Abstract：As the demand for vanadium-containing products continuously increasing,the output of vanadium extraction tailings has also increased year by year. If it is not effectively and comprehensively utilized,it will not only occupy a large amount of land,cause a lot of waste of valuable metals,but also cause serious pollution to the environment. Combined with the physical and chemical characteristics of vanadium extraction tailings, the research progress of vanadium extraction tailings in four aspects are reviewed,such as the recovery of valuable components,preparation of special functional materials,removal of harmful elements,and production of building materials. At present,although some progress has been made in the comprehensive utilization of vanadium extraction tailings,there are still disadvantages such as the insufficient economy and environmental protection,and limited consumption. With the continuous improvement of people′s awareness of environmental protection and the decrease of high-grade rich ore reserves year by year. The comprehensive utilization of vanadium extraction tailings in the future will inevitably lead to the comprehensive recovery of multiple valuable elements,reducing the content of toxic and radioactive elements in productions. At the same time,it is necessary to further simplify the process flow and use the vanadium extraction tailings to prepare high value-added products,so as to reduce production costs,expand the use range of products,increase the consumption of vanadium extraction tailings,and achieve environmental protection and sustainable development of economic growth.
[1] 李兰杰. 提钒尾渣资源化利用应用基础研究[D]. 沈阳:东北大学,2013.(LI Lan-jie. Fundamental Applied Research on Resource Utilization of Vanadium Tailings[D]. Shenyang:Northeastern University,2013.) [2] 许崇光,王海林,杨欢,等. 提钒尾渣的综合利用[J]. 铁合金,2018,49(1):40.(XU Chong-guang,WANG Hai-lin,YANG Huan,et al. Comprehensive utilization of vanadium extraction tailings[J]. Ferro-Alloys,2018,49(1):40.) [3] WANG Xin,XIANG Jun-yi,LING Jia-wei,et al. Comprehensive utilization of vanadium extraction tailings:A brief review [C]//Energy Technology 2020: Recycling, Carbon Dioxide Management, and Other Technologies. The Minerals, Metals and Materials Series. California:Springer, Cham, 2020:327. [4] 廖盈盈. 提钒尾渣处理技术浅谈[J]. 四川化工,2018,21(6):39.(LIAO Ying-ying. Discussion on treatment technology of vanadium tailings[J]. Sichuan Chemical Industry,2018,21(6):39.) [5] 刘义,李兰杰,王春梅,等. 提钒尾渣资源化利用技术[J]. 河北冶金,2020(6):79.(LIU Yi,LI Lan-jie,WANG Chun-mei,et al. Resource utilization technology of vanadium extraction tailings[J]. Hebei Metallurgy,2020(6):79.) [6] 李国庭,韩宇,刘玉伟. 150 t转炉低钒铁水提钒生产实践[J]. 中国冶金,2015,25(5):47. (LI Guo-ting,HAN Yu,LIU Yu-wei. Vanadium extraction from low-vanadium hot metal in 150 t converter[J]. China Metallurgy,2015,25(5):47.) [7] 侯静,吴恩辉,李军. 提钒尾渣的综合利用研究现状及进展[J]. 矿产保护与利用,2017(6):103.(HOU Jing,WU En-hui,LI Jun. Current situation and progress of comprehensive utilization of vanadium extraction tailings[J]. Conservation and Utilization of Mineral Resources,2017(6):103.) [8] 孟利鹏,赵楚,王少娜,等. 国内提钒尾渣再提钒技术研究进展[J]. 钢铁钒钛,2015,36(3):49.