Influences of preparation techniques on glass-forming ability of Fe–P– B–Si–C amorphous alloys

Ji-jun Zhang,,, . Ya-qiang Dong, . Lu-yang Bie . Qiang Li . Jia-wei Li, . Xin-min Wang,

钢铁研究学报（英文版） ›› 2018, Vol. 25 ›› Issue (6) : 674-679.

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钢铁研究学报（英文版） ›› 2018, Vol. 25 ›› Issue (6) : 674-679.

Influences of preparation techniques on glass-forming ability of Fe–P– B–Si–C amorphous alloys

  • Ji-jun Zhang1,2,3,4 . Ya-qiang Dong1,2 . Lu-yang Bie4 . Qiang Li4 . Jia-wei Li1,2 . Xin-min Wang1,2
作者信息 +

Influences of preparation techniques on glass-forming ability of Fe–P– B–Si–C amorphous alloys

  • Ji-jun Zhang1,2,3,4 . Ya-qiang Dong1,2 . Lu-yang Bie4 . Qiang Li4 . Jia-wei Li1,2 . Xin-min Wang1,2
Author information +
文章历史 +

摘要

It has widely been accepted that the ultrahigh cooling rate is required for the glass formation of amorphous alloys. Here, the larger glass forming ability (GFA) of Fe76P5(B0.5Si0.3C0.2)19 amorphous alloy is achieved by water quenching at lower cooling rate under argon atmosphere. Cylindrical rods with diameters of 1 to 2 mm are prepared by water quenching without flux treatment, Cu-mold injection casting, and Cu-mold suction casting, respectively. The influences of the preparation techniques with different cooling rates on GFA, thermal property, and nucleation/growth behavior are examined. The critical diameter of the Fe76P5(B0.5Si0.3C0.2)19 amorphous alloys is 1.7 mm for water quenching while smaller than 1 mm for injection casting. Microstructure analysis indicates that the crystallization and solidification processes are quite different between the water-quenched and the injection casted rods. This finding provides fundamental understanding on the relationship between the cooling rate, techniques, and GFA of Fe-based amorphous alloys.

Abstract

It has widely been accepted that the ultrahigh cooling rate is required for the glass formation of amorphous alloys. Here, the larger glass forming ability (GFA) of Fe76P5(B0.5Si0.3C0.2)19 amorphous alloy is achieved by water quenching at lower cooling rate under argon atmosphere. Cylindrical rods with diameters of 1 to 2 mm are prepared by water quenching without flux treatment, Cu-mold injection casting, and Cu-mold suction casting, respectively. The influences of the preparation techniques with different cooling rates on GFA, thermal property, and nucleation/growth behavior are examined. The critical diameter of the Fe76P5(B0.5Si0.3C0.2)19 amorphous alloys is 1.7 mm for water quenching while smaller than 1 mm for injection casting. Microstructure analysis indicates that the crystallization and solidification processes are quite different between the water-quenched and the injection casted rods. This finding provides fundamental understanding on the relationship between the cooling rate, techniques, and GFA of Fe-based amorphous alloys.

关键词

Fe-based amorphous alloysPreparation techniquesGlass forming abilityCrystallization behaviors

Key words

Fe-based amorphous alloys Preparation techniques Glass forming ability Crystallization behaviors

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张继君, Yaqiang Dong, Luyang Bie, 等. Influences of preparation techniques on glass-forming ability of Fe–P– B–Si–C amorphous alloys[J]. 钢铁研究学报（英文版）, 2018, 25(6): 674-679
ZHANG Ji-Jun, YAQIANG -Dong, LUYANG -Bie, et al. Influences of preparation techniques on glass-forming ability of Fe–P– B–Si–C amorphous alloys[J]. Journal of Iron and Steel Research International, 2018, 25(6): 674-679

