|
|
Effect of titanium treatment on inclusions and microstructure in EH36 shipbuilding steel |
LUO Deng1, HONG Zhi-wei2, LI Li3, LI Jian3, YANG Li3, ZHANG Xue-wei3 |
1. Xiangtan Iron and Steel Co., Ltd. of Hunan Valin, Xiangtan 411101, Hunan, China; 2. Zhongkexin Engineering Consulting (Beijing) Co., Ltd., Beijing 100039, China; 3. Institute for Engineering Steel, Central Iron and Steel Research Institute, Beijing 100081, China |
|
|
Abstract In order to study the influence of titanium treatment (the mold feeding titanium wire) on inclusions in EH36 steel,the size,composition and three-dimensional morphologies of inclusions in EH36 shipbuilding steel were obtained by electrolytic extraction method using non-aqueous electrolytes combined with SEM method. The experimental results show that the Ca-Si-Al system oxide inclusion+MnS in the steel was transformed into Ca-Si-Al-Ti system oxide inclusion+MnS after feeding the titanium wire in the mold,and the three-dimensional surfaces of them changes from smoother to rough and porous. After the welding thermal simulation,the microstructure had transformed from the grain boundary ferrite and side slatted ferrite in a titanium-free sample into acicular ferrite in the containing titanium specimen. What is more,the morphology of ferrite around the inclusion was transformed from block into acicular,the toughness was increased by 70 J. The forming conditions of titanium oxide inclusions in shipbuilding steel were analyzed by the thermodynamic calculation. The calculation results show that there was a competitive relationship between titanium and aluminum which react with oxygen to form oxide. The mass percent of aluminum should be strictly controlled not more than 0.003 5% in liquid steel when the mass percent of Ti was 0.02% in steel. Thus,so as to ensure that a substantial amount of titanium-containing oxide particles could be generated in liquid steel.
|
Received: 25 November 2019
|
|
|
|
[1] 赵梦静,王峰,习小军,等. 钇对EH36船板钢夹杂物特性和拉伸性能的影响[J]. 钢铁,2019,54(7):61. (ZHAO Meng-jing,WANG Feng,XI Xiao-jun,et al. Effect of Y on inclusions characteristics and tensile properties in EH36 shipbuilding steel[J]. Iron and Steel,2019,54(7):61.) [2] 周宇涛,杨树峰,李京社,等. 高级别船板钢生产过程中夹杂物的演变规律[J]. 钢铁,2019,54(1):33. (ZHOU Yu-tao,YANG Shu-feng,LI Jing-she,et al. Inclusions evolution of high-grade ship plate steel in practical production processes[J]. Iron and Steel,2019,54(1):33. [3] 陈晓康,杨树峰,李京社. 含钇E36船板钢夹杂物改性[J]. 中国冶金,2019,29(12):25. (CHEN Xiao-kang,YANG Shu-feng,LI Jing-she. Inclusion modification of E36 shipbuilding steel containing yttrium[J]. China Metallurgy,2019,29(12):25.) [4] 王红涛,田勇,叶其斌,等. 极寒环境下厚规格船舶用钢的发展[J]. 轧钢,2018,35(5):48. (WANG Hong-tao,TIAN Yong,YE Qi-bin,et al. Development of heavy ship plate in extremely cold environment[J]. Steel Rolling,2018,35(5):48.) [5] Vanovsek W,Bernhard C,Fiedler M,et al. Effect of titanium on the solidification and postsolidification microstructure of high-strength steel welds[J]. Welding in the World,2013,57(5):665. [6] 赵晶军,龙木军,汪勤政,等. 不同冷速下钛微合金化Q345B钢的HAZ组织及性能[J]. 