合金元素对Cr-Mo钢第二类回火脆性影响研究综述

doi:10.13228/j.boyuan.issn0449-749x.20200524

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (2493 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract For some Cr-Mo steels (2.25Cr1Mo) which are usually serviced at medium temperature for a long time,the critical problem of the second type temper embrittlement is existed in these steels because of the continuous segregations of P,S and other harmful impurities to the grain boundary during the service. In order to explore some effective methods to reduce the temper embrittlement tendency of this kind of Cr-Mo steels and improve the reliability of the material,starting from the segregation mechanism of solute elements,the intrinsic essences of alloy elements segregation at grain boundary and its function on improving the temper brittleness of steel were analyzed. The segregation phenomena of several common elements and their influence on temper embrittlement of steel were mainly summarized. At the same time,the main reasons for the difference between theoretical calculation and experimental study are also analyzed. It is expected to provide some effective methods for temper embrittlement of medium temperature steel during long-term service,and offer some references for the study of grain boundary segregation behavior of alloying elements in future.

Key words： the second type temper embrittlement segregation at grain boundary Cr-Mo steel alloying element auger electron spectroscopy (AES)

Received: 16 October 2020

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LI Xiao-bing
	DONG Xin
	XING Wei-wei
	CHEN Bo
	LIU Kui
	MA Ying-che

Cite this article:

LI Xiao-bing,DONG Xin,XING Wei-wei等. Effect of alloying elements addition on the secondary tempering brittleness of Cr-Mo steels review[J]. Iron and Steel, 2021, 56(3): 1-12.

URL:

http://www.chinamet.cn/Jweb_gt/EN/10.13228/j.boyuan.issn0449-749x.20200524 OR http://www.chinamet.cn/Jweb_gt/EN/Y2021/V56/I3/1

