加热过程钢中夹杂物演变的研究进展

doi:10.13228/j.boyuan.issn0449-749x.20200631

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (10657 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract Inclusions control is an important topic in the research field of clean steel, which is vital to the quality of steel and product performance. In recent years, the research on inclusion expands from the traditional control of refining and continuous casting processes to the evolution study of re-heating, hot rolling and other hot working processes. In order to fully understand the evolution of inclusions during heating process and obtain the control strategy of inclusions, the evolution researches of MnS, TiN, and oxide in steel during the heating process at home and abroad was reviewed, the changes of morphology, composition, and size of inclusions, as well as the inclusions evolution mechanisms during the heating process was summarized, the application of inclusions evolution in oxide metallurgy technology was prospected, in order to provide a reference for the inclusions control research in the hot working process and the reasonable adjustment of the hot working technology.

Key words： heating process MnS inclusion TiN inclusion oxide evolution mechanism

Received: 25 December 2020

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHAN Dong-ping
	YANG Yong-kun
	JIANG Zhou-hua
	LEI Hong

Cite this article:

ZHAN Dong-ping,YANG Yong-kun,JIANG Zhou-hua等. A review of research on inclusions evolution in steel during heating process[J]. Iron and Steel, 2021, 56(10): 16-27.

URL:

http://www.chinamet.cn/Jweb_gt/EN/10.13228/j.boyuan.issn0449-749x.20200631 OR http://www.chinamet.cn/Jweb_gt/EN/Y2021/V56/I10/16

