ironmaking[J]. China Metallurgy, 2019, 29(10): 1.) [14] 张琦,刘帅,徐化岩,等.钢铁企业智慧能源管控系统开发与实践[J].钢铁,2019,54(10):125.(ZHANG Qi, LIU Shuai, XU Hua-yan, et al. Development and practice of smart energy management and control system in iron and steel works[J]. Iron and Steel, 2019, 54(10): 125.) [15] Hamadeh H, Mirgaux O, Patisson F. Detailed modeling of the direct reduction of iron ore in a shaft furnace[J]. Materials, 2018, 11(10):1865. [16] LI W, FU G Q, CHU M S, et al. Influence of Cr2O3 addition on the gas-based direct reduction behavior of hongge vanadium titanomagnetite pellet with simulated shaft furnace gases[J]. ISIJ International, 2018, 58(4): 604. [17] 吴开基,陈凌,张涛,等.气基竖炉工况焦炉煤气甲烷改质行为试验[J].钢铁,2014,49(3):11.(WU Kai-ji, CHEN Ling, ZHANG Tao, et al. Experimental on CH4 reforming behavior of coke oven gas in gas-based shaft furnace[J]. Iron and Steel, 2014, 49(3): 11.) [18] BAI M H, GE J L, PIAO Y M, et al. The study of the ventilation influence to gas-based direct reduction shaft furnace flow field[J]. Applied Mechanics and Materials, 2013, 2685: 2990. [19] 梁之凯,黄柱成,易凌云.焦炉煤气竖炉法生产DRI的煤气用量及利用率[J].中国冶金,2017,27(11):18. (LIANG Zhi-kai, HUANG Zhu-cheng, YI Ling-yun. Coke oven gas consumption and its utilization ratio for DRI production in shaft furnace[J]. China Metallurgy, 2017, 27(11): 18.) [20] 高成亮,王太炎.利用焦炉煤气生产直接还原铁技术[J].燃料与化工,2010,41(6):15. (GAO Cheng-liang, WANG Tai-yan. Technology of producing direct-reduced iron with coke oven gas[J]. Fuel and Chemical Processes, 2010, 41(6):15.) [21] 朴英敏. 气基直接还原竖炉流场研究及优化[D].秦皇岛:燕山大学,2013.(PIAO Ying-min. Research on Gas Based Direct Reduction Shaft Furnace Flow Field and Optimization[D]. Qinhuangdao:Yanshan University, 2013.) [22] 刘振海.分析化学手册(第6分册:热分析)[M].北京:化学工业出版社,1994.(LIU Zhen-hai. Handbook of Analytical Chemistry (Volume 6: Thermal Analysis) [M]. Beijing: Chemical Industry Press, 1994.) [23] 傅献彩,沈文霞,姚天扬.物理化学[M].北京:高等教育出版社,1980.(FU Xian-cai, SHEN Wen-xia, YAO Tian-yang. Physical and Chemical[M].Beijing: Higher Education Press,1980.) [24] 梁英教.无机物热力学数据手册[M].沈阳:东北大学出版社,1993.(LIANG Ying-jiao. Data Manual on Thermodynamics of Inorganic Matter[M].Shenyang: Northeastern University Press, 1993.) [25] 黄希祜.钢铁冶金原理 [M].3版.北京:冶金工业出版社,2002.(HUANG Xi-hu. Principles of Steel Metallurgy[M]. 3rd ed. Beijing: Metallurgical Industry Press, 2002.)