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2009年, 第16卷, 第3期 刊出日期:2009-06-15
  

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    Metallurgy and Metal Working
  • SHEN Feng-man,LI Guang-sen,DING Zhi-min,MU Lin
    中国钢铁期刊网. 2009, 16(3): 1-5.
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    The melting characteristics and wettability of the binding phase in high basicity sinter were studied. By changing nCaO∶nFe2O3 (molar ratio of CaO to Fe2O3) as well as the percentage of MgO, SiO2, and Al2O3, the melting characteristics and wettability of the binding phase were discussed. The results indicated that the characteristic melting temperature was the lowest and wettability was the best at nCaO∶nFe2O3=1∶1 (without addition); the addition of MgO increased the characteristic melting temperature and contact angles; when the percentage of SiO2 or Al2O3 was 3%, the characteristic melting temperature was the lowest, whereas the contact angles increased with an increase in SiO2 and Al2O3 contents.
  • TIAN Zhi-hong,LI Ben-hai,ZHANG Xiao-ming,JIANG Zhong-hang
    中国钢铁期刊网. 2009, 16(3): 6-14.
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    A study on the production of low phosphorus steel by double slag operation in 210 t converter was carried out. A phosphorus content of less than 0. 005% (mass percent) was obtained before tapping. About 80% phosphorus could be removed by the first slag after 5 min. High Fe3+ content and high basicity in the first slag were in favor of dephosphorization. On the other hand, Fe3+ content had less effect on dephosphorization during second slag treatment. In the second slag period, the fraction of dephosphorization increased with the increase of basicity up to a basicity of 6. Further increase of basicity of the second slag had very little effect on dephosphorization. The tapping temperature had great impact on dephosphorization. It was impossible to get phosphorus less that 0. 005% when the tapping temperature was higher than 1 943 K. The optimum operation conditions were suggested. On the basis of these conditions, the amount of the second slag and the effect of the remaining first slag were estimated.
  • WANG Shi-jun,PENG Jun,,DONG Yuan-chi,LIU Li-xia,ZHOU Yun,CHEN Er-bao
    中国钢铁期刊网. 2009, 16(3): 15-19.
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    The solubility of nitrogen in Fe-C-B-N system was measured at 1 758 K, and the computational model on activity (action concentration) of nitrogen and boron was established based on phase diagram and the coexistence theory about metal melt structure model. Comparing the computed results with the experimental results, satisfactory conclusion can be obtained. The result shows that BN and B4C can exist in Fe-C-B-N molten metal at high temperature, which consequently restrains the nitrogen removal from the melt. However, B4C content is extremely low. Before graphite is precipitated, the influence of carbon on activity of nitrogen in melt is higher in ternary system than in binary system; however, this effect is contrary to that after graphite is precipitated.
  • ZHAO Ke-wen,,ZENG Jian-hua,WANG Xin-hua
    中国钢铁期刊网. 2009, 16(3): 20-26.
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    Inclusion has an important effect on quality of high speed rail steel. In consideration of the lower acceptance percentage of the inclusion and its constraint against the requirement for large scale production of 350 km/h high speed rail steel in Panzhihua Iron and Steel (Group) Co, the technology of nonmetallic inclusion control for 350 km/h high speed rail steel was studied. An optimized model of the argon-blowing in ladle furnace (LF), the control of the components of the ladle slag, and the technique of calcium treatment for the molten steel was brought forward. Using the researched technology, the removal ratio of the inclusion was increased and the components, distribution, and shape of the inclusion in the rail steel were changed, which resulted in a reduction in the average total oxygen content to 10. 17×10-6 and an increase in the comprehensive acceptance percentage of the nonmetallic inclusion from 48. 21% to 98. 1%. Test has shown that this metallurgical technology can meet the requirement for large scale production of 350 km/h high speed steel in Panzhihua Iron and Steel (Group) Co.
  • CUI Miao,CHEN Hai-geng,XU Li,WU Bin
    中国钢铁期刊网. 2009, 16(3): 27-31.