[1] 赵禹. 无间隙原子钢和2.25Cr1Mo 钢的脆化机制研究[D]. 哈尔滨:哈尔滨工业大学,2018.(ZHAO Yu. Study on Embrittlement Mechanisms of Interstitial-free and 2.25Cr1Mo Steels[D]. Harbin:Harbin Institute of Technology,2018.)
[2] WAN R,SUN F,ZHANG L,et al. Effect of Mo addition on strength of fire-resistant steel at elevated temperature[J]. Journal of Materials Engineering and Performance,2014,23(8):2780.
[3] 潘相相. 钠冷快堆蒸汽发生器主材研究进展[J]. 世界有色金属,2017,477(9):181.(PAN Xiang-xiang. Development of steam generator main materials for fast reactor[J]. World Nonferrous Metals,2017,477(9):181.)
[4] 凌纯,姚智颖. 结构钢的回火脆性综述[J]. 热加工工艺,2018,47(2):11.(LING Chun,YAO Zhi-ying. A summarize of tempering brittleness of structual steel[J]. Hot Working Technology,2018,47(2):11.)
[5] 沈冬冬,袁泽喜. 2.25Cr1Mo钢韧脆转变温度影响因素分析[J]. 武汉科技大学学报,2011,34(6):12.(SHEN Dong-dong,YUAN Ze-xi. Factors influencing the DBTT of 2.25Cr1Mo steel[J]. Journal of Wuhan University of Science and Technology,2011,34(6):12.)
[6] 崔忠圻,覃耀春. 金属学与热处理[M]. 北京:机械工业出版社,2007.(CUI Zhong-qi,QI Yao-chun. Metallography and Heat Treatment[M]. Beijing:China Machine Press,2007.)
[7] Yoshino K,McMahon C J. The cooperative relation between temper embrittlement and hydrogen embrittlement in a high strength steel[J]. Metallurgical Transactions,1974,5(2):363.
[8] McMahon Jr C J,Cianelli A K,Feng H C. The influence of Mo on P-induced temper embrittlement in Ni-Cr steel[J]. Metallurgical Transition A,1977,8(7):1055.
[9] McLean D,Northcott R J. Micro-examination and electrode-potential measurements of temper-brittle steel[J]. Transactions of the Iron and Steel Institute of Japan,1948,158:169.
[10] Guttmann M. Equilibrium segregation in a ternary solution:A model for temper embrittlement[J]. Surface Science,1975,53(1):213.
[11] XU T D,CHENG B Y. Kinetics of non-equilibrium grain boundary segregation[J]. Progress in Materials Science,2004,49(2):109.
[12] Lejček P. Grain Boundary Segregation in Metals[M]. Berlin:Springer,2010.
[13] Aust K T,Hanneman R E,Niessen P,et al. Solute induced hardening near grain boundaries in zone refined metals[J]. Acta Metallurgica,1968,16(3):291.
[14] Anthony T R. Solute segregation in vacancy gradients generated by sintering and temperature Changes[J]. Acta Metallurgica,1969,17(5):603.
[15] 徐庭栋,郑磊. 非平衡晶界偏聚和晶间脆性断裂研究的进展[J]. 材料导报,2004,18(1):1.(XU Ting-dong,ZHENG Lei. Progress in study of non-equilibrium grain boundary segregation and embrittlement[J]. Materials Reports,2004,18(1):1.)
[16] XU T D,SONG S H. A kinetic model of non-equilibrium grain boundary segregation[J]. Acta Metallurgica,1989,37(9):2499.
[17] SONG S H,SHEN D D,YUAN Z X,et al. Combined equilibrium and non-equilibrium phosphorus segregation to grain boundaries in a 2.25Cr1Mo steel[J]. Scripta Materialia,2003,49(5):473.
[18] 石德珂. 材料科学基础[M]. 北京:机械工业出版社,2003.(SHI De-ke. Fundamentals of Material Science[M]. Beijing:China Machine Press,2003.)
[19] 曹建春,刘铖霖,高鹏,等. 钢中元素偏聚的研究现状及其发展趋势[J]. 钢铁,2019,54(6):11.(CAO Jian-chun,LIU Cheng-lin,GAO Peng,et al. Research status and development trend of elemental segregation in steel[J]. Iron and Steel,2019,54(6):11.)
[20] Guttmann M,Mclean D. Interfacial Segregation[M]. [S.L.]:American Society for Metals,Metal Park,1979.
[21] 安彦兼次,鈴木茂,木村宏. 鉄の粒界に偏析したリンの化学結合状態[J]. 鐵と鋼:日本鐡鋼協會々誌,1983,69:625.
[22] Yin L,Sridhar S. Effects of residual elements arsenic,antimony,and tin on surface hot shortness[J]. Metallurgical and Materials Transactions B,2011,42(5):1031.
[23] Jones R H,Baer D R,Charlot L A,et al. Grain boundary segregation of sulfur and antimony in iron alloys[J]. Metallurgical Transactions A,1988,19(8):2005.
[24] Seah M P. Adsorption-induced interface decohesion[J]. Acta Metallurgica,1980,28:955.
[25] Lejč'ek P,Šob M,Paidar V. Interfacial segregation and grain boundary embrittlement:An overview and critical assessment of experimental data and calculated results[J]. Progress in Materials Science,2017,87:83.
[26] YANG Y,CHEN S L. Thermodynamic and kinetic modeling of grain boundary equilibrium segregation of P in α-Fe[J]. CALPHAD:Computer Coupling of Phase Diagrams and Thermochemistry,2017,57:134.
