|
|
Heating process on oxidation behavior of P-bearing high strength steel |
JIANG Guang-rui1,2,WANG Hai-quan1,2,3,LIU Li-bin1,2,4 |
(1. Thin Strip Department, Shougang Technology Research Institute, Beijing 100043, China 2. Beijing Key Laboratory of Green Recyclable Process for Iron and Steel Production Technology, Beijing 100043, China 3. National Engineering Lab of Advanced Coating Technology for Metal Materials, China Iron and Steel Research Institute Group, Beijing 100081, China 4. State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China) |
|
|
Abstract With excellent formability and high strength,P-bearing high strength steel is utilized to stamping parts in automobile industry. Except P,several other alloying elements,such as Mn,Si,are added into the P-bearing high strength steel for solid solution strengthing. These alloying elements are prone to be selectively oxidized during annealing. A P-bearing steel was studied through a Hot-Dip Process Simulator to investigate effect of dew point during heating on oxidation behavior. Scanning electron microscope (SEM),glow-discharge optical omission spectroscopy (GD-OES) and X-ray photo-electron spectroscopy (XPS) were used to illustrate micromorphology of the surface, alloying elements depth distribution profile and kinds of compound on the external surface respectively. Results show that the dew point during heating greatly impact the oxidation behavior of alloying elements on the external surface. Moreover higher dew point during heating results in suppressing selective oxidation of Mn and Si on the external surface while promoting enriching of P to the external surface. Furthermore,it indicates that the P exists in phosphates on the external surface.
|
Received: 21 March 2017
Published: 29 September 2017
|
|
|
|
[1] |
Bleck W. Cold-rolled, high-strength sheet steels for auto applications[J]. JOM, 1996, 48(7): 26-30.
|
[2] |
Kim S I, Choi S H, Lee Y. Influence of phosphorous and boron on dynamic recrystallization and microstructures of hot-rolled interstitial free steel[J]. Materials Science and Engineering: A, 2005, 406(1): 125-133.
|
[1] |
Bleck W. Cold-rolled, high-strength sheet steels for auto applications[J]. JOM, 1996, 48(7): 26-30.
|
[3] |
夏明生, 李桂兰, 张洪波, 等. 冷轧退火含磷高强 IF 钢的组织和性能[J]. 钢铁研究学报, 2015, 27(12): 54-57.XIA Ming-sheng, LI Gui-lan, ZHANG Hong-bo, et al. Microstructures and properties of phosphorus-containing high strength cold rolled and annealed IF steels[J]. Journal of Iron and Steel Research, 2015, 27(12): 54-57.
|
[4] |
王先进, 王作成, 唐荻, 等. 成分及工艺对加磷高强 IF 钢成形性能的影响[J]. 钢铁, 1993 (3): 34-38.WANG Xian-jin, WANG Hua-cheng, TANG Di, et al. Effect of Chemical composition and process of extra-low-carbon P-added high-strength IF steel on drawability[J]. Iron and Steel, 1993 (3): 34-38.
|
[2] |
Kim S I, Choi S H, Lee Y. Influence of phosphorous and boron on dynamic recrystallization and microstructures of hot-rolled interstitial free steel[J]. Materials Science and Engineering: A, 2005, 406(1): 125-133.
|
[3] |
夏明生, 李桂兰, 张洪波, 等. 冷轧退火含磷高强 IF 钢的组织和性能[J]. 钢铁研究学报, 2015, 27(12): 54-57.XIA Ming-sheng, LI Gui-lan, ZHANG Hong-bo, et al. Microstructures and properties of phosphorus-containing high strength cold rolled and annealed IF steels[J]. Journal of Iron and Steel Research, 2015, 27(12): 54-57.
|
[4] |
王先进, 王作成, 唐荻, 等. 成分及工艺对加磷高强 IF 钢成形性能的影响[J]. 钢铁, 1993 (3): 34-38.WANG Xian-jin, WANG Hua-cheng, TANG Di, et al. Effect of Chemical composition and process of extra-low-carbon P-added high-strength IF steel on drawability[J]. Iron and Steel, 1993 (3): 34-38.
|
[5] |
Vanden Eynde X, Servais J P, Lamberigts M. Investigation into the surface selective oxidation of dual‐phase steels by XPS, SAM and SIMS[J]. Surface and interface analysis, 2003, 35(12): 1004-1014.
|
[5] |
Vanden Eynde X, Servais J P, Lamberigts M. Investigation into the surface selective oxidation of dual‐phase steels by XPS, SAM and SIMS[J]. Surface and interface analysis, 2003, 35(12): 1004-1014.
|
[6] |
Liu H, Li F, Shi W, et al. Challenges in hot-dip galvanizing of high strength dual phase steel: Surface selective oxidation and mechanical property degradation[J]. Surface and Coatings Technology, 2012, 206(16): 3428-3436.
|
[6] |
Liu H, Li F, Shi W, et al. Challenges in hot-dip galvanizing of high strength dual phase steel: Surface selective oxidation and mechanical property degradation[J]. Surface and Coatings Technology, 2012, 206(16): 3428-3436.
|
[7] |
Hertveldt I, De Cooman B C, Claessens S. Influence of annealing conditions on the galvanizability and galvannealing properties of TiNb interstitial-free steels, strengthened with phosphorous and manganese[J]. Metallurgical and Materials Transactions A, 2000, 31(4): 1225-1232.
