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2023年, 第30卷, 第11期 刊出日期:2023-11-25
  

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  • Shun-hu Zhang, Yi Zhang, Wei-gang Li, Wen-hao Tian, Yan Li, Li-zhi Che
    钢铁研究学报(英文版). 2023, 30(11): 2111-2121.
    https://doi.org/10.1007/s42243-023-01067-4
    摘要 ( )   可视化   收藏
    The rolling force model is the basis for reasonable selection of rolling equipment and optimization of rolling process, and the establishment of an accurate mathematical model as well as doing the corresponding parameter analysis has been the focus of research in this field for many years. Different modeling methods of the rolling force and their research progress were introduced, the main methods of which are the theoretical analysis, the finite element simulation, the artificial neural network modeling, the hybrid modeling of theory and neural network, as well as the hybrid modeling of finite element and neural network. Meanwhile, the application examples of rolling force models in thickness control, strip crown control, and schedule optimization were presented, and an outlook on the new directions of future development was made, including establishing new type of hybrid models, solving the black box problem, and realizing the multi-objective optimization accounting for some special requirements.
  • 论著
  • Shi-hong Peng, Hao Liu, Ze-zheng Sun, Chang-wei Li, Yue-lin Qin, Wei-qiang Liu, Guang Wang
    钢铁研究学报(英文版). 2023, 30(11): 2122-2132.
    https://doi.org/10.1007/s42243-023-00980-y
    摘要 ( )   可视化   收藏
    To achieve high-efficiency utilization of complex and unmanageable iron-containing minerals, the effects of oxygen enrichment on productivity, yield, flame front speed, exhaust gas peak temperature, and desulphurization reaction of the vanadium–titanium magnetite sintering process as well as sinter tumble index and mineralogy were clarified, with oxygen enrichment concentrations ranging from 21 to 29 vol.%. Results indicated that with increasing the oxygen enrichment concentration from 21 to 27 vol.%, the flame front speed increased from 30.3 to 40.0 mm min-1, the yield enhanced from 72% to 77%, and the productivity augmented from 1.83 to 2.67 t m-2 h-1; in the meantime, the tumble index was improved from 73.7% to 77.9%, and the exhaust gas peak temperature rose from 376.4 to 484.8 °C. The main reason for the improvement in sintering properties was the increased combustibility of fuels and the generation of proper liquid phase that improved the permeability of the packed bed. The improved sinter strength is mainly due to the increase in the phase fraction of silico-ferrites of calcium and aluminium. In addition, oxygen enrichment sintering could significantly increase the desulphurization level of vanadium–titanium magnetite sinter and the rate of desulphurization reaction during sintering process.
  • Teng-fei Qi, Hai-feng Li, Jun-jie Sun, Guo-jun Chen, Yong-jie Zhang
    钢铁研究学报(英文版). 2023, 30(11): 2133-2142.
    https://doi.org/10.1007/s42243-023-00983-9
    摘要 ( )   可视化   收藏
    The velocity distribution of sinter and gas in vertical cooling furnace (VCF) has an important influence on gas–solid heat transfer. Based on the slot model of single hopper in the VCF of Meishan Iron and Steel Co., Ltd., the velocity and particle size distribution of sinter and the velocity and pressure distribution of gas were studied using a computational fluid dynamics–discrete element method model to obtain the gas–solid flow rule in the VCF. The results showed that the velocity of sinter near the wall and the edge of vent cowl was lower than that in the rest of the same plane. Therefore, the rectangular section of the vertical cooling furnace can be divided into a quasi-static zone, a plug flow zone and a convergent flow zone according to the flow velocity of the sinter. The average particle size and the void fraction of sinter bed were distributed in ‘‘W’’ and ‘‘V’’ shape along the width direction, respectively. The distribution of gas velocity in the furnace cavity was uneven, and the high-velocity area gradually changed from the center to the edge of the furnace cavity with the rise of gas. Reducing the ratio of edge to center gas flow from 2.7:1 to 0.7:1 could improve the gas velocity, but could not change the gas velocity distribution. The gas velocity distribution was more affected by the average particle size distribution of the sinter bed. It was suggested that measures need be taken to adjust it to improve the gas velocity distribution in the VCF.
