欢迎访问《钢铁研究学报(英文版)》官方网站!今天是

2010年, 第17卷, 第5期 刊出日期:2010-05-15
  

  • 全选
    |
    工艺
  • CHEN Jian-bin;CHen Qi-zhong;et al
    中国钢铁期刊网. 2010, 17(5): 1-1.
    摘要 ( )   可视化   收藏
    Nitrogen desorption in molten stainless steel for AISI 304 and 316 has been investigated by immersion argon blowing through an immersed alumina nozzle with 3mm in I.D.. Some kinetic parameter such as reaction order, rate constant and apparent activation energy of nitrogen desorption reaction for AISI 304 and 316 have been given out. Results show that (1) the correlation coefficients of regression straight line of second order reaction for nitrogen desorption reaction for stainless steel AISI 304 and 316 are most close to one. (2) Nitrogen desorption reaction from molten stainless steel for AISI 304 and 316 is the second order reaction. The rate constant at 1550℃ and 1580℃ for AISI 316 is respectively 0.08407 and 0.8237 wt%-1·min-1. The rate constant at 1550℃ for AISI 304 is 0.4166 wt%-1·min-1. (3) The apparent activation energy Ea of nitrogen desorption reaction for AISI 316 is 2136.47 kJ·mol-1. This huge value of apparent activation energy evidences that the nitrogen desorption reaction has a complex and multistep reaction mechanism. (4) The rate of nitrogen desorption reaction from molten stainless steel is mixed controlling by desorbing reaction of diatomic molecule nitrogen or monatomic nitrogen from molten metal at the gas-metal interface and the mass transfer in molten metal.
  • YUE Qiang;ZOU Zong-shu;et al
    中国钢铁期刊网. 2010, 17(5): 6-6.
    摘要 ( )   可视化   收藏
    The mechanism of inclusion aggregation in liquid steel in swirling flow tundish is analyzed by applying the theory of flocculation which was developed in the field of colloid engineering. The gas bridge forces due to the micro bubbles on hydrophobic inclusion surfaces were considered responsible for the inclusion collision and agglomeration, which can avoid the aggregation to breakup. The quantity of micro bubbles on hydrophobic inclusion particle is more than that on hydrophilic one. The trend of forming gas bridges between micro bubbles on particles is strong in the course of collision. The liquid film on hydrophobic particles is easy to break during collision process. Hydrophobic particles are liable to aggregate in collision. According to the analysis of forces on a non-metallic inclusion particle in swirling chamber, the chance of inclusion collision and aggregation can be improved by the centripetal force. Hydrophobic particles in water are liable to aggregate in collision. Hydrophilic particles in water are dispersed although collision happens. The wettabiliy can be changed by changing solid-liquid interface tension. The non-metallic inclusion removal in swirling flow tundish is studied. It shows that, under certain turbulent conditions, the particle concentration and the wettability between particles and liquid steel are the main factors to induce collision and aggregation.
  • YU Xiong;WEN Guang-hua;et al
    中国钢铁期刊网. 2010, 17(5): 11-11.
    摘要 ( )   可视化   收藏
    Due to its high content in the Al-TRIP steel, [Al] reacts with (SiO2) in the mold slag during the casting process, which results in the increase of w(Al2O3)/w(SiO2) ratio and the Al2O3 content, respectively, the characteristic of heat transfer through the slag film is then changed, which effects the smooth operation of the continuous casting process. In this paper, the mold slag simulator was used to study the change tendency of the heat flux density through slag film and the results were discussed, at the same time, the crystals in the 15# slag were characterized by BSE and XRD. The results obtained show that:(i) Heat flux density decreases with the increase of w(Al2O3)/w(SiO2) ratio; (ii) Heat flux density increases with the increase of Li2O and/or B2O3 content in the mold slag which contain 30% Al2O3; (iii) Compared with the heat flux density of common slag of peritectic steel, an appropriated mold slag contain 4% B2O3 and 4% Li2O is designed. The heat flux density is 0.645MW•m-2 when w(Al2O3)/w(SiO2)=1.46. (iv) In the equilibrium state, mold slag used for Al-TRIP steel precipitates CaF2 crystals.
  • CAI Xiao-hui;ZHANG Dian-hua;et al
    中国钢铁期刊网. 2010, 17(5): 17-17.
    摘要 ( )   可视化   收藏
    Based on the finite difference method, the factors affecting the temperature distribution along the thickness of plate during cooling process were analyzed. They include heat of transformation, heat conduction coefficient, specific heat, carbon content, cooling time, plate thickness and water flow. These factors form the basis of cooling specifications. In order to ensure the temperature distribution homogenous along the thickness, some cooling strategies, such as, interval cooling, zonal arrangement of header, were applied on line. The on-line results showed that the finite difference method can correct simulate the cooling process and that the structure permanence of the steel improved greatly.
  • TAN Ming-hao;LI Shu-jiang;et al
    中国钢铁期刊网. 2010, 17(5): 23-23.
