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Morphology and precipitation mechanism of large carbides in M2 high speed steel |
WANG Qi-ming,CHENG Guo-guang,HUANG Yu |
(State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing 100083,China) |
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Abstract The types and precipitation behavior of carbides in M2 high speed steel were studied. On the one hand,the scanning electron microscope was used to observe the morphology and distribution of carbides,and the chemical composition of these carbides was detected by energy dispersive spectroscopy. On the other hand,the Thermo-Calc was used to calculate the precipitation of carbides in equilibrium and Scheil model meanwhile. In the M2 HSS after annealing,the large carbides distributed along the network,which included MC,M6C,M2C carbides and mixture of them. After forging,the zonal distribution and accumulation of carbides arised in M2 HSS. MC and M6C carbides precipitate at 1 294 and 1 288 ℃ respectively in equilibrium,higher than the austenitizing temperature. However,in Scheil solidification,MC,M6C and M2C carbide would precipitate in turn. It is difficult to eliminate large carbides in M2 HSS through heat treating and forging,but controlling the precipitation of carbides could be of great significance.
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Received: 24 May 2017
Published: 05 February 2018
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[1] |
邓玉昆, 陈景榕, 王世章.高速工具钢[M]. ., 2002., :-
|
[1] |
邓玉昆, 陈景榕, 王世章.高速工具钢[M]. ., 2002., :-
|
[2] |
郭三耕.高速钢及其热处理[M]. ., 1985., :-
|
[2] |
郭三耕.高速钢及其热处理[M]. ., 1985., :-
|
[3] |
宋维锡.金属学[M]. ., 1989., :-
|
[3] |
宋维锡.金属学[M]. ., 1989., :-
|
[4] |
Barkalow R H, Kraft R W, Goldstein J I.Solidification of M2 high speed steel[J].Metallurgical Transactions, 1972, 3(4):919-926
|
[4] |
Barkalow R H, Kraft R W, Goldstein J I.Solidification of M2 high speed steel[J].Metallurgical Transactions, 1972, 3(4):919-926
|
[5] |
McLaughlin J, Wayne R, Goldstein J I.Characterization of the solidification structures within the dendritic core of M2 high speed steel[J].Metallurgical Transactions A, 1977, 8(11):1787-1792
|
[5] |
McLaughlin J, Wayne R, Goldstein J I.Characterization of the solidification structures within the dendritic core of M2 high speed steel[J].Metallurgical Transactions A, 1977, 8(11):1787-1792
|
[6] |
Galda E J, Kraft R W.The effects of MO and W on solidification of high speed steels[J].Metallurgical transactions, 1974, 5(8):1727-1733
|
[6] |
Galda E J, Kraft R W.The effects of MO and W on solidification of high speed steels[J].Metallurgical transactions, 1974, 5(8):1727-1733
|
[7] |
Serna M M, Rossi J L.MC complex carbide in AISI M2 high-speed steel[J].Materials Letters, 2009, 63(8):691-693
|
[7] |
Serna M M, Rossi J L.MC complex carbide in AISI M2 high-speed steel[J].Materials Letters, 2009, 63(8):691-693
|
[8] |
Zhou X, Fang F, Li G, et al.Morphology and properties of M2C eutectic carbides in AISI M2 steel[J].ISIJ international, 2010, 50(8):1151-1157
|
[8] |