(MENG Li-peng,ZHAO Chu,WANG Shao-na,et al. Improvement of vanadium extraction from extracted vanadium residue in china[J]. Iron Steel Vanadium Titanium,2015,36(3):49.) [9] 陈炼,谢兵,戈文荪,等. 减少转炉提钒过程碳烧损[J]. 钢铁研究学报,2020,32(7):654. (CHEN Lian,XIE Bing,GE Wen-sun,et al. Reducing carbon loss during vanadium-extraction process in converter[J]. Journal of Iron and Steel Research,2020,32(7):654.) [10] TENG Ai-jun,XUE Xiang-xin. A novel roasting process to extract vanadium and chromium from high chromium vanadium slag using a NaOH-NaNO3 binary system[J]. Journal of Hazardous Materials,2019,379(5):1. [11] LI Hong-yi,WANG Cheng-jie,YUAN Yi-heng,et al. Magnesiation roasting-acid leaching:A zero-discharge method for vanadium extraction from vanadium slag[J]. Journal of Cleaner Production,2020,260:109. [12] ZHANG Ju-hua,ZHANG Wei,XUE Zheng-liang. An environment-friendly process featuring calcified roasting and precipitation purification to prepare vanadium pentoxide from the converter vanadium slag[J]. Metals,2018,9(1):21. [13] WANG Jian,CHEN Lian,JIANG Long-kui,et al. Research on application mechanism of vanadium extraction tailings by cleaner production[J]. Applied Mechanics and Materials,2012,260/261:637. [14] ZHANG Bo,LIU Cheng-jun,LIU Zhuang-zhuang,et al. Remediation of the vanadium slag processing residue and recovery of the valuable elements[J]. Process Safety and Environmental Protection,2019,128:362. [15] 李秀敏. 攀钢提钒尾渣二次提钒研究[D]. 武汉:武汉理工大学,2013.(LI Xiu-min. The Research on Secondary Vanadium Extraction from Vanadium Residue from Pangane Group Company[D]. Wuhan:Wuhan University of Technology,2013.) [16] 刘静,李兰杰,常福增. 提钒尾渣深度提钒技术研究[J]. 北方钒钛,2018(1):26.(LIU Jing,LI Lan-jie,CHANG Fu-zeng. Study on the technology of deep extracting vanadium from vanadium tailings[J]. Northern Vanadium and Titanium,2018(1):26.) [17] WANG Guang,LIN Min-min,DIAO Jiang,et al. Novel strategy for green comprehensive utilization of vanadium slag with high-content chromium[J]. ACS Sustainable Chemistry and Engineering,2019,2019(7):133. [18] 向俊一. 转炉钒渣钙化提钒工艺优化及提钒尾渣综合利用基础研究[D]. 重庆:重庆大学,2018.(XIANG Jun-yi. Fundamental Study on the Optimization of Vanadium Extraction from LD Converter Slag by Calcification Based Process and the Comprehensive Utilization of Tailings[D]. Chongqing:Chongqing University,2018.) [19] 黄艳,贾秀,刘洪. 盐酸对提钒尾渣再提钒的影响[J]. 科技风,2016(16):127.(HUANG Yan,JIA Xiu,LIU Hong. Effect of hydrochloric acid on vanadium extraction tailings[J]. Technology Trend,2016(16):127.) [20] CHEN Lian,WANG Jian,GE Wen-sun,et al. Research on application of vanadium extraction tailings for BOF steelmaking[J]. Advanced Materials Research,2012,581/582:944. [21] WANG Guang,DIAO Jiang,LIU Liang,et al. Highly efficient utilization of hazardous vanadium extraction tailings containing high chromium concentrations by carbothermic reduction[J]. Journal of Cleaner Production,2019,237(10):1. [22] 杨慧芬,王静静,景丽丽,等. 焙烧温度对高铁提钒尾渣煤基直接还原效果的影响[J]. 北京科技大学学报,2010,32(10):1258.(YANG Hui-fen,WANG Jing-jing,JING Li-li,et al. Effect of roasting temperature on the coal-based direct reduction of high-iron vanadium tailings[J]. Journal of University of Science and Technology Beijing,2010,32(10):1258.) [23] 喻雄,孙丽枫,王鹤松,等. 提钒尾渣碳热还原过程实验[J]. 重庆大学学报,2015(2):123.