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Effect of calciumtreatment on non-metallic inclusions in high carbon aluminum killed steel |
GAO Sheng-ya,JIANG Min,HOU Ze-wang,WANG Xin-hua |
(School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China) |
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Abstract Influence of calciumtreatment on the composition and morphology of non-metallic inclusions in high carbon aluminum killed steel was studied by automatic SEM(ASPEX). The results indicated that inclusions transformed from MgO·Al2O3 spinel at LF ending to complicated[x(MgO·Al2O3)·(1-x)CaS]inclusions after calciumtreatment, instead of low-melting calcium-aluminates. The mass ratio of MgO/Al2O3 in inclusions which was nearly 1[∶]3 maintained almost constant during calciumtreatment.Because of[w([S])/w(T[O])]in steel being so high, calcium combined with sulfur to generate CaS and didn’t modify MgO·Al2O3 inclusions.On the other hand, due to the basicity of refining slag being so low, calcium in steel cannot reduce MgO of MgO·Al2O3 inclusions. On this basis, the generation and evolution mechanisms of inclusions during calciumtreatment were discussed.
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Received: 12 July 2016
Published: 18 April 2017
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