|
|
Experiment on optimization of vanadium extraction from vanadium-titanium magnetite by response surface methodology |
YANG Shuang-ping, YANG Xin, CAO Shuan-wei, WANG Miao, LI Jiang-han, WANG Yu-ping |
School of Metallurgical Engineering, Xi′an University of Architecture and Technology, Xi′an 710055, Shaanxi, China |
|
|
Abstract The efficient recovery of iron, vanadium, titanium, and other elements in vanadium-titanium magnetite is of great significance for the comprehensive utilization of vanadium-titanium magnetite resources. Studies have shown that a variety of factors have an important influence on the degree of melting and the yield of elements in the process of sodiumization-reduction-melting coupling of vanadium-titanium magnetite. According to the design scheme of the Box-Behnke principle, this experiment selects three test factors: coal blending amount, alkali blending amount, and reduction temperature. The response surface method is used to study the influence of each factor on the vanadium sodium leaching index and optimize the test factors. By analyzing the experimental results, the corresponding polynomial model was established, and the optimal process conditions were obtained: coal blending amount 25.00%, alkali blending amount 58.29%, reducing melting temperature 1 251.84 ℃, and sodium leaching index response value 90.19%. The verification test was conducted under the best conditions, and it was found that the sodium leaching index was 87.15%, and the error was only 3.37%, which proved that the response surface method prediction model had reliability and accuracy.
|
Received: 04 June 2020
|
|
|
|
[1] 张俊,戴晓天,严定鎏,等.钒钛磁铁矿碳热钠化还原工艺[J].钢铁,2016,51(10):6.(ZHANG Jun, DAI Xiao-tian, YAN Ding-liu, et al. Carbothermal sodium reduction process of vanadium-bearing titanomagnetite[J]. Iron and Steel, 2016,51(10):6.) [2] 王帅,郭宇峰,姜涛,等. 钒钛磁铁矿综合利用现状及工业化发展方向[J]. 中国冶金, 2016, 26(10): 40. (WANG Shuai,GUO Yu-feng,JIANG Tao,et al. Comprehensive utilization and industrial development direction of vanadium-titanium magnetite[J]. China Metallurgy, 2016, 26(10): 40.) [3] 何占伟,薛向欣.典型钒钛磁铁矿的烧结基础特性[J].钢铁,2020,55(5):20.(HE Zhan-wei, XUE Xiang-xin. Basic sintering characteristics of several typical vanadium titanium magnetite[J]. Iron and Steel, 2020,55(5):20.) [4] 刘帅, 张宗旺, 张建良, 等. 高钛型高炉渣钛提取工艺研究现状及发展展望[J]. 中国冶金, 2020, 30(3): 1. (LIU Shuai, ZHANG Zong-wang, ZHANG Jian-liang, et al. Research status and development prospect of titanium extraction from high titanium blast furnace slag[J]. China Metallurgy, 2020, 30(3): 1.) [5] WU En-hui, ZHU Rong, YANG Shao-li, et al.Influences of technological parameters on smelting-separation process for metallized pellets of vanadium-bearing titanomagnetite concentrates[J]. Journal of Iron and Steel Research, International, 2016, 23 (7):655. [6] 苟淑云.对提高攀枝花钛资源利用率的思考[J].钢铁钒钛,2009,30(3):89.(GOU Shu-yun. Discussing on increasing the utilization rate of titanium in Panzhihua mineral resources[J]. Iron Steel Vanadium Titanium,2009,30(3):89.) [7] 张建良, 王春龙, 刘征建, 等.钒钛磁铁矿含碳球团还原的影响因素[J].北京科技大学学报, 2012, 34 (5):512.(ZHANG Jian-liang, WANG Chun-long, LIU Zheng-jian, et al.Influencing factors of the reduction of vanadium titano-magnetite carbon composite pellets[J].Journal of University of Science and Technology Beijing, 2012, 34 (5):512.) [8] 谢洪恩. Ti(C,N)对高钛型高炉渣脱硫能力的影响[J].中国冶金, 2020, 30(1): 32.(XIE Hong-en. Effect of Ti(C,N) on desulfurization capacity of high-titanium-type blast furnace slag[J]. China Metallurgy, 2020, 30(1): 32.) [9] 张宗旺, 吴轩, 陈士朝, 等.优化钒钛磁铁矿金属化球团熔分还原工艺铁回收率的研究[J].钢铁钒钛, 2013, 34 (2):39.(ZHANG Zong-wang, WU Xuan, CHEN Shi-zhao, et al.Research on increase of iron recovery during smelting and reduction of metallized pellet of vanadium-bearing titaniferous magnetite[J].Iron Steel Vanadium Titanium, 2013, 34 (2):39.) [10] 张艳华, 龙红明, 春铁军, 等.钒钛磁铁矿深度直接还原熔分提铁[J].钢铁研究学报, 2016, 28 (9):17.