  • Jie Lei, Xu Gao, Jing-shu An, Guang-da Bao, Yu-qi Kong, Hong-ming Long
    钢铁研究学报(英文版). 2023, 30(11): 2143-2152.
    https://doi.org/10.1007/s42243-023-00994-6
    摘要 ( )   可视化   收藏
    The construction of blast furnace charge structure based on pellet and the development of short process from non-blast furnace to electric furnace will be an efficient way to accomplish ‘‘carbon peak, carbon neutral’’. Since drop strength is one of the most crucial quality indexes for green pellet, the crack detection in the collision process is an indispensable segment; however, the present crack determination is basically completed manually. Due to a series of problems including high labor intensity and poor detection conditions, it is urgent to develop an accurate, convenient and fast standardized method for drop strength detection. In view of the above issues, combined with plenty of experimental studies, it is found that whether rebound occurs after the collision of green ball can be used as the basis for judging if there are cracks on the surface, and the mechanism of this segment is explained by the energy conversion of collision process that the plastic deformation of the collision is a cumulative process. Each collision will cause a slight displacement of the iron ore particles; until the cumulative displacement exceeds the binding force between the particles, they will slip in a large range, that is, cracks will occur. The drop strength can be detected based on the drop-rebound mechanism determining crack generation during collision process by high-speed cameras, and the method is fully applicable to oxidized pellets with particle size of 8–16 mm though various pellet plasticities and masses increase the difficulty of bounce height monitoring. Based on the drop-rebound mechanism of green pellet, three methods for automatically detecting the drop strength are proposed, which are high-speed camera, photoelectric sensor and pressure sensor methods.
  • Zhi-yun Ji, Yi-fan Wang, Xiao-hui Fan, Gai-ge Zhao, Min Gan, Le-yun Tang, Yong Tu, Xiao-long Wang, Hao-xiang Zheng, Xu-ling Chen, Xiao-xian Huang, Zeng-qing Sun
    钢铁研究学报(英文版). 2023, 30(11): 2153-2162.
    https://doi.org/10.1007/s42243-023-00915-7
    摘要 ( )   可视化   收藏
    Iron ore sintering process is the main CO2 emission source throughout the integrate steelworks, which primarily comes from the combustion of solid fuels. Improving the combustion efficiency and reducing the solid fuel consumption are important ways to reduce the CO2 emission in the sintering process. Around the efficient combustion of fuel, the migration behavior and combustion characteristics of solid fuel in the granulation process were investigated. The results indicated that during the granulation process, fuel particles with size less than 0.5 mm mainly migrated into the granules with grain size of 1–3, 3–5 and 5–8 mm; fuel particles with size of 0.5–1 mm mainly migrated into granules of 1–3 mm; fuel particles with size of 1–3, 3–5 and 5–8 mm mainly entered the granules with the same grain size. With the increase in fuel particles grain size from - 0.5 to ? 8 mm, the combustion efficiency exhibited a firstly-increasing and then decreasing tendency, while the NOx exhibited a decreasing tendency. Potential reason can be described that finer fuel particles (- 1 mm) easily distributed in the outer layer of the granules, which combusted fiercely due to its larger specific surface area, leading to the development of incomplete combustion and the conversion of fuel nitrogen; the combustion efficiency of larger fuel particles was restricted by the inner diffusion of O2, which then contributed to the reduction of NOx under the inadequate combustion atmosphere.
  • Zi-yu Wang, Dong Han, Zheng-gen Liu, Man-sheng Chu, Yong-jie Zhang, Li-feng Zhang, Ji-wei Bao, Ming-yu Wang
    钢铁研究学报(英文版). 2023, 30(11): 2163-2172.