[1] Tripathi N N, Nzotta M, Sandberg A, et al. Effect of ladle age on formation of non-metallic inclusions in ladle treatment[J]. Ironmaking and Steelmaking, 2004, 31(3): 235.
[2] Kitamura S. Preface to the special issue on “fundamentals and applications of non-metallic inclusions in solid steel”[J]. ISIJ International, 2011, 51(12): 1943.
[3] Takahashi I, Sakae T, Yoshida T. Changes of the nonmetallic inclusion by heating[J]. Tetsu-to-Hagané, 1967, 53(3): 350.
[4] Ito Y, Masumitsu N, Matsubara K. Formation of manganese sulfide in steel[J]. Transactions of the Iron and Steel Institute of Japan, 1981, 21(7):477.
[5] Wilson P C, Murty Y V, Kattamis T Z, et al. Effect of homogenization on sulphide morphology and mechanical properties of rolled AISI 4340 steel[J]. Metals Technology, 1975, 2(1): 241.
[6] Murty Y V, Morral J E, Kattamis T Z, et al. Initial coarsening of manganese sulfide inclusions in rolled steel during homogenization[J].Metallurgical Transactions A, 1975, 6: 2031.
[7] Murty Y V, Kattamis T Z, Mehrabian R, et al. Behavior of sulfide inclusions during thermomechanical processing of AISI steel[J]. Metallurgical Transactions A, 1977, 8: 1275.
[8] Flowers J W, Karas S W. Coalescence of sulfides during secondary growth in 3%silicon-iron[J]. Journal of Applied Physics, 1967, 38(3):1085.
[9] Gnanamuthu D, Kattamis T Z, Flemings M C, et al. Effect of homogenization on sulfide inclusions in ferrous alloys[J]. Metallurgical Transactions, 1974, 5: 2557.
[10] Hanamura T, Shibata H, Waseda Y, et al. In-situ observation of intragranular ferrite nucleation at oxide particles[J]. ISIJ International, 1999, 39(11): 1188.
[11] 邵肖静, 王新华, 姜敏, 等. 加热过程中硫系易切削钢中MnS夹杂物行为的动态原位观察[J]. 金属学报, 2011, 47(9): 1210. (SHAO Xiao-jing, WANG Xin-hua, JIANG Min, et al. In situ observation of MnS inclusion behavior in resulfurized free-cutting steel during heating[J]. Acta Metallurgica Sinica, 2011, 47(9): 1210.)
[12] SHAO X J, WANG X H, JIANG M, et al. Effect of heat treatment conditions on shape control of large-sized elongated MnS inclusions in resulfurized free-cutting steels[J]. ISIJ International, 2011, 51(12): 1995.
[13] SHAO X J, WANG X H, JI C X, et al. Morphology, size and distribution of MnS inclusions in non-quenched and tempered steel during heat treatment[J]. International Journal of Minerals, Metallurgy and Materials, 2015, 22(5): 483.
[14] Nichols F A. On the spheroidization of rod-shaped particles of finite length[J]. Journal of Materials Science, 1976, 11:1077.
[15] 张学伟, 张立峰, 杨文, 等. 重轨钢铸坯和钢轨加热过程中MnS夹杂转变机制[J]. 炼钢, 2016, 32(5): 25. (ZHANG Xue-wei, ZHANG Li-feng, YANG Wen, et al. Effects of heating and holding process on the MnS inclusions in the bloom and rail of heavy rail steels[J]. Steelmaking, 2016, 32(5):25.)
[16] 齐江华, 杨成威, 朱万军, 等. 加热保温除了对重轨钢中MnS夹杂的影响[J]. 钢铁, 2013, 48(11): 79. (QI Jiang-hua, YANG Cheng-wei, ZHU Wan-jun, et al. Effect of heat and insulation treatment on MnS inclusion in heavy rail steel[J]. Iron and Steel, 2013, 48(11): 79.)
[17] 张学伟, 杨才福, 柴峰, 等. 热力学分析MnS夹杂物析出与控制[J]. 钢铁, 2019, 54(12): 27. (ZHANG Xue-wei, YANG Cai-fu, CHAI Feng, et al. Precipitation and control of MnS inclusions by thermodynamic analysis[J]. Iron and Steel, 2019, 54(12): 27.)
[18] 林腾昌, 门兵, 程雄, 等. 热处理对铸态钢中硫化锰夹杂物的影响[J]. 中国冶金, 2021, 31(4): 48. (LIN Teng-chang, MEN Bing, CHENG Xiong, et al. Influence of heat treatment on MnS inclusion in as-cast steel[J]. China Metallurgy, 2021, 31(4): 48.)
[19] Matsuda S, Okumura N. Effect of distribution of TiN precipitate particles on the austenite grain size of low carbon low alloy steels[J]. Transactions of the Iron and Steel Institute of Japan, 1978, 18: 198.
[20] Gregg J M, Bhadeshia H K D H. Solid-state nucleation of acicular ferrite on minerals added to molten steel[J]. Acta Materialia, 1997, 45: 739.
[21] Choi W, Matsuura H, Tsukihashi F. Effect of nitrogen on the formation and evolution of non-metallic inclusions in Fe-Al-Ti-N alloy[J]. ISIJ International, 2013, 53(11): 2007.
[22] Choi W, Matsuura H, Tsukihashi F. Effect of non-metallic inclusions in Fe-Al-Ti-O-N-S alloy on grain size[J]. Metallurgical and Materials Transactions B, 2016, 47, 1851.
