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Research progress of CO removal in flue gas of typical steel production process |
LONG Hongming1,2, DING Long1, ZHAO Hexi1, KANG Jiangang3, CHUN Tiejun1, QIAN Lixin1 |
1. School of Metallurgical Engineering, Anhui University of Technology, Maanshan 243032, Anhui, China; 2. Anhui Province Key Laboratory of Metallurgy Engineering and Resources Recycling, Maanshan 243002, Anhui, China; 3. Engineering Technology Research Center, MCC Changtian International Engineering Co., Ltd., Changsha 410205, Hunan, China |
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Abstract CO,one of the six standard air pollutants,is toxic to human body and the environment. The steel industry releases large amounts of industrial tail gas containing CO into the atmosphere every year. Under the background of "carbon peaking" and "carbon neutral",the whole steel industry is facing huge CO emission reduction pressure. The present situation of CO emission from flue gas in typical steel production process was summarized. Continuous emissions included coke oven flue gas,sintering flue gas and rotary kiln flue gas,etc. The CO concentration in these flue gases was low and the flue gas emissions were large. For CO reduction in flue gas,the research works on source control,process reduction and terminal treatment technologies were summarized. Source control refers to replacing fossil energy with environmentally friendly hydrogen and electrical energy. Process reduction focuses on improving fossil fuel combustion conditions to reduce CO emissions. Terminal treatment involves physically/chemically separating CO from the flue gas or oxidizing it to CO2. Among the terminal treatment technologies,catalytic oxidation technology has low investment cost,no operational energy consumption and secondary pollution,and significant emission reduction effect. In addition,it can be combined with flue gas desulfurization and denitrification technology and has the possibility of industrial practice,but the current catalysts need to be optimized in terms of anti-poisoning and preparation cost. Finally,according to the CO emission reduction of sintering flue gas is an urgent problem to be solved,the feasible technical routes and challenges for CO emission reduction of sintering flue gas were analyzed. It is suggested that low input and high efficiency CO emission reduction can be achieved by coupling flue gas cycle,medium spraying,fuel improvement and catalytic oxidation technology.
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Received: 20 March 2023
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[1] OZTURK B,ARIHAN O,COSKUN F,et al. Acute carbon monoxide poisoning alters hemorheological parameters in human[J]. Clinical Hemorheology and Microcirculation,2015,61(4):591. [2] 胡洁琼,谢明,陈永泰,等. Au-Pt-Ni 三元催化剂体系纳米相图的研究进展[J]. 材料导报,2021,34(合刊): 338.(HU J Q,XIE M,CHEN Y T,et al. Research progress on the nanophase diagram of Au-Pt-Ni catalyst system[J]. Materials Reports,2021,34(Z2):338.) [3] 程扬,李杰,朱金伟,等. 烧结烟气CO减排研究动态[J]. 矿产综合利用,2022,43(2):22.(CHENG Y,LI J,ZHU J W,et al. Research progress of CO emission reduction in sintering flue gas[J]. Multipurpose Utilization of Mineral Resources,2022,43(2):22.) [4] 吴宏亮,罗云飞,周江虹,等. 