Effect of titanium content in steel on slag-metal reaction in continuous casting mold
WANG Xing-juan1,2, JIN He-bin1,2, ZHU Li-guang2,3, WANG Bao-hua4, ZHANG Ming-bo4, WANG Bo1,2
1. College of Metallurgy and Energy,North China University of Science and Technology, Tangshan 063210, Hebei, China; 2. Hebei Engineering Research Center of High Quality Steel Continuous Casting, Tangshan 063000, Hebei, China; 3. School of Material Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, Hebei, China; 4. Wire Rod Products Business Department, HBIS Group Chengsteel Company, Chengde 067002, Hebei, China
Abstract:In the casting of high titanium steel,the slag-metal reaction was prone to the floater,which deteriorated the quality of the slab and caused steel leakage in severe cases. Scanning electron microscopy was used to analyze the floater that appeared in the field pouring. The slag-metal reaction was studied in combination with a high-temperature vacuum pressure sintering furnace. The comprehensive properties of slag were discussed in detail by using a rotary viscosity meter,melting point tester,XRD,and OPA metal in-situ analyzer. The result shows that with the increase of Ti content in high titanium steel,the degree of slag-metal interface reaction increases;No slag-metal reaction occurred when high titanium steel w(Ti)=0.05%. When w(Ti)=0.10% and w(Ti)=0.20% of high-titanium steel,slag-metal interface reaction occurs. w(Ti) in steel decreased by 0.02% and 0.04%,and w(Si) increased by 0.02% and 0.03%,respectively. w(SiO2) in the mold flux decreased by 0.36% and 0.8%,and w(TiO2) increased by 2.17% and 4.3%,respectively. After the slag-metal reaction occurs,the slag basicity increases. Ti enters the slag as an oxide and does not dissolve,resulting in an increase in the viscosity and melting point of the slag.
王杏娟, 靳贺斌, 朱立光, 王宝华, 张明博, 王博. 钢中钛含量对连铸结晶器内渣金反应的影响[J]. 钢铁, 2020, 55(12): 46-55.
WANG Xing-juan, JIN He-bin, ZHU Li-guang, WANG Bao-hua, ZHANG Ming-bo, WANG Bo. Effect of titanium content in steel on slag-metal reaction in continuous casting mold[J]. Iron and Steel, 2020, 55(12): 46-55.
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