中国冶金,2019,29(3):11. (ZHAO Jing-jun,LONG Mu-jun,WANG Qin-zheng,et al. Microstructure and properties of titanium microalloyed Q345B steel in heat affected zone at different cooling rates[J]. China Metallurgy,2019,29(3):11.) [7] Byun J S,Shim J H,Cho Y W,et al. Non-metallic inclusion and intragranular nucleation of ferrite in Ti-killed C-Mn steel[J]. Acta Materialia,2003,51(6):1593. [8] ZHOU B,LI G,WAN X,Y. et al. In-situ observation of grain refinement in the simulated heat-affected zone of high-strength low-alloy steel by Zr-Ti combined deoxidation[J]. Metals and Materials International,2016,22(2):267. [9] Yamada T,Terasaki H,Komizo Y. Microscopic observation of inclusions contributing to formation of acicular ferrite in steel weld metal[J]. Science and Technology of Welding and Joining,2008,13(2):118. [10] Moon J,Lee C,Uhm S,et al. Coarsening kinetics of TiN particle in a low alloyed steel in weld HAZ:Considering critical particle size[J]. Acta Materialia,2006,54(4):1053. [11] Suzuki S,Ichimiya K,Akita T. High tensile strength steel plates for shipbuilding with excellent HAZ toughness-JFE EWEL technology for excellent quality in large heat input welded joints[J]. JFE Technical Report,2004(5):9. [12] Abe K,Izumi M,Shibata M,et al. High tensile strength steel plates for high-heat input welding[J]. Research and Development Kobe,2005,55(2):26. [13] 张学伟,张立峰,杨文,等. 重轨钢中MnS析出热力学和动力学分析[J]. 钢铁,2016,51(9):30. (ZHANG Xue-wei,ZHANG Li-feng,YANG Wen,et al. Thermodynamics and dynamics of MnS inclusions precipitation during solidification process in heavy rail steels[J]. Iron and Steel,2016,51(9):30.) [14] ZHANG X,ZHANG L,YANG W,et al. Characterization of MnS particles in heavy rail steels using different methods[J]. Steel Research International, 2017,88(1):1. [15] 张学伟,张立峰,杨文,等. 非金属夹杂物三维形貌及其包裹的非夹杂物颗粒物来源分析[J]. 冶金分析,2016,36(11):1. (ZHANG Xue-wei,ZHANG Li-feng,YANG Wen,et al. Three-dimensional morphology of non-metallic inclusions and the source analysis of wrapped non-inclusion particles[J]. Metallurgical Analysis,2016,36(11):1.) [16] ZHANG X,ZHANG L,YANG W. Characterization of the three-dimensional morphology and formation mechanism of inclusions in linepipe steels[J]. Metallurgical and Materials Transactions B,2017,48(1):701. [17] Khaled F,Garcia C,Hua M,et al. Particle-stimulated nucleation of ferrite in heavy steel sections[J]. ISIJ International,2006,46(8):1233. [18] Hino M,Ito K. Thermodynamic Data for Steelmaking[M]. Sendai:Tohoku University Press,2009. |
[1] |
SUN Li-gen, LEI Ming, ZHANG Xin, LIU Yun-song, ZHU Li-guang. In-situ research on microstructure refining effect of Mg treatment for shipbuilding steel at high temperature[J]. Iron and Steel, 2020, 55(5): 94-102. |
[2] |
ZHU Li-guang, ZHENG Shi-wei, ZHANG Qing-jun, CAO Sheng-li. Influence of oxide metallurgy and pulsed magnetic field parameters on steel microstructure[J]. Iron and Steel, 2020, 55(3): 74-79. |
[3] |
DOU Wei-xue,WANG He-song,KANG Jian,LI Zhen-lei,YUAN Guo. Effect of cooling rate on microstructure of low-carbon steel produced by strip casting[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2019, 31(8): 748-753. |
[4] |
ZHAO Mengjing,WANG Feng,XI Xiaojun,YANG Shufeng,LI Jingshe. Effect of Y on inclusions characteristics and tensile #br# properties in EH36 shipbuilding steel[J]. Iron and Steel, 2019, 54(7): 61-67. |
[5] |
LU Ai-feng, WANG Yan-guo, WANG Jing, LIU Jin-chao, MIN Fan-qi. Analysis of surface oxidation and corrosion of ship building steel[J]. PHYSICS EXAMINATION AND TESTING, 2019, 37(3): 48-52. |
[6] |
LOU Hao-nan,WANG Bing-xing,WANG Zhao-dong. Microstructure and properties of Ti-Mg oxide metallurgy steel under TMCP process[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2019, 31(12): 1039-1045. |
|
|
|
|