    摘要 ( )   可视化   收藏
    The use of computer simulation techniques in the control system design of the laminar cooling process in a hot mill can significantly reduce the development cost while ensuring maximum production safety. The case-based modelling strategy that the authors proposed was implemented in a software package. The functional structure of the software package was discussed in detail. The interfaces and functions of the software package were introduced. The results of industrial experiments can be directly visualized in the software package, allowing accurate and instant comparison of the model predictions with real measurements. The software package provides the simulation platform for research into advanced modelling and control strategies of the laminar cooling process in a hot rolling mill.
  • FU Li-Jun;DONG Xiang-huai;et al
    中国钢铁期刊网. 2010, 17(5): 28-33.
    摘要 ( )   可视化   收藏
    In the traditional one-step formulations using shell elements, the computations of the curvature variation and bending stiffness matrix are simplified by omitting the rotational DOFs on the basis of initial flat blank and fully known final configuration. They are highly efficient but not suitable either for the forming processes with non-flat initial configurations, or for one-step forward and multi-step analyses. Thus a one-step formulation based on the rotation-free BST (Basic Shell Triangular) element is presented here. In this formulation, the following improvements are made: 1) the curvature variation can be calculated exactly and efficiently resorting to a patch of four elements without rotational DOFs, which makes the formulation suitable for non-flat initial configurations, one-step and multi-step forward or inverse analyses, 2) The penalty method, instead of traditional sliding constraint, is employed to treat contacts in the forming processes, which makes it possible to inspect some deformation defects such as wrinkling et al directly. To verify the improved formulation, a program has been developed, and the bending process of a rectangular tube is simulated, with particular attentions paid on cross-sectional distortion. The numerical results of the one-step simulation agree with those of incremental analysis and experimental values.
  • 材料
  • LI Qun;WANG Tian-sheng;et al
    中国钢铁期刊网. 2010, 17(5): 34-37.
    摘要 ( )   可视化   收藏
    Difference in warm deformation was investigated for 0.45C, 0.79C and 1.26C steels with martensite starting structure, using the Gleeble 3500 thermal-mechanical simulator. The temperature range was 873-973 K, and the strain rate was varied between 0.1 and 0.001 s-1. The results showed the decrease of deformation resistance with increasing carbon content. The peak stress of 1.26C steel decreased 16.2% compared with 0.45C steel under the same conditions. The effect of increasing carbon content on the activation energy of deformation, the Z value and the deformation resistance was analyzed. The phenomenon might be attributed to the weakening effect of solid solution strengthening outweighing precipitation strengthening.
  • ZHANG Han;BAI Bing-zhe;et al
    中国钢铁期刊网. 2010, 17(5): 38-43.
    摘要 ( )   可视化   收藏
    A new Mn series oil quenching super strong bainitic steel was developed on the basis of the alloy system of the original Mn series air cooling bainitic steel. The mechanical properties of the new steel are well combined while precious alloy elements and complicated technologies are not needed for its production. Experimental results show that: bainite/martensite(B/M) dual phase microstructure can be obtained within a very wide cooling rate range and bainite microstructure exists even when the cooling rate reaches as fast as 60oC/s; the hardenability of the steel is better than that of 40CrNiMo and 42CrMo; the round bar made of the steel with the diameter of 250mm, which goes through tempering at 350oC after oil quenching, exhibits its central mechanical properties as follows: σb=1550MPa, σ0.2=1270MPa, δ5=15%, aku=95J/cm2 (at room temperature).
  • A. Nouri;H Saghafian;Sh Kheirandish
    中国钢铁期刊网. 2010, 17(5): 44-44.
    摘要 ( )   可视化   收藏
    Steels of constant manganese and carbon contents with 0.34-2.26 wt. % silicon content were cast. The as-cast steels were then hot rolled at 1100°C in five passes to reduce the cast ingot thickness from 80 to 4 mm, air cooled to room temperature and cold rolled to 2 mm thickness. Dual-phase microstructures with different the volume fraction of martensite were obtained through the intercritical annealing of the steels at different temperatures for 15 min followed by water quenching. In addition of intercritical annealing temperature, silicon content also altered the volume fraction of martensite in dual-phase steels. The partitioning of manganese in dual-phase silicon steels were investigated using energy-dispersive X-ray spectrometry (EDS). The partitioning coefficient, defined as the ratio of the amounts of alloying element in the austenite to that in the adjacent ferrite, for manganese increased with increasing intercritical annealing temperature and silicon content of steels. It was also shown that the solubility of manganese in ferrite and austenite decreased with increasing intercritical temperature. The results were discussed by the diffusivity and the solubility of manganese in ferrite and austenite present in dual-phase silicon steels.
  • G. Magudeeswaran
    中国钢铁期刊网. 2010, 17(5): 51-56.