[27] ZHAO Y, SONG S H. Combined effect of phosphorus grain boundary segregation, yield strength, and grain size on embrittlement of a Cr-Mo low alloy steel[J]. Steel Research International,2018,89(8):6.
[28] Ho P,Mitchell D F,Graham M J. Surface and grain boundary segregation related to the temper embrittlement of a 2 1/4Cr-1Mo steel[J]. Applications of Surface Science,1983,15(1-4):108.
[29] 付贵勤,朱苗勇. 磷元素在钢中的晶界偏聚[J]. 鞍钢技术,2006(5):5.(FU Gui-qin,ZHU Miao-yong. Phosphorus segregation on steel grain boundary[J]. Angang Technology,2006(5):5.)
[30] 王洁,聂宝华,蔡成,等. 加氢反应器环境服役的2.25 Cr1Mo钢性能退化研究[J]. 材料工程,2015,43(1):82.(WANG Jie,NIE Bao-hua,CAI Cheng,et al. Performance degradation of 2.25Cr1Mo steel served in hydrogenation reactor[J]. Journal of Materials Engineering,2015,43(1):82.)
[31] Qu Z,McMahon Jr C J. The effects of tempering reactions on temper embrittlement of alloy steels[J]. Metallurgical Transitions A,1983,14:1101.
[32] Murza J C,Mcmahon C J. The effects of composition and microstructure on temper embrittlement in 2 1/4 Cr-1 Mo steel[J]. Journal of Engineering Materials and Technology,1980,102(4):369.
[33] Dumoulin P,Guttmann M,Maynier P,et al. Influence of segregated transition metals on intergranular brittleness of tempered martensitic steels[J]. Materials Science and Technology,1983,17:70.
[34] Geng W T,Freeman A J,Olson G B. Influence of alloying additions on the impurity induced grain boundary embrittlement[J]. Solid State Communications,2001,119:585.
[35] Lee D Y,Barrera E V,Stark J P,et al. The influence of alloying elements on impurity induced grain boundary embrittlement[J]. Metallurgical and Materials Transactions A,1984,15:1415.
[36] Yu J,McMahon C J. The effects of composition and carbide precipitation on temper embrittlement of 2.25Cr1Mo steel. Part 1. Effects of P and Sn[J]. Metallurgical Transition A,1980,11:277.
[37] Menyhard M,C J McMahon Jr. On the effect of molybdenum in the embrittlement of phosphorus-doped iron[J]. Acta Metallurgical,1989,37:2287.
[38] Ivani De Souza Bott,Luís Felipe Guimaraes De Souza,Jorge Carlos ferreira Jorge,et al. Comparison between real and simulated degradation in a 1.25%Cr0.5%Mo steel for high temperature service[J]. Materials Characterization,2005,54(3):206.
[39] Yu J,McMahon C J. The effects of composition and carbide precipitation on temper embrittlement of 2.25Cr1Mo steel. Part 2. Effects of Mn and Si[J]. Metallurgical Transition A,1980,11:291.
[40] Dumoulin,P,Guttmann M,Foucault M,et al. Role of molybdenum in phosphorus-induced temper embrittlement[J]. Metal Science,1980,14:1.
[41] 吴承建,汤晓丽. 铈、钼和磷在钢中的晶界偏聚行为与高温回火脆性[J]. 钢铁,1991,26(12):31.(WU Cheng-jian,TANG Xiao-li. Grain boundary segregation of Ce,Mo and P and temper embrittlement of steel[J]. Iron and Steel,1991,26(12):31.)
[42] 张东彬,吴承建. Ce在α-Fe晶界的偏聚及其对磷的晶界平衡偏聚的影响[J]. 金属学报,1988,24(2):100.(ZHANG Dong-bin,WU Cheng-jian. Behavior of cerium in grain boundary segregation and its influence on equilibrium segregation of phosphorus at grain boundary in α-iron[J]. Acta Metallurgical Sinica,1988,24(2):100.)
[43] 李平安,吴承建. 铈在Fe-0.1%Ce合金中晶界偏聚的测定及合金中Fe₅Ce相的物相分析[J]. 钢铁,1983,18(9):32.(LI Ping-an,WU Cheng-jian. Determination of grain-boundary segregation of cerium alloy and analysis of Fe₅Ce intermediate phase in Fe-Ce(0.10%) alloy[J]. Iron and Steel,1983,18(9):32.)
[44] 王海洋,高雪云,任慧平,等. 稀土Ce在α-Fe中占位倾向与作用机理的密度泛函理论研究[J]. 稀有金属材料与工程,2014,43(11):2739.(WANG Hai-yang,GAO Xue-yun,REN Hui-ping,et al. Density functional theory study on cerium occupying tendency and effecting mechanism in bcc α-Fe[J]. Rare Metal Materials and Engineering,2014,43(11):2739.)
[45] 张东彬,吴承建,杨让. 铈与磷晶界共偏聚状态的AES分析[J]. 中国稀土学报,1991,9(1):67.(ZHANG Dong-bin,WU Cheng-jian,YANG Rang. Analysis on the co-segregation of Ce and P at grain boundary[J]. Journal of the Chinese Society of Rare Earths,1991,9(1):67.)
[46] Yuan Z X,Song S H,Faulkner R G,et al. Effect of cerium on temper embrittlement of P-doped Mn structural steels[J]. Acta Metallurgica et Materialia,1994,42(1):127.