富氧协同烟气循环对烧结矿质量指标和CO排放的影响[J]. 中南大学学报(自然科学版),2022,53(4):1179. (WU H L,LUO Y F,ZHOU J H,et al. Influence of oxygen enrichment and flue gas circulation on quality index of sinter and CO emissions[J]. Journal of Central South University(Science and Technology),2022,53(4):1179.) [5] 李乾坤,裴元东,周晓冬,等. 超厚料层烧结料面喷吹天然气生产实践[J]. 烧结球团,2022,47(3):32. (LI Q K,PEI Y D,ZHOU X D,et al. Production practice of natural gas injection on sintering material surface of ultra-thick layer[J]. Sintering and Pelletizing,2022,47(3):32.) [6] 陈绍国,张晓臣,梁洁,等. 首钢京唐公司超厚料层烧结的试验分析[J]. 中国冶金,2023,33(3):94.(CHEN S G,ZHANG X C,LIANG J,et al. Experimental analysis on ultra-deep bed sintering in Shougang Jingtang[J]. China Metallurgy,2023,33(3):94.) [7] 袁兵,马洛文,王跃飞,等. 宝钢烧结固体燃料粒度控制探索与实践[J]. 烧结球团,2010,35(1):44.(YUAN B,MA L W,WANG Y F,et al. Exploration and practice on control of sintering solid fuels particle size in Baosteel[J]. Sintering and Pelletizing,2010,35(1):44.) [8] 杨晓东,张丁辰,刘锟,等. 球团替代烧结:铁前节能低碳污染减排的重要途径[J]. 工程研究(跨学科视野中的工程),2017,9(1):44.(YANG X D,ZHANG D C,LIU K,et al. Substituted pelleting for sintering:An important approach of energy-saving,low-carbon and emission reduction before ironmaking[J]. Journal of Engineering Studies,2017,9(1):44.) [9] 龙红明,丁龙,陶家杰,等. 烧结烟气脱硝废弃钒钨钛催化剂资源化利用途径分析[J]. 钢铁,2022,57(7):162.(LONG H M,DING L,TAO J J,et al. Analysis on resource utilization of spent V2O5-WO3/TiO2 catalyst produced in sintering flue gas[J]. Iron and Steel,2022,57(7):162.) [10] 刘文强,李杰,朱金伟,等. 配碳量对烧结烟气排放规律的影响[J]. 烧结球团,2020,45(1):61.(LIU W Q,LI J,ZHU J W,et al. Effect of carbon addition on emission of sintering flue gas[J]. Sintering and Pelletizing,2020,45(1):61.) [11] 裴元东,廖继勇,张俊杰,等. 铁矿粉烧结过程CO减排探讨[J]. 烧结球团,2019,44(1):69.(PEI Y D,LIAO J Y,ZHANG J J,et al. Discussion on CO emission reduction in iron ore fines sintering process[J]. Sintering and Pelletizing,2019,44(1):69.) [12] 李辉. 钢铁企业煤气系统优化调度模型及应用[D]. 沈阳:东北大学,2018.(LI H. Optimal Scheduling and Application of By-Product Gas System in Iron and Steel Works[D]. Shenyang:Northeastern University,2018.) [13] 王跃欣. 焦炉烟气资源化分析与实践[J]. 燃料与化工,2022,53(2):52.(WANG Y X. Analysis and practice in utilization of coke oven flue gas[J]. Fuel and Chemical Processes,2022,53(2):52.) [14] 王雅新,刘俊,易红宏,等. 钢铁行业烧结烟气脱硫脱硝技术研究进展[J]. 环境工程,2022,40(9):253.(WANG Y X,LIU J,YI H H,et al. Research progress of desulfurization and desulfurization and denitration technologies for sintering flue gas in iron and steel industry[J]. Environmental Engineering,2022,40(9):253.) [15] 胡延永,段明官,姜林,等. 高氧高氮球团焙烧烟气SCR超低排放应用实践[J]. 矿业工程,2021,19(4):59.(HU Y Y,DUAN M G,JIANG L,et al. Application practice of SCR ultra-low emission of flue gas from induration of high-oxygen and high-nitrogen pellet[J]. Mining Engineering,2021,19(4):59.) [16] 杨春善,高古忠. 转底炉烟气系统堵塞、腐蚀及防腐探索[J]. 中国冶金,2019,29(9):82.(YANG C S,GAO G Z. Exploration on blockage,corrosion and antisepsis of rotary hearth furnace flue system[J]. China Metallurgy,2019,29(9):82.) [17] 李汉华,原辉. 转底炉烟气余热再利用发电[J]. 中国设备工程,2015(5):60.(LI H H,YUAN H. Reuse of waste heat from flue gas of rotary hearth furnace to generate electricity[J]. China Plant Engineering,2015(5):60.) [18] 王新东,赵志龙,李传民,等. 基于富氢焦炉煤气零重整的氢冶金工程技术[J].钢铁,2023,58(5):11.