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Optimization on ore-blending of PMC concentrate and two typical limonite ores |
HOU Jian1,2, BAI Chenguang1, HU Meilong1, LIU Xiaoming2, HUANG Xiaobo2, GUO Lanfen2 |
1. College of Materials Science and Engineering, Chongqing University, Chongqing 400044, China; 2. Produce and Manufacture Department, Handan Iron and Steel Group Co., Ltd., Handan 056015, Hebei, China |
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Abstract The mass percent of TFe and TiO2 for PMC concentrate (PMC for short) is relatively high, with a value of 62.5% and 2.6% respectively. Compared to iron ore fines of Carajas (IOC) from Brazil and other imported iron ore concentrates, PMC has an advantage in price and hence a strong liquidity in iron ore market. As a result, it is widely used in iron ore sintering process by many domestic steelworks. The proportion of PMC in iron ore mixtures for sintering in Hansteel is about 4% to 6%. To make full use of PMC in sintering, based on the ore-blending practice in Hansteel, the optimization on binary and ternary systems of PMC and two limonite ores (Yandi fine and FMG blend) was studied thoroughly. Firstly, the physicochemical properties, sintering basic characteristics and mineralogical composition after the test of bonding-phase strength for the aforementioned ores were examined. Considering the sintering basic characteristics of the tested iron ores, taking liquid-phase fluidity and bonding-phase strength as the sintering performance indexes, the ore-blending optimization between PMC and the two limonite ores was carried out. The experimental results show that the high contents of TFe, CaO and MgO and low contents of SiO2 and Al2O3 are the advantages of PMC, while the main problems of PMC for sintering are high contents of TiO2 and P, high digestion temperature and poor fluidity of liquid phase. Property complementarity in chemical composition, particle sizes and the sintering basic characteristics between PMC and the two limonite ores can be found and applied to ore-blending of the sinter mixtures. Increasing PMC content in the binary ore blending would weaken its liquid-phase fluidity gradually. However, the bonding-phase strength will basically be enhanced firstly and then drop sharply with the increase of PMC content from 0 to 100%. When the mass ratio of PMC to Yandi fine or to FMG blend is 1∶3 or 1∶2, the maximum bonding-phase strength of the mixtures can be obtained, with a value of 1 785 N or 1 605 N separately. The bonding-phase strength of the ternary mixture derived from the optimized binary blending was also high, that is 1 270 N. With the mass ratio of limonite ores to PMC increasing from 2.5∶1 to 4∶1, FMG blend has a stronger influence than Yandi fine on bonding-phase strength, with its value dropped to 740 N, while that is 1 170 N for the Yandi fine. Mineral phase analysis on samples after bonding-phase strength test indicated that: with the liquid-phase fluidity of the mixture falling in the range of 3.0 to 3.5, both the quantity of macro pore and the mean pore diameter in mineral phases can be decreased significantly, and thus the bonding-phase strength of the sample can be improved effectively.
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Received: 06 December 2022
