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Thermodynamics and industrial practice of non-metallic inclusions formation during solidification and cooling of Q195 hot rolled strip |
ZHANG Xu-hui1, WANG Ju-jin2, KONG Xiang-yu1, MENG Run-ze1, REN Ying2 |
1. Tangshan Xinbaotai Iron and Steel Co., Ltd., Tangshan 064000, Hebei, China; 2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China |
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Abstract In order to control the transformation of non-metallic inclusions in Q195 steel during solidification and cooling, the transformation of inclusions in practical production process was studied by ASPEX automatic scanning electron microscope, and the thermodynamic principle of the transformation was calculated by FactSage software. The results show that inclusions in molten steel of Si-Mn-Al deoxidized Q195 hot rolled strip are mainly SiO2-MnO-Al2O3. There is a sharp increase in sulfide inclusions in bloom after solidification and cooling. An increase of SiO2 and an decrease of MnO in oxide inclusions can also be detected. The composition of inclusions in steel have obvious corresponding relationship with the size of inclusions, which is that the content of Al2O3 in inclusions increase with diameter of inclusion, while the content of SiO2 decreases. As the size of the inclusion in bloom decreases, content of sulfides and SiO2 in oxide inclusions have a dramatic increase. Thermodynamic calculation by FactSage indicates that SiO2, Mn2Al4Si5O18 and MnS precipitate during solidification and cooling of steel, and the size of precipitated phase is generally small, which results in the increase of content of SiO2 and MnS in small size inclusions. Thermodynamic theoretical calculation can explain the transformation of inclusion composition duiring solidification and cooling process.
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Received: 24 September 2019
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[1] |
王举金, 任英, 张立峰,等. Q195 带钢中硅铝酸盐夹杂物的来源与控制[C]//2019 年(第二十一届) 全国炼钢学术会议文集. 陕西西安: 中国金属学会炼钢分会, 2019.
|
[2] |
ZHANG Li-feng,Brian G Thomas.State of the art in evaluation and control of steel cleanliness[J]. ISIJ international, 2003, 43(3): 271.
|
[3] |
ZHANG Li-feng,Brian G Thomas.State of the art in the control of inclusions during steel ingot casting[J]. Metallurgical and Materials Transactions:B, 2006, 37(5): 733.
|
[4] |
张立峰, 李燕龙, 任英. 钢中非金属夹杂物的相关基础研究 (Ι)——非稳态浇铸中的大颗粒夹杂物及夹杂物的形核, 长大, 运动, 去除和捕捉[J]. 钢铁, 2013, 48(11): 1.
|
[5] |
KANG Youn-Bae,Hae-Geon Lee.Inclusions chemistry for Mn/Si deoxidized steels: thermodynamic predictions and experimental confirmations[J]. ISIJ international,2004,44(6):1006.
|
[6] |
Hideaki Suito,Ryo Inoue.Thermodynamics on control of inclusions composition in ultraclean steels[J]. ISIJ international, 1996, 36(5): 528.
|
[7] |
REN Ying,ZHANG Li-feng,P Chris Pistorius. Transformation of oxide inclusions in type 304 stainless steels during heat treatment[J]. Metallurgical and Materials Transactions:B,2017,48:1.
|
[8] |
WANG J,LI W,REN Y,et al.Thermodynamic and kinetic analysis for transformation of oxide inclusions in solid 304 stainless steels[J]. Steel Research International,2019.
|
[9] |
YANG W,GUO C,LI C,et al.Transformation of inclusions in pipeline steels during solidification and cooling[J]. Metallurgical and Materials Transactions:B,2017,48(5): 2267.
|
[10] |
YANG Wen,GUO Chang-bo,ZHANG Li-feng,et al.Evolution of oxide inclusions in Si-Mn killed steels during hot-rolling process[J]. Metallurgical and Materials Transactions:B, 2017, 48(5): 2717.
|
[11] |
Marc Wintz,Manuel Bobadilla,Jean Lehmann,et al.Experimental study and modeling of the precipitation of non-metallic inclusions during solidification of steel[J]. ISIJ international, 1995, 35(6): 715.
|
[12] |
CHU Yan-ping, LI Wei-fu, REN Ying,et al.Transformation of inclusions in linepipe steels during heat treatment[J]. Metallurgical and Materials Transactions: B, 2019: 1.
|
[13] |
张立峰. 连铸过程夹杂物控制[J]. 连铸, 2016, 41(1): 5.
|
[14] |
许建飞, 刘志远, 王重君,等. 板坯连铸过程夹杂物控制研究[J]. 连铸, 2018, 43(6): 61.
|
[15] |
李吉东, 许庆太, 孙中强,等. SPHE连铸坯夹杂物的检验和分析[J]. 连铸, 2012(6): 36.
|
[16] |
李涛, 孙大利, 安杰. 汽车齿轮钢8620RH连铸坯中夹杂物研究[J]. 连铸, 2017, 42(3): 39.
|
[17] |
亓伟伟, 杨旭, 亓昌秋. 船板钢铸坯中大型夹杂物的分析[J]. 连铸, 2014(6): 46.
|
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