Research progress of low-order coal pyrolysis process and semi-coke production process
NING Xiao-jun1,2, DANG Han1, ZHANG Jian-liang1, WANG Guang-wei1, ZHANG Nan1, YUE Huai-zhong3
1. School of Metallurgy and Ecological Engineering, University of Science and Technology Beijing, Beijing100083, China; 2. Guanzhuang Campus, University of Science and Technology Beijing, Beijing 100083,China; 3. Project Department, Henan Hongqi Coal Industry Co., Ltd., Zhengzhou 450000, Henan, China
Abstract:Nowadays, fossil energy is increasingly depleted, so it is necessary to make full use of existing resources and develop new renewable resources. The low-rank coal has high volatilization, good combustion and reactivity, and direct combustion cannot fully explore its potential value. Pyrolysis technology, as a kind of technology that can utilize coal resources efficiently, has attracted more attention from many scholars. According to the characteristics of low-rank coal reactivity in different conversion stages, blue carbon can be prepared by controlling coal pyrolysis. The gasification activity of blue carbon powder is better than that of coke powder and anthracite powder, when used in blast furnace injection, the mixed injection of blue carbon and anthracite can also improve the injection performance of mixed coal and promote the steady production of the blast furnace. Blue carbon has become a new type of carbon material with high fixed carbon, high chemical activity, low ash content, low phosphorus, and low sulfur, the production and preparation technology of blue carbon has also become a hot topic for many scholars. The global energy consumption and the energy structure of our country in recent years, introduces some low-order coal pyrolysis processes, the application of blue carbon in blast furnace injection and sintering, and the production process of blue carbon was analyzed briefly. The properties of blue carbon and common fuel in the blast furnace are compared. The prospect of low-order coal pyrolysis process and blue carbon production process is prospected. It is suggested that the development of the large scale, automatic, and environment-friendly plant is the development trend of the pyrolysis process in the future.
宁晓钧, 党晗, 张建良, 王广伟, 张楠, 岳怀忠. 低阶煤热解与兰炭生产工艺研究进展[J]. 钢铁, 2021, 56(1): 1-11.
NING Xiao-jun, DANG Han, ZHANG Jian-liang, WANG Guang-wei, ZHANG Nan, YUE Huai-zhong. Research progress of low-order coal pyrolysis process and semi-coke production process[J]. Iron and Steel, 2021, 56(1): 1-11.
[1] 施瑞盟,张龙,邹冲,等.兰炭和喷吹煤组成与结构特征对可磨性的影响[J].钢铁,2020,55(8):86.(SHI Rui-meng, ZHANG long, ZOU Chong, et al. Effects of composition and structure characteristics of blue carbon and blowing coal on abrasive properties[J]. Iron and Steel,2020,55(8):86.) [2] BP Statistical Review of World Energy[EB]. https://www.bp.com/en/global/corporate/energy-economics.html, 2018-06-20. [3] 高天明,张艳.中国煤炭资源高效清洁利用路径研究[J].煤炭科学技术,2018,46(7):157.(GAO Tian-ming, ZHANG Yan. A study on efficient and clean utilization path of voal resources in China[J]. Coal Science and Technology,2018,46(7):157.) [4] 范雯阳,王理想,林远奎,等.低阶煤提质工艺优化研究进展[J].应用化工,2019,48(7):1667.(FAN Wen-yang, WANG Li-xiang, LIN Yuan-kui, et al. Advances in optimization of quality improvement process for low grade coal[J]. Applied Chemical,2019,48(7):1667.) [5] 常慧.预处理对低变质煤热解特性影响的研究[D].西安:西北大学,2019.(CHANG Hui.Effects of Pretreatment on Pyrolysis Characteristics of Low Metamorphic Coal[D].Xi′an: Northwestern University,2019.) [6] 毕传光,黄椿朝,宁晓钧,等.高炉喷吹兰炭的最佳配比[J].钢铁,2020,55(6):25.