Effects of Solution Depletion and Segregation Oxidation on Morphology of Modified 310 Austenitic Stainless Steel
Hong- ying SUN1,Qiang HE1,Zhang- jian ZHOU2,Man WANG2,Guang- ming ZHANG2,Shao- fu LI2
1. Key Laboratory of Key Functional Parts of Machine, Anyang Institute of Technology, Anyang 455002,Henan, China 2. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
Effects of Solution Depletion and Segregation Oxidation on Morphology of Modified 310 Austenitic Stainless Steel
Hong- ying SUN1,Qiang HE1,Zhang- jian ZHOU2,Man WANG2,Guang- ming ZHANG2,Shao- fu LI2
1. Key Laboratory of Key Functional Parts of Machine, Anyang Institute of Technology, Anyang 455002,Henan, China 2. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China
ժҪ The oxidation morphologies of modified 310 steel exposed in 900 and 1100 �� air were investigated. A double layer morphology consisting of a (Cr,Mn)- rich outer layer and a fine Cr- rich inner layer was formed at 900 ��. It was related to the breakaway oxidation induced by the Cr- depletion and the Mn- segregation in inner layer. Some Cr- rich oxides with amorphous state were formed along grain boundaries. And some new finer oxide grains, voids and Cr- rich precipitates were observed in spallation areas at 1100 ��. Correspondingly, the oxidation kinetic curve dropped with the spallation of scale and increased with the formation of some new oxide grains. It was caused by segregation of Cr and the transformation of oxides from Cr2O3 to the volatile oxides at elevated temperature. XRD analysis showed that the precipitates were mainly composed of CrO3. Segregation and depletion for solutions were also discussed by oxidation diffusion mechanisms.
Abstract��The oxidation morphologies of modified 310 steel exposed in 900 and 1100 �� air were investigated. A double layer morphology consisting of a (Cr,Mn)- rich outer layer and a fine Cr- rich inner layer was formed at 900 ��. It was related to the breakaway oxidation induced by the Cr- depletion and the Mn- segregation in inner layer. Some Cr- rich oxides with amorphous state were formed along grain boundaries. And some new finer oxide grains, voids and Cr- rich precipitates were observed in spallation areas at 1100 ��. Correspondingly, the oxidation kinetic curve dropped with the spallation of scale and increased with the formation of some new oxide grains. It was caused by segregation of Cr and the transformation of oxides from Cr2O3 to the volatile oxides at elevated temperature. XRD analysis showed that the precipitates were mainly composed of CrO3. Segregation and depletion for solutions were also discussed by oxidation diffusion mechanisms.
Hong- ying SUN,Qiang HE,Zhang- jian ZHOU,Man WANG,Guang- ming ZHANG,Shao- fu LI. Effects of Solution Depletion and Segregation Oxidation on Morphology of Modified 310 Austenitic Stainless Steel[J]. �й������ڿ���, 2016, 23(4): 393-400.
Hong- ying SUN,Qiang HE,Zhang- jian ZHOU,Man WANG,Guang- ming ZHANG,Shao- fu LI. Effects of Solution Depletion and Segregation Oxidation on Morphology of Modified 310 Austenitic Stainless Steel. Chinese Journal of Iron and Steel, 2016, 23(4): 393-400.
2016, Vol. 23 