    https://doi.org/10.1007/s42243-023-01046-9
    摘要 ( )   可视化   收藏
    The release characteristics of CH4, H2, CO and CO2 from iron coke hot briquette (ICHB) during carbonization were studied. The results show that compared with briquette without iron ore, Fe3O4 can inhibit the release rate of H2 and promote the production of CO and CO2. In addition, when the heating rate increases from 3 to 7 °C/min, the release rates of CH4 and H2 increase, while the release rates of CO and CO2 first increase and then decrease. The carbonization process of ICHB was segmented, and corresponding kinetic analysis was carried out. The results show that the activation energy of Stage II and Stage IV is higher in the carbonization process of ICHB, and the active pyrolysis of coal and the reduction of iron ore occur in these two stages. In addition, the effect of heating rate on the kinetic parameters of ICHB carbonization process was investigated. It was found that when the heating rate increased, the reaction activation energy of Stage IV decreased first and then increased, which was consistent with the release law of CO and CO2. The analysis showed that the increase in heating rate leads to more reactions at higher temperatures, resulting in an increase in the release rate of some gases. In addition, thermal hysteresis can also cause some processes to fail to fully react at the end of heating. It is also found that the apparent activation energy and preexponential factor have kinetic compensation effect during the carbonization of ICHB.
  • Dian-yu E, Ling-yi Weng, Guang-wu Tang, Jing Li, Guang-chao Wei, Jia-xin Cui
    钢铁研究学报(英文版). 2023, 30(11): 2173-2185.
    https://doi.org/10.1007/s42243-023-00965-x
    摘要 ( )   可视化   收藏
    The methane combustion with hydrogen addition can effectively reduce carbon emissions in the iron and steel making industry, while the combustion mechanism is still poorly understood. The oxy-fuel combustion of methane with hydrogen addition in a 0.8 MW oxy-natural gas combustion experimental furnace was numerically studied to investigate six different combustion mechanisms. The results show that the 28-step chemical reaction mechanism is the optimal recommendation for the simulation balancing the numerical accuracy and computational expense. As the hydrogen enrichment increases in fuel, the highest flame temperature increases. Consequently, the chemical reaction accelerates with enlarging the peak of the highest flame temperature and intermediate OH radicals. When the hydrogen enrichment reaches 75 vol.%, the flame front is the farthest, and the flame high-temperature zone occupies the largest proportion corresponding to the most vigorous chemical reactions in the same oxygen supply.
  • Jian-zhao Shang, Bao-liang Liu, Kai Shi, Yang Liu, Yong-hao Mi, Wen-hao Fan, Yi-xian He
    钢铁研究学报(英文版). 2023, 30(11): 2186-2193.
    https://doi.org/10.1007/s42243-023-00938-0
    摘要 ( )   可视化   收藏
    MgO–C refractories with stainless steel fibers were prepared to investigate the effects of stainless steel fibers addition on the thermal shock resistance, oxidation resistance, and microstructure of MgO–C refractories, and the optimum amount of stainless steel fibers was determined. The results showed that adding stainless steel fiber in MgO–C refractories can increase flexural strength and thermal shock resistance, with an optimal addition of 2 wt.%, owing to the bridging effect and crack deflection toughening of stainless steel fibers inside the material. The formation of MgAl1.9Fe0.1O4 composite spinel, which was responsible for higher oxidation resistance, produced volume expansion and prevented the diffusion of oxygen. The strengthening mechanism is physical embedding at room temperature, while it is reaction bonding at high temperature.
  • He-nan Cui, Tao Li, Chen-guang Bai, Min Tan, Yu-lin Zhu
    钢铁研究学报(英文版). 2023, 30(11): 2194-2209.
    https://doi.org/10.1007/s42243-023-00949-x
    摘要 ( )   可视化   收藏
    The smelting reduction process of the ilmenite in an electric arc furnace (EAF) is a commonly used technology for producing titanium slag in the world. It has particular significance to analyze the velocity–temperature–electromagnetics multi-physical field in an EAF for improving its productivity and reducing energy consumption. A transient threedimensional mathematical model was developed to characterize the flow, heat transfer, and electromagnetic behavior in a titanium slag EAF. For describing the electromagnetic field and its effects on velocity and temperature distribution in the furnace, magnetohydrodynamic equations and conservation equations for mass, momentum, and energy were solved simultaneously by compiling the user-defined function program. The numerical model was verified by comparing with the literature data. The results indicate that the Lorentz force is the main driving force of the velocity and temperature distribution. Moreover, the influence of input current and location of electrodes on the multi-physical field distribution was also investigated. It is found that the appropriate range of input current and diameter of pitch circle are about 30,000 A and 3000–3500 mm, respectively. The mathematical model established can characterize the multi-physical field more accurately than before, which can provide valuable guidance for the operation improvement and design optimization of the EAF for producing titanium slag.
