|
|
Kinetics of high temperature oxidation of 0.09C-0.5Mn-0.22/1.9Si steel |
SUN Bin,YOU Hong-guang,HAO Ming-xin |
(Mechanical Engineering Institute, Shenyang University, Shenyang 110044, Liaoning, China) |
|
|
Abstract In order to evaluate the effects of Si on oxidation kinetics behavior of steels, the oxidation behaviors of Fe-0.2Si steel and Fe-2Si steel at 900-1 200 ℃ in the air-steam atmosphere were investigated by TGA in order to calculate the oxidation rates of two steels. The activation energies of the two steels were obtained. The results show that the oxidation kinetics cures of the two steels obey linear law in the early stage of oxidation process. It appeared that a critical thickness of scale existed,at which the law of the scale-growth mechanism changed from linear to parabolic. The critical thickness of scale increased with the silicon mass percent in the steel increasing and the temperature rising.
|
Received: 06 March 2018
Published: 11 October 2018
|
|
|
|
[1] |
Zhu Z, Xu H, Jiang D, et al. Influence of temperature on the oxidation behaviour of a ferritic-martensitic steel in supercritical water[J]. Corrosion Science, 2016, 113:172-179
|
[1] |
Zhu Z, Xu H, Jiang D, et al. Influence of temperature on the oxidation behaviour of a ferritic-martensitic steel in supercritical water[J]. Corrosion Science, 2016, 113:172-179
|
[2] |
Rex Y. Chen,W. Y. D. Yuen. Short-time Oxidation Behavior of Low-carbon, Low-silicon Steel in Air at 850–1,180℃––I:Oxidation Kinetics[J]. Oxidation of Metals,2008,70(1):39-68.
|
[2] |
Rex Y. Chen,W. Y. D. Yuen. Short-time Oxidation Behavior of Low-carbon, Low-silicon Steel in Air at 850–1,180℃––I:Oxidation Kinetics[J]. Oxidation of Metals,2008,70(1):39-68.
|
[3] |
Pieraggi B, Rolland C, Bruckel P. Morphological characteristics of oxide scales grown on H11 steel oxidised in dry or wet air[J]. Materials at High Temperatures, 2005, 22(22):61-68.
|
[3] |
Pieraggi B, Rolland C, Bruckel P. Morphological characteristics of oxide scales grown on H11 steel oxidised in dry or wet air[J]. Materials at High Temperatures, 2005, 22(22):61-68.
|
[4] |
KofstadP.Prediction the Numerical Model of Metal Non Isothermal Oxidation Kinetics[J].Acta Chemical Scandinavica,1958,12(2):701.
|
[4] |
KofstadP.Prediction the Numerical Model of Metal Non Isothermal Oxidation Kinetics[J].Acta Chemical Scandinavica,1958,12(2):701.
|
[5] |
S.NevioBalo,F.Yakuphanoglu. The effects of Cr on isothermal oxidation behavior of Fe-30Mn-6Si alloy[J].Thermochimica Acta,2013(560):43-46.
|
[5] |
S.NevioBalo,F.Yakuphanoglu. The effects of Cr on isothermal oxidation behavior of Fe-30Mn-6Si alloy[J].Thermochimica Acta,2013(560):43-46.
|
[6] |
刘小江,李振宇.热轧无取向硅钢高温氧化行为及其氧化铁皮控制技术的研究与应用 [D]. 沈阳:东北大学,2014Liu Xiaojiang, Li Zhenyu. Reseach on High Tempreture Oxidation Behavior and Countrolling Technology and Application of Oxide Scale of Hot-rolled Non-oriented Silicon Steel[D]. Shenyang: Northeastern University,2014.
|
[6] |
刘小江,李振宇.热轧无取向硅钢高温氧化行为及其氧化铁皮控制技术的研究与应用 [D]. 沈阳:东北大学,2014Liu Xiaojiang, Li Zhenyu. Reseach on High Tempreture Oxidation Behavior and Countrolling Technology and Application of Oxide Scale of Hot-rolled Non-oriented Silicon Steel[D]. Shenyang: Northeastern University,2014.
|
[7] |
Rex Y. Chen,W. Y. D. Yuen. Short-Time Oxidation Behavior of Low-Carbon,Low-Silicon Steel in Air at 850–1180 _C: II. Linear to Parabolic Transition Determined Using Existing Gas-Phase Transport and Solid-Phase Diffusion Theories[J].Oxidation of Metals, 2010, 73(1): 353 -373.
|
[7] |
Rex Y. Chen,W. Y. D. Yuen. Short-Time Oxidation Behavior of Low-Carbon,Low-Silicon Steel in Air at 850–1180 _C: II. Linear to Parabolic Transition Determined Using Existing Gas-Phase Transport and Solid-Phase Diffusion Theories[J].Oxidation of Metals, 2010, 73(1): 353 -373.
|
[8] |
W.Y.D.Yuen, R.Y.Chen. Short-time Oxidation Behavior of Low-carbon, Low-silicon Steel in Air at 850–1,180 _C—III: Mixed Linear-and-Parabolic to Parabolic Transition Determined Using Local Mass-Transport Theories[J].Oxidation of Metals, 2010, 74(1):255-274.
|
[8] |
W.Y.D.Yuen, R.Y.Chen. Short-time Oxidation Behavior of Low-carbon, Low-silicon Steel in Air at 850–1,180 _C—III: Mixed Linear-and-Parabolic to Parabolic Transition Determined Using Local Mass-Transport Theories[J].Oxidation of Metals, 2010, 74(1):255-274.
|
[1] |
ZHOU Cong-rui, CHEN Xiao-long, ZHOU Ming-ke,FAN Lei, MEI Peng, BAO Si-qian. Cause analysis of surface blackening of SPHC hot rolled strip after pickling[J]. PHYSICS EXAMINATION AND TESTING, 2020, 38(3): 41-. |
[2] |
zhong-peng. Analysis of the formation mechanism of surface skin on tinplate[J]. , 2020, 45(3): 0-0. |
[3] |
CAO Guang- ming,LI Zhi- feng,WANG Hao,LIU Zhen- yu. Progress of pickling- free reductive annealing hot- dip galvanization on hot- rolled steel[J]. , 2019, 31(2): 159-167. |
[4] |
REN Pei- dong,WU Xiao- qiang,WANG Chang- bo,HUI Kai,LI Ju- bao. Effect of solution treatment on structure of oxide scales for 2205 duplex stainless steel[J]. , 2018, 30(12): 1006-1012. |
[5] |
WANG Shui-ze,LIU Yang,SUN Yi-qiang,HU Kuan-hui. Control technology of oxide scale for thin gauge hot rolled strip in CSP process[J]. Iron and Steel, 2018, 53(1): 54-58. |
[6] |
LI Sheng-cun. Discussion of the red rust on the surface of high Si high strength steel[J]. Chinese Journal of Iron and Steel, 2017, 35(5): 47-50. |
|
|
|
|