参考文献

[1]Yang, H. Liu, Y. Zhao, A. Inoue, K. Jiang, J. Huo, H. Ling, Q. Li, B. Shen, .Mechanical properties and structural features of novel Fe-based bulk metallic glasses with unprecedented plasticity[J].Sci. Rep., 2014, 4:6233-
[2] M.J. Duarte, J. Klemm, S. O. Klemm, K. J. J. Mayrhofer, M. Stratmann, S. Borodin, A. H. Romero, M. Madinehei, D. Crespo, J. Serrano, S. S. A. Gerstl, P. P. Choi, D. Raabe, F. U. Renner, Element-Resolved Corrosion Analysis of Stainless-Type Glass-Forming Steels, science 341 (2013) 372–376.
[3] F.Wang, A. Inoue, Y. Han, S. L. Zhu, F. L. Kong, E. Zanaeva, G. D. Liu, E. Shalaan, F. Al-Marzouki, A. Obaid, Soft magnetic Fe-Co-based amorphous alloys with extremely high saturation magnetization exceeding 1.9 T and low coercivity of 2 A/m, J. Alloys Compd 723 (2017) 376–384.
[4] C.Suryanarayana, A. Inoue, Iron-based bulk metallic glasses, Int. Mater. Rev. 58 (2013) 131–166.
[5] T.D. Shen, R. B. Schwarz, Bulk ferromagnetic glasses prepared by flux melting and water quenching, Appl. Phys. Lett. 75 (1999) 49–51.
[6] W.H. Wang, Roles of minor additions in formation and properties of bulk metallic glasses, Prog. Mater. Sci. 52 (2007) 540–596.
[7] A.Chrobak, V. Nosenko, G. Haneczok, L. Boichyshyn, B. Kotur, A. Bajorek, Effect of rare earth additions on magnetic properties of Fe82Nb2B14RE2 (RE= Y, Gd, Tb and Dy) amorphous alloys, Mater. Chem. Phys. 130 (2011) 603–608.
[8] W.H. Wang, M. X. Pan, D. Q. Zhao, Y. Hu, H. Y. Bai, Enhancement of the soft magnetic properties of FeCoZrMoWB bulk metallic glass by microalloying, J. Phys.: Condens. Matter. 16 (2004) 3719–3723.
[9] V.Ponnambalam, S. J. Poon, G. J. Shiflet, Fe–Mn–Cr–Mo–(Y, Ln)–C–B (Ln= Lanthanides) bulk metallic glasses as formable amorphous steel alloys, J. Mater. Res. 19 (2004) 3046–3052.
[10] H.Jian, W. Luo, S. Tao, M. Yan, Mechanical and magnetic properties of (Fe72Mo 4B24)100?xTbx (x= 4, 5, 6, 7at.%) bulk glassy alloys, J. Alloys Compd. 505 (2010) 315–318.
[11] S.L. Lin, S. F. Chen, J. K. Chen, Y. L. Lin, Formation and magnetic properties of Fe–Si–B–Dy amorphous alloy, Intermetallics 18 (2010) 1826–1828.
[12] T.Bitoh, A. Makino, A. Inoue, A. L. Greer, Large bulk soft magnetic [(Fe0.5Co0.5)0.75B0.2Si0.05]96Nb4 glassy alloy prepared by B2O3 flux melting and water quenching, Appl. Phys. Lett. 88, 182510 (2006).
[13] Z.P. Lu, C. T. Liu, W. D. Porter, Structural Amorphous Steels, Phys. Rev. Lett. 92 (2004) 245503–245506.
[14] Z.P. Lu, C. T. Liu, W. D. Porter, Role of yttrium in glass formation of Fe-based bulk metallic glasses, Appl. Phys. Lett. 83, 2581 (2003).
[15] B.L. Shen, M. Akiba, A. Inoue, A. Inoue, Excellent soft-ferromagnetic bulk glassy alloys with high saturation magnetization, Appl. Phys. Lett. 88, 131907 (2006).
[16] Z.Jiao, H. Li, Y. Wu, J. Gao, S. Wang, S. Yi, Effects of Mo additions on the glass-forming ability and magnetic properties of bulk amorphous Fe-C-Si-B-P-Mo alloys, Sci. China, Ser. G 53 (2010) 430–434.