  • Wen-liang Dong, Guo-hui Ding, An-jun Xu, Ning Hao, Chen-xi Ji, Li-peng Ji, Hai-bo Li, Rong Zhu
    钢铁研究学报(英文版). 2023, 30(11): 2210-2218.
    https://doi.org/10.1007/s42243-023-00927-3
    摘要 ( )   可视化   收藏
    The performance of a recycling process for CO2 capture and utilization of exhaust gas in the steelmaking plant was reported. A facility capable of capturing CO2 at 3200 m3/h was established in the steelmaking plant, resulting in the CO2 production of 50,000 t/a. The CO2 concentration of the exhaust gas from the lime kiln increased from 25.0 to 99.8 vol.% using the comprehensive method of the pressure swing adsorption and cryogenic separation. The captured and purified CO2 was successfully applied in the converter process by the top blowing and bottom blowing. The utilization of CO2 was 3.5 m3/t through these two modes. After optimizing parameters of CO2–O2 mixed top blowing, the value of [C] 9 [O] and the content of TFe in slag were reduced by 1.33 9 10-4 and 1.27%, respectively, and the dephosphorization rate of the molten steel increased by 2.31%. For the CO2 bottom blowing, the [N] content in the molten steel was significantly reduced by 5.7 9 10-6.
  • Yun-long Su, Tao Jin, Yu Wang, Meng-jun Wang, Xiao-fang Shi, Li-zhong Chang
    钢铁研究学报(英文版). 2023, 30(11): 2219-2228.
    https://doi.org/10.1007/s42243-023-01035-y
    摘要 ( )   可视化   收藏
    For in-depth investigation of the effect of low-frequency and DC remelting on the cleanliness of electroslag ingot, laboratory experiments were performed with different current densities and slag compositions to analyze the variation of oxygen content and inclusions in electroslag ingots. When 70% CaF2 + 30% Al2O3 binary slag is used for remelting, the current density has different effects on the cleanliness of electroslag ingots with different power supply modes. At the power frequency of 2 Hz, the oxygen content and the number of inclusions in the electroslag ingot increase significantly with the increase in remelting current density. By contrast, when consumable electrode connected to cathode (DCSP) or consumable electrode connected to anode (DCRP) is employed, the current density has little influence on ingot cleanliness. At the same current density, DCSP remelting has a more adverse effect on ingot cleanliness compared with DCRP remelting. Compared with the use of 70% CaF2 + 30% Al2O3 binary slag, using 60% CaF2 + 20% Al2O3 + 20% CaO ternary slag significantly reduces the oxygen content and the number of inclusions in electroslag ingots, regardless of whether low-frequency or DC electroslag remelting occurs. The increase in oxygen and inclusions in electroslag ingot is caused by the electrolysis of Al2O3 in the slag pool. The increased inclusions mainly involve Al2O3 or Al-containing oxides with small size. As regards the power supply mode, low frequency, DCRP, and DCSP promote the electrolysis of Al2O3 in the slag pool. From the perspective of remelting slag composition, the slag with lower Al2O3 content can reduce the pollution of electrolysis on electroslag ingot.
  • Jia-chen Pang, Guo-yu Qian, Sheng Pang, Wen-hui Ma, Guo-guang Cheng
    钢铁研究学报(英文版). 2023, 30(11): 2229-2241.
    https://doi.org/10.1007/s42243-023-01042-z
    摘要 ( )   可视化   收藏
    To solve slag entrapment and casting slab defects in the process of stainless steel continuous casting, submerged entry nozzle (SEN) for slab casters operating at casting speed of 1 m/min was developed based on 3D numerical simulation and water modeling experiments by controlling the outlet shape and angle of original SEN with oval and 15° angle outlet under current industrial use. Mathematical simulations of fluid velocity at outlets with different shapes and angles of SENs have been carried out. The results showed that oval outlet with 5° and 15° angle led to asymmetric rotating flow pattern at outlet, as well as square outlet with 15° angle, but symmetric flow pattern formed at square outlet with 5° angle. The effect of these SENs on meniscus stability, flow field and slag entrapment behavior of stainless steel slab casting mold was further studied by water modeling experiments. The results showed that difficult floating fine droplets formed when the angle of outlet was 15° under the dual effect of vortex convection and shear force due to the strong swirling flow from outlet and rotating flow of outlet. However, outlet with 5° angle could lead to the formation of larger slag droplets, while the oval outlet with 5° angle could result in the scour to the mold wall. Thus, the square outlet with 5° angle was a relatively ideal solution for the submerged entry nozzle from the aspects of the stability of the mold and the slag entrapment behavior. After the design of a new SEN according to the experimental result, the solidification structure of continuous casting slab was obviously improved by industrial test.
