The chromium-bearing titanomagnetite ore will turn to be the important raw material for blast furnace process in Panxi area, China. The reduction behavior of Cr₂O₃ between CaO–SiO₂–Al₂O₃–TiO₂–Cr₂O₃ and Fe–C systems was investigated. The effect of TiO₂ content in the slag system on the reduction of Cr₂O₃, TiO₂, and SiO₂ and the consumption of C in hot metal was investigated by both theoretical calculation and physical experiment. The theoretical calculation results reveal that higher reduction temperature promotes the reduction of Cr and Ti, while high basicity and TiO₂ content have little influence on the reduction of chromium but significantly influence the reduction of Ti. The smelting reduction experiment results show that the content of Cr in hot metal significantly increases with extending the reduction time and decreases with the increase in TiO₂ content. However, the content of Ti in hot metal significantly increases as the TiO₂ increases, reaching 0.073, 0.085, 0.107, and 0.121 wt.% for 5, 10, 15, and 20 wt.% of TiO₂ input, respectively. Kinetic studies proved that the reduction of Cr₂O₃ was a first-order reaction. The addition of TiO₂ inhibited the reduction of Cr₂O₃ and resulted in the decrease in reaction rate constant.