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[1] 于银俊, 龙防, 陈伟, 等. 烧结矿成分体系对软熔滴落性能的影响[J]. 烧结球团, 2021, 46(6): 55.(YU Y J, LONG F, CHEN W, et al. Effect of sinter composition system on soft droplet performance[J]. Sintering and Pelletizing, 2021,46(6): 55.) [2] 金永龙,何志军,王川. 不同炉料结构高炉实现低碳排放的解析[J]. 钢铁, 2019, 54(7): 8.(JIN Y L, HE Z J, WANG C. Analysis on low carbon emission of blast furnace with different raw materials structure[J]. Iron and Steel, 2019, 54(7): 8.) [3] 刘颂, 赵亚迪, 甘丽,等. 烧结系统智能制造与大数据技术应用探讨[J]. 钢铁, 2021, 56(10): 54. (LIU S, ZHAO Y D, GAN L, et al. Discussion on intelligent manufacturing of sintering system and application of big data technology[J]. Iron and Steel, 2021, 56(10): 54.) [4] 陈绍国, 裴元东, 潘文, 等. 首钢京唐主流铁矿粉单种矿烧结试验研究[C]//全国炼铁原料学术会议, 兰州:中国金属学会,2015:87.(CHEN S G, PEI Y D, PAN W, et al. Experimental research on single sintering pot test of mainstream ion ore in Shougang Jingtang[C]//Proceedings of National Academic Meeting on Ironmaking Raw Materials. Lanzhou:The Chinese Society for Metals, 2015: 87.) [5] 贾文君, 刘晓明, 王金龙, 等. 邯钢非主流矿的基础特性与互补配矿的试验研究[J]. 河南冶金, 2016, 24(6): 12.(JIA W J, LIU X M, WANG J L, et al. Test research on basic sintering characteristics and complementary ore proportioning of non-mainstream ore in Hansteel[J]. Henan Metallurgy, 2016, 24(6): 12.) [6] 周明顺, 王义栋, 赵东明, 等. 高配比磁铁精矿烧结技术的研究进展[J]. 钢铁, 2020, 55(5): 1. (ZHOU M S, WANG Y D, ZHAO D M, et al. Development on sintering technologies with high proportion of magnetite concentrates[J]. Iron and Steel, 2020, 55(5): 1.) [7] 王永红,孙立伟,于原浩,等.不同SiO2质量分数精粉对烧结指标的影响[J].中国冶金,2019,29(5):10.(WANG Y H, SUN L W, YU Y H, et al. Influence of different SiO2 mass fraction on of fine powder on sinter Index[J]. China Metallurgy,2019,29(5):10.) [8] 王桂林, 张建良, 刘征建, 等. 高硫精矿配比对烧结矿性能的影响[J]. 钢铁, 2022, 57(2): 19. (WANG G L, ZHANG J L, LIU Z J, et al. Effect of high-sulfur concentrate on properties of sinter[J]. Iron and Steel, 2022, 57(2): 19.) [9] 寇明银, 张众, 曾旺, 等. 铁矿粉烧结优化配矿及其模型研究进展[J]. 钢铁, 2022, 57(2): 1.(KOU M Y, ZHANG Z, ZENG W, et al. Research progress on optimization technology and its model of ore-blending for sinter process[J]. Iron and Steel, 2022, 57(2): 1.) [10] 吴胜利, 戴宇明, DAUTER O, 等. 基于铁矿粉高温特性互补的烧结优化配矿[J]. 北京科技大学学报, 2010,32 (6):719.(WU S L, DAI Y M, DAUTER O, et al. Optimization of ore blending during sintering based on complementation of high temperature properties[J]. Journal of University of Science and Technology Beijing, 2010, 32(6):719.) [11] 白凯凯, 左海滨, 刘燊辉, 等. 塞拉利昂高铝矿对烧结矿性能的影响[J]. 烧结球团, 2019, 44(3): 1.(BAI K K, ZUO H B, LIU S H, et al. Effects of high alumina sierra leone ores on sinter performance[J]. Sintering and Pelletizing, 2019, 44(3): 1.) [12] 王天雄, 丁成义, 赵伟, 等. 南非PMC钒钛精矿基础性能及对烧结过程的影响[J]. 重庆大学学报(自然科学版), 2019, 42(8): 8.(WANG T X, DING C Y, ZHAO W, et al. Basic properties and sintering performance of pmc vanadium titanium concentrate of South Africa[J]. Journal of Chongqing University(Natural Science), 2019, 42(8): 8.) [13] 刘凯, 陈树军, 吕庆. PMC磁铁精矿粉性能的研究[J]. 烧结球团, 2016, 41(4): 54.(LIU K, CHEN S J, LÜ Q. Study on properties of PMC magnetite concentrate[J]. Sintering and Pelletizing, 2016, 41(4): 54.) [14] 李彬, 张宗旺, 吴胜利, 等. 不同铁矿粉替代澳洲低铝矿粉对烧结黏结相高温行为的影响[J]. 中国冶金, 2021, 31(12): 8.(LI B, ZHANG Z W, WU S L, et al. Effect of different iron ore replaced australian low aluminum ore powder on high temperature behavior of sintered binder phase[J]. China Metallurgy, 2021, 31(2): 8.) [15] 洪益成. 褐铁矿烧结基础性能的研究[J]. 钢铁研究学报, 2010, 22(9): 9.(HONG Y C. Study on fundamental properties of limonite in sinter process[J]. Journal of Iron and Steel Research, 2010, 22(9): 9.) [16] 杨杰康, 王福才. 高配比不同粒级贵沙褐铁矿烧结试验研究[J]. 烧结球团, 2016, 41(1): 78.(YANG J K, WANG F C. The sintering test of guisha limonite powder ore with high proportion and the different size fraction[J]. Sintering and Pelletizing, 2016, 41(1): 78.) [17] 张国成, 罗果萍, 柴轶凡, 等. 