(BI Chuan-guang, HUANG Chun-chao, NING Xiao-jun, et al. Optimum ratio of carbon dioxide in blast furnace injection[J]. Iron and Steel,2020,55(6):25.) [7] 刘竹林,蒋友源,寿擎,等.高炉混合喷吹用生物质燃料可磨性及燃烧性能分析[J].中国冶金,2020,30(3):8.(LIU Zhu-lin, JIANG You-yuan, SHOU Qing, et al. Analysis on the abrasibility and combustion performance of biomass fuel for mixed blast furnace injection[J]. China Metallurgy,2020,30(3):8.) [8] 阙志刚,吴胜利,王金生,等.无烟煤代替焦粉燃烧行为及对烧结NOx排放的影响[J].钢铁,2019,54(10):23. (QUE Zhi-gang, WU Sheng-li, WANG Jin-sheng, et al. Combustion behavior of anthracite instead of coke powder and its influence on sintering NOx emission[J].Iron and Steel,2019,54(10):23.) [9] 王朋. 生物质半焦应用于高炉喷吹的基础研究[D].北京:北京科技大学,2019.(WANG Peng. Basic Research on the Application of Biomass Coke in Blast Furnace Injection[D]. Beijing:University of Science and Technology Beijing,2019.) [10] 刘振宇.煤化学的前沿与挑战:结构与反应[J].中国科学:化学,2014,44(9):1431.(LIU Zhen-yu. Frontiers and challenges of coal chemistry: Structure and reaction[J]. Chinese Science: Chemistry,2014,44(9):1431.) [11] 李杰,宋灿阳,李小静,等.高炉喷吹煤粉燃烧性与反应性的研究与应用[J].中国冶金,2019,29(1):8.(LI Jie, SONG Can-yang, LI Xiao-jing, et al. Research and application of blast furnace pulverized coal combustion and reactivity[J]. China Metallurgy,2019,29(1):8.) [12] 高强健,何耘丰,刘曌,等.喷吹用煤粉爆炸特性及抑爆措施[J].钢铁,2018,53(12):24.(GAO Qiang-jian, HE Yun-feng, LIU Zhao, et al. Explosion characteristics and explosion suppression measures of coal powder for injection[J]. Iron and Steel, 2018,53(12):24.) [13] 谢全安,魏侦凯,郭瑞,等.焦炭热性质评价方法的研究进展[J].钢铁,2018,53(9):1.(XIE Quan-an, WEI Zhen-kai, GUO Rui, et al. Research progress of coke thermal property evaluation method[J]. Iron and Steel, 2018,53(9):1.) [14] 兰玉顺,陈文文.煤热解技术研究与开发进展[J].煤化工,2017,45(2):66.(LAN Yu-shun, CHEN Wen-wen. Advances in research and development of coal pyrolysis technology[J].Coal Chemical Industry,2017,45(2):66.) [15] 顾凯,吴胜利,寇明银.焦炭热态性能对高炉产质量影响的统计解析[J].钢铁,2019,54(2):20.(GU Kai,WU Sheng-li, KOU Ming-yin. Statistical analysis of the influence of coke thermal properties on blast furnace production quality[J]. Iron and Steel,2019,54(2):20.) [16] 李青松,李如英,马志远,等.美国LFC低阶煤提质联产油技术新进展[J].中国矿业,2010,19(12):82.(LI Qing-song, LI Ru-ying, MA Zhi-yuan, et al. New progress LFC low-order coal quality and co-production oil technology in America[J]. China Mining,2010,19(12):82.) [17] 周琦.低阶煤提质技术现状及完善途径[J].洁净煤技术,2016,22(2):23.(ZHOU Qi. Current status and ways to improve the quality technology of low grade coal[J].Clean Coal Technology,2016,22(2):23.) [18] 线梦瑶.兰炭生产工艺的HAZOP分析[D].西安:西安科技大学,2017.(XIAN Meng-yao. Analysis of Blue Carbon Production Process[D]. Xi′an: Xi′an University of Science and Technology,2017.) [19] 全荣.高效煤炭热分解气化技术的开发[J].世界金属导报,2015-03-10(B08).(QUAN Rong.Development of high efficiency coal thermal decomposition gasification technology [J]. World Metal Guide,2015-03-10(B08).) [20] 陈兆辉,高士秋,许光文.煤热解过程分析与工艺调控方法[J].化工学报,2017,68(10):3693.(CHEN Zhao-hui, GAO Shi-qiu, XU Guang-wen. Analysis and control method of coal pyrolysis process[J]. Journal of Chemical Industry,2017,68(10):3693.) [21] 赵沛,董鹏莉.碳排放是中国钢铁业未来不容忽视的问题[J].钢铁,2018,53(8):1.(ZHAO Pei, DONG Peng-li. Carbon emission is an issue that cannot be ignored in the future of China's steel industry[J]. Iron and Steel, 2008,53(8):1.) [22] 周琦,白立强,陈兆辉,等.复合流化床低阶煤热解制备兰炭的工艺条件[J].过程工程学报,2016,16(3):516.(ZHOU Qi, BAI Li-qiang, CHEN Zhao-hui, et al. Conditions for preparation of blue carbon by pyrolysis of low grade coal in compound fluidized bed[J]. Journal of Process Engineering,2016,16(3):516.) [23] 李伟,杨晓乐,程磊,等.不同高炉煤粉的基础性能分析[J].中国冶金,2019,29(11):67.