(WANG X D, ZHAO Z L, LI C M, et al. Hydrogen metallurgy engineering technologies based on zero reforming of hydrogen enriched coke oven gas[J]. Iron and Steel,2023,58(5):11.) [19] 杨涛,刘爽,钱立新,等. 废塑料在钢铁生产流程中资源化利用研究进展[J]. 钢铁研究学报,2022,34(10):1047.(YANG T,LIU S,QIAN L X,et al. Recycling waste plastics in iron and steel production process:A review[J]. Journal of Iron and Steel Research,2022,34(10):1047.) [20] 杨天钧,张建良,刘征建,等. 低碳炼铁 势在必行[J]. 炼铁,2021,40(4):1.(YANG T J,ZHANG J L,LIU Z J,et al. Low carbon ironmaking is imperative in facing environment challenge[J]. Ironmaking,2021,40(4):1.) [21] 王新东,李建新,刘宏强,等. 河钢创新技术的研发与实践[J]. 河北冶金,2020,42(2):1.(WANG X D,LI J X,LIU H Q,et al. Research and practice of innovative technology in HBIS[J]. Hebei Metallurgy,2020,42(2):1.) [22] 朱荣,魏光升,张洪金. 近零碳排电弧炉炼钢工艺技术研究及展望[J]. 钢铁,2022,57(10):1.(ZHU R,WEI G S,ZHANG H J. Research and prospect of EAF steelmakingwith near-zero carbon emissions[J]. Iron and Steel,2022,57(10):1.) [23] 李建,毛晓明,熊林. 铁矿石微波烧结试验研究[J]. 烧结球团,2022,47(1):80.(LI J,MAO X M,XIONG L. Experimental study on microwave sintering of iron ore[J]. Sintering and Pelletizing,2022,47(1):80.) [24] 范晓慧,余志元,甘敏,等. 循环烟气性质影响铁矿烧结的规律研究[C]//2013年全国烧结烟气综合治理技术研讨会论文集. 大同:中国金属学会,2013:54. (FAN X H,YU Z Y,GAN M,et al. Study on the effect of circulating flue gas properties on sintering of iron ore[C]//Proceedings of 2013 National Symposium on Sintering Gas Comprehensive Treatment Technology. Datong:The Chinese Society for Metals,2013:54.) [25] 王涛,谢春帅. 烧结烟气循环技术研究进展与展望[J]. 冶金能源,2020,39(2):55.(WANG T,XIE C S. Research progress and prospect of sintering flue gas recycling technology[J]. Energy for Metallurgical Industry,2020,39(2):55.) [26] 陈思墨,周浩宇,朱蓉甲,等. 烧结热风循环罩数值模拟与结构优化[J]. 中国冶金,2022,32(3):119.(CHEN S M,ZHOU H Y,ZHU R J,et al. Numerical simulation and structure optimization of sintering hot air circulating hood[J]. China Metallurgy,2022,32(3):119.) [27] 李超群,徐文青,朱廷钰. 烧结烟气循环技术研究现状与发展前景[J]. 河北冶金,2019(增刊1):1.(LI C Q,XU W Q,ZHU T Y. Recent advances and development prospect of sintering flue gas cycle technology[J]. Hebei Metallurgy,2019(s1):1.) [28] 刘天新,沈青. 水蒸气助燃机理的研究与应用[J]. 中国能源,1995,18(10):20.(LIU T X,SHEN Q. Research and application of steam combustion aid mechanism[J]. Energy of China,1995,18(10):20.) [29] WANG Y,YANG T,WANG H,et al. Application of steam injection in iron ore sintering:Fuel combustion efficiency and CO emissions[J]. Journal of Iron and Steel Research International,2023,30(1):31. [30] 裴元东,欧书海,马怀营,等. 烧结料面喷吹蒸汽对烧结矿质量和CO排放影响研究 [J]. 烧结球团,2018,43(1):35.(PEI Y D,OU S H,MA H Y,et al. Effect of steam spraying on sintering bed on sinter quality and CO emission[J]. Sintering and Pelletizing,2018,43(1):35.) [31] 裴元东,史凤奎,吴胜利,等. 烧结料面喷洒蒸汽提高燃料燃烧效率研究[J]. 烧结球团,2016,41(6):16.(PEI Y D,SHI F K,WU S L,et al. Research on spraying steam on surface of sintering material bed to increase fuel combustion efficiency[J]. Sintering and Pelletizing,2016,41(6):16.) [32] OYAMA N,IWAMI Y,YAMAMOTO T,et al. Development of secondary-fuel injection technology for energy reduction in the iron ore sintering process[J]. ISIJ International,2011,51(6):913. [33] 范晓慧,甘敏,季志云,等. 复合气体介质烧结的节能减排技术开发与应用[J]. 