褐铁矿在烧结工艺中的优化配置[J]. 工程科学学报, 2020, 44(1): 39.(ZHANG G C, LUO G P, CHAI Y F, et al. Optimal allocation of limonite in sintering process[J]. Chinese Journal of Engineering, 2020, 44(1): 39.) [18] 贺淑珍. 高比例褐铁矿与细磁精矿粉配矿技术研究[J]. 钢铁, 2010, 45(9): 22.(HE S Z. Ore blending research of high proportion limonite with ultra-fine magnetite concentrate[J]. Iron and Steel, 2010, 45(9): 22.) [19] 吴胜利, 刘宇, 杜建新, 等. 铁矿粉与 CaO同化能力的试验研究[J]. 北京科技大学学报, 2002, 24(3): 258.(WU S L, LIU Y, DU J X, et al. Experiment study of assimilation ability between iron ores and CaO[J]. Journal of University of Science and Technology Beijing, 2002, 24(3):258.) [20] 阎丽娟, 吴胜利, 尤艺, 等. 各种铁矿粉的同化性及其互补配矿方法[J]. 北京科技大学学报, 2010, 32(3): 298.(YAN L J, WU S L, YOU Y, et al. Assimilation of iron ores and ore matching method based on complementary assimilation[J]. Journal of University of Science and Technology Beijing, 2010, 32(3):298.) [21] 杨聪聪, 朱德庆, 潘建, 等. 铁矿石高温烧结基础特性评价方法的国外研究进展[J]. 钢铁, 2022, 57(5): 11.(YANG C C, ZHU D Q, PAN J, et al. Overseas research advances in evaluation methods of high-temperature fundamental sintering characteristics of iron ores[J]. Iron and Steel, 2022, 57(5): 11.) [22] 吕学伟.炼铁流程中铁矿石评价体系构建[D]. 重庆:重庆大学, 2010.(LÜ X W. The Construction of Evaluation System of Iron Ore in Iron-making Process[D]. Chongqing:Chongqing University, 2010.) [23] 张艳允, 刘晓明, 郭兰芬,等. 对铁矿石烧结特性试验方法的探讨[C]//2009年河北省冶金学会炼铁技术暨学术年会. 唐山:河北省冶金总公司炼铁分公司, 2009:233.(ZHANG Y Y, LIU X M, GUO L F, et al. Discussion on test method of sintering characteristics of iron ores[C]//Proceedings of 2009 Ironmaking Technology and Academic Annual Meeting. Tangshan: Ironmaking Branch of Hebei Metallurgy, 2009:233.) [24] 亢庆锋, 张建良, 刘征建, 等. 烧结熔剂的同化行为试验[J]. 中国冶金, 2017, 27(9): 59.(KANG Q F, ZHANG J L, LIU Z J, et al. Assimilation behavior experiment of sinter fluxes[J]. China Metallurgy, 2017, 27(9): 59.) [25] 赵艳霞, 罗果萍, 郝志忠, 等. MgO对包钢烧结矿粘结相性能的影响[J]. 内蒙古科技大学学报, 2008, 27(1): 5.(ZHAO Y X, LUO G P, HAO Z Z, et al. Effect of MgO on bonding phase properties of sinter of Baotou Iron and Steel(Group) Co.[J]. Journal of Inner Mongolia University of Science and Techology, 2008, 27(1): 5.) [26] 苏步新, 张建良, 常健, 等. 铁矿粉的烧结特性及优化配矿试验研究[J]. 钢铁, 2011, 46(9): 22.(SU B X, ZHANG J L, CHANG J, et al. Sintering characteristics of iron ores and experiment study on optimizing ore-blending[J]. Iron and Steel, 2011, 46(9): 22.) [27] 张文兴, 黄苑龄, 张周位. 烧结矿的矿物组成和气孔特征对黏结相强度的影响[J]. 现代矿业, 2018(7): 118.(ZHANG W X, HUANG Y L, ZHANG Z W. Effects of pore characteristics and mineral composition on bonding phase strength of sintered ores[J]. Modern Mining, 2018(7): 118.) [28] 张勇, 周密, 储满生, 等. 进口高铬型钒钛磁铁矿的烧结基础特性[J]. 钢铁, 2012, 47(12): 18.(ZHANG Y, ZHOU M, CHU M S, et al. Basic sintering characteristics of imported vanadium and titanium mangnetite with high chrome content[J]. Iron and Steel, 2012, 47(12): 18.) [29] POWNCEBY M I, CLOUT J M F. Phase relations in the Fe-rich part of the system Fe2O3(-Fe3O4)-CaO-SiO2 at 1 240-1 300 ℃ and oxygen partial pressure of 5 × 10-3 atm: Implications for iron ore sinter[J]. Mineral Processing and Extractive Metallurgy, 2000, 109: 36. [30] JIANG X, ZHAO J, WANG L, et al. Effects of liquidus temperature and liquid amount on the fluidity of bonding phase and strength of sinter[J]. ISIJ International, 2020, 61(1): 86. [31] LOO C E, LEUNG W. Factors influencing the bonding phase structure of iron ore sinters[J]. ISIJ International, 2003, 43(9): 1393. |
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