Asynchronous responses of mechanical and magnetic properties to structure relaxation for FeNbB bulk metallic glass

Zhi-kai Gao, . An-ding Wang,, . Ping-bo Chen . Cheng-liang Zhao, . Fu-shan Li . Ai-na He, . Chun-tao Chang, . Xin-min Wang, . Chain-tsuan Liu

钢铁研究学报(英文版) ›› 2018, Vol. 25 ›› Issue (6) : 637-643.

PDF(8397 KB)
欢迎访问《钢铁研究学报(英文版)》官方网站!今天是 2025年8月2日 星期六
PDF(8397 KB)
钢铁研究学报(英文版) ›› 2018, Vol. 25 ›› Issue (6) : 637-643.

Asynchronous responses of mechanical and magnetic properties to structure relaxation for FeNbB bulk metallic glass

  • Zhi-kai Gao1,2 . An-ding Wang2,3,4 . Ping-bo Chen2 . Cheng-liang Zhao2,3 . Fu-shan Li1 . Ai-na He2,3 . Chun-tao Chang2,3 . Xin-min Wang2,3 . Chain-tsuan Liu4
作者信息 +

Asynchronous responses of mechanical and magnetic properties to structure relaxation for FeNbB bulk metallic glass

  • Zhi-kai Gao1,2 . An-ding Wang2,3,4 . Ping-bo Chen2 . Cheng-liang Zhao2,3 . Fu-shan Li1 . Ai-na He2,3 . Chun-tao Chang2,3 . Xin-min Wang2,3 . Chain-tsuan Liu4
Author information +
文章历史 +

摘要

Abstract: Asynchronous responses of mechanical and magnetic properties to structure relaxation for the Fe71Nb6B23 bulk metallic glass were systematically investigated. It is interesting that this ternary alloy can combinedly exhibit outstanding magnetic and mechanical properties, especially good ductility, after optimally annealing in structure relaxation stage for eliminating the internal stress and homogenizing the microstructure. The alloy exhibits low coercive force of 1.6 A/m, high effective permeability of 15 9 103, high fracture strength of 4.2 GPa and good plastic strain of 1.8%. It is also found that responses of mechanical and magnetic properties to structure relaxation are asynchronous. The glass transition and crystallization will greatly deteriorate the magnetic and mechanical properties. Here we propose a physical picture and demonstrate that the primary structure factors determining magnetic and mechanical properties are different. This work will bring a promising material for application and a new perspective to study the effect of annealing-induced structure relaxation on mechanical and magnetic properties.

Abstract

Abstract: Asynchronous responses of mechanical and magnetic properties to structure relaxation for the Fe71Nb6B23 bulk metallic glass were systematically investigated. It is interesting that this ternary alloy can combinedly exhibit outstanding magnetic and mechanical properties, especially good ductility, after optimally annealing in structure relaxation stage for eliminating the internal stress and homogenizing the microstructure. The alloy exhibits low coercive force of 1.6 A/m, high effective permeability of 15 9 103, high fracture strength of 4.2 GPa and good plastic strain of 1.8%. It is also found that responses of mechanical and magnetic properties to structure relaxation are asynchronous. The glass transition and crystallization will greatly deteriorate the magnetic and mechanical properties. Here we propose a physical picture and demonstrate that the primary structure factors determining magnetic and mechanical properties are different. This work will bring a promising material for application and a new perspective to study the effect of annealing-induced structure relaxation on mechanical and magnetic properties.

关键词

Bulk metallic glass, Annealing, Mechanical property, Magnetic property, Structure relaxation

Key words

Bulk metallic glass, Annealing, Mechanical property, Magnetic property, Structure relaxation

图表

引用本文

导出引用
Zhikai Gao, Wang Anding, Pingbo Chen, . Asynchronous responses of mechanical and magnetic properties to structure relaxation for FeNbB bulk metallic glass[J]. 钢铁研究学报(英文版), 2018, 25(6): 637-643
ZHIKAI -Gao, ANDING -Wang, PINGBO -chen, et al. Asynchronous responses of mechanical and magnetic properties to structure relaxation for FeNbB bulk metallic glass[J]. Journal of Iron and Steel Research International, 2018, 25(6): 637-643

