Separation of phosphorus from dephosphorization slag modified by alkaline oxide by HCl leaching
Hui Kong1, Chuan-ming Du2
1 School of Metallurgical Engineering, Anhui University of Technology, Ma’anshan 243002, Anhui, China 2 School of Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China
Separation of phosphorus from dephosphorization slag modified by alkaline oxide by HCl leaching
Hui Kong1, Chuan-ming Du2
1 School of Metallurgical Engineering, Anhui University of Technology, Ma’anshan 243002, Anhui, China 2 School of Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China
摘要 Dephosphorization slag is one of the bulk solid wastes generated from steelmaking. If P is effectively removed from dephosphorization slag, a phosphate source which can substitute for phosphate rocks is obtained; meanwhile, the tailings can be reutilized as a feedstock in steel plant. To realize the integrated utilization of dephosphorization slag, selective leaching was applied for removing the P-bearing mineral phase from dephosphorization slag. Alkaline oxide was added as the slag modifier and HCl was selected as the acid lixiviant. The P selective leaching from dephosphorization slags modified by Na2O or K2O was studied at different pH values. By modification, the mass fraction of P in the 2CaO∙SiO2–3CaO∙P2O5 phase increased, indicating that it was in favor of P2O5 enrichment. As the Na2O or K2O content increased, the P leaching ratio from slag increased at pH 4, reaching about 80%, and that of Fe was nearly zero. Na2O and K2O modification played a similar role in enhancing the P leaching. The effect of alkaline oxide modification became weak at pH 3, and the slag without modification also realized a good P selective leaching in the HCl solution. To facilitate the P removal, the leaching of Fe from dephosphorization slag needs to be restrained.
Abstract：Dephosphorization slag is one of the bulk solid wastes generated from steelmaking. If P is effectively removed from dephosphorization slag, a phosphate source which can substitute for phosphate rocks is obtained; meanwhile, the tailings can be reutilized as a feedstock in steel plant. To realize the integrated utilization of dephosphorization slag, selective leaching was applied for removing the P-bearing mineral phase from dephosphorization slag. Alkaline oxide was added as the slag modifier and HCl was selected as the acid lixiviant. The P selective leaching from dephosphorization slags modified by Na2O or K2O was studied at different pH values. By modification, the mass fraction of P in the 2CaO∙SiO2–3CaO∙P2O5 phase increased, indicating that it was in favor of P2O5 enrichment. As the Na2O or K2O content increased, the P leaching ratio from slag increased at pH 4, reaching about 80%, and that of Fe was nearly zero. Na2O and K2O modification played a similar role in enhancing the P leaching. The effect of alkaline oxide modification became weak at pH 3, and the slag without modification also realized a good P selective leaching in the HCl solution. To facilitate the P removal, the leaching of Fe from dephosphorization slag needs to be restrained.
Hui Kong,Chuan-ming Du. Separation of phosphorus from dephosphorization slag modified by alkaline oxide by HCl leaching[J]. Journal of Iron and Steel Research International, 2023, 30(4): 687-696.
2023, Vol. 30 