钢铁,2020,55(8):62. (FAN X H,GAN M,JI Z Y,et al. Development and application of techniques for energy conservation and emission reduction during sintering process based on multiple-component gases medium[J]. Iron and Steel,2020,55(8):62.) [34] 冯根生,吴胜利,赵佐军. 改善厚料层烧结热态透气性的研究[J]. 烧结球团,2011,36(1):1.(FENG G S,WU S L,ZHAO Z J. Research on improving hot permeability of deep bed sintering[J]. Sintering and Pelletizing,2011,36(1):1.) [35] 张建良,阚永海,张士军,等. 全活性石灰强化烧结技术在超厚料层中的应用[J]. 钢铁,2020,55(8):56.(ZHANG J L,KAN Y H,ZHANG S J,et al. Application of full active lime intensified sintering technology in ultra-thick layer[J]. Iron and Steel,2020,55(8):56.) [36] MURAKAMI K,SUGAWARA K,KAWAGUCHI T. Analysis of combustion rate of various carbon materials for iron ore sintering process[J]. ISIJ International,2013,53(9):1580. [37] NANDANWAR S V. 基于烧结工艺中固体燃料处理的CO2减排技术:印度比莱钢铁厂愿景[J]. 世界钢铁,2013,12(1):23.(NANDANWAR S V.CO2 reduction through innovative technologies for solid fuel processing in sinter making:Perspective of Bhilai Steel Plant,SAIL,India[J]. World Iron and Steel,2013,12(1):23.) [38] 程扬,李杰,杨爱民,等. 添加剂降低烧结烟气中CO含量的试验行为[J]. 中国冶金,2020,30(12):99.(CHENG Y,LI J,YANG A M,et al. Experimental behavior of additives to reduce CO content in sintering flue gas[J]. China Metallurgy,2020,30(12):99.) [39] 潘建. 铁矿烧结烟气减量排放基础理论与工艺研究[D]. 长沙:中南大学,2007.(PAN J. Theoretical and Process Studies of the Abatement of Flue Gas Emissions During Iron Ore Sintering[D]. Changsha:Central South University,2007.) [40] 王兆才,刘臣,李继淦,等. 烧结烟气COx的生成机理及减排措施[J]. 烧结球团,2021,46(1):14.(WANG Z C,LIU C,LI J G,et al. Generation mechanism and emission reduction measures of COx in sintering flue gas[J]. Sintering and Pelletizing,2021,46(1):14.) [41] QIE J,ZHANG C,GUO Y,et al. Reducing the sintering flue gas pollutants emissions based on the accumulation heat effect in iron ore sintering process[J]. Transactions of the Indian Institute of Metals,2019,72:581. [42] DAI M,GU B,MA X,et al. Nitrogen monoxide reduction by carbon monoxide to combustion control with calcium ferrite redox in iron ore sintering[J]. Fuel,2023,337:127172. [43] 苏珊珊. 深冷分离一氧化碳工艺模拟分析与改造研究[D]. 大连:大连理工大学,2012.(SU S S. Study on the Simulation and Reform of CO Cryogenic Separationp[D]. Dalian:Dalian University of Technology,2012.) [44] 陈星,李野. CO净化方法的研究进展[J]. 消防科学与技术,2011,30(6):482.(CHEN X,LI Y. Research progress on CO purifying methods[J]. Fire Science and Technology,2011,30(6):482.) [45] 景志宏. 煤制CO技术经济分析[J]. 油气田地面工程,2006,29(11):51.(JING Z H. Technical and economic analysis of CO from coal[J]. Oil-Gasfield Surface Engineering,2006,29(11):51.) [46] 董霓,林艳军,崔玉东. 治理VOCs的新工艺:沸石转轮吸附浓缩+催化燃烧[J]. 环境与发展,2017,29(7):118.(DONG N,LIN Y J,CUI Y D.A new process for controlling VOCs-Zeolite runner adsorption concentration+catalytic combustion[J]. Environment and Development,2017,29(7):118.) [47] 成毅. 烧结烟气低浓度CO脱除优化处理研究[D]. 杭州:浙江大学,2020.(CHENG Y. Study on the Removal of Low Concentration CO in Sintering Flue Gas[D]. Hangzhou:Zhejiang University,2020.) [48] 廖继勇,郑浩翔,甘敏,等. 烧结烟气CO的产生及治理途径:末端治理技术[J]. 烧结球团,2021,46(2):17. (LIAO J Y,ZHENG H X,GAN M,et al. Generation and governance way of CO in sintering flue gas:End treatment technology[J]. Sintering and Pelletizing,2021,46(2):17.) [49] 吕丽,王东辉,史喜成,等. 臭氧催化氧化VOCs和CO研究进展[J]. 环境工程,2011,29(增刊1):162.