(YU Xiong,SUN Li-feng,WANG He-song,et al. Analysis on transfer and enrichment of metal elements during reduction roasting of vanadium tailings[J]. Journal of Chongqing University,2015(2):123.) [24] 杨合,毛林强,薛向欣,等. 提钒尾渣配碳直接还原铁试验[J]. 钢铁钒钛,2013,34(5):28.(YANG He,MAO Lin-qiang,XUE Xiang-xin,et al. Experiment on direct reduction of iron from vanadium extraction tailings by adding carbon[J]. Iron Steel Vanadium Titanium,2013,34(5):28.) [25] 吴恩辉,黄平,杨绍利,等. 提钒尾渣内配碳球团直接还原试验[J]. 有色金属(冶炼部分),2011(11):17.(WU En-hui,HUANG Ping,YANG Shao-li,et al. Experimental study on direct reduction of vanadium tailings carbon-containing pellets[J]. Nonferrous Metals(Extractive Metallurgy),2011(11):17.) [26] 杜维玲,陈华. 提钒尾渣返回钢铁流程的资源化利用[J]. 北方钒钛,2011(1):22.(DU Wei-ling,CHEN Hua. Resource utilization of vanadium extraction tailings returned to steel process[J]. Northern Vanadium and Titanium,2011(1):22.) [27] 丁满堂,祝明进,颜婷婷,等. 提钒尾渣提镓研究[J]. 四川冶金,2019,41(3):26.(DING Man-tang,ZHU Ming-jin,YAN Ting-ting,et al. Research of gallium extraction from extracting vanadium tailings[J]. Sichuan Metallurgy,2019,41(3):26.) [28] 高磊,施哲,阴树标,等. 提钒尾渣镓回收方法研究[J]. 矿冶,2014,23(3):73.(GAO Lei,SHI Zhe,YIN Shu-biao,et al. Comparative study on the recovery of gallium from V-recovering tail slag[J]. Mining and Metallurgy,2014,23(3):73.) [29] 杨久俊,李建伟,肖宇领,等. 常压石灰法处理烧结法赤泥脱碱及其机理研究[J]. 无机盐工业,2012,44(6):40.(YANG Jiu-jun,LI Jian-wei,XIAO Yu-ling,et al. Research on dealkalization of sintering process red mud by lime process at normal atmosphere and its mechanism[J]. Inorganic Chemicals Industry,2012,44(6):40.) [30] 李兰杰,赵备备,王海旭,等. 提钒尾渣高效脱碱及配矿炼铁工艺[J]. 过程工程学报,2017,17(1):138.(LI Lan-jie,ZHAO Bei-bei,WANG Hai-xu,et al. The process of high efficiency dealkalization and ore blending in ironmaking of the extracted vanadium residue[J]. The Chinese Journal of Process Engineering,2017,17(1):138.) [31] 曾冠武,郝建璋. 提钒尾渣脱钠技术研究[J]. 钢铁钒钛,2019,40(1):78.(ZENG Guan-wu,HAO Jian-zhang. Research on removing sodium from extracted vanadium residue[J]. Iron Steel Vanadium Titanium,2019,40(1):78.) [32] 张海平,丁跃华,郝建璋,等. 钠化提钒尾渣脱钠实验[J]. 昆明理工大学学报(自然科学版),2015,40(6):8.(ZHANG Hai-ping,DING Yue-hua,HAO Jian-zhang,et al. Technology of eliminating sodium from extracted vanadium tailings[J]. Journal of Kunming University of Science and Technology(Natural Science),2015,40(6):8.) [33] 张海平. 钠化提钒尾渣脱钠试验研究[D]. 昆明:昆明理工大学,2015.(ZHANG Hai-ping. Experimental Study on Sodium Removal from the Sodiumized Vanadium Extraction Tailings[D]. Kunming:Kunming University of Science and Technology,2015.) [34] 汪其,姜茂发,王猛,等. 提钒尾渣中钒铬的浸出与萃取[J]. 有色金属(冶炼部分),2016(9):13.(WANG Qi,JIANG Mao-fa,WANG Meng,et al. Leaching and extraction of vanadium and chromium from vanadium tailings[J]. Nonferrous Metals(Extractive Metallurgy),2016(9):13.) [35] WANG Guang,LIN Min-min,DIAO Jiang,et al. A novel strategy for green comprehensive utilization of vanadium slag with high content chromium[J]. ACS Sustainable Chemistry and Engineering,2019,7:133. [36] WANG Guang,DIAO Jiang,LIN Min-Min,et al. Highly efficient utilization of hazardous vanadium extraction tailings containing high chromium concentrations by carbothermic reduction[J]. Journal of Cleaner Production,2019,237:832. [37] WANG Guang,DIAO