|
Abstract The solidification structures and the thermal properties of Fe-Mn-C steel ingots containing different Mn mass fraction have been investigated to assist the development of the continuous casting technology of Fe-Mn-C steels. The results show that the thermal conductivity of the 0Mn steel is higher than that of the 3Mn steel. The thermal conductivity of the 6Mn steel is the lowest in the three kinds of steels below 750 ℃ and the highest above 900 ℃. The 0Mn steel has the highest value of the proportion of equiaxed grain zone area in the three kinds of steels,whereas the 3Mn steel has the lowest value of it in the steels. Mn has the effect of promoting the coarsening of grains. The mean thermal expansion coefficients of the steels are at the range from 1.0×10-5~1.6×10-5 ℃-1. Using RA<60 % as the criterion,the third brittle temperature region of the 6Mn steel is 600 ℃ to 800 ℃,whereas those of the 3Mn steel and the 0Mn steel are 600 ℃ to 850 ℃ and 600 ℃ to 900 ℃,respectively. In the 6Mn and 3Mn steels,the deformation-induced ferrite(DIF) forming in sufficient quantities causes the recovery of the ductility at the low temperature end. However,since low strains are present when straightening,sufficient quantities of DIF cannot be formed. Thus,the ductility of the 6Mn and 3Mn steels cannot be improved during the continuous casting process.
|
Received: 09 January 2017
Published: 29 September 2017
|
|
|
|
[3] |
MILLER R L. Ultrafine-grained microstructures and mechanical properties of alloy steels[J]. Metallurgical Transactions, 1972, 3(4): 905-912.
|
[4] |
FURUKAWA T, HUANG H, MATSUMURA O. Effects of carbon content on mechanical properties of 5% Mn steels exhibiting transformation induced plasticity[J]. Materials science and technology, 1994, 10(11): 964-970.
|
[1] |
GIBBS P J, DE MOOR E, MERWIN M J, et al. Austenite stability effects on tensile behavior of manganese-enriched-austenite transformation-induced plasticity steel[J]. Metallurgical and Materials Transactions A, 2011, 42(12): 3691-3702.
|
[2] |
MATLOCK D K, SPEER J G. Third generation of AHSS: microstructure design concepts[M]//Microstructure and texture in steels. Springer London, 2009: 185-205.
|
[5] |
ARLAZAROV A, GOUNé M, BOUAZIZ O, et al. Evolution of microstructure and mechanical properties of medium Mn steels during double annealing[J]. Materials Science and Engineering: A, 2012, 542: 31-39.
|
[6] |
HUANG H, MATSUMURA O, FURUKAWA T. Retained austenite in low carbon, manganese steel after intercritical heat treatment[J]. Materials science and technology, 1994, 10(7): 621-626.
|
[3] |
MILLER R L. Ultrafine-grained microstructures and mechanical properties of alloy steels[J]. Metallurgical Transactions, 1972, 3(4): 905-912.
|
[4] |
FURUKAWA T, HUANG H, MATSUMURA O. Effects of carbon content on mechanical properties of 5% Mn steels exhibiting transformation induced plasticity[J]. Materials science and technology, 1994, 10(11): 964-970.
|
[7] |
范倚,王明林,张慧,等.第三代汽车钢的热塑性及断裂机理[J].北京科技大学学报,2013,35(5):607-612.
|
[8] |
陶红标,王明林,范倚,等.第三代汽车钢的热物性及相变特征研究[J].炼钢,2013,29(5):65-69.
|
[5] |
ARLAZAROV A, GOUNé M, BOUAZIZ O, et al. Evolution of microstructure and mechanical properties of medium Mn steels during double annealing[J]. Materials Science and Engineering: A, 2012, 542: 31-39.
|
[9] |
PARKER W J, JENKINS R J, BUTLER C P, et al. Flash method of determining thermal diffusivity, heat capacity, and thermal conductivity[J]. Journal of applied physics, 1961, 32(9): 1679-1684.
|
[10] |
张立强,包燕平,王敏,等.GCr15钢的热膨胀系数[J].钢铁研究学报,2012,24(9):40-44.
|
[6] |
HUANG H, MATSUMURA O, FURUKAWA T. Retained austenite in low carbon, manganese steel after intercritical heat treatment[J]. Materials science and technology, 1994, 10(7): 621-626.
|
[11] |
EPPELSHEIMER D S, PENMAN R R. Thermal dilation of copper[J]. Physica, 1950, 16(10): 792-794.
|
[12] |
钱宏智,张家泉,崔立新.钢铸态热膨胀特性研究[J].钢铁研究学报,2011,23(3):44-49,62.
|
[7] |
范倚,王明林,张慧,等.第三代汽车钢的热塑性及断裂机理[J].北京科技大学学报,2013,35(5):607-612.
