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Mechanism and experimental for dephosphorizion and chromium conservation of chromium containing melted iron |
ZHAO Hai-quan1, 2,QI Yuan-hong1,SHI Yong-lin2,FENG Huan-lin2,NA Xian-zhao1 |
(1. State Key Laboratory of Advanced Steel Processing and Products, Central Iron and Steel Research Institute, Beijing 100081, China 2. Technology Centre, Taiyuan Iron and Steel (Group) Co., Ltd., Taiyuan 030003, Shanxi, China) |
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Abstract To solve the problem on the iron utlizion limition as high P,calculation and industry test on dephosphorization and chromium conservation of iron with Cr and Ni was studied,so as stainless steel dust could be recycled by the process of shaft furnace. But the liquid iron smelted by this process had the problem of high phosphorus content, which then led to the use of liquid iron restricted. For realizing dephosphorization and chromium conservation of liquid iron, through calculation, including thermodynamic conditions of the reduction of chrome, nickel and iron oxide and the critical oxygen potentials of phosphorus, chromium and carbon oxidized, three measures were put forward. The measures were using CaO alkaline slag series, controlling oxygen potential and tapping temperature. On the basis of the theoretical calculation, experimental study about dephosphorization and chromium conservation of chromium-nickel containing liquid iron which was smelted by shaft furnace, was carried out in industry. 35 t of chromium-nickel containing liquid iron was smelted in experiment. The results show that when the slag basicity is 1.15, the content of FeO in slag is controlled at about 5%, the tapping temperature is controlld within 1 673-1 684 K, dephosphorization rate could be reached to more than 36%, content of phosphorus in molten iron could be dropped to 0.023%, and Cr yield is over 88%. Experiment indicates that the purpose of dephosphorization and chromium conservation could be achieved by using the measures studied, and the problem of high phosphorus content in liquid iron containing chromium and nickel could be solved.
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Received: 23 March 2017
Published: 21 December 2017
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参考文献:
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参考文献:
|
[1] |
彭兵,张传福,彭及等.不锈钢电弧炉粉尘直接还原回收工艺研究[J].上海金属,2002,24(5):33.(PENG Bing, ZHANG Chuan-fu, PENG Ji.et al. Study on Recycling Process for Direct Reduction of EAF Stainless Steel Dust[J].Shanghai Metals. 2002, 24(5) :33.)
|
[1] |
彭兵,张传福,彭及等.不锈钢电弧炉粉尘直接还原回收工艺研究[J].上海金属,2002,24(5):33.(PENG Bing, ZHANG Chuan-fu, PENG Ji.et al. Study on Recycling Process for Direct Reduction of EAF Stainless Steel Dust[J].Shanghai Metals. 2002, 24(5) :33.)
|
[2] |
武拥军,姜周华,梁连科,姜茂发等.不锈钢冶炼过程中相关热力学问题的解析(Ⅰ)—原料预处理时的热力学问题(J).钢铁研究学报,2003,15(3):1
|
[2] |
武拥军,姜周华,梁连科,姜茂发等.不锈钢冶炼过程中相关热力学问题的解析(Ⅰ)—原料预处理时的热力学问题(J).钢铁研究学报,2003,15(3):1
|
[3] |
武拥军,姜周华,梁连科,姜茂发等.不锈钢冶炼过程中相关热力学问题的解析(Ⅱ)—含铬铁水的去磷保铬(J).钢铁研究学报,2003,15(4):12
|
[3] |
武拥军,姜周华,梁连科,姜茂发等.不锈钢冶炼过程中相关热力学问题的解析(Ⅱ)—含铬铁水的去磷保铬(J).钢铁研究学报,2003,15(4):12
|
[4] |
黄宗泽,陈兆平,姜周华,梁连科等.AOD前期含铬铁水去磷保铬的热力学分析[J].中国稀土学报,2004,22(8):42
|
[4] |
黄宗泽,陈兆平,姜周华,梁连科等.AOD前期含铬铁水去磷保铬的热力学分析[J].中国稀土学报,2004,22(8):42
|
[5] |
Kubaschewski O,Evans E L L.Metallurgical Thermochemistry[M].London:M S,1958.
|
[5] |
Kubaschewski O,Evans E L L.Metallurgical Thermochemistry[M].London:M S,1958.
|
[6] |
刘平,丁伟中,李一为.不锈钢母液的凝固点及流动性的实验研究[J].铁合金,2004(2)总 175
|
[6] |
刘平,丁伟中,李一为.不锈钢母液的凝固点及流动性的实验研究[J].铁合金,2004(2)总 175
|
[7] |
Peckner D,Bernstein IM.Handbook of Stainless Steels[M].USA:McGraw-Hill Book inc,1977.
|
[7] |
Peckner D,Bernstein IM.Handbook of Stainless Steels[M].USA:McGraw-Hill Book inc,1977.
|
[8] |
H. E. Powell et al.,Converting Stainless SteelFurnace Flue Dust and Wastes to a Recyclable Al-loy,US Bureau of Mines,Report of Investigations8039,24,1975.
|
[8] |
H. E. Powell et al.,Converting Stainless SteelFurnace Flue Dust and Wastes to a Recyclable Al-loy,US Bureau of Mines,Report of Investigations8039,24,1975.
|
[9] |
Hasegawa,Shinji Kokubu,Haruo Development of asmeltin greduction process for recycling steelmaking dust Kawasaki Steel Technical Report 38 Apr 1998Kawasaki Steel Corp.
|
[9] |
Hasegawa,Shinji Kokubu,Haruo Development of asmeltin greduction process for recycling steelmaking dust Kawasaki Steel Technical Report 38 Apr 1998Kawasaki Steel Corp.
|
[10] |
李花兵,姜周华,黄晓颖,梁连科.含铬铁水氧化脱磷的实验研究[J].中国特殊钢年会2005论文集,2005(5):48-50.
|
[10] |
李花兵,姜周华,黄晓颖,梁连科.含铬铁水氧化脱磷的实验研究[J].中国特殊钢年会2005论文集,2005(5):48-50.
|
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