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2020年, 第27卷, 第5期 刊出日期:2020-05-25
  

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  • Qi-hang Liu, Shuang-ping Yang, Chen Wang, Yi-long Ji
    钢铁研究学报(英文版). 2020, 27(5): 489-499.
    https://doi.org/10.1007/s42243-020-00399-9
    摘要 ( )   可视化   收藏
    The pore structure of coke under CO2 atmosphere was investigated by the carbon solution-loss reaction experiment. The results show that the pore size distribution of coke gradually changes from dispersion to relative concentration with the increase in carbon loss rate, but it tends to be dispersed again in the late stage of the reaction, and the pore volume and specific surface area also increase first and then decrease with the increase in carbon loss rate. Scanning electron microscopy results show that the evolution of coke pores is from the formation of micropores to the expansion of micropores, and finally the micropore and mesopores collapse to form a large number of string holes. The chemical bonds and functional groups of different reacted cokes were analyzed by Fourier-transform infrared spectroscopy. Furthermore, the microstructure of reacted cokes was analyzed by optical microscopy, and then the ordering of the affinity of different microstructures with CO2 was given. The volume hypothesis which was the theory about energy size of comminution was adopted to analyze the degradation behavior of reacted cokes. The breakage energy of reacted cokes was calculated by volume hypothesis, and the power consumption coefficient CK of different reacted cokes was determined by drum experiment, and then the degradation behavior of reacted cokes under different power consumptions was predicted.
  • Cheng‑ming Ni, Hua‑wei Fan, Xu‑dong Wang, Man Yao
    钢铁研究学报(英文版). 2020, 27(5): 500-505.
    https://doi.org/10.1007/s42243-020-00364-6
    摘要 ( )   可视化   收藏
    Magnesium aluminate spinel (MgAl2O4) is widely used in steel metallurgy industry. Thermal conductivity at high temperature signifcantly infuences the cooling process of blast furnace and the heat preservation of steel converter. The efect of external (temperature) and internal (antisite defect and grain boundary) factors on the thermal conductivity of MgAl2O4 was studied with non-equilibrium molecular dynamics. The main factors afecting the thermal conductivity of MgAl2O4 were summarized. In the temperature range of 100–2000 K, the results showed that the thermal conductivity of MgAl2O4 changed from 11.54 to 4.95 W/(m K) with the increase in temperature and was relatively stable at the temperature above 1000 K. The thermal conductivity of MgAl2O4 declined frst and then rose with the increase in the antisite defects, and the minimum value was 6.95 W/(m K) at the inversion parameter i= 0.35. In addition, grain boundaries reduced the thermal conductivity of MgAl2O4 by 20%–30% at temperature below 1000 K comparing with the non-grain boundary system. The grain boundary rotation angle at temperature above 1000 K had less efect on the thermal conductivity than that below 1000 K. Present simulation scheme for thermal conductivity of MgAl2O4 can also be applied to the study of other nonmetallic ceramics.
  • Xiao-ping Ma, Dian-zhong Li
    钢铁研究学报(英文版). 2020, 27(5): 506-516.
    https://doi.org/10.1007/s42243-019-00311-0
    摘要 ( )   可视化   收藏
    The evolution of microstructures during the solidification of 20SiMn steel was investigated. The dominant role of coalescence was revealed by analyzing the quenched microstructures and the solute distribution. In the parameter range investigated, including the slow solidification, the fast solidification and the directional solidification, the coalescence can happen at multiple solidification stages and on multi-scales. During the directional solidification, the ternary and fourth dendritic arms coalesce into the secondary dendritic arms, and the secondary dendritic arms further coalesce to produce the cellular crystals. The cellular crystals become coarse through further coalescence. During the non-directional solidification, the initial microstructures are discrete crystals without the dendritic pattern. Both the dendritic arms and dendritic stems appearing in the later solidification stage are produced by the coalescence on multi-scales. The coalescence is more significant in the later solidification stage. The mechanism of coalescence is attributed to different melt compositions in different local domains and the reduction of the interface energy.
