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Evaluating oxygen level of Si-deoxidized H13 die steel using ferrous oxide-containing slags at 1873 K |
Shao-ying Li1,2, Bin Li1,2, Xing-ming Zhao3, Xiao-jun Xi1,2, Sheng-chao Duan1,2, Jing Guo1,2, Han-jie Guo1,2 |
1 School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
2 Beijing Key Laboratory of Special Melting and Preparation of High-End Metal Materials, Beijing 100083, China
3 Shandong Tianwu Forming Technology Co., Ltd., Liaocheng 252024, Shandong, China |
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Abstract Laboratory-scale experiments were conducted to investigate the oxygen content of Si-deoxidized H13 die steel by ferrous oxide-containing slags at 1873 K. The calculation of thermodynamics and kinetics was performed to evaluate the oxygen level of molten steel through [Si]–[O] equilibrium and [Fe]–[O] equilibrium. The results show that as the FeO content in slag increases, the oxygen content with [Si]–[O] equilibrium (w([O])Si) has almost no change. When both the oxygen content with [Fe]–[O] equilibrium (w([O])Fe) and w([O])Si are less than the initial oxygen content in steel (w(TO)i), the oxygen content in steel (w([O])) depends on the higher value between w([O])Si and w([O])Fe. In the case of w([O])Fe> w(TO)i, the value of w([O]) is the difference between the sum of w(TO)i and w([O])Si and the value of w([O])Fe. The reaction rates of [Si]–[O] and [Fe]–[O] are equal, which are controlled by the mass transfer of oxygen in molten steel. The evaluation method is suitable to the whole smelting process of Si-deoxidized H13 die steel.
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Received: 26 May 2020
Published: 25 August 2021
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Cite this article: |
Shao-ying Li,Bin Li,Xing-ming Zhao, et al. Evaluating oxygen level of Si-deoxidized H13 die steel using ferrous oxide-containing slags at 1873 K[J]. Journal of Iron and Steel Research International, 2021, 28(8): 978-989.
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