(LI Wei, YANG Xiao-le, CHENG Lei, et al. Analysis of basic properties of pulverized coal in different blast furnaces[J]. China Metallurgy,2019,29(11):67.) [24] 白凤强,王小东.新兴铸管3号高炉喷吹兰炭工业试验[J].炼铁,2019,38(3):16.(BAI Feng-qiang, WANG Xiao-dong. Industrial test of injecting blue carbon into Xinxing Cast Tube No.3 blast furnace[J]. Ironmaking,2019,38(3):16.) [25] 巩黎伟.太钢高炉喷吹兰炭煤生产实践[J].炼铁,2018,37(5):16.(GONG Li-wei. Production practice of blue carbon coal injection in blast furnace of Taigang[J]. Ironmaking,2018,37(5):16.) [26] 付利俊,李晓炅,孙睿.半焦在包钢高炉喷吹工艺中的应用研究[J].燃料与化工,2020,51(3):1.(FU Li-jun, LI Xiao-jiong, SUN Rui. Application of semi-coke in blast furnace blowing process of Baogang[J]. Fuel and Chemical,2020,51(3):1.) [27] 张典波,徐辉,朱锦明.宝钢2号高炉喷吹兰炭生产试验[J].炼铁,2015,34(1):40.(ZHANG Dian-bo, XU Hui, ZHU Jin-ming. Production test of carbon injection into No.2 BF of Baosteel[J]. Ironmaking, 2015,34(1):40.) [28] 杨双平,蔡文淼,郑化安,等.高炉喷吹半焦及其性能分析[J].过程工程学报,2014,14(5):896. (YANG Shuang-ping, CAI Wen-miao, ZHENG Hua-an, et al. Injection of semi-coke into blast furnace and its performance analysis[J].Journal of Process Engineering, 2014,14 (5):896.) [29] 彭政富,张建良,毕传光,等.焦粉与兰炭对高炉混煤燃烧特性的影响[J].钢铁,2019,54(12):10. (PENG Zheng-fu, ZHANG Jian-liang, BI Chuan-guang, et al. Effect of coke powder and semi-coke on combustion characteristics of blast furnace mixed coal[J]. Iron and Steel,2019,54(12):10.) [30] 高冰,张建良,左海滨,等.高炉用冶金焦与兰炭气化反应行为研究[J].煤炭转化,2015,38(2):62.(GAO Bing, ZHANG Jian-liang, ZUO Hai-bin, et al. Reaction behavior of metallurgical coke and carbon gasification in blast furnace[J]. Coal Conversion, 2015,38 (2): 62.) [31] 郗小亮,马杰,巨建涛,等.兰炭作烧结燃料对生产小球团烧结矿的影响[J].烧结球团,2017,42(1):9.(XI Xiao-liang, MA Jie, JU Jian-tao, et al. Effect of lantan as sinter fuel on the production of pellet sinter[J]. Sinter Pellets,2017,42 (1):9.) [32] 李杰,李小静,李帮平,等.兰炭用作高炉喷吹燃料的试验分析[J].中国冶金,2019,29(12):14.(LI Jie,LI Xiao-jing, LI Bang-ping, et al. Experimental analysis of blue carbon used as injection fuel for blast furnace[J].China Metallurgy,2019,29(12):14.) [33] 张智立,张明飞.鲁奇气化炉技术探讨[J].中国科技博览,2011(22):20.(ZHANG Zhi-li, ZHANG Ming-fei. Discussion on the gasifier technology of Luqi[J].China Science and Technology Expo,2011(22):20.) [34] 陈海波.低阶煤兰炭干馏炉热工特性研究及工艺参数优化[D].西安:西安建筑科技大学,2013. (CHEN Hai-bo. Study on Thermal Characteristics and Optimization of Process Parameters of Low-order Coal, Orchid and Carbon retort[D].Xi′an:Xi′an University of Architecture and Technology,2013.) [35] 任华伟,储满生,吕青青,等.铁矿粉对铁焦性能的影响及机理[J].钢铁,2018,53(8):21.(REN Hua-wei, CHU Man-sheng, LÜ Qing-qing, et al. Effect of iron ore powder on the properties of ferrocoke and its mechanism[J]. Iron and Steel, 2018,53(8):21.) [36] 朱书全.褐煤提质技术开发现状及分析[J].洁净煤技术,2011,17(1):1.(ZHU Shu-quan. Development status and analysis of lignite extraction technology[J].Clean Coal Technology, 2011,17 (1): 1.) [37] 朱利,折媛,湛文龙,等.焦炭高温性能对高炉焦炭负荷影响的生产实践[J].钢铁,2018,53(4):8.(ZHU Li, SHE Yuan, ZHAN Wen-long, et al. Production practice of coke high-temperature performance on coke load in blast furnace[J]. Iron and Steel, 2018,53(4):8.) [38] 郭慧冬.煤质对鲁奇气化炉经济运行的影响分析[J].化工管理,2019(2):121. (GUO Hui-dong. Effect of coal quality on economic operation of Luqi Gasifier[J]. Chemical Industry Management, 2019(2): 121.) [39] 钟林.新疆五彩湾不粘煤气力分级及其热解制备兰炭初步研究[D].乌鲁木齐:新疆大学,2011.(ZHONG Lin. Preliminary Study on Preparation of Blue Carbon by Pyrolysis and Non-Adhesive Gas Force Classification in Xinjiang Wucaiwan[D]. Urumqi:Xinjiang University,2011.) [40] 庞克亮,武吉,刘冬杰,等.焦炉燃料燃烧控制及污染物排放特性[J].钢铁,2018,53(4):83.(PANG Ke-liang,WU Ji,LIU Dong-jie,et al. Combustion control and pollutant emission characteristics of coke oven fuel[J]. Iron and Steel,2018,53(4):83.)