  • Teng Xu, Dong‑xiao Hou, Zheng‑nan Sun, Da‑wu Guo
    钢铁研究学报(英文版). 2020, 27(5): 517-527.
    https://doi.org/10.1007/s42243-020-00404-1
    摘要 ( )   可视化   收藏
    A dynamic rolling force model with multi-parametric excitations and multi-frequency external excitations caused by entry thickness fuctuation of strip was established. Based on the dynamic rolling force, a nonlinear vertical vibration model with multi-parametric excitations and multi-frequency external excitations was established. The method of multiple scales was used to solve the amplitude-frequency characteristic equation of primary resonance of the nonlinear vibration system of a rolling mill. The transition set and the topology structure of systematic global bifurcation were obtained by using the singularity theory. Finally, primary resonance characteristics of the system under entry thickness fuctuation of strip were analyzed by using actual parameters of the rolling mill. The global bifurcation curves with the change of amplitude and frequency of entry thickness fuctuation of strip were obtained by using numerical simulation, and many dynamic behaviors were found such as single-cycle motion, multi-cycle motion and chaotic motion, which can provide a theoretical reference for further restraining the vibration of a rolling mill.
  • Jie-bin Qi, Xin-xin Wang, Xiao-qiang Yan
    钢铁研究学报(英文版). 2020, 27(5): 528-536.
    https://doi.org/10.1007/s42243-020-00375-3
    摘要 ( )   可视化   收藏
    The rolling mill vibration is characterized by the coupling effects among mechanical, electrical, hydraulic and interfacial subsystems. The influence of the mill modulus control gain in automatic gauge control on the vibration in hot rolling mills was investigated. Firstly, an experiment related to the mill modulus control gain was carried out in the hot rolling mill process, and it was found that the rolling mill vibration increases with the mill modulus control gain. Then, based on the Sims rolling force method, the coupling dynamic model was established to explain this phenomenon. Finally, the influence of mill modulus control gain on the vibration was analyzed numerically on the basis of the coupling dynamic model. Moreover, the agreement between the experimental results and the simulation results was confirmed and the measure reducing the mill modulus control gain was obtained to relieve mill vibration.
  • Ming Lei, Wei‑jun Hui, Jiao‑jiao Wang, Yong‑jian Zhang, Xiao‑li Zhao
    钢铁研究学报(英文版). 2020, 27(5): 537-548.
    https://doi.org/10.1007/s42243-020-00400-5
    摘要 ( )   可视化   收藏
    The microstructure and mechanical properties of a V-microalloyed Al-containing medium-Mn steel after hot rolling and intercritical annealing (IA) are explored. The tested steel exhibits a fne multiphase microstructure consisting of bimodal sizes of ferrite and retained austenite plus considerable amount of fne VC and/or M3C precipitates. Physical–chemical phase analysis shows that about 71.0% of the total V is in VC phase and more than 93% of VC particles is less than 5 nm. The calculated precipitation strengthening values of VC are ~ 347 and ~ 234 MPa for the specimens intercritically annealed at 625 and 750 °C, respectively. An excellent combination of strength and ductility as high as ~ 50 GPa% and yield strength (YS) of 890 MPa was obtained at intercritical temperature (TIA) of 725 °C, although it does not correspond to the maximum precipitation strengthening of VC phase. Therefore, it is suggested that an optimization of TIA corresponding to both excellent combination of strength and ductility and high YS should be further explored through chemical composition and IA process optimization.