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    Modified mathematical models based on imaginary plane zone method in reheating furnace were developed in which non-gray radiation properties of gas were considered, and the Newton′s method and the finite difference method were adopted. Effects of productivity, fuel consumption, fuel-air ratio, calorific value of fuel and inserting depth of thermocouple on total heat exchange factor along the length of reheating furnace were investigated. The results show that total heat exchange factor increases with productivity or inserting depth of thermocouple, and it decreases when fuel consumption, fuel-air ratio or calorific value of fuel increases. The results are valuable for dynamical compensation of total heat exchange factor for online control mathematical models in reheating furnace.
  • Material
  • Havva Kazdal Zeytin,Ceylan Kubilay,Hüseyin Aydin,Ali Aslan Ebrinc,Bilal Aydemir
    中国钢铁期刊网. 2009, 16(3): 32-36.
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    Ductile cast irons are used as high temperature materials in internal combustion engines, because they are microstructurally stable at high operating temperatures. SiMo granular graphite cast irons contain Fe2MoC and M6C carbide precipitates due to their higher concentration of both silicon and molybdenum. The microstructure of these cast irons consists of carbides dispersed within the ferrite matrix. The microstructural change and the crack formation mechanism in manifolds produced from SiMo ductile iron are studied. Chemical analysis, optical and scanning electron microscope studies have been completed and evaluated.
  • LIU Zhong-li,CHEN Xiang,LI Yan-xiang,HU Kai-hua
    中国钢铁期刊网. 2009, 16(3): 37-42.
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    High boron iron-based alloy, a new kind of wear-resistant material was developed, and its microstructure and mechanical properties were studied. Moreover, the modification with V, Ti and RE-Mg was carried out as well. The results indicate that the high boron iron-based alloy comprises a dendritic matrix and interdendritic eutectic borides under as-cast condition. The matrix is made up of fine pearlite, and the eutectic boride has a crystal structure of M2B (M represents Fe, Cr or Mn). The boride has a microhardness of HV 1 425 and is distributed in the form of continuous network, which is detrimental to the toughness of high boron iron-based alloy. Nevertheless, high boron iron-based alloy has a higher toughness than that of white cast iron, which is attributed to the matrix that is made up of lath-type martensite with high toughness. In order to increase the toughness further, V, Ti and RE-Mg were adopted to improve the morphology of boride. The results indicate that after modification the matrix grain is decreased in size by half, and the size of boride is also decreased, moreover, it is distributed more even though it is still continuous. After heat treatment, the boride network is break up and results in the further improvement of toughness of high boron iron-based alloy.
  • LI Zhuang
    中国钢铁期刊网. 2009, 16(3): 43-48.
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    Thermomechanical controlled processing (TMCP) of low carbon cold heading steel in different austenite conditions were conducted by a laboratory hot rolling mill. Effect of various processing parameters on the mechanical properties of the steel was investigated. The results showed that the mechanical properties of the low carbon cold heading steel could be significantly improved by TMCP without heat treatment. The improvement of mechanical properties can be attributed mainly to the ferrite grain refinement due to low temperature rolling. In the experiments the better ultimate tensile strength and ductility are obtained by lowering finishing cooling temperature within the temperature range from 650 ℃ to 550 ℃ since the interlamellar space in pearlite colonies become smaller. Good mechanical properties can be obtained in a proper austenite condition and thermomechanical processing parameter. The ferrite morphology has a more pronounced effect on the mechanical behavior than refinement of the microstructure. It is possible to realize the replacement of medium-carbon by low-carbon for 490 MPa grade cold heading steel with TMCP.
  • XIAO Gui-zhi,DI Hong-shuang
    中国钢铁期刊网. 2009, 16(3): 49-54.
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    To investigate the effect of heat treatment on mechanical properties and delayed fracture resistance of high strength steel, 30MnSi prestressed concrete (PC) steel bars are quenched and tempered. Tensile results show that, after 950 ℃ quenching and about 430 ℃ tempering, 30MnSi PC steel bars have superior mechanical properties and delayed fracture resistance. Microstructural observation shows that 30MnSi steel bar is mainly composed of fine tempered sorbite (troostite) with carbide distributed along the lath martensite boundaries. It can be concluded that thermal refining is an effective way to improve mechanical properties and delayed fracture resistance of 30MnSi PC steel bar.
