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Preparation of fusible pellets from fine-grained iron ore concentrates |
WEN Bao-liang1, ZHANG Xiao-ping1,2, LI Jia-xin1, WU Hong-liang1,2, YANG Jia-long1 |
1. School of Metallurgical Engineering, Anhui University of Technology, Maanshan 243032, Anhui, China; 2. Technical Center, Maanshan Iron and Steel Co., Ltd., Maanshan 243003, Anhui, China |
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Abstract The current research on the pelletization of fine-grained iron ore concentrate mainly focuses on the production of acidic pellets. To further improve the industrial application of fine-grained iron ore concentrate and to relieve the resource pressure of pellet production, the preparation of fusible pellets using fine-grained iron ore concentrate under different methods was investigated. The results show that: the fusible pellets prepared from fine-grained iron ore concentrate with 0.8-1.2 alkalinity and bentonite with limestone have better pellet quality, with a drop strength of 7.3 times/0.5 m and compressive strength of 16 N/pc, while the pellets prepared with slaked lime as binder and flux require an alkalinity greater than 1.0 to meet the production standard. Based on the model fitting results, the molten pellets with bentonite and limestone added to the fine-grained iron ore concentrate had a longer drying completion time than the molten pellets with slaked lime only, which were 360 s and 270 s. Based on the model fitting results, the molten pellets with slaked lime only had a higher water transfer and diffusion coefficient with Bi value less than 0.1, and the temperature distribution inside the raw pellets tended to be uneven during the drying process. Whether bentonite or slaked lime is used as binder for the production of fine-grained concentrate fusible pellets, a higher roasting temperature is required to promote the formation of large continuous crystals between hematite ores, and the strength of bentonite pellets with limestone is 3 656 N/pc and slaked lime pellets is 3 398 N/pc at a roasting temperature of 1 250 ℃. At 0.8-1.2 alkalinity, compared to the addition of bentonite and limestone, the addition of slaked lime only The fine-grained iron ore concentrate fusible pellets with slaked lime will slightly reduce the pellet reduction, but can improve the reduction swelling and reduction pulverization of the pellets, and the fine-grained iron ore concentrate fusible pellets prepared by both methods have good metallurgical properties.
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Received: 13 March 2023
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[1] 王新东,金永龙. “双碳”背景下高炉使用高比例球团的展望[J]. 过程工程学报,2022,22(10):1379.(WANG X D,JIN Y L. Prospect on high ratio pellet utilized in blast furnace under the background of carbon peaking and carbon neutrality[J]. The Chinese Journal of Process Engineering,2022,22(10):1379.) [2] 王新东,金永龙. 高炉使用高比例球团的战略思考与球团生产的试验研究[J]. 钢铁,2021,56(5):7.(WANG X D,JIN Y L. Strategy analysis and testing study of high ratio of pellet utilized in blast furnace[J]. Iron and Steel,2021,56(5):7.) [3] 赵连达,刘迎立,苏鸿,等. 添加赤铁矿对碱性球团性能的影响[J]. 中国冶金,2021,31(3):11.(ZHAO L D,LIU Y L,SU H,et al. Effect of adding hematite on properties of alkaline pellets[J]. China Metallurgy,2021,31(3):11.) [4] 张福明. 炼铁系统低碳技术发展前景与途径[J]. 钢铁, 2022,57(9):11.(ZHANG F M. Development prospects and methods on low-carbon technology in ironmaking system[J]. Iron and Steel,2022,57(9):11.) [5] 邵远敬,徐蕾,刘校平,等. 中国钢铁生产“碳中和”解决方案探讨[J]. 中国冶金,2022,32(4):1.(SHAO Y J,XU L,LIU X P,et al. Discussion on solution of "carbon neutrality" in China's steel production[J]. China Metallurgy,2022,32(4):1.) [6] BAI K,LIU L,PAN Y,et al. A review: Research progress of flux pellets and their application in China[J]. Ironmaking and Steelmaking,2021,48(9):1048. [7] ZHU D,WANG D,PAN J,et al. Utilization of hydrated lime as binder and fluxing agent for the production of high basicity magnesium fluxed pellets[J]. ISIJ International,2022,62(4):632. [8] 乔红梅,张建良,王耀祖,等. 国内外钙质碱性球团生产实践及发展趋势[J]. 钢铁研究学报,2021,33(10):1031.(QIAO H M,ZHANG J L,WANG Y Z,et al. Production practice and development trend of calcareous alkaline pellets around the world[J]. Journal of Iron and Steel Research,2021,33(10):1031.) [9] 田筠清,青格勒,刘长江,等. 使用石灰石生产低硅碱性球团矿试验[J]. 中国冶金,2018,28(4):13.(TIAN J Q,QING G L,LIU C J,et al. Production experiment of low silica alkaline pellet by limestone[J]. China Metallurgy,2018,28(4):13.) [10] PAL J,ARUNKUMAR C,RAJSHEKHAR Y,et al. Development on iron ore pelletization using calcined lime and MgO combined flux replacing limestone and bentonite[J]. ISIJ International,2014,54(10):2169. [11] PRUSTI P,BARIK K,DASH N,et al. Effect of limestone and dolomite flux on the quality of pellets using high LOI iron ore[J]. Powder Technology,2021,379:154. [12] PAL J. Innovative development on agglomeration of iron ore fines and iron oxide wastes[J]. Mineral Processing and Extractive Metallurgy Review,2019,40(4):248. [13] 易毅辉,张津,张鑫,等. 煤基胶体复合黏结剂制备钒钛磁铁矿球团的研究[J]. 中国矿业大学学报,2022,51(3):445.(YI Y H,ZHANG J,ZHANG X,et al. Study of preparation of vanadium-titanium magnetite pellets using coal-based colloidal composite binder[J]. Journal of China University of Mining and Technology,2022,51(3):445.) [14] 于洪军,路明,王兴锋,等. 铁矿粉粒度组成对球团矿性能影响的研究进展[J]. 冶金能源,2022,41(1):21.(YU H J,LU M,WANG X F,et al. Research progress on the effect of iron fine particle size on pellet properties[J]. Energy for Metallurgical Industry, 2022,41(1):21.) [15] ZHANG F,ZHU D,PAN J,et al. Improving roasting performance and consolidation of pellets made of ultrafine and super-high-grade magnetite concentrates by modifying basicity[J]. Journal of Iron and Steel Research International,2020,27:770. [16] 温宝良,张晓萍,刘德楼,等. 含硼磁铁矿对超细粒级磁铁矿球团性能的影响[J]. 钢铁,2022,57(11):33.(WEN B L, ZHANG X P, LIU D L,et al. Effect of boron-containing magnetite on properties of ultrafine-grained magnetite pellets[J]. Iron and Steel,2022,57(11):33.) [17] 朱德庆,徐梦杰,潘建,等. 改善超细铁精矿成球性能的实验研究[J]. 钢铁研究学报,2017,29(9):704.(ZHU D Q,XU M J,PAN J,et al. Experimental research to improve ballability of ultrafine concentrate[J]. Journal of Iron and Steel Research,2017,29(9):704.) [18] YANG C,ZHU D,PAN J,et al. Oxidation and induration characteristics of pellets made from western australian ultrafine magnetite concentrates and its utilization strategy[J]. Journal of Iron and Steel Research International,2016,23(9):924. [19] 潘建,田宏宇,朱德庆,等. 超微细铁精矿的粒度特性和润湿性对其成