|
[13] |
张先棹.冶金传输原理[M]//冶金工业出版社,北京,1987:433.
|
[8] |
陶红标,王明林,范倚,等.第三代汽车钢的热物性及相变特征研究[J].炼钢,2013,29(5):65-69.
|
[9] |
PARKER W J, JENKINS R J, BUTLER C P, et al. Flash method of determining thermal diffusivity, heat capacity, and thermal conductivity[J]. Journal of applied physics, 1961, 32(9): 1679-1684.
|
[14] |
MENG Y A, THOMAS B G. Heat-transfer and solidification model of continuous slab casting: CON1D[J]. Metallurgical and Materials Transactions B, 2003, 34(5): 685-705.
|
[10] |
张立强,包燕平,王敏,等.GCr15钢的热膨胀系数[J].钢铁研究学报,2012,24(9):40-44.
|
[15] |
MINTZ B, TULING A, DELGADO A. Influence of silicon, aluminium, phosphorus and boron on hot ductility of TRansformation Induced Plasticity assisted steels[J]. Materials science and technology, 2003, 19(12): 1721-1726.
|
[11] |
EPPELSHEIMER D S, PENMAN R R. Thermal dilation of copper[J]. Physica, 1950, 16(10): 792-794.
|
[16] |
MINTZ B, CROWTHER D N. Hot ductility of steels and its relationship to the problem of transverse cracking in continuous casting[J]. International Materials Reviews, 2010, 55(3): 168-196.
|
[12] |
钱宏智,张家泉,崔立新.钢铸态热膨胀特性研究[J].钢铁研究学报,2011,23(3):44-49,62.
|
[13] |
张先棹.冶金传输原理[M]//冶金工业出版社,北京,1987:433.
|
[17] |
DONG H, SUN X. Deformation induced ferrite transformation in low carbon steels[J]. Current Opinion in Solid State and Materials Science, 2005, 9(6): 269-276.
|
[18] |
董瀚,孙新军,刘清友,等.变形诱导铁素体相变现象与理论[J].钢铁,2003,38(10):56-67.
|
[14] |
MENG Y A, THOMAS B G. Heat-transfer and solidification model of continuous slab casting: CON1D[J]. Metallurgical and Materials Transactions B, 2003, 34(5): 685-705.
|
[15] |
MINTZ B, TULING A, DELGADO A. Influence of silicon, aluminium, phosphorus and boron on hot ductility of TRansformation Induced Plasticity assisted steels[J]. Materials science and technology, 2003, 19(12): 1721-1726.
|
[16] |
MINTZ B, CROWTHER D N. Hot ductility of steels and its relationship to the problem of transverse cracking in continuous casting[J]. International Materials Reviews, 2010, 55(3): 168-196.
|
[17] |
DONG H, SUN X. Deformation induced ferrite transformation in low carbon steels[J]. Current Opinion in Solid State and Materials Science, 2005, 9(6): 269-276.
|
[18] |
董瀚,孙新军,刘清友,等.变形诱导铁素体相变现象与理论[J].钢铁,2003,38(10):56-67.
|
[19] |
HONG S C, LIM S H, LEE K J, et al. Effect of undercooling of austenite on strain induced ferrite transformation behavior[J]. ISIJ international, 2003, 43(3): 394-399.
|
[19] |
HONG S C, LIM S H, LEE K J, et al. Effect of undercooling of austenite on strain induced ferrite transformation behavior[J]. ISIJ international, 2003, 43(3): 394-399.
|
[20] |
HURLEY P J, HODGSON P D. Effect of process variables on formation of dynamic strain induced ultrafine ferrite during hot torsion testing[J]. Materials science and technology, 2001, 17(11): 1360-1368.
|
[20] |
HURLEY P J, HODGSON P D. Effect of process variables on formation of dynamic strain induced ultrafine ferrite during hot torsion testing[J]. Materials science and technology, 2001, 17(11): 1360-1368.
|
[21] |
MINTZ B, LEWIS J, JONAS J J. Importance of deformation induced ferrite and factors which control its formation[J]. Materials science and technology, 1997, 13(5): 379-388.
|
[21] |
MINTZ B, LEWIS J, JONAS J J. Importance of deformation induced ferrite and factors which control its formation[J]. Materials science and technology, 1997, 13(5): 379-388.
|
[22] |
CHOI J K, SEO D H, LEE J S, et al. Formation of ultrafine ferrite by strain-induced dynamic transformation in plain low carbon steel[J]. ISIJ international, 2003, 43(5): 746-754.
|
[22] |
CHOI J K, SEO D H, LEE J S, et al. Formation of ultrafine ferrite by strain-induced dynamic transformation in plain low carbon steel[J]. ISIJ international, 2003, 43(5): 746-754.