Zhou X, Fang F, Li G, et al.Morphology and properties of M2C eutectic carbides in AISI M2 steel[J].ISIJ international, 2010, 50(8):1151-1157
|
[9] |
Ghomashchi M R.The morphology of eutectic carbides in M2-grade high speed steel[J].Metallurgical Transactions A, 1985, 16(12):2341-2342
|
[9] |
Ghomashchi M R.The morphology of eutectic carbides in M2-grade high speed steel[J].Metallurgical Transactions A, 1985, 16(12):2341-2342
|
[10] |
周雪峰, 朱旺龙, 江红兵, 等.高速钢过回火合金碳化物演变行为[J].材料热处理学报, 2016, 37(9):139-143
|
[10] |
周雪峰, 朱旺龙, 江红兵, 等.高速钢过回火合金碳化物演变行为[J].材料热处理学报, 2016, 37(9):139-143
|
[11] |
Chaus A S, Dománková M.Precipitation of secondary carbides in M2 high-speed steel modified with titanium diboride[J].Journal of materials engineering and performance, 2013, 22(5):1412-1420
|
[11] |
Chaus A S, Dománková M.Precipitation of secondary carbides in M2 high-speed steel modified with titanium diboride[J].Journal of materials engineering and performance, 2013, 22(5):1412-1420
|
[12] |
Inoue A, Masumoto T.Carbide reactions (M3C→ M7C3→ M23C6→ M6C) during tempering of rapidly solidified high carbon Cr-W and Cr-Mo steels[J].Metallurgical Transactions A, 1980, 11(5):739-747
|
[12] |
Inoue A, Masumoto T.Carbide reactions (M3C→ M7C3→ M23C6→ M6C) during tempering of rapidly solidified high carbon Cr-W and Cr-Mo steels[J].Metallurgical Transactions A, 1980, 11(5):739-747
|
[13] |
迟宏宵, 马党参, 吴立志, 等.M2 高速钢中 M2C 共晶碳化物的相变行为[J].[J].金属热处理, 2010, 35(5):19-22
|
[13] |
迟宏宵, 马党参, 吴立志, 等.M2 高速钢中 M2C 共晶碳化物的相变行为[J].[J].金属热处理, 2010, 35(5):19-22
|
[14] |
Fredriksson H, Hillert M, Nica M.The Decomposition of the M 2 C Carbide in High Speed Steel[J].Scandinavian Journal of Metallurgy, 1979, 8(3):115-122
|
[14] |
Fredriksson H, Hillert M, Nica M.The Decomposition of the M 2 C Carbide in High Speed Steel[J].Scandinavian Journal of Metallurgy, 1979, 8(3):115-122
|
[15] |
Pan F, Wang W, Tang A, et al.Phase transformation refinement of coarse primary carbides in M2 high speed steel[J].Progress in Natural Science: Materials International, 2011, 21(2):180-186
|
[15] |
Pan F, Wang W, Tang A, et al.Phase transformation refinement of coarse primary carbides in M2 high speed steel[J].Progress in Natural Science: Materials International, 2011, 21(2):180-186
|
[16] |
赵志刚, 颜慧成, 仇圣桃, 等.冷却速率对 高速工具钢铸锭凝固组织的影响[J].特殊钢, 2014, 35(3):45-48
|
[16] |
赵志刚, 颜慧成, 仇圣桃, 等.冷却速率对 高速工具钢铸锭凝固组织的影响[J].特殊钢, 2014, 35(3):45-48
|
[17] |
周雪峰, 方峰, 涂益友, 等.Al 对 M2 高速钢凝固组织的影响[J][J].金属学报, 2014, 50(7):769-776
|
[17] |
周雪峰, 方峰, 涂益友, 等.Al 对 M2 高速钢凝固组织的影响[J][J].金属学报, 2014, 50(7):769-776
|
[18] |
王维青, 潘复生, 吴立志, 等.硅对热处理态 高速钢中共晶碳化物的影响[J].重庆大学学报: 自然科学版, 2011, 34(11):44-49
|
[18] |
王维青, 潘复生, 吴立志, 等.硅对热处理态 高速钢中共晶碳化物的影响[J].重庆大学学报: 自然科学版, 2011, 34(11):44-49
|
[19] |
Boccalini Jr M, Correa A V O, Goldenstein H.Rare earth metal induced modification of γ-M2 C,γ-M6 C,and γ-MC eutectics in as cast M2 high speed steel[J].Materials science and technology, 1999, 15(6):621-626
|
[19] |
Boccalini Jr M, Correa A V O, Goldenstein H.Rare earth metal induced modification of γ-M2 C,γ-M6 C,and γ-MC eutectics in as cast M2 high speed steel[J].Materials science and technology, 1999, 15(6):621-626
|
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