    摘要 ( )   可视化   收藏
    Quenched and tempered (Q&T) steels are prone to hydrogen induced cracking in the HAZ after welding. Austenitic stainless steel (ASS) welding consumables are traditionally used for welding of high hardness Q&T steels as they have higher solubility for hydrogen. The use of stainless steel consumables for a non stainless steel base metal is not economical. In recent years, the developments of low hydrogen ferritic steel (LHF) consumables that contain no hygroscopic compounds are utilized for welding of Q&T steels. The armour grade Q&T steel joints fabricated using LHF filler exhibited superior joint efficiency due to preferential ferrite microstructure in the welds and also they offered required resistance to HIC. However, the combat vehicles used in military operations will be required to operate under a wide range of road conditions ranging from first class to cross country. Structural components in combat vehicles are subjected to dynamic loading with high strain rates during operation. Stress loadings within the vehicle hull of these vehicles are expected to fluctuate considerably and structural cracking especially in welds during the service life of these vehicles can lead to catastrophic failures. Under these conditions fracture behaviour of high strain rate sensitive structural steels can be better understood by dynamic fracture toughness (K1d). Hence, an attempt was made in this paper to study dynamic fracture toughness (K1d) of the armour grade Q&T steel and their welds fabricated using LHF consumables. The dynamic fracture toughness (K1d) of the armour grade Q&T steel and their welds are comparable with each other.
  • LI Xing-gang;YAN Qing-zhi;et al
    中国钢铁期刊网. 2010, 17(5): 57-62.
    摘要 ( )   可视化   收藏
    Ferritic/martensitic steels with 9-12 wt%Cr are favored candidates for fuel cladding tube and in-core applications for construction of supercritical water cooled reactor. 9Cr-3WVTiTaN reduced activation ferritic/martensitic steel, designated as China Nuclear Steel-I (CNS-I), is patterned after T91 steel. The idea of low activation material and microalloy technology were introduced into the design of the steel. A characterization program is being performed to determine the relevant mechanical and physical metallurgical properties in order to qualify it for fuel cladding and in-core applications in supercritical water cooled reactor. The hardening, tempering and transformation behavior of CNS-I steel was investigated. The steel has advantages in tensile properties at elevated temperature relative to zircaloy that has been widespread applied as cladding material in conventional light water reactors. CNS-I steel exhibits comparable tensile properties and impact toughness to T91 steel which exhibites availability in the present fission reactors and fast breeder reactor but includes undesired elements such as molybdenum and niobium for reduced activation.
  • TAN Shu-ping;WANG Zhen-hua;et al
    中国钢铁期刊网. 2010, 17(5): 63-68.
    摘要 ( )   可视化   收藏
    Abstract: The precipitation characteristics and effect on strengthening mechanism of Cu-rich phases during short-time and long-time aging in the Super 304H steels with different Cu contents were investigated by the use of X-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscopy (TEM). The results show that the size of Cu-rich phase particles increases, the distance of Cu-rich phase particles decreases and the density of Cu-rich phases increases with the increase of Cu content during short-time aging (~ 800 h) at 650℃ in the Super 304H steels. During long-time aging (>2000 h) at 650℃, Cu-rich phases precipitate sufficiently and the strengthening effect of Cu-rich phases is preferable in the Super 304H steel with 4% Cu. The strengthening effect of Cu-rich phases in the Super 304H steels with 2.2 % Cu or 5 % Cu is weaker than that with 4% Cu during long-time aging (>2000 h).
  • GUO Jin-hua;GAO Zhen;NI Xiao-jun;et al
    中国钢铁期刊网. 2010, 17(5): 69-69.
    摘要 ( )   可视化   收藏
    Fe55Ni2Cr12Mo10B6C13Y2,Fe55Cu2Cr12Mo10B6C13Y2 and Fe55Nb2Cr12Mo10B6C13Y2 alloys with diameter of 4mm were produced by copper mold casting. The role of alloying additions (Ni, Cu or Nb) on corrosion resistance of Fe55Nb2Cr12Mo10B6C13Y2, Fe55Ni2Cr12Mo10B6C13Y2 and Fe55Cu2Cr12Mo10B6C13Y2 alloys were studied by polarization curves and electrochemical impedance spectroscopy (EIS). The results show that Fe55Ni2Cr12Mo10B6C13Y2 and Fe55Cu2Cr12Mo10B6C13Y2 alloys can be cast into bulk metallic glasses. Fe55Ni2Cr12Mo10B6C13Y2 and
  • TAO Peng;ZHANG Chi;YANG Zhi-gang;et al
    中国钢铁期刊网. 2010, 17(5): 74-78.
    摘要 ( )   可视化   收藏
    Transformation and coarsening of carbides in 2.25Cr-1Mo steel weld metal during tempering at 700 oC for different time intervals ranging from 1 to 150 h has been examined by transmission electron microscopy and scanning electron microscopy. M3C carbides were observed in the as-welded specimens and when tempered the precipitates were mainly composed of M3C, M7C3 and M23C6 carbides. A sequence for corresponding carbide transformation during tempering with initial precipitation of M3C and followed by M7C3 and M23C6 has been proposed. The precipitation of M7C3 with higher Cr content is the main factor contributing to the decrease of coarsening rate of precipitates after prolonged tempering. The decrease of hardness in the tempered specimens agreed well with the prediction of the weakening of precipitation strengthening due to the coarsening of carbides.