  • Yong-kun Yang, Jia-yu Zhu, Xiao-ming Li, Yang Wang, Dong-ping Zhan
    钢铁研究学报(英文版). 2023, 30(11): 2242-2253.
    https://doi.org/10.1007/s42243-023-00916-6
    摘要 ( )   可视化   收藏
    Banded structure is a common harmful microstructure for low carbon microalloyed steel, which seriously shortens the service life of processed parts. In order to study the effect of oxide metallurgy on improving banded structure, the Ti–Zr deoxidized low carbon microalloyed steel that can play the oxide metallurgical role of inclusion was chosen as the research object, and the inclusion characteristics, microstructure and transverse and longitudinal mechanical properties after hot rolling were analyzed. The results showed the inclusion number density increased in all experimental steels after hot rolling, and a large number of long strip inclusions with aspect ratio greater than 3 appeared along the rolling direction. In addition, after hot rolling, there were element segregation bands in the experimental steels, and granular bainite bands were formed in the element enrichment zone. However, the intragranular ferrite generated in the cooling process destroyed the continuity of granular bainite bands, so that the microstructure anisotropy indexes of experimental steels were small. The mechanical properties analysis showed that the anisotropy of performance was mainly reflected in plasticity and toughness in the experimental steels. Among them, the difference ratio of elongation, section shrinkage and impact energy of No. 2 steel was 1.69%, 3.87% and 1.69%, respectively, which were less than those of No. 1 steel and No. 3 steel. The anisotropy of microstructure and mechanical properties of No. 2 steel that full played the role of oxide metallurgy were improved, and the banded structure control of low carbon microalloyed steel can be realized by oxide metallurgy technology.
  • Hao Li, Qiang Ren, Li-feng Zhang
    钢铁研究学报(英文版). 2023, 30(11): 2254-2266.
    https://doi.org/10.1007/s42243-022-00887-0
    摘要 ( )   可视化   收藏
    Effects of varied levels of cerium (28 9 10–6, 65 9 10–6 and 150 9 10–6) on inclusions in a high-carbon chromium bearing steel at different stages (before adding cerium, after adding cerium for 1, 5, 10 min and ingot) were studied using laboratory experiments. An automatic scanning electron microscope system with energy-dispersive spectroscopy was used to analyze the amount, composition, size and morphology of inclusions in the steel at different stages. When the cerium content in the molten steel increased from 0 to 150 9 10–6, the evolution sequence of inclusions was as follows: Al2- O3 ? CeAl11O18 ? CeAlO3 ? Ce2O2S. After 28 9 10–6 cerium was added, Al2O3 inclusions were modified into CeAl11O18 inclusions in the molten steel and then were further transformed into Al2O3 and CeAlO3 inclusions in the solid steel during cooling. With the addition of 65 9 10–6 cerium, inclusions in the molten steel were modified into CeAlO3 and a small number of Ce2O2S inclusions. When the addition amount of cerium increased to 150 9 10–6, inclusions were transformed to Ce2O2S. The size of inclusions in the molten steel decreased obviously with cerium addition. On the other hand, the size of inclusions increased during the cooling process in solid steels of No. 1 steel (with 28 9 10–6 cerium) and No. 2 steel (with 65 9 10–6 cerium). During the cooling process, unmodified MnS inclusions were precipitated in the solid steel of No. 1 steel and wrapped outside the Al2O3 and CeAlO3 inclusions to form large complex inclusions. During the cooling process of No. 2 steel, the inclusion size of CeAlO3 increased due to the collision and polymerization. In the No. 3 steel (with 150 9 10–6 cerium), the average size of inclusions decreased rapidly and remained at a lower size during the cooling process, which was beneficial to improving the fatigue life of the steel.