[47] XIN W B,SONG B,SONG M M,et al. Effect of cerium on characteristic of inclusions and grain boundary segregation of arsenic in iron melts[J]. Steel Research International,2015,86(12):1430.
[48] JIANG X,SONG S H. Enhanced hot ductility of a Cr-Mo low alloy steel by rare earth cerium[J]. Materials Science and Engineering A,2014,613(34):171.
[49] 刘伟建. 硼的固溶和析出行为对低碳钢性能影响的研究[D]. 北京:北京科技大学,2015. (LIU Wei-jian. Study on the Effect of Dissolution and Precipitation Behavior of Boron on the Properties of Low-Carbon Steel[D]. Beijing:University of Science and Technology Beijing,2015.)
[50] 童志博,彭其春,沈冬冬,等. 硼在钢中的作用及应用[J]. 中国冶金,2013,23(5):12.(TONG Zhi-bo,PENG Qi-chun,SHEN Dong-dong,et al. Function and application of boron in steel[J]. China Metallurgy,2013,23(5):12.)
[51] SONG S H,GUO M A,SHEN D D,et al. Effect of boron on the hot ductility of 2.25Cr1Mo steel[J]. Materials Science and Engineering A,2003,360:96.
[52] Jahazi M,Jonas J J. The non-equilibrium segregation of boron on original and moving austenite grain boundaries[J]. Materials Science and Engineering A,2002,335:49.
[53] Jones R B,Younas C M,Heard P J. The effect of microscale distribution of boron on the yield strength of C-Mn steels subjected to neutron irradiation[J]. Acta Metallurgical,2002,50(17):4395.
[54] Rosa G D,Maugis P,Portavoce A,et al. Grain-boundary segregation of boron in high-strength steel studied by nano-SIMS and atom probe tomography[J]. Acta Materialia,2020,182:226.
[55] 刘春明,周燕岛,安彦兼次,等. 微量硼对高纯硫合金沿晶断裂和硫沿晶偏析的影响[J]. 东北大学学报(自然科学版),1999,21(1):57.(LIU Chun-ming,ZHOU Yan-dao,Abiko Kenji,et al. Effect of trace of boron on grain boundary segregation of sulfur and sulfur-induced intergranular fracture in high purity iron with sulfur[J]. Journal of Northeastern University(Natural Science),1999,21(1):57.)
[56] Suzuki S,Abiko K,Kimura H. Phosphorus segregation related to the grain boundary structure in a Fe-P alloy[J]. Scripta Metallurgy,1981,15(10):1139.
[57] Emhart H,Grabke H J. Equilibrium segregation of phosphorus at grain boundaries of Fe-P,Fe-C-P,Fe-Cr-P,and Fe-Cr-C-P Alloys[J]. Materials Science and Technology,1981,15:401.
[58] Suzuki S,Obata M,Abiko K,et al. Role of carbon in preventing the intergranular fracture in iron-phosphorus alloys[J]. Tetsu-to-Hagané,1984,70:2262.
[59] 胡静,姜玉仙,林栋梁. 碳含量对含Mo钢中磷、钼、碳晶界偏聚的影响[J]. 材料热处理学报,2002,23(1):8.(HU Jing,JIANG Yu-xian,LIN Dong-liang. Effect of carbon content on grain boundary segregation of phosphorus,molybdenum and carbon in Mo-bearing steels[J]. Transactions of Materials and Heat Treatment,2002,23(1):8.)
[60] Takahashi J,Kawakami K,Ushioda K,et al. Quantitative analysis of grain boundaries in carbon- and nitrogen added ferritic steels by atom probe tomography[J]. Scripta Materialia,2012,66:207.
[61] Han J C,Seolb J B,Jafari M,et al. Competitive grain boundary segregation of phosphorus and carbon governs delamination crack in a ferritic steel[J]. Materials Characterization,2018,145:454.
[62] Takeda K,Nakada N,Tsuchiyama T,et al. Effect of interstitial elements on Hall-Petch coefficient of ferritic iron[J]. ISIJ International,2008,48(8):1122.
[63] WANG Y,XIE G S,ZHANG Z,et al. Effect of carbide content of temper embrittlement of 2.25Cr1Mo steel[C]//Pressure Vessels and Piping Conference. Vancouver:American Society of Mechanical Engineers,2016:17.
[64] Bor H Y,Chao C G,Ma C Y. The influence of magnesium on carbide characteristics and creep behavior of the Mar-M247 superalloy[J]. Scripta Materialia,1997,38(2):329.
[65] 孙文山,丁桂荣,罗铭蔚,等. 镁在35CrNi3MoV钢中的作用[J]. 兵器材料科学与工程,1997,20(4):3.(SUN Wen-shan,DING Gui-rong,LUO Ming-wei,et al. Effect of Mg in 35CrNi3MoV steel[J]. Ordnance Material Science and Engineering,1997,20(4):3.)
[66] LI X B,DONG X,ZHAO P X,et al. Effect of Mg addition on the temper embrittlement in 2.25Cr-1Mo Steel doped with 0.056% P-Mg segregation behavior at grain boundary[J]. Journal of Iron and Steel Research,International,2020,DOI: 10.1007/s42243-020-00506-w.