参考文献

[1]W.H. Wang, C. Dong, C.H. Shek.Bulk metallic glasses[J].Mater. Sci. Eng., R, 2004, 44(2-3):45-89
[2]W.F. Wu, Y. Li, C.A. Schuh.Strength, plasticity and brittleness of bulk metallic glasses under compression: statistical and geometric effects[J].Philos. Mag., 2008, 88(1):71-89
[3]A. Inoue, B.L. Shen, H. Koshiba, H. Kato, A.R. Yavari. Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties[J].Nat. Mater., 2003, 2(10):661-663
[4]C.J. Gilbert, R.O. Ritchie, W.L. Johnson, .Fracture toughness and fatigue-crack propagation in a Zr-Ti-Ni-Cu-Be bulk metallic glass[J].Appl. Phys. Lett., 1997, 71(4):476-478
[5]A.R. Yavari, J.J. Lewandowski, J. Eckert.Mechanical properties of bulk metallic glasses[J].Mrs Bull., 2007, 32(8):635-638
[6]D. Zander, B. Heisterkamp, I. Gallino, .Corrosion resistance of Cu-Zr-Al-Y and Zr-Cu-Ni-Al-Nb bulk metallic glasses[J].J. Alloys Compd., 2007, 434(suppl.):234-236
[7]W. Li, Y. Gao, H. Bei.On the correlation between microscopic structural heterogeneity and embrittlement behavior in metallic glasses[J].Sci. Rep., 2015, 5(14786):1-15
[8]A. Castellero, B. Moser, D.I. Uhlenhaut, F.H. Dalla Torre, J.F. Loeffler.Room-temperature creep and structural relaxation of Mg-Cu-Y metallic glasses[J].Acta Mater., 2008, 56(15):3777-3785
[9]L. Hu, Y. Yue.Secondary Relaxation in Metallic Glass Formers: Its Correlation with the Genuine Johari-Goldstein Relaxation[J].J. Phys. Chem. C, 2009, 113(33):15001-15006
[10]K.J. Laws, D. Granata, J.F. Loeffler.Alloy design strategies for sustained ductility in Mg-based amorphous alloys - Tackling structural relaxation[J].Acta Mater., 2016, 103(suppl.):735-745
[11]Y.C. Niu, X.F. Bian, W.M. Wang.Origin of ductile-brittle transition of amorphous Fe78Si9B13 ribbon during low temperature annealing[J].J. Non-Cryst. Solids, 2004, 341(1-3):40-45
[12]X.H. Xu, G. Wang, F.J. Ke, W.H. Wang.In situ observations on the fracture process of metallic glassy ribbons[J].Scr. Mater., 2008, 59(6):657-660
[13]C.A. Schuh, T.C. Hufnagel, U. Ramamurty.Overview No.144 - Mechanical behavior of amorphous alloys[J].Acta Mater., 2007, 55(12):4067-4109
[14]A. Makino, C. Chang, T. Kubota, A. Inoue.Soft magnetic Fe-Si-B-P-C bulk metallic glasses without any glass-forming metal elements[J].J. Alloys Compd., 2009, 483(1-2):616-619
[15]J. Zhang, C. Chang, A. Wang, B. Shen.Development of quaternary Fe-based bulk metallic glasses with high saturation magnetization above 1.6 T[J].J. Non-Cryst. Solids, 2012, 358(12-13):1443-1446
[16]M. Zhang, J. Li, F. Kong, J. Liu.Magnetic properties and magnetocaloric effect of FeCrNbYB metallic glasses with high glass-forming ability[J].Intermetallics, 2015, 59(suppl.):18-22
[17]J.H. Yao, J.Q. Wang, Y. Li.Ductile Fe–Nb–B bulk metallic glass with ultrahigh strength[J].Appl. Phys. Lett., 2008, 92(25):251906-1-251906-3
[18]O. Haruyama, K. Sugiyama, M. Sakurai, Y. Waseda.A local structure change of bulk Pd40Ni40P20 glass during full relaxation[J].J. Non-Cryst. Solids, 2007, 353(32-40):3053-3056
[19]A. Wang, C. Zhao, A. He, H. Men, C. Chang, X. Wang.Composition design of high Bs Fe-based amorphous alloys with good amorphous-forming ability[J].J. Alloys Compd., 2016, 656(suppl.):729-734
[20]X. Liang, A. He, A. Wang, J. Pang, C. Wang, C. Chang, K. Qiu, X. Wang, C.-T. Liu.Fe content dependence of magnetic properties and bending ductility of FeSiBPC amorphous alloy ribbons[J].J. Alloys Compd., 2017, 694(suppl.):1260-1264
[21]O. ?ivotsky, A. Hendrych, L. Klim?a, Y. Jirásková, J. Bur?ík, J.A.M. Gómez, D. Jani?kovi?.Surface microstructure and magnetic behavior in FeSiB amorphous ribbons from magneto-optical Kerr effect[J].J. Magn. Magn. Mater., 2012, 324(4):569-577
[22]Q. Hu, X.-R. Zeng, M.W. Fu.Characteristic free volumes of bulk metallic glasses: Measurement and their correlation with glass-forming ability[J].J. Appl. Phys., 2011, 109(5):053520-1-053520-5
[23]C. Zhao, A. Wang, A. He, S. Yue, C. Chang, X. Wang, R.-W. Li.Correlation between soft-magnetic properties and Tx1-Tc in high Bs FeCoSiBPC amorphous alloys, J. Alloys Compd. 659 (2016) 193-197.[J].J. Alloys Compd., 2016, 659(suppl.):193-197
[24]P. Denis, C.M. Meylan, C. Ebner, A.L. Greer, M. Zehetbauer, H.J. Fecht.Rejuvenation decreases shear band sliding velocity in Pt-based metallic glasses[J].Mater. Sci. Eng., A, 2017, 684(suppl.):517-523
[25]A. Inoue.Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta Mater., 2000, 48(1):279-306
[26]Q. Wang, S.T. Zhang, Y. Yang, Y.D. Dong, C.T. Liu, J. Lu.Unusual fast secondary relaxation in metallic glass[J].Nat Commun, 2015, 6(7876):1-6
[27]G.R. Garrett, M.D. Demetriou, M.E. Launey, W.L. Johnson.Origin of embrittlement in metallic glasses[J].Proc. Natl. Acad. Sci. U. S. A., 2016, 113(37):10257-10262

基金

The National Key Research and Development Program of China;the National Natural Science Foundation of China; Ningbo International Cooperation Projects

PDF(8397 KB)

6

Accesses

0

Citation

Detail

段落导航
相关文章

/