  • Zhi-jun Gao, Guang-fei Pan, Yu Song, Shui-ze Wang, Xiao-yu Ye, Xin-ping Mao
    钢铁研究学报(英文版). 2023, 30(11): 2267-2279.
    https://doi.org/10.1007/s42243-023-00963-z
    摘要 ( )   可视化   收藏
    The realization of an ideal combination of mechanical and fatigue properties is prerequisites for practical application of titanium (Ti) microalloyed steel in automotive field. The fatigue behavior of four Ti microalloyed high-strength beam steels with different Ti contents was systematically studied. The results show that the content of microalloying element Ti has a significant effect on the fatigue properties, especially in the steel with a high Ti content. For the experimental Ti microalloyed steel, inclusion-induced crack initiation is the main fatigue failure mode. Different from general fatigue fracture mechanism in Ti-contained steel, no TiN, which is the most detrimental to fatigue behavior, was found in fatigue crack initiation area. However, the large-sized TiN and oxide complex inclusion with a core–shell structure is the dominant cause of fatigue fracture. Because of the intense-localized deformation at the interface between complex inclusion and matrix, the angular TiN in the outer shell has a serious deteriorating effect on the fatigue properties, which is consistent with the result of the Kernel average misorientation map. Besides, the modification effect of a small amount of MnS on large-sized inclusion is not obvious and has little effect on the fatigue behavior. For more practical guidance, the critical inclusion sizes of the experimental steels were also investigated by experimental extrapolation method. With the increasing tensile strength, the inclusion sensitivity of the experimental steels increases, leading to the small critical inclusion size.
  • Fan Wang, De-ning Zou, Xing-yu Yan, Ying-bo Zhang, Ji-xiang Pan, Yun-xia Cheng, Ran Xu, Yi-cheng Jiang
    钢铁研究学报(英文版). 2023, 30(11): 2280-2292.
    https://doi.org/10.1007/s42243-023-01024-1
    摘要 ( )   可视化   收藏
    The effects of different annealing processes on the phase precipitation behavior and corrosion properties of copper-bearing 430 ferritic stainless steel were systematically investigated. The shape, quantity and distribution of copper-rich precipitates by different annealing processes were characterized by scanning electron microscopy, transmission electron microscopy, backscatter electron and backscatter diffraction. The pitting resistance behavior in simulated physiological saline environments (0.9 wt.% NaCl) was investigated using electrochemical workstation and X-ray photoelectron spectroscopy. The results showed that the copper-rich phase prepared by repeated rolling and annealing gradually changed from long needlelike to short thick rod-like and granular, whose distribution tended to be uniform and diffusive, and the number of copperrich phases increased. After solution/antibacterial annealing process, the size and density of the copper-rich phase increase, resulting in a discontinuity of the passivation film on the stainless steel, which reduces the pitting resistance to some extent. The refinement mechanism revealed that pre-deformation brings about a modification in both precipitation mechanism and growth kinetics of epsilon copper.
  • Xiang Li, Linyi Cui, Sara Shonkwiler, Sara McMains
    钢铁研究学报(英文版). 2023, 30(11): 2293-2300.
    https://doi.org/10.1007/s42243-022-00907-z
    摘要 ( )   可视化   收藏
    The microstructural characteristics of spherical metal powders play an important role in determining the quality of mechanical parts manufactured by powder metallurgy processes. Identifying the individual powder particles from their microscopic images is one of the most convenient and cost-efficient methods for the analysis of powder characteristics. Although numerous image processing algorithms have been developed for automating the powder particle identification process, they perform less accurately in identifying adjacent particles that are heavily overlapped in their image regions. We propose an automatic algorithm to robustly and accurately identify spherical powder particles, especially heavily overlapped particles, from their microscope images. A parallel computing framework is designed to further enhance the computational efficiency of the proposed algorithm. Powder characteristics such as particle size distribution and the location of potential satellite particles have been derived from our identification results. The accuracy and efficiency of our algorithm are validated by real-world scanning electron microscope images, outperforming other existing methods and achieving both precision and recall above 99%.