|
[7] |
Hertveldt I, De Cooman B C, Claessens S. Influence of annealing conditions on the galvanizability and galvannealing properties of TiNb interstitial-free steels, strengthened with phosphorous and manganese[J]. Metallurgical and Materials Transactions A, 2000, 31(4): 1225-1232.
|
[8] |
Mahieu J, Claessens S, De Cooman B C, et al. Surface and Sub-surface Characterization of Si-, Al-and P-alloyed TRIP-aided Steel[C]// Proceedings of 6th International Conference on Zinc and Zinc Alloy Coated Steel Sheet. Chicago: Association for Iron and Steel Technology, 2004.
|
[8] |
Mahieu J, Claessens S, De Cooman B C, et al. Surface and Sub-surface Characterization of Si-, Al-and P-alloyed TRIP-aided Steel[C]// Proceedings of 6th International Conference on Zinc and Zinc Alloy Coated Steel Sheet. Chicago: Association for Iron and Steel Technology, 2004.
|
[9] |
Jiang G, Teng H, Wang H, et al. Selective Oxidation in Press Hardening Steel during Annealing with Different Dew Points[C]//Proceedings of 9th International Conference on Zinc and Zinc Alloy Coated Steel Sheet & 2nd Asia-Pacific Galvanizing Conference. Beijing: Metallurgical Industry Press, 2013.
|
[9] |
Jiang G, Teng H, Wang H, et al. Selective Oxidation in Press Hardening Steel during Annealing with Different Dew Points[C]//Proceedings of 9th International Conference on Zinc and Zinc Alloy Coated Steel Sheet & 2nd Asia-Pacific Galvanizing Conference. Beijing: Metallurgical Industry Press, 2013.
|
[10] |
蒋光锐, 王海全, 刘李斌, 刘广会. 加热过程露点对一种先进高强钢选择性氧化的影响[J]. 金属热处理,已录用.JIANG Guang-rui, WANG Hai-quan, LIU Guang-hui. Effect of dew point during heating on selective oxidation behavior of an advanced high strength steel[J]. Heat Treatment of Metals, Accepted.
|
[10] |
蒋光锐, 王海全, 刘李斌, 刘广会. 加热过程露点对一种先进高强钢选择性氧化的影响[J]. 金属热处理,已录用.JIANG Guang-rui, WANG Hai-quan, LIU Guang-hui. Effect of dew point during heating on selective oxidation behavior of an advanced high strength steel[J]. Heat Treatment of Metals, Accepted.
|
[11] |
Maki J, Mahieu J, De Cooman B C, et al. Galvanisability of silicon free CMnAl TRIP steels[J]. Materials science and technology, 2003, 19(1): 125-131.
|
[11] |
Maki J, Mahieu J, De Cooman B C, et al. Galvanisability of silicon free CMnAl TRIP steels[J]. Materials science and technology, 2003, 19(1): 125-131.
|
[12] |
Huin D, Flauder P, Leblond J B. Numerical Simulation of Internal Oxidation of Steels during Annealing Treatments[J]. Oxidation of Metals, 2005, 64(1-2): 131-167.
|
[12] |
Huin D, Flauder P, Leblond J B. Numerical Simulation of Internal Oxidation of Steels during Annealing Treatments[J]. Oxidation of Metals, 2005, 64(1-2): 131-167.
|
[13] |
Parezanovic I, Spiegel M. Influence of B, S, P, Si and C segregation on the selective oxidation of dual phase and interstitial free steels[C]//Proceedings of 6th International Conference on Zinc and Zinc Alloy Coated Steel Sheet. Chicago: Association for Iron and Steel Technology, 2004.
|
[13] |
Parezanovic I, Spiegel M. Influence of B, S, P, Si and C segregation on the selective oxidation of dual phase and interstitial free steels[C]//Proceedings of 6th International Conference on Zinc and Zinc Alloy Coated Steel Sheet. Chicago: Association for Iron and Steel Technology, 2004.
|
[1] |
GUO Hai-xia, ZHANG Xin-yao, LI Hui. Cause analysis of leakage for heating coil[J]. PHYSICS EXAMINATION AND TESTING, 2020, 38(3): 46-. |
[2] |
. Improvement and Control of Edge Skin-warping Defect in Ultra-low Carbon IF Steel[J]. , 2020, 45(2): 0-0. |
[3] |
ZHOU Yun, YANG Xiao-wei, CHEN Huan-de, ZHANG Yu. Effect of heating temperature on microstructure and properties of 600 MPa grade high strength steel rebars[J]. Iron and Steel, 2020, 55(1): 101-107. |
[4] |
HAN Yi, XIAO Yao, ZHANG Ao-yin, ZHAO Yu-fei, LIU Feng, LI Hong-bin. Recessive defects in electromagnetic heating process of electrical resistance welding steel pipe[J]. Iron and Steel, 2020, 55(1): 108-118. |
[5] |
CHEN Wen1,LEI Ying2,HE Wen-hao3,LIAO Zhen-hong1,WANG Xin2. Iron increase and phosphorous reduction mechanism of oolitic hematite by microwave heating[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2020, 32(1): 9-19. |
[6] |
FENG Lu-lu1,2,3,WU Kai-ming1,LI Ping-ping2,CHEN Shu-min2,LU Xiu-yu4,QIAO Wen-wei3. Effect of Nb on microstructure transformation in reheating process of 2000MPa bridge cable steel[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2020, 32(1): 60-65. |
|
|
|
|