(L L,WANG D H,SHI X C,et al. Research process on catalytic oxidation of VOCs and CO with ozone[J]. Environmental Engineering,2011,29(s1):162.) [50] ALLIAN A D,TAKANABE K,FUJDALA K L,et al. Chemisorption of CO and mechanism of CO oxidation on supported platinum nanoclusters[J]. Journal of the American Chemical Society,2011,133(12):4498. [51] OVER H,KIM Y D,SEITSONEN A P,et al. Atomic-scale structure and catalytic reactivity of the RuO2 (110) surface[J]. Science,2000,287(5457):1474. [52] WANG C,GU X,YAN H,et al. Water-mediated Mars-van Krevelen mechanism for CO oxidation on ceria-supported single-atom Pt1 catalyst[J]. ACS Catalysis,2017,7(1):887. [53] ZHOU Y,WANG Z,LIU C. Perspective on CO oxidation over Pd-based catalysts[J]. Catalysis Science and Technology,2015,5(1):69. [54] VASILCHENKO D,TOPCHIYAN P,BERDYUGIN S,et al. Tetraalkylammonium salts of platinum nitrato complexes:Isolation,structure,and relevance to the preparation of PtOx/CeO2 catalysts for low-temperature CO oxidation[J]. Inorganic Chemistry,2019,58(9):6075. [55] HARUTA M,KOBAYASHI T,SANO H,et al. Novel gold catalysts for the oxidation of carbon monoxide at a temperature far below 0 ℃[J]. Chemistry Letters,1987,16(2):405. [56] DU M,SUN D,YANG H,et al. Influence of Au particle size on Au/TiO2 catalysts for CO oxidation[J]. The Journal of Physical Chemistry C,2014,118(33):19150 [57] LOU Y,CAI Y,HU W,et al. Identification of active area as active center for CO oxidation over single Au atom catalyst[J]. ACS Catalysis,2020,10(11):6094. [58] 朱梦婷,邢金媛,李艳明,等. 载体焙烧温度对Pt/FeOx催化剂的CO催化氧化及其抗H2O和CO2的影响[J]. 浙江师范大学学报(自然科学版),2021,44(2):171.(ZHU M T,XING J Y,LI Y M,et al. Effect support calcination temperature on CO oxidation over Pt/FeOx catalysts and their resistance to H2O and CO2[J]. Journal of Zhejiang Normal University(Natural Sciences),2021,44(2):171.) [59] 李浩鸣,唐银华,康建刚,等. 基于Pt-Ce-Ti催化剂的烧结烟气CO氧化性能研究[J]. 中南大学学报(自然科学版),2022,53(12):4886.(LI H M,TANG Y H,KANG J G,et al. Study on CO oxidation in sintering flue gas based on Pt-Ce-Ti catalyst[J]. Journal of Central South University(Science and Technology),2022,53(12):4886.) [60] SHAO Z,ZHANG S,LIU X,et al. Maximizing the synergistic effect between Pt0 and Ptδ+ in a confined Pt-based catalyst for durable hydrogen production[J]. Applied Catalysis B: Environmental,2022,316:121669. [61] MURAVEV V,SPEZZATI G,SU Y Q,et al. Interface dynamics of Pd-CeO2 single-atom catalysts during CO oxidation[J]. Nature Catalysis,2021,4(6):469. [62] SPEZZATI G,BENAVIDEZ A D,DELARIVA A T,et al. CO oxidation by Pd supported on CeO2 (100) and CeO2 (111) facets[J]. Applied Catalysis B: Environmental,2019,243:36. [63] CAI Y,XU J,GUO Y,et al. Ultrathin,polycrystalline,two-dimensional Co3O4 for low-temperature CO oxidation[J]. ACS Catalysis,2019,9(3):2558. [64] BAE J,SHIN D,JEONG H,et al. Highly water-resistant La-doped Co3O4 catalyst for CO oxidation[J]. ACS Catalysis,2019,9(11):10093. [65] 刘婷,李经纬,刘永鑫,等. Cu2O@HKUST-1前驱物法合成CuO中空管状超级结构及其CO催化氧化性能[J]. 应用化学,2018,35(6):687.(LIU T,LI J W,LIU Y X,et al. CuO hollow tubular superstructure fabricated from Cu2O@HKUST-1 nanowire for CO oxidation[J]. Chinese Journal of Applied Chemistry,2018,35(6):687.) [66] 魏金涛,韩小金,黄张根,等. CO预处理Cu基催化剂用于CO催化氧化的研究[J]. 烧结球团,2022,47(5):81.