  • Cheng-yu Wang, Teng An, Yu Gu, Zhong-nan Bi, Jin-hui Du, Jing-long Qu
    钢铁研究学报(英文版). 2023, 30(11): 2301-2317.
    https://doi.org/10.1007/s42243-023-01019-y
    摘要 ( )   可视化   收藏
    The inhomogeneous microstructure of the Ni-based superalloys used for turbine disks was an intolerable defect for the mechanical performance. The effects of the distribution of c0 precipitate, forging temperature, and strain level on the microstructure evolution of GH4730 alloy were investigated by EBSD during hot deformation. The results showed that the heterogeneous factor peaked at the transition temperature from the single-phase to the double-phase region. The coupling effect of heat and stress led to the heterogeneous precipitation and distribution of c0 phase during the transition region, which was the main reason for the formation of inhomogeneous microstructures. The coherent c0 phases of approximately 0.3 lm were diffusely distributed inside the large grains, increasing the grain strength, making recrystallization refinement difficult, and thus forming large unrecrystallized grains. The incoherent c0 phases with a size of approximately 1.1 lm located at the grain boundaries and pinned the grain boundaries, and thus the accumulated strain at the grain boundaries caused the occurrence of discontinuous dynamic recrystallization and promoted continuous refinement of the grains. The microstructure evolution of new Ni-based superalloys during hot forging was focused, and the formation mechanism of inhomogeneous microstructure and control measures was explained. A theoretical basis for improving the microstructure homogeneity of the new cast and wrought superalloys was provided.
  • Rui-zhi Gao, Lin-zhu Wang, Chao-yi Chen, Shu-feng Yang, Xiang Li, Yin Zhang
    钢铁研究学报(英文版). 2023, 30(11): 2318-2327.
    https://doi.org/10.1007/s42243-023-01052-x
    摘要 ( )   可视化   收藏
    Understanding the interactive forces of inclusions on the surface of molten nickel-based superalloys and finding methods to disperse these inclusions help improve performance and service life. The aggregation behavior of aluminum oxide (Al2O3) and calcium aluminate inclusions with different sizes and spacings on the surface of molten nickel-based superalloys was observed in-situ using a high-temperature confocal laser scan microscope. The attractive force acted on Al2O3 inclusions with radii of 3.5–6 lm was found ranging from 6.2 9 10–18 to 3.6 9 10–15 N, and that of CaO 2Al2O3 (CA2) inclusions with radii of 3–5.5 lm ranging from 3.5 9 10–19 to 8.3 9 10–15 N. The capillary force acted on inclusions on the surface of nickel-based superalloy was calculated based on the Kralchevsky–Paunov model and investigated as a function of inclusion size, spacing, and composition. The calculated results were in the same trend as the experimental results. The capillary force acted on inclusions was also affected by their contact angle, the density, surface energy, and oxygen content of the molten alloy. It decreased with increasing alloy density and decreasing contact angle between inclusion with alloy. Thus, the attractive force acted on Al2O3 inclusions was smaller on the surface of molten nickel-based superalloy than that of molten steel. Decreasing the oxygen content in the molten nickel-based alloy could increase its surface energy, and the attractive force acted on the inclusions would decrease. When the oxygen content in the molten nickel-based alloy decreased from 0.05 to 0.0001 wt.%, the capillary force acted on the Al2O3 inclusions decreased from 1.7×10-18 to 3.6×10-19 N, reduced by 79% (1.4 9 10–18 N).
  • Yuan-yi Peng, Chong Li, Qian-ying Guo, Hui-jun Li, Yong-chang Liu
    钢铁研究学报(英文版). 2023, 30(11): 2328-2339.
    https://doi.org/10.1007/s42243-023-01016-1
    摘要 ( )   可视化   收藏
    For the bonding couple of S31042 steel and Ni3Al-based superalloy, joint microstructure regulation plays a pivotal role in improving joint performance. Different pretreatment approaches including solution and cold rolling treatments were severally applied to the two substrates before vacuum diffusion bonding. Cold rolling treatment in S31042 steel substrate before bonding promoted the coarsening and precipitation behaviors of large amounts of Z (NbCrN) phases during the bonding process so that the AlN phase decreased in the joint area because of the consumption of N atom in the Z phase. And solution treatment for Ni3Al-based superalloy increased the grain boundary mobility and led to the occurrence of dynamic recrystallization in the diffusion area of the joint by reducing segregation and homogenizing the microstructure within the substrate. As a result, the bonded sample with two substrates that are pretreated exhibited a better tensile strength and elongation at 700 °C.