(ZHANG Yan-hua, LONG Hong-ming, CHUN Tie-jun, et al.Recovery of iron from vanadium-bearing titanomagnetite by deep direct reduction and melting process[J].Journal of Iron and Steel Research, 2016, 28 (9):17.) [11] 洪陆阔,齐渊洪,孙彩娇,等.钒钛磁铁矿煤基直接还原试验[J].钢铁,2017,52(11):15.(HONG Lu-kuo,QI Yuan-hong,SUN Cai-jiao,et al. Direct reduction of coal based vanadium-bearing titanomagnetite[J]. Iron and Steel,2017,52(11):15.) [12] 韩吉庆,陈晓,张力,等.钒钛磁铁精矿还原产物的磁选与熔分研究[J].稀有金属,2019,10(9):1.(HAN Ji-qing,CHEN Xiao,ZHANG Li,et al. Study on magnetic separation and melting of the reduced product of vanadium titanium magnetite concentrate[J]. Chinese Journal of Rare Metals,2019,10(9):1.) [13] 吕亚男,郭宇峰,陈栋.钒钛磁铁精矿预还原球团电炉冶炼研究[J].有色金属(冶炼部分),2016(7):38.(LÜ Ya-nan,GUO Yu-feng,CHEN Dong. Study on smelting of vanadium titanium magnetite concentrate pre-reduced pellet electric furnace[J]. Nonferrous Metals(Extractive Metallurgy),2016(7):38.) [14] 付自碧.钒钛磁铁矿提钒工艺发展历程及趋势[J].中国有色冶金,2011,40(6):29.(FU Zi-bi. Development history and trend of vanadium-titanium magnetite extraction process[J]. China Nonferrous Metallurgy,2011,40(6):29.) [15] 殷兆迁,李千文,付自碧,等.钒渣钠化球团化焙烧技术研究[J].钢铁钒钛,2016,37(1):12.(YIN Zhao-qian,LI Qian-wen,FU Zi-bi,et al. Technology research on sodium salt roasting of vanadium slag pellet[J]. Iron Steel Vanadium Titanium,2016,37(1):12.) [16] 李建兵.采用南非某钒钛磁铁矿直接提钒的工艺研究[J].湖南有色金属,2020,36(2):42.(LI Jian-bing. Study on extraction vanadium directly using vanadium-titanium magnetite from south africa[J]. Hunan Nonferrous Metals,2020,36(2):42.) [17] 李大成,纪安,扈玫珑.钒钛磁铁矿提钒新工艺研究[J].重庆大学学报,2018,41(10):45.(LI Da-cheng,JI An,HU Mei-long. Study on new technology of extracting vanadium from vanadium titanium magnetite[J].Journal of Chongqing University,2018,41(10):45.) [18] 左君,严丽君,杨秀琴,等.响应曲面法优化超细氧化亚铜光催化降解对硝基苯酚[J].北京科技大学学报,2010,32(8):1045.(ZUO Jun,YAN Li-jun,YANG Xiu-qin,et al. Photocatalytic degradation optimization of p-nitrophenol liquid by using ultrafine cuprous oxide with response surface methodology[J]. Journal of University of Science and Technology Beijing,2010,32(8):1045.) [19] 卢臣,张化武,乔永平,等.响应曲面法优化金浸出条件试验研究[J].黄金,2020,41(4):54.(LU Chen, ZHANG Hua-wu, QIAO Yong-ping,et al. Experimental research on the optimization of gold ore leaching conditions by response surface methodology[J]. Gold, 2020,41(4):54.) [20] 杨双平,张攀辉,郭拴全,等.响应曲面法优化内配兰炭赤铁矿球团焙烧工艺[J].钢铁,2017,52(1):13.(YANG Shuang-ping, ZHANG Pan-hui, GUO Shuan-quan, et al. Roasting technology of semicoke-burdened hematite pellets optimized by response surface methodology[J]. Iron and Steel,2017,52(1):13.) |
[1] |
OU Yang1,2,SUN Yongsheng1,2,3,YU Jianwen1,2,3,LI Yanjun1,2. Research status and development prospect of utilization of vanadiumtitanium magnetite[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2021, 33(4): 267-278. |
[2] |
PANG Zheng-de, LÜ Xue-wei, YAN Zhi-ming, BAI Chen-guang, XIE Hong-en, PAN Cheng. Viscosity and free running temperature of ultra-high TiO2 bearing blast furnace slag[J]. Iron and Steel, 2020, 55(8): 181-186. |
[3] |
MA Li-ming,ZHANG Jian-liang,WU Sheng-li,LIU Zheng-jian,WANG Yao-zu,XU Chen-yang. Treatment of vanadiumtitanium magnetite based on fluxed green ball composite agglomeration process[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2020, 32(6): 462-469. |
[4] |
HE Zhan-wei, XUE Xiang-xin. Basic sintering characteristics of several typical vanadium titanium magnetite[J]. Iron and Steel, 2020, 55(5): 20-25. |
[5] |
CHU Man-sheng,TANG Jue,LIU Zheng-gen,YING Zi-wei. Present situation and progress of comprehensive utilization for high-chromium vanadium-bearing titanomagnetie[J]. Chinese Journal of Iron and Steel, 2017, 29(5): 335-344. |
[6] |
WANG Yao-zu,ZHANG Jian-liang,LIU Zheng-jian,ZHANG Ya-peng,LIU Dong-hui,DU Cheng-bo. Effects of[w(TiO2)]on mineral structure and softening-melting property of sinter[J]. Iron and Steel, 2017, 52(3): 20-28. |
|
|
|
|