[17] J.Wang, R. Li, N. Hua, L. Huang, T. Zhang, Ternary Fe–P–C bulk metallic glass with good soft-magnetic and mechanical properties, Scripta Mater. 65 (2011) 536–539.
[18] A.Makino, T. Kubota, C. T. Chang, M. Makabe, A. Inoue, FeSiBP Bulk Metallic Glasses with Unusual Combination of High Magnetization and High Glass-Forming Ability, Mater. Trans. 48 (2007) 3024–3027.
[19] Q.Li, J. Li, P. Gong, K. Yao, J. Gao, H. Li, Formation of bulk magnetic ternary Fe80P13C7 glassy alloy, Intermetallics (2012) 62–65.
[20] A.Makino, C. T. Chang, T. Kubota, A. Inoue, Soft magnetic Fe–Si–B–P–C bulk metallic glasses without any glass-forming metal elements, J. Alloys Comp. 483 (2009) 616–619.
[21] X.H. Lin, W. L. Johnson, Formation of Ti–Zr–Cu–Ni bulk metallic glasses, J. Appl. Phys. 78 (1995) 6514–6519.
[22] Q.Li, Numerical Calculation of the Cooling Rate in the J-Quenching Technique, Metall. Mater. Trans. B 40 (2009) 405–410.
[23] Q.Li, Formation of ferromagnetic bulk amorphous Fe40Ni40P14B6 alloys, Mater. Lett. 60 (2006) 3113–3117.
[24] Y.Q. Cheng, E. Ma, Atomic-level structure and structure–property relationship in metallic glasses, Prog. Mater. Sci. 56 (2011) 379–473.
[25] X.Hu, S. Ng, Y. Feng, Y. Li, Cooling-rate dependence of the density of Pd40Ni10Cu30P20 bulk metallic glass, Phys. Rev. B 64 (2001) 172201–172204.
[26] H.H. Liebermann, C. D. Graham Jrand, P. J. Flanders, Changes in Curie temperature, physical dimensions, and magnetic anisotropy during annealing of amorphous magnetic alloys, IEEE Trans. Magn. 13 (1977) 1541–1543.
[27] J.H. Martin, B. D. Yahata, J. M. Hundley, J. A. Mayer, T. A. Schaedler, T. M. Pollock, 3D printing of high-strength aluminium alloys, Nature 549 (2017) 365–369.
[28] Z.H. Zeng, M. J. Chen, W. W. Li, L. C. Zhou, X. Xue, Z. Zhang, Microstructure Design of Lightweight, Flexible, and High Electromagnetic Shielding Porous Multiwalled Carbon Nanotube/Polymer Composites, Small 1701388 (2017) 1–9.
[29] Z.P. Lu, C. T. Liu, A new glass-forming ability criterion for bulk metallic, Acta Mater. 50 (2002) 3501–3512
[30] C.Suryanarayana, A. Inoue, Bulk Metallic Glasses, first ed., CRC Press, Boca Raton, 2010.
[31] P.Tiberto, R. Piccin, N. Lupu, H. Chiriac, M. Baricco, Magnetic properties of Fe–Co-based bulk metallic glasses, J. Alloys Comp. 483 (2009) 608–612.
[32] D.A. Poter, K.E. Esterling, Phase transformations in metals and alloys, second ed., CRC Press, Boca Raton, 1992.
[33] A.Inoue, High-strength bulk amorphous alloys with low critical cooling rates, Mater. Trans., JIM 36 (1995) 866–875.
[34] M.A. Easton, D. Stjohn, Grain refinement of aluminum alloys: Part I. the nucleant and solute paradigms—a review of the literature, Metall. Mater. Trans. A 30 (1999) 1613–1623.

基金

National Key Research and Development Program of China;National Natural Science Foundation of China;Ningbo Municipal Nature Science Foundation

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