|
[23] |
WENG Y Q, SUN X J, DONG H. Overview on the theory of deformation induced ferrite transformation[J]. Iron & Steel, 2005, 40(S1): 9-15.
|
[24] |
惠卫军,田鹏,董瀚,等.形变温度对中碳钢组织转变的影响[J].金属学报,2005,41(6):611-616.
|
[23] |
WENG Y Q, SUN X J, DONG H. Overview on the theory of deformation induced ferrite transformation[J]. Iron & Steel, 2005, 40(S1): 9-15.
|
[24] |
惠卫军,田鹏,董瀚,等.形变温度对中碳钢组织转变的影响[J].金属学报,2005,41(6):611-616.
|
[25] |
THOMAS B G, BRIMACOMBE J K, SAMARASEKERA I V. The formation of panel cracks in steel ingots, A state of the art review, Part I: Hot ductility of steel[J]. Transactions of the Iron and Steel Society, 1986, 7(10): 7-20.
|
[25] |
THOMAS B G, BRIMACOMBE J K, SAMARASEKERA I V. The formation of panel cracks in steel ingots, A state of the art review, Part I: Hot ductility of steel[J]. Transactions of the Iron and Steel Society, 1986, 7(10): 7-20.
|
[26] |
MAEHARA Y, YASUMOTO K, TOMONO H, et al. Surface cracking mechanism of continuously cast low carbon low alloy steel slabs[J]. Materials Science and Technology, 1990, 6(9): 793-806.
|
[26] |
MAEHARA Y, YASUMOTO K, TOMONO H, et al. Surface cracking mechanism of continuously cast low carbon low alloy steel slabs[J]. Materials Science and Technology, 1990, 6(9): 793-806.
|
[27] |
TURKDOGAN E T. Causes and effects of nitride and carbonitride precipitation in HSLA steels in relation to continuous casting[C]//Steelmaking Conference Proceedings, 1987, 70(399): 399-409.
|
[27] |
TURKDOGAN E T. Causes and effects of nitride and carbonitride precipitation in HSLA steels in relation to continuous casting[C]//Steelmaking Conference Proceedings, 1987, 70(399): 399-409.
|
[28] |
MINTZ B. The influence of composition on the hot ductility of steels and to the problem of transverse cracking[J]. ISIJ international, 1999, 39(9): 833-855.
|
[28] |
MINTZ B. The influence of composition on the hot ductility of steels and to the problem of transverse cracking[J]. ISIJ international, 1999, 39(9): 833-855.
|
[29] |
MINTZ B, YUE S, JONAS J J. Hot ductility of steels and its relationship to the problem of transverse cracking during continuous casting[J]. International Materials Reviews, 1991, 36(1): 187-220.
|
[30] |
OUCHI C, MATSUMOTO K. Hot ductility in Nb-bearing high-strength low-alloy steels[J]. Transactions of the iron and steel institute of Japan, 1982, 22(3): 181-189.
|
[29] |
MINTZ B, YUE S, JONAS J J. Hot ductility of steels and its relationship to the problem of transverse cracking during continuous casting[J]. International Materials Reviews, 1991, 36(1): 187-220.
|
[31] |
MINTZ B, ARROWSMITH J M. Hot-ductility behaviour of C–Mn–Nb–Al steels and its relationship to crack propagation during the straightening of continuously cast strand[J]. Metals Technology, 2013.
|
[30] |
OUCHI C, MATSUMOTO K. Hot ductility in Nb-bearing high-strength low-alloy steels[J]. Transactions of the iron and steel institute of Japan, 1982, 22(3): 181-189.
|
[32] |
TULING A, BANERJEE J R, MINTZ B. Influence of peritectic phase transformation on hot ductility of high aluminium TRIP steels containing Nb[J]. Materials Science and Technology, 2011, 27(11): 1724-1731.
|
[31] |
MINTZ B, ARROWSMITH J M. Hot-ductility behaviour of C–Mn–Nb–Al steels and its relationship to crack propagation during the straightening of continuously cast strand[J]. Metals Technology, 2013.
|
[33] |
SUZUKI H G, NISHIMURA S, YAMAGUCHI S. Characteristics of the Embrittlement of Steels above 600 deg C[J]. Tetsu-to-Hagane(Journal of the Iron and Steel Institute of Japan), 1979, 65(14): 2038-2046.
|
[32] |
TULING A, BANERJEE J R, MINTZ B. Influence of peritectic phase transformation on hot ductility of high aluminium TRIP steels containing Nb[J]. Materials Science and Technology, 2011, 27(11): 1724-1731.