  • Xiao‑long Liang, Hui Wang, Qian‑fu Pan, Ji‑yun Zheng, Hui‑qun Liu, Rui‑qian Zhang, Yang Xu, Yu Xu, Dan‑qing Yi
    钢铁研究学报(英文版). 2020, 27(5): 549-565.
    https://doi.org/10.1007/s42243-020-00387-z
    摘要 ( )   可视化   收藏
    The efect of cold rolling and annealing on the microstructure and properties of an Fe–13Cr–4.5Al–2.2Mo–1.1Nb alloy was investigated. The results showed that the recrystallization rate increased with increasing annealing temperature and rolling reduction. Recrystallization kinetics was constructed based on Johnson–Mehl–Avrami–Kolmogorov equation. The apparent activation energies of recrystallization were 161.385, 144.770, and 95.362 kJ/mol for the samples with 30%, 50%, and 70% cold-rolling reduction, respectively. With the cold-rolling reduction increasing, the texture γ fber partly changed to <100>// ND. After annealing, γ fber of the alloy with 30% thickness reduction retained, the subgrains disappeared through merging, and the proportion of coincident site lattice grain boundaries increased and became more continuous. 30% cold-rolling reduction alloy annealed at 730 °C for 120 min not only possessed relatively high yield strength (YS) of ~ 730 MPa and ultimate tensile strength (UTS) of ~ 880 MPa, but also exhibited elongation of ~ 16% at room temperature. After annealing at 730 °C for 120 min, 70% cold-rolled alloy has fner and more uniform grain, with higher elongation of ~ 22%, YS of ~ 615 MPa and UTS of ~ 774 MPa. The mechanism of mechanical properties diference was explained according to Schmid factor analysis. These results provided an efective way for tuning strength and ductility of FeCrAl alloy.
  • Bo Xia, Xiao‑ming Zhang, R.D.K. Misra, Ming‑ming Pan, Yu‑qian Wang
    钢铁研究学报(英文版). 2020, 27(5): 566-576.
    https://doi.org/10.1007/s42243-020-00386-0
    摘要 ( )   可视化   收藏
    The infuences of cold-rolling deformation and annealing on the damping capacity of Fe–19Mn–8Cr alloy were investigated. It was observed that the cold-rolled Fe–19Mn–8Cr alloy with a reduction of 10% showed the relatively excellent damping capacity because of the relatively more ε-martensite and lower dislocation density, and the reduction of slopes of diferent damping curves increased along with increasing the cold-rolling reduction. Besides, the subsequent annealing process can further enhance the damping capacity. After 70% cold-rolling deformation, the austenite grain would grow up with the increase in the annealing temperature, which resulted in a signifcant change in the content and morphology of ε-martensite infuencing the damping capacity of the experimental steel. The damping capacity was optimum when annealed at 800 °C for 30 min, displaying that the size of ε-martensite has a vital infuence on the damping capacity of the experimental alloy. This study may enrich the fundamental knowledge about how to ameliorate the damping capacity of Fe–Mn–Cr damping steels.
  • Joong-ki Hwang
    钢铁研究学报(英文版). 2020, 27(5): 577-587.
    https://doi.org/10.1007/s42243-019-00328-5
    摘要 ( )   可视化   收藏
    The effect of drawing speed on temperature rise and microstructure distribution in twinning-induced plasticity (TWIP) steel during wire drawing has been investigated to improve drawability for wire rod applications. Although wire drawing process is performed at room temperature, heat is generated due to the plastic deformation and friction at the wire–die interface. The steel wires subjected to the low drawing speed (LD) of 0.5 m/min and the high drawing speed (HD) of 5.0 m/min were analyzed using the numerical simulation and electron backscatter diffraction techniques. Interestingly, the specimens subjected to the HD had a higher drawability by about 18% compared to the LD, which is totally different from the general behavior of plain carbon pearlitic steels. The LD wire had uniform temperature distribution along the radial direction during wire drawing. In contrast, the HD wire had a temperature gradient along the radial direction due to the higher frictional effect at surface: the minimum temperature of 58 C at center area and the maximum temperature of 143 C at surface area. The higher stacking fault energy of HD wire at the surface area due to the high temperature rise retarded twinning rate, resulting in the prevention of fast exhaustion in ductility in comparison with the LD wires since the earlier depletion of twins at surface area is known as the main reason for the fracture of TWIP steel during wire drawing. Consequently, HD process delayed the fracture strain of wire and increased the uniformity of microstructure and mechanical properties along the radial direction.