(WEI J T,HAN X J,HUANG Z G,et al. Research on CO pretreatment Cu-based catalyst used for CO catalytic oxidation[J]. Sintering and Pelletizing,2022,47(5):81.) [67] SONG X Z,SU Q F,LI S J,et al. Triple-shelled CuO/CeO2 hollow nanospheres derived from metal-organic frameworks as highly efficient catalysts for CO oxidation[J]. New Journal of Chemistry,2019,43(40):16096. [68] 刘爽,丁龙,王毅璠,等. 工业燃煤废气挥发性有机物催化减排研究进展[J]. 安徽工业大学学报(自然科学版),2022,39(2):119.(LIU S,DING L,WANG Y F,et al. Research progress on emission reduction of volatile organic compounds in industrial flue gas[J]. Journal of Anhui University of Technology(Natural Science),2022,39(2):119.) [69] EINAGA H,NASU Y,ODA M,et al. Catalytic performances of perovskite oxides for CO oxidation under microwave irradiation[J]. Chemical Engineering Journal,2016,283:97. [70] DROSOU C,NIKOLARAKI E,NIKOLAOU V,et al. Activity and thermal aging stability of La1-xSrxMnO3 (x=0.0,0.3,0.5,0.7) and Ir/La1-xSrxMnO3 catalysts for CO oxidation with excess O2[J]. Nanomaterials,2023,13(4):663. [71] 丁龙,杨涛,钱立新,等. 烧结烟气中含钾化合物对钒钨钛催化剂脱硝/二噁英性能的影响[J]. 工程科学学报,2022,44(12):2189.(DING L,YANG T,QIAN L X,et al. Effect of potassium compounds in sintering flue gas on the removal of NO and dioxin performance over V2O5-WO3/TiO2 catalyst[J]. Chinese Journal of Engineering,2022,44(12):2189.) [72] 钱立新,丁龙,魏进超,等. Ti/Sn掺杂CeMn基催化剂的低温脱硝活性及抗水性能[J]. 过程工程学报,2022,22(12):1691.(QIAN L X,DING L,WEI J C,et al. Low-temperature denitrification activity and water tolerance of Ti/Sn doped CeMn-based catalyst[J]. The Chinese Journal of Process Engineering,2022,22(12):1691.) [73] 何凯琳,杨本涛,叶恒棣,等. 烧结烟气CO脱除Pt催化剂的SO2中毒与再生[J]. 烧结球团,2021,46(3):72.(HE K L,YANG B T,YE H D,et al. SO2 poisoning and regeneration of Pt catalyst for CO removal from sintering flue gas[J]. Sintering and Pelletizing,2021,46(3):72.) |
[1] |
WEN Zhenjing1,2,HUANG Bangfu1,2,YANG Zhengyu1,2,DAI Meng1,2,LI Wanjun1,2. Research status and prospect of poisoning in denitration catalysts[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2022, 34(7): 605-612. |
[2] |
LONG Hong-ming, DING Long, TAO Jia-jie, QIAN Li-xin. Analysis on resource utilization of spent V2O5-WO3/TiO2 catalyst produced in sintering flue gas[J]. Iron and Steel, 2022, 57(7): 162-178. |
[3] |
FAN Xiaohui, ZHU Yuan, GAN Min, JI Zhiyun, SUN Zengqing, WU Yufeng . Effect of SO2 and H2O(g) in flue gas of pellet on SCR catalytic denitrification [J]. JOURNAL OF IRON AND STEEL RESEARCH , 2022, 34(5): 429-437. |
[4] |
Zeng-hui Su, Shan Ren, Tian-shi Zhang, Jie Yang, Yu-han Zhou, Lu Yao. Effects of PbO poisoning on Ce–Mn/AC catalyst for low-temperature selective catalytic reduction of NO with NH3[J]. JOURNAL OF IRON AND STEEL RESEARCH,INTERNATIONAL, 2021, 28(2): 133-139. |
[5] |
QIAN Li-xin1,DING Long1,LONG Hong-ming1,2,ZHANG Xiao-xia1,YU Zheng-wei1. Effect of alkali poisoning on simultaneous removal NO and dioxins over SCR catalysts for sintering flue gas[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2020, 32(7): 542-549. |
[6] |
CHEN Yu-xin, XU Dong-li, WANG Li, HUANG Jun, XUE Yong-qiang. Theoretical Analysis for Splashing in Iron Ladle of Mechanical Stirring Desulphurization Process[J]. Iron and Steel, 2014, 49(10): 24-29. |
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