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Microstructure and magnetic properties of Fe81.3Si4B13Cu1.7 nanocrystalline alloys with minor Nb addition |
Xiang-cheng Ren1 . Yan-hui Li1 . Xing-jie Jia1 . Zhi-yong Qiu1 . Guo-qiang Xie2 . Wei Zhang1 |
1 Key Laboratory of Solidification Control and Digital Preparation Technology Liaoning Province, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China 2 School of Materials Science and Engineering, Harbin Institute of Technology Shenzhen,Shenzhen 518055, Guangdong, China |
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Abstract The amorphous matrix containing dispersive high number density (Nd) ��-Fe nuclei with average grain sizes (D) of 4.3�C6.2 nm were formed in the melt-spun Fe81.3-xSi4B13Cu1.7Nbx (x = 0�C2) alloys, and the Nd and D values reduce with increasing the Nb content. The fine nanocrystalline structure with ��-Fe grains in size of 14.0�C21.6 nm was obtained for the alloys after annealing, which show high saturation magnetic flux density of 1.60�C1.77 T and low coercivity (Hc) of 7.1�C16.2 A/m. Addition of minor Nb significantly expands the optimum annealing temperature range for obtaining low Hc, while coarsens the ��-Fe grains, leading to a slight increase in the Hc. The mechanism for the effect of Cu and Nb elements on the structure and magnetic properties was discussed in terms of the formation and growth of the ��-Fe nuclei of the alloys.
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Received: 05 December 2017
Published: 23 October 2018
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