[23] 曾泽芸, 李长荣, 黎志英, 等. HRB500E抗震钢筋中钛化物析出热力学分析[J]. 钢铁, 2020, 55(5): 45. (ZENG Ze-yun, LI Chang-rong, LI Zhi-ying, et al. Thermodynamic analysis of titanium precipitation in HRB500E seismic steel[J]. Iron and Steel, 2020, 55(5): 45.)
[24] 张京, 薛正良, 蒋跃东, 等. 帘线钢SWRH82A铸坯加热过程中钛夹杂的固溶[J]. 材料与冶金学报, 2014, 13(4): 242. (ZHANG Jing, XUE Zheng-liang, JIANG Yue-dong, et al. Solid solution of Ti inclusions during heating process for cast bloom of tire cord steel SWRH82A[J]. Journal of Materials and Metallurgy, 2014, 13(4): 242.)
[25] 雍歧龙. 钢铁材料中的第二相[M]. 北京:冶金工业出版社, 2006. (YONG Qi-long. Secondary Phases in Steels[M]. Beijing: Metallurgical Industry Press, 2006.)
[26] Takano K, Nakano R, Fukumoto S, et al. Grain size control by oxide dispersion in austenitic stainless steel[J]. Tetsu-to-Hagané, 2003, 89(5): 616.
[27] Shibata H, Tanaka T, Kimura K, et al. Composition change in oxide inclusions of stainless steel by heat treatment[J]. Ironmaking and Steelmaking, 2010, 37(7): 522.
[28] Shibata H, Kimura K, Tanaka T, et al. Mechanism of change in chemical composition of oxide inclusions in Fe-Cr alloys deoxidized with Mn and Si by heat treatment at 1473 K[J]. ISIJ International, 2011, 51(12): 1944.
[29] Ren Y, Zhang L F, Pistorius P C. Transformation of oxide inclusions in type 304 stainless steels during heat treatment[J]. Metallurgical and Materials Transactions B, 2017, 48: 1.
[30] WANG J J, LI W F, REN Y, et al. Thermodynamic and kinetic analysis for transformation of oxide inclusions in solid 304 stainless steels[J]. Steel Research International, 2018, 90: 1800600.
[31] GUO J, CHEN X R, HAN S W, et al. Evolution of plasticized MnO-Al₂O₃-SiO₂-based nonmetallic inclusion in 18wt%Cr-8wt%Ni stainless steel and its properties during soaking process[J]. International Journal of Minerals Metallurgy and Materials, 2020, 27(3): 328.
[32] Taniguchi T, Satoh N, Saito Y, et al. Investigation of compositional change of inclusions in martensitic stainless steel during heat treatment by newly developed analysis method[J]. ISIJ International, 2011, 51(12): 1957.
[33] ZHANG X L, YANG S F, LI J S, et al. Evolution of oxide inclusions in stainless steel containing yttrium during thermo-mechanical treatment[J]. Journal of Materials Research and Technology, 2020, 9(3): 5982.
[34] ZHANG X L, YANG S F, LI J S, et al. Transformation of oxide inclusions in stainless steel containing yttrium during isothermal heating at 1 473 K[J]. Metals, 2019, 9(9): 961.
[35] Ahmad S, Herrmann M, Mahmoud M M, et al. Crystallisation studies of RE₂O₃-Al₂O₃-SiO₂ glasses under long heat-treatment conditions[J]. Journal of Alloys and Compounds, 2016, 688: 762.
[36] Choi W, Matsuura H, Tsukihashi F. Changing behavior of non-metallic inclusions in solid iron deoxidized by Al-Ti addition during heating at 1473 K[J]. ISIJ International, 2011, 51(12): 1951.
[37] Li M G, Matsuura H, Tsukihashi F. Evolution of Al-Ti oxide inclusion during isothermal heating of Fe-Al-Ti alloy at 1 573 K (1 300 ℃)[J]. Metallurgical and Materials Transactions B, 2017, 48: 1915.
[38] Li M G, Matsuura H, Tsukihashi F. Time-dependent evolution of Ti-bearing oxide inclusions during isothermal holding at 1 573 K (1 300 ℃)[J]. Metallurgical and Materials Transactions A, 2019, 50: 863.
[39] CHU Y P, LI W F, REN Y, et al. Transformation of inclusions in linepipe steels during heat treatment[J]. Metallurgical and Materials Transactions B, 2019, 50: 2047.
[40] CHENG G, LI W F, ZHANG X G, et al. Transformation of inclusions in solid GCr15 bearing steels during heat treatment[J]. Metals, 2019, 9: 642.
[41] ZHANG Y X, ZHANG L F, CHU Y P, et al. Transformation of inclusions in a complicated-deoxidized heavy rail steels during heating[J]. Steel Research International, 2020, 91: 2000120.
[42] Liu C S, Webler B. Evolution of non-metallic inclusions during heat treatment[J]. Metallurgical Research and Technology, 2020, 117: 408.
