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铝土矿中镓的提取与回收研究进展

Research progress on extraction and recovery of gallium from bauxite

  • 摘要: 镓是一种重要的稀有金属矿产, 镓和镓化合物广泛应用于太阳能、半导体、生物、化工和合金等领域。随着镓需求量的不断增长, 镓资源已成为一种重要的战略资源。镓以极为稀少的含量分散于铝土矿、磷灰石、霞石和明矾石等矿物中, 世界90%以上的原生镓来自于氧化铝生产的副产品。目前, 从拜耳母液回收镓的方法有沉淀法、电化学法、萃取法和树脂吸附法等, 然而提升镓的回收效率和降低其回收成本仍是业内关注的重点。阐述了铝土矿镓的赋存形式、镓在拜耳循环过程中的迁移规律、镓的分离提取方法和回收工艺的研究成果, 重点介绍了铝土矿中镓资源回收现状, 总结了现有技术的优缺点, 并展望了从铝土矿中提镓的研究发展方向。

     

    Abstract: Gallium is an important rare metal resource. Gallium and its compounds have been found extensive applications in diverse fields, e.g. solar energy, semiconductors, biology, chemical engineering, and alloys. Gallium resources have evolved into a crucial strategic asset owing to the continually increased demand. Gallium is sparsely distributed within minerals like bauxite, apatite, nepheline, and alunite in an extremely scarce quantity. More than 90% of the world's primary gallium is derived from the by-products of alumina production. Currently, methods for recovering gallium from Bayer liquor can be included as precipitation, electrochemistry, extraction, and resin adsorption. However, improving the recovery efficiency of gallium and reducing its recovery cost are remained key concerns in the relevant industry. Recent research findings on the occurrence forms of gallium in bauxite, the migration behavior of gallium during the Bayer process cycle, and methodologies for gallium separation, extraction, and recovery are presented. The current status of gallium resource recovery from bauxite is mainly introduced, the advantages and disadvantages of the employed technologies are summarized, and some future research directions for gallium extraction from bauxite are outlined.

     

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