|
[34] |
SUZUKI H G, NISHIMURA S, IMAMURA J, et al. Hot ductility in steels in the temperature range between 900 and 600 deg C: related to the transverse facial cracks in continuously cast slabs[J]. Tetsu-to-Hagane(Journal of the Iron and Steel Institute of Japan), 1981, 67(8): 1180-1189.
|
[33] |
SUZUKI H G, NISHIMURA S, YAMAGUCHI S. Characteristics of the Embrittlement of Steels above 600 deg C[J]. Tetsu-to-Hagane(Journal of the Iron and Steel Institute of Japan), 1979, 65(14): 2038-2046.
|
[35] |
MINTZ B, COWLEY A. Deformation induced ferrite and its influence on the elevated temperature tensile flow stress–elongation curves of plain C–Mn and Nb containing steels[J]. Materials science and technology, 2006, 22(3): 279-292.
|
[34] |
SUZUKI H G, NISHIMURA S, IMAMURA J, et al. Hot ductility in steels in the temperature range between 900 and 600 deg C: related to the transverse facial cracks in continuously cast slabs[J]. Tetsu-to-Hagane(Journal of the Iron and Steel Institute of Japan), 1981, 67(8): 1180-1189.
|
[36] |
COWLEY A, MINTZ B. Relative importance of transformation temperatures and sulphur content on hot ductility of steels[J]. Materials science and technology, 2004, 20(11): 1431-1439.
|
[35] |
MINTZ B, COWLEY A. Deformation induced ferrite and its influence on the elevated temperature tensile flow stress–elongation curves of plain C–Mn and Nb containing steels[J]. Materials science and technology, 2006, 22(3): 279-292.
|
[37] |
MINTZ B. Understanding the low temperature end of the hot ductility trough in steels[J]. Materials Science and Technology, 2008, 24(1): 112-120.
|
[36] |
COWLEY A, MINTZ B. Relative importance of transformation temperatures and sulphur content on hot ductility of steels[J]. Materials science and technology, 2004, 20(11): 1431-1439.
|
[38] |
MINTZ B, BANERJEE J R. Influence of C and Mn on hot ductility behaviour of steel and its relationship to transverse cracking in continuous casting[J]. Materials science and Technology, 2010, 26(5): 547-551.
|
[37] |
MINTZ B. Understanding the low temperature end of the hot ductility trough in steels[J]. Materials Science and Technology, 2008, 24(1): 112-120.
|
[39] |
B. Mintz, A. Cowley, and R. Abushosha: Mater. Sci. Technol., 2000, vol. 16, pp. 1-5.
|
[38] |
MINTZ B, BANERJEE J R. Influence of C and Mn on hot ductility behaviour of steel and its relationship to transverse cracking in continuous casting[J]. Materials science and Technology, 2010, 26(5): 547-551.
|
[39] |
B. Mintz, A. Cowley, and R. Abushosha: Mater. Sci. Technol., 2000, vol. 16, pp. 1-5.
|
[1] |
Ming Lei, Wei‑jun Hui, Jiao‑jiao Wang, Yong‑jian Zhang, Xiao‑li Zhao. Microstructure and mechanical properties of hot-rolled V-microalloyed Al-containing medium-Mn steel[J]. JOURNAL OF IRON AND STEEL RESEARCH,INTERNATIONAL, 2020, 27(5): 537-548. |
[2] |
Bo Xia, Xiao‑ming Zhang, R.D.K. Misra, Ming‑ming Pan, Yu‑qian Wang. Signifcant impact of cold-rolling deformation and annealing on damping capacity of Fe–Mn–Cr alloy[J]. JOURNAL OF IRON AND STEEL RESEARCH,INTERNATIONAL, 2020, 27(5): 566-576. |
[3] |
Jin‑long Lu, Guo‑guang Cheng, Meng Wu, Guo Yang, Ju‑long Che. Detection and analysis of magnetic particle testing defects on heavy truck crankshaft manufactured by microalloyed medium-carbon forging steel[J]. JOURNAL OF IRON AND STEEL RESEARCH,INTERNATIONAL, 2020, 27(5): 608-616. |
[4] |
FENG Lu-lu1,2,HU Feng1,QIAO Wen-wei3,LU Xiu-yu4,ZHANG Guo-hong5. Microstructure and properties of 150mm ultra heavy 07MnCrMoVR hydropower steel[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2020, 32(5): 400-405. |
[5] |
WANG Yi, ZHANG Li-feng, REN Ying, REN Qiang. Mechanism of inclusion evolution during refining process of 37Mn5 steel production[J]. Iron and Steel, 2020, 55(5): 39-44. |
[6] |
CAO Yun-fei, YU Wei, LIU Min, JIANG Rui, WANG Chun. Austenite grain growth model of 38MnSiVS bearing microalloyed forging steel[J]. Iron and Steel, 2020, 55(5): 103-108. |
|
|
|