[43] YANG Y K, ZHAN D P, LEI H, et al. Formation of non-metallic inclusion and acicular ferrite in Ti-Zr deoxidized steel[J]. ISIJ International, 2019, 59(9): 1545.
[44] YANG Y K, ZHAN D P, LEI H, et al. Research on inclusion evolution during re-heating process in Ti-Zr deoxidized low carbon steel[J]. Metallurgical and Materials Transactions B, 2021, 52: 1839.
[45] Harrison P L, Farrar R A. Influence of oxygen-rich inclusions on the γ-α phase transformation in high-strength low-alloy (HSLA) steel weld metals[J]. Journal of Materials Science, 1981, 16(8): 2218.
[46] Takamura J I, Mizoguchi S. Roles of oxides in steel performance[C]// Proceedings of the 6^th International Iron and Steel Congress. Nagoya: ISIJ, 1990: 591.
[47] Mizoguchi S, Takamura J I. Control of oxides as inoculants[C]// Proceedings of the 6^th International Iron and Steel Congress. Nagoya: ISIJ, 1990: 598.
[48] Mu W Z, Jönsson P G, Nakajima K. Recent aspects on the effect of inclusion characteristics on the intragranular ferrite formation in low alloy steels: A review[J]. High Temperature Material Process, 2017, 36(4): 309.
[49] 孙立根, 刘云松, 郝剑桥, 等. 诱发IAF夹杂物与原晶粒的尺寸匹配关系[J]. 钢铁, 2019, 54(6): 63. (SUN Li-gen, LIU Yun-song, HAO Jian-qiao, et al. Size matching relationship between inclusion that IAF induced and original grain[J]. Iron and Steel, 2019, 54(6): 63.)
[50] SHAO Y, LIU C X, YAN Z S, et al. Formation mechanism and control methods of acicular ferrite in HSLA steels: A review[J]. Journal of Materials Science and Technology, 2018, 34: 737.
[51] Zhang Z, Farrar R A. Role of non-metallic inclusions in formation of acicular ferrite in low alloy weld metals[J]. Materials Science Technology, 1996, 12(3): 237.
[52] Bramfitt B L. The effect of carbide and nitride additions on the heterogeneous nucleation behavior of liquid iron[J]. Metallurgical Transactions, 1970, 1: 1987.
[53] Ishikawa F, Takahashi T, Ochi T. Intragranular ferrite nucleation in medium-carbon vanadium steels[J]. Metallurgical and Materials Transactions A, 1994, 25: 929.
[54] Mu W Z, Mao H H, Jönsson P G, et al. Effect of carbon content on the potency of the intragranular ferrite formation[J]. Steel Research International, 2016, 87(3): 311.
[55] WEN B, SONG B, PAN N, et al. Effect of SiMg alloy on inclusions and microstructures of 16Mn steel[J]. Ironmaking and Steelmaking, 2011, 38(8), 577.
[56] Liu Z Z, Kobayashi Y, Yin F, et al. Nucleation of acicular ferrite on sulfide inclusion during rapid solidification of low carbon steel[J]. ISIJ International, 2007, 47(12): 1781.
[57] Zhang S H, Hattori N, Enomoto M, et al. Ferrite nucleation at ceramic/austenite interfaces[J]. ISIJ International, 1996, 36(10): 1301.
[58] Mu W Z, Jönsson P G, Nakajima K. Prediction of intragranular ferrite nucleation from TiO, TiN, and VN inclusions[J]. Journal of Materials Science, 2016, 51: 2168.
[59] Shim J H, Oh Y J, Suh J Y, et al. Ferrite nucleation potency of non-metallic inclusions in medium carbon steels[J]. Acta Materialia, 2001, 49: 2115.[60] 王丙兴, 朱伏先, 王超, 等. 氧化物冶金在大线能量焊接用钢中的应用[J]. 钢铁, 2019, 54(9): 12. (WANG Bing-xing, ZHU Fu-xian, WANG Chao, et al. Application of oxide metallurgy in high heat input welding steels[J]. Iron and Steel, 2019, 54(9): 12.)
[61] 谢毓敏, 宋明明, 门超奇, 等. 钙处理对稀土在大线能量焊接HAZ中作用的影响[J]. 钢铁, 2021, 56(3): 146. (XIE Yu-min, SONG Ming-ming, MEN Chao-qi, et al. Influence of Ca treatment on application of rare earth in HAZ during high heat input welding progress[J]. Iron and Steel, 2021, 56(3): 146.)
[62] WANG C, WANG Z D, WANG G D. Effect of hot deformation and controlled cooling process on microstructures of Ti-Zr deoxidized low carbon steel[J]. ISIJ International, 2016, 56(10): 1800.
[63] ZOU X D, ZHAO D P, SUN J C, et al. An integrated study on the evolution of inclusions in EH36 shipbuilding steel with Mg addition: from casting to welding[J]. Metallurgical and Materials Transactions B, 2018, 49: 481.
[64] ZOU X D, SUN J C, ZHAO D P, et al. Effects of Zr addition on evolution behavior of inclusions in EH36 shipbuilding steel: from casting to welding[J]. Journal of Iron and Steel Research, International, 2018, 25(2): 164.