  • Bai‑song Li, Wen‑zhi Chen, Yu‑lin Zhao, Pei Zhao
    钢铁研究学报(英文版). 2020, 27(5): 588-597.
    https://doi.org/10.1007/s42243-020-00381-5
    摘要 ( )   可视化   收藏
    Inclusions have a great infuence on the quality of FeSiB amorphous ribbon. The evolution behavior of inclusions was analyzed. The results show that the spherical and elliptical inclusions, consisting of Al2O3 and SiO2, mainly come from industrial pure iron. Ellipsoidal inclusions of 20–30 μm in pure iron were removed by foatation during the smelting process, and spherical inclusions of 1–3 μm combined with deoxidized products in FeSiB melt form Al2O3·SiO2 and CaO·Al2O3·SiO2 inclusions. Some inclusions accumulated on the inner wall of the nozzle during the spraying process, and others fowed out of the nozzle and remained in FeSiB amorphous ribbon. By controlling the total oxygen content in industrial pure iron to 31 × 10?6, clogging on the inner wall of the nozzle can be reduced and the free surface smoothness of the amorphous ribbon can be improved.
  • E. Batuecas, C. Mayo, R. Díaz, F. J. Pérez
    钢铁研究学报(英文版). 2020, 27(5): 598-607.
    https://doi.org/10.1007/s42243-019-00339-2
    摘要 ( )   可视化   收藏
    The environmental behavior of four steels was analyzed. In the operation phase of concentrating solar power plants, steels withstand high temperature because of its contact with molten salts. Hence, choosing the steel type for the molten salt tanks remains a great challenge. In the cold tank, carbon steel is usually used although an approach with low chromium content steel is being studied for these applications. Likewise, in high temperature applications, such as hot store tank, austenitic stainless steel is the most frequent choice. However, ferritic steel is being considered as a promising material in these applications. As many researchers studied the steel technical properties without considering their environmental damages, this work aimed to introduce the environmental aspects into the material choice by using the life cycle assessment technique. On one hand, the results showed the environmental adequacy of carbon steel against low chromium content steel. On the other hand, the results obtained in those steels suitable in high temperature application revealed signifcant environmental benefts from the ferritic steel instead of the austenitic steel.
  • Jin‑long Lu, Guo‑guang Cheng, Meng Wu, Guo Yang, Ju‑long Che
    钢铁研究学报(英文版). 2020, 27(5): 608-616.
    https://doi.org/10.1007/s42243-019-00334-7
    摘要 ( )   可视化   收藏
    An unqualifed six-cylinder heavy truck crankshaft has been studied to investigate the cause of magnetic particle testing defects on the rod journals. Large-sized long-striped MnS inclusions are regarded as the major cause for the magnetic particle testing failure because they have been detected in situ under the magnetic particle indications. Through the observation of macroscopic structures of the rod journals and corresponding counterweight blocks, it is found that for the 1# and 3# rod journals, the center metal of the original hot-rolled bar has been extruded to the inboard edge of the rod journals and large-sized long-striped MnS inclusions are exposed on the surface after fash removal, leading to the failure of magnetic particle testing. As for the 2# rod journal, the center metal of the original bar has not been extruded to the surface and MnS inclusions on the rod journal surface are small in size, few in number, resulting in passing the magnetic particle testing. If the quality of the hot-rolled bars fuctuates, it is more recommended to apply magnetic particle testing on samples at the center of bars before forging to evaluate the severity of defects caused by the long-striped MnS inclusions for fear of the scrap of the fnal crankshafts.