  • Oguzhan Kelestemur,M Halidun Kelestemur,Servet Yildiz
    中国钢铁期刊网. 2009, 16(3): 55-63.
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    SAE1010 structural carbon steel, which has a low cost price and wide range of use in the construction industry, has been studied as dual phase (DP) steel subjected to appropriate heat treatment, and its mechanical properties have been investigated under various tempering conditions. Intercritical annealing heat treatment has been applied to the reinforcing steel in order to obtain DP steels with different martensite volume fraction. In addition, these DP steels have been tempered at 200, 300 and 400 ℃ for 45 min and then cooled to the room temperature. Mechanical properties such as tensile strength, yield strength, reduction in cross-sectional area, total elongation, resilience modulus and toughness have been examined. Furthermore, fractographic examination has been done with scanning electron microscope (SEM) as well as metallographic examination of the steels. As a result of this study, it is found that mechanical properties of DP steel have changed according to the hardness and ratio of martensite phase. In addition, tensile strength, yield strength and resilience modulus of the steels have been reduced. In contrast, the total elongation, reduction of the cross-sectional area and toughness have been increased.
  • MA Qing-long,WANG Dong-cheng,LIU Hong-min,LU Hai-ming
    中国钢铁期刊网. 2009, 16(3): 64-67.
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    The tensile properties of steel after temper rolling are affected by the reduction; low-Si Al-killed sheet steel was taken to study the effect of temper rolling on the tensile properties. The results indicate that the yield strength first decreases with the increase of reduction, and then increases. The relationship between the yield strength and the reduction can be expressed using quadratic function. The tensile strength increases with the increase of the reduction, while the total elongation decreases with the increase of the reduction, and the relationship between them and the reduction can be expressed using power function. Under the same condition, the results also indicate that the yield strength and tensile strength of steels across the rolling direction are all larger than those along the rolling direction; there is no obvious distinction between the total elongation along the rolling direction and that across the rolling direction.
  • FANG Fang,YONG Qi-long,YANG Cai-fu,SU Hang
    中国钢铁期刊网. 2009, 16(3): 68-72.
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    Three steels containing 0. 05%C-0. 1%V-0. 01%N (steel V-LN), 0. 05%C-0. 1%V-0. 02%N (steel V-HN), and 0. 05%C-0. 1%V-0. 02%N-0. 01%Ti (steel V-HN-Ti), which were all essentially vanadium microalloyed steels, were subjected to simulating the microstructure of a coarse grained heat affected zone (CGHAZ). The process involved reheating to 1 350 ℃, rapid cooling to room temperature, and varying the welding heat input from 15 kJ/cm to 54 kJ/cm, including four cooling rates of t8/5 equal to 7. 5 s, 20 s, 40 s, 100 s, and the relationship of heat input to t8/5 was calculated by Quiksim software. The microstructure and precipitation of vanadium and titanium carbon nitrides are studied. The results indicate that the microstructure consists of granular bainite and some side plate ferrite in the grain boundary when the steels are produced with the highest heat input. As the heat input decreased, numerous polygonal ferrites and grain boundary ferrites appeared, and the size apparently increased. When the steel contained high nitrogen, it was considerably easier to form martensite-austenite island, which was even worse for the toughness and other properties of the steel. For the limitation of cooling time, vanadium carbon nitrides could not precipitate sufficiently, but as titanium was added, the unmelted or precipitated TiN on cooling absorbed some fraction of nitrogen in the matrix and made more precipitate positions for the round V(C, N), and thus several useful round particles could be seen in titanium-contained steel, and most of them were around TiN. By this experiment, we can conclude that with the help of titanium, nitrogen-enhanced steel had a better prior austenite grain size, was considerably easier to precipitate, reduced free nitrogen in the matrix effectively, and provided a very effective mechanism for restriction grain growth in the HAZ.
