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Tuning magnetocaloric effect of Gd�CEr�CAl�CCo metallic glass through crystallization |
Qiang Luo1 . Jun Shen1 |
1 School of Materials Science and Engineering, Tongji University, Shanghai 201804, China |
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Abstract Abstract: Magnetization and magnetocaloric effect (MCE) of as-cast Gd-based bulk metallic glass (BMG) Gd24Er32Co24Al20 and the crystallized samples were investigated. Reentrant-spin-glass-like behavior was observed in the as-cast sample. With increasing degree of crystallization, the magnetic frustration increased, which could be seen from the increased divergence of the zero-.eld-cooled and .eld-cooled magnetization behavior (i.e., the spin-glass-like freezing behavior). The Curie temperature and magnetization decreased after crystallization. The as-cast BMG showed a large maximum magnetic entropy change (-DSm)of9.9(J kg -1K -1) under a .eld change of 5 T, which was comparable with that of Gd metal and other Gd-based metallic glasses. The maximum -DSm reduced to 6.7 (J kg -1K -1) after crystallization, which was still superior to the Fe-/Co-based amorphous alloys. Their good MCE combining with high electrical resistivity, outstanding mechanical properties, tunable nature, and suf.ciently soft magnetic property makes them to be attractive candidate for magnetic refrigerants in the low-temperature range.
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Received: 07 February 2018
Published: 23 October 2018
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