Jiang,LIU Liang,et al. Production of high-carbon ferrochromium by carbothermal reduction of vanadium extraction tailings with high chromium content[C]//11th International Symposium on High-Temperature Metallurgical Processing. The Minerals, Metals and Materials Series. San Diego: Springer, 2020:823. [38] LI Xin,YU Hong-hao. Synthesis of hollow spheres of Fe2O3 using vanadium extraction tailings for removal of MO dyes[J]. Materials Science,2018,24:45. [39] LIU Li-ying,DU Tao,TAN Wen-jun,et al. A novel process for comprehensive utilization of vanadium slag[J]. International Journal of Minerals,Metallurgy,and Materials,2016,23:156. [40] 程殿祥. 利用提钒尾渣生产高钒生铁[J]. 铁合金,1990(2):40.(CHENG Dian-xiang. Production of vanadium bearing pig iron from extracted vanadium residue[J]. Ferro-Alloys,1990(2):40.) [41] 于洪浩,张候芳,李鑫. 酸浸法回收提钒尾渣中铁及中空Fe2O3的制备研究[J]. 有色矿冶,2015,31(6):28.(YU Hong-hao,ZHANG Hong-fang,LI Xin. Study on recovery of iron from vanadium tailings by acid leaching method and the preparation of hollow Fe2O3[J]. Non-Ferrous Mining and Metallurgy,2015,31(6):28.) [42] 李亮,彭富昌. 浇注法制备提钒尾渣多孔陶瓷试验研究[J]. 钢铁钒钛,2017,38(3):78.(LI Liang,PENG Fu-chang. Experimental study on the preparation of porous ceramic with vanadium tailings by casting method[J]. Iron Steel Vanadium Titanium,2017,38(3):78.) [43] 郝建璋,刘安强,马明龙. 提钒尾渣远红外涂料性能研究[J]. 涂料工业,2009,39(9):13.(HAO Jian-zhang,LIU An-qiang,MA Ming-long. Research of vanadium tailings based far-infrared radiation coatings[J]. Paint and Coatings Industry,2009,39(9):13.) [44] 郝建璋. 提钒尾渣防脱碳涂料性能研究[J]. 攀枝花科技与信息,2013,38(3):19.(HAO Jian-zhang. Study on the performance of anti-decarburization coating for vanadium extraction tailings[J]. Panzhihua Sci-Tech and Information,2013,38(3):19.) [45] 秦磊,包申旭,张一敏,等. 页岩提钒尾渣-赤泥混合煅烧制备地聚物研究[J]. 有色金属(冶炼部分),2020(4):51.(QIN Lei,BAO Shen-xu,ZHANG Yi-min,et al. Preparation of geopolymer from vanadium tailings and red mud by mixed calcination[J]. Nonferrous Metals(Extractive Metallurgy),2020(4):51.) [46] 孟锐,刘涛,张一敏. 激发剂的性质对页岩提钒尾渣基地聚物性能的影响[J]. 矿产保护与利用,2019,39(3):63.(MENG Rui,LIU Tao,ZHANG Yi-min. Effects of properties of activators on compressive strength of shale vanadium tailings based geopolymer[J]. Conservation and Utilization of Mineral Resources,2019,39(3):63.) [47] 刘祥,张一敏,包申旭. 不同活化方法对提钒尾渣地聚物性能的影响[J]. 硅酸盐通报,2015,34(11):3106.(LIU Xiang,ZHANG Yi-min,BAO Shen-xu. Preparation and performance of geopolymer by activated vanadium tailing[J]. Bulletin of the Chinese Ceramic Society,2015,34(11):3106.) [48] 马莹. 石煤直接浸出提钒尾矿制备建筑材料的研究[D]. 西安:西安建筑科技大学,2014.(MA Ying. Research of Building Materials Prepared with Tailings of Vanadium Direct Leaching from Stone Coal[D]. Xi′an:Xi′an University of Architecture and Technology,2014.) [49] 杨青莹,钟炎涛. 利用攀枝花提钒尾渣制备蒸压砖试验研究[J]. 钢铁钒钛,2019,40(4):79.(YANG Qing-ying,ZHONG Yan-tao. Preparation of autoclaved bricks from residue after vanadium extraction in Panzhihua[J]. Iron Steel Vanadium Titanium,2019,40(4):79.) [50] 李亮. 利用提钒尾渣制备烧结广场砖实验研究[J]. 硅酸盐通报,2018,37(6):1970.(LI Liang. Experimental study about preparation of sintered square brick by using vanadium tailings[J]. Bulletin of the Chinese Ceramic Society,2018,37(6):1970.)
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