  • MI Guo-fa,LIU Yan-lei,ZHANG Bin,FU Xiu-qin,ZHANG Hong,SONG Guo-xiang
    中国钢铁期刊网. 2009, 16(3): 73-77.
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    Wear property of material plays a key role in the service time of workpiece. A major objective in the development of new wheel materials is to improve the wear performance. The wear property of B and B+ grade cast steel materials was reported. The results showed that B+ grade cast steel material exhibited better wear property than the B grade material. Carbon content related to the hardness match was the principal factor affecting the wear properties.
  • QI Yong-tian,ZOU Zeng-da
    中国钢铁期刊网. 2009, 16(3): 78-82.
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    Fe-based layer with Ti(CxN1-x) particulates on Adamite roller surface was obtained by a 5 kW traverse-flowing CO2 laser cladding technology. The microstructures of the layer were detected by optical microscopy (OM), X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microscopy analysis (EMPA). The tests of wear resistance was carried out on the test machine. It was seen that a good metallurgical bonding between the coating and the substrate was achieved. The microstructure contains bulky dendritic crystal and small size Ti(CxN1-x) grains that are uniformly distributed in the solid solution matrix. The wear tests showed that the laser coating provided an excellent wear resistance property at room temperature.
  • DONG Xiao-ping,YANG Li-ying,ZHANG Yang-huan,WANG Xin-lin
    中国钢铁期刊网. 2009, 16(3): 83-88.
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    As the alloy with the most suitable Ni/(La+Mg) ratio has higher capacity and good cycle stability, the effects of Ni/(La+Mg) ratios on the electrochemical performances of the La0. 80Mg0. 20Nix (x=3. 5 to 5. 0) alloys have been investigated to find the most suitable Ni/(La+Mg) ratio. The results of XRD and SEM observations show that the phase composition of the alloys varies with different Ni/(La+Mg) ratios. When Ni/(La+Mg) is not more than 4. 25, all the alloys contain LaNi5 and (La, Mg)2Ni7 phases, in addition, the LaMg and (La, Mg)Ni3 phases exist in the x=3. 5 and 3. 75 alloys, respectively. The LaMg2Ni9 phase exists in the x=4. 25 alloy. There are the LaNi5 and LaMg2Ni9 phases in the x=4. 5, 4. 75, and 5. 0 alloys. The phase abundance and cell volume change with different Ni content. When the Ni/(La+Mg) ratio is not more than 4. 25, the alloys possess excellent activation capability, however, the activation capabilities of the alloys decrease with a further increase in the Ni/(La+Mg) ratio. With increasing the Ni/(La+Mg) ratio, the maximum discharge capacities, the medium voltages, and the cycle stabilities of the alloys first increase and then decrease. When the Ni/(La+Mg) ratio is 3. 75, the corresponding alloy has the maximum discharge capacity among all the alloys. However, the cycle stability of the Ni/(La+Mg)=4. 0 alloy is better than that of the others.
  • SONG Lai-zhou,YANG Zhi-yong
    中国钢铁期刊网. 2009, 16(3): 89-94.
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    The Ni-P/TiO2 composite film on sintered NdFeB permanent magnet was investigated by X-ray diffraction (XRD), environmental scanning electron microscopy (ESEM), and energy dispersive X-ray spectrometer (EDX). The corrosion resistance of Ni-P/TiO2 film coated on NdFeB magnet, in 0. 5 mol/L NaCl solution, was studied by potentiodynamic polarization, salt spray test and electrochemical impedance spectroscopy (EIS) techniques. The self-corrosion current density (icorr) and the polarization resistance (Rp) of Ni-P/TiO2 film are 0. 22 μA/cm2 (about 14% of that of Ni-P coating), and 120 kΩ·cm2 (about 2 times of that of Ni-P coating), respectively. The anti-salt spray time of Ni-P/TiO2 film is about 2. 5 times of that of the Ni-P coating. The results indicate that Ni-P/TiO2 film has a better corrosion resistance than Ni-P coating, and the composite film increases the corrosion resistance of NdFeB magnet markedly.