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2021年, 第28卷, 第7期 刊出日期:2021-07-25
  

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  • Cui Wang, Long‑zhi Chen, Zheng‑jian Liu, Yang Li, Yao‑zu Wang, Ke‑xin Jiao
    钢铁研究学报(英文版). 2021, 28(7): 773-784.
    https://doi.org/10.1007/s42243-020-00453-6
    摘要 ( )   可视化   收藏
    At present, lots of municipal solid wastes (MSWs) are treated by incineration technology, which produces a large amount of fly ash that needs to be treated innocuously. A new method of using metallurgical shaft furnace to treat the MSW fly ash was thus proposed, and some research was done for this method. Firstly, the basic physical properties of MSW fly ash were analyzed, and then, the briquetting experiment and melting treatment of MSW fly ash were explored. In the process of briquet? ting, the influence of different factors (water content, cement content, forming pressure and curing time) on the compressive strength of the briquettes was studied. The results showed that with the increase in water content, cement content, forming pressure and curing time, the compressive strength of the briquettes increased correspondingly. However, the compressive strength of the briquettes showed a downward trend when these values exceeded a specific range. In the melting experiment, it was found that some heavy metals (such as Cr, Be and Ba) could be solidified in the slag when the fly ash was treated at 1450 °C for 50 min, and the leaching toxicity of heavy metals was lower than the landfill standard of waste in China. At the same time, the decomposition rate of dioxins in fly ash reached 99.66% after melting treatment.
  • Yun-hua Zhou, Ping Zhou, Jia-yun Dan, Hong-jie Yan, Dong-ling Wu
    钢铁研究学报(英文版). 2021, 28(7): 785-798.
    https://doi.org/10.1007/s42243-020-00556-0
    摘要 ( )   可视化   收藏
    Pulverized coal utilization in the blast furnace is decided by the particle flow and combustion behaviors in the raceway. Under a specific operating condition, these behaviors are directly related to the lance configuration in the upstream tuyere zone. Focusing on single straight lance, six types of single lance configurations were designed by assembling four parameters in different ways. These four parameters are the lance diameter, lance insertion angle, and the horizontal and vertical distances from the lance tip to the tuyere tip. With different lance configuration schemes applied, the pulverized coal combustion process in the lance–blowpipe–tuyere zone was simulated. The simulation results regarding particle diffusion and combustion behaviors were characterized by three indicators from the viewpoint of a coal plume. They are the plume diffusion angle, diffusion uniformity, and the average plume temperature at the tuyere outlet. To promote coal utilization, the values of these indicators under different configurations were analyzed, yielding two optimal configurations. The first one is to reduce the lance length immersed in the blowpipe–tuyere by 100 mm. The other is to increase the horizontal distance from the lance tip to the tuyere outlet by 50 mm, and the insertion angle to 11° with the lance tip located at the tuyere centerline. The findings can enhance the understanding of the influence mechanism of lance configuration on the coal utilization and provide guidelines for the design of new lance configurations.
  • Zhou Pu, Feng Zhou, Yue Sun, Ming Zhang, Bo-quan Li
    钢铁研究学报(英文版). 2021, 28(7): 799-808.
    https://doi.org/10.1007/s42243-020-00485-y
    摘要 ( )   可视化   收藏
    A mathematical model based on the computational fluid dynamics method, heat and mass transfer in porous media and the unreacted shrinking core model for the oxidation reaction of an individual magnetite pellet during preheating was established. The commercial software COMSOL Multiphysics was used to simulate the change in the oxidation degree of the pellet at different temperatures and oxygen concentrations, and the simulated results were compared with the experimental results. The model considered the influence of the exothermic heat of the reaction, and the enthalpy change was added to calculate the heat released by the oxidation. The results show that the oxidation rate on the surface of the pellet is much faster than that of the inside of the pellet. Temperature and oxygen concentration have great influence on the pellet oxidation model. Meanwhile, the exothermic calculation results show that there is a non-isothermal phenomenon inside the pellet, which leads to an increase in temperature inside the single pellet. Under the preheating condition of 873–1273 K (20% oxygen content), the heat released by the pellet oxidation reaction in a chain grate is 7.8 9 106–10.8 9 106 kJ/h, which is very large and needs to be considered in the magnetite pellet oxidation modelling.
  • Peng Han, Wen-long Zhan, Hao-bin Zhu, Lei Gao, Ying-chang Yu, Zhi-jun He, Jun-hong Zhang, Qing-hai Pang
    钢铁研究学报(英文版). 2021, 28(7): 809-817.
    https://doi.org/10.1007/s42243-021-00590-6
    摘要 ( )   可视化   收藏
    Pulverized coal injection technique has been widely used as a means of reducing coke consumption during ironmaking process. Owing to the increasing shortage of fossil fuels, other substitutes such as biomass, plastic, and waste tires have been studied in recent years. Coke breeze as one of the by-products of coking industries has been investigated as a substitute for partial pulverized coals. The combustion characteristics of blended fuels were estimated based on the flammability index C and the combustion characteristic index S. For different coke breeze additions, the combustion was divided into two stages, and the apparent kinetic parameters of the two stages were estimated by fitting the experimental data to the shrinkage reaction model and shrinkage diffusion model, respectively. Results showed that with the increase in coke breeze addition from 15% to 60%, the indexes C and S decrease, and the activation energy of the first stage remains almost constant, while that of the last stage increases from 16.89 up to 67.18 kJ mol-1, which indicates that adding coke breeze decreases the combustion efficiency of pulverized coal. Comparing the combustion and kinetic parameters under different coke breeze addition conditions, the optimal addition amount is suggested to be within 15%.
  • Yang Li, An-yuan Deng, Bin Yang, Hao Xu, En-gang Wang
    钢铁研究学报(英文版). 2021, 28(7): 818-829.
    https://doi.org/10.1007/s42243-020-00468-z
    摘要 ( )   可视化   收藏
    A new method was presented to inhibit bulging deformation and fluctuation of free surface by magnetic pressure. A research combined with numerical and experimental methods was conducted to investigate the feasibility and inhibition efficiency. The parameters including magnetic flux density, frequency and action area of magnetic pressure were analyzed. The results show that the method is feasible, and the bulged free surface is fully inhibited by the proper magnetic pressure. The inhibition efficiency increases as the increase in magnetic flux density and frequency, which shows a linear relationship with the magnetic flux density. The frequency has a great influence on the inhibition efficiency when the frequency is changed from 0.15 to 5.00 kHz. However, the frequency more than 5.00 kHz has little influence on the inhibition efficiency and is recommended in application process. When the ratio of the action area to the area of bulged free surface is 0.8, the best inhibition is achieved. However, when the ratio is more than 1.2, a distinct W-shaped free surface is observed. The surficial and internal flow is strengthened with proper magnetic pressure imposed. Moreover, under the action of magnetic pressure, the fluctuation amplitude of free surface decreases from 4.0 to 1.2 mm and the main fluctuation with frequency of 2.34 Hz is dispersed into several minor fluctuations with frequency of 0.4–4.3 Hz.
  • Jie Dong, Ying-ze Tian, Kai-xiang Peng
    钢铁研究学报(英文版). 2021, 28(7): 830-841.
    https://doi.org/10.1007/s42243-021-00611-4
    摘要 ( )   可视化   收藏
    The mechanical properties of hot rolled strip are the key index of product quality, and the soft sensing of them is an important decision basis for the control and optimization of hot rolling process. To solve the problem that it is difficult to measure the mechanical properties of hot rolled strip in time and accurately, a soft sensor based on ensemble local modeling was proposed. Firstly, outliers of process data are removed by local outlier factor. After standardization and transformation, normal data that can be used in the model are obtained. Next, in order to avoid redundant variables participating in modeling and reducing performance of models, feature selection was applied combing the mechanism of hot rolling process and mutual information among variables. Then, features of samples were extracted by supervised local preserving projection, and a prediction model was constructed by Gaussian process regression based on just-in-time learning (JITL). Other JITL-based models, such as support vector regression and gradient boosting regression tree models, keep all variables and make up for the lost information during dimension reduction. Finally, the soft sensor was developed by integrating individual models through stacking method. Superiority and reliability of proposed soft sensors were verified by actual process data from a real hot rolling process.
  • Tao Peng, Bin Yang, Gang Yang, Lu Wang, Zhi-hua Gong
    钢铁研究学报(英文版). 2021, 28(7): 842-852.
    https://doi.org/10.1007/s42243-020-00495-w
    摘要 ( )   可视化   收藏
    Microstructural change, stress rupture property, deformation and fracture mechanisms of Nimonic 105 superalloy at 750 °C have been studied. Experimental results showed that the stress rupture strength of the alloy at 750 °C for 105 h is about 200 MPa. c0 precipitates and M23C6 carbides grew gradually with prolonging the rupture time, while no significant change was observed in MC carbide morphology. After stress rupture test at 750 °C and 250 MPa for 23,341 h, a transition from spherical to cuboidal morphology of c0 precipitates was found, and nearly continuous chains of M23C6 carbides formed on the grain boundary. Orowan looping and strongly coupled dislocation pairs cutting and microtwinning were the dominant deformation mechanisms at 750 °C and 350–450 MPa, while the main deformation mode was Orowan looping at 750 °C and 250 MPa. The failure of the alloy was mainly attributed to the nucleation, growth and interlinkage of voids.
  • Fu-xing Yin, Xu-chen Li, Cui-xin Chen, Lin Zhao, Yun Peng, Zhi-ling Tian
    钢铁研究学报(英文版). 2021, 28(7): 853-861.
    https://doi.org/10.1007/s42243-020-00503-z
    摘要 ( )   可视化   收藏
    Fiber laser and gas metal arc hybrid welding of 440-MPa-grade high-strength marine steel was carried out at different welding speeds. The influence of welding speed on the microstructure and mechanical properties of weld metal was investigated. The weld-metal microstructure mainly consisted of pre-eutectoid ferrite, side-plate ferrite, acicular ferrite and lath bainite at a low welding speed. With the increase in welding speed, acicular ferrite and lath bainite were the dominant weld-metal microstructures. All samples failed at the base metal during tensile tests, which indicates that there is no soft zone in the hybrid welds. The welding speed had a significant effect on the impact toughness of the weld metal. The impact absorbed energy of the weld metal increased from 35 to 105 J with the increase in welding speed from 0.8 to 2.0 m/min. Large amounts of acicular ferrite and lath bainite were formed in the weld metal at a high welding speed, which resulted in an excellent impact toughness.
  • Ming-jun Zhong, Ke-lu Wang, Shi-qiang Lu, Xin Li, Xuan Zhou, Rui Feng
    钢铁研究学报(英文版). 2021, 28(7): 862-873.
    https://doi.org/10.1007/s42243-020-00531-9
    摘要 ( )   可视化   收藏
    The isothermal compression test for Ti–6Al–7Nb alloy was conducted by using Gleeble-3800 thermal simulator. The hot deformation behavior of Ti–6Al–7Nb alloy was investigated in the deformation temperature ranges of 940–1030 °C and the strain rate ranges of 0.001–10 s-1. Meanwhile, the activation energy of thermal deformation was computed. The results show that the flow stress of Ti–6Al–7Nb alloy increases with increasing the strain rate and decreasing the deformation temperature. The activation energy of thermal deformation for Ti–6Al–7Nb alloy is much greater than that for self-diffusion of a-Ti and b-Ti. Considering the influence of strain on flow stress, the strain-compensated Arrhenius constitutive model of Ti–6Al–7Nb alloy was established. The error analysis shows that the model has higher accuracy, and the correlation coefficient r and average absolute relative error are 0.9879 and 4.11%, respectively. The processing map (PM) of Ti–6Al–7Nb alloy was constructed by the dynamic materials model and Prasad instability criterion. According to PM and microstructural observation, it is found that the main form of instability zone is local flow, and the deformation mechanisms of the stable zone are mainly superplasticity and dynamic recrystallization. The optimal processing parameters of Ti–6Al–7Nb alloy are determined as follows: 960–995 °C/0.01–0.18 s-1 and 1000–1030 °C/0.001–0.01 s-1.
  • Hua Zhang, Yao-zha Lv, Chang Chen, Rong-sheng Chen, Yang Li, Hong-wei Ni, Feng Zheng
    钢铁研究学报(英文版). 2021, 28(7): 874-888.
    https://doi.org/10.1007/s42243-020-00548-0
    摘要 ( )   可视化   收藏
    A series of zinc oxide (ZnO) nanorods arrays with different morphologies are synthesized on stainless steel mesh via a facile electrodeposition method. The influences of electrodeposition parameters on the diameter, length, density and morphology of obtained ZnO nanorods are investigated systematically. The results indicate that the electrodeposition potential is the key factor for the morphology of the obtained ZnO nanorods, which further showed the effect on the photocatalytic property of the obtained samples. Meanwhile, the prepared ZnO nanorods array exhibits an excellent photocatalytic activity for methylene blue (MB) in ultraviolet light. The degradation efficiency for MB solution reaches 95.1% under the irradiation of ultraviolet light for 120 min. In addition, the photocatalytic property of the prepared ZnO nanorods can be extended to the visible light region after the modified with graphene oxide (GO). The obtained GO/ZnO composite also shows remarkable photocatalytic activity and photostability. The photodegradation efficiency for MB is 83.6%, and the catalytic performance retains 97.3% of its initial photocatalytic activity after five cycles.
  • Zhao-qiang Tan, Ulf Engstro¨m, Kun Li, Yong Liu
    钢铁研究学报(英文版). 2021, 28(7): 889-900.
    https://doi.org/10.1007/s42243-020-00549-z
    摘要 ( )   可视化   收藏
    During a powder metallurgy process such as sintering, the primary role played by the atmosphere in furnace is to prevent an excessive oxidation of powder compacts in case of the formation of oxides as residuals on powder surfaces. In particular, the adjustment of furnace atmosphere is the key to eliminate the phenomenon ‘‘decarburization’’ likely to occur in carbon-containing compacts. A continuous belt furnace was used to stabilize the potentials of carbon and oxygen in zones divided by sintering, delubrication, and cooling. Chromium and manganese, which are sensitive to oxygen, were added to improve mechanical properties in a cost-effective way. Powders of steel containing chromium were sintered in an atmosphere composed of CO, O2, and H2. The effects of atmosphere, lubricant, and graphite on oxidation (or reduction) and decarburization (or carburization) were investigated. Superior quality was achieved under the control of delubrication atmosphere. It is indicated that in a protective atmosphere, the chemical reactions occurring at various stages took remarkable effect on the quality of sintered compact. The potentials of oxygen and carbon in a continuous belt furnace were monitored and analyzed using an on-line thermal measuring unit consisting of thermocouple, oxygen probe, and carbon monoxide sensor. The avoidance of oxidation and decarburization promises desired microstructure and carbon content and satisfactory properties through the adjustment of technical parameters, e.g., the composition of gases in delubrication and various sintering zones, the rate of gas inlet, and cooling rate.
  • Xing‑fei Xie, Jing‑long Qu, Jin‑hui Du, Zhong‑nan Bi
    钢铁研究学报(英文版). 2021, 28(7): 901-909.
    https://doi.org/10.1007/s42243-020-00474-1
    摘要 ( )   可视化   收藏
    High-temperature fatigue property of Ni-based GH4720Li superalloy at 550 °C has been investigated at maximum strain from 0.8% to 1.1%. Microstructural characterization and oxidation behavior of superalloy during high-temperature fatigue have been analyzed by transmission electron microscopy and scanning transmission electron microscopy. The results show that a stable response following a slight cyclic hardening during initial cycles was revealed at the maximum strain from 0.8% to 1.0%. The stable response decreased with an increase in maximum strain. Continuous cyclic hardening was observed at the maximum strain of 1.1%. There is difference in dislocation substructures between primary γ′ precipitates and γ grains. Dislocation cell and mechanical twin were formed in the interior of primary γ′ precipitates and γ grains. The primary γ′ precipitate interface would migrate toward the interior of primary γ′ precipitates along twin boundaries, leading to instability of primary γ′ precipitates. The secondary γ′ depleted zone was distinctly generated near the surface due to the decomposition of secondary γ′ precipitates. The crack initiation and propagation during high-temperature fatigue were found inside the secondary γ′ depleted zone. The primary γ′ precipitates could effectively hinder the crack propagation. Al-rich oxide films (Al2O3) were initially produced at crack tips, because the rate of diffusion of Al was relatively higher than that of other elements at crack tips.
  • Zhi-hua Gong, Yuan-yuan Ma, Han-sheng Bao, Gang Yang
    钢铁研究学报(英文版). 2021, 28(7): 910-919.
    https://doi.org/10.1007/s42243-021-00562-w
    摘要 ( )   可视化   收藏
    The formation and properties of precipitates in wrought Ni-based superalloys with different W contents during long-term exposure to high temperatures were investigated. The scanning electron microscope, transmission electron microscope, and chemical phase analysis were used to investigate the formation and properties of precipitates. It is found that with increasing W content, the quantity and thermal stability of MC carbide in Ni-based superalloys increased, while the quantity of M23C6 carbides decreased. As the results show, W has a higher partition coefficient in c0- and c-matrix, and the addition of W promotes the precipitation of c0 phase. W content has no significant effect on the morphology, size, crystal structure, and coarsening rate of c0 precipitates. The influence of W content on high-temperature tensile and creep properties of the alloys was investigated. The results showed that W content has no obvious influence on the hightemperature yield strength, but the elongation and area reduction decreased significantly when the addition of W was more than 4 wt.%. Because of the similar volume fractions of c0 phase, the creep fracture strengths in the tested alloys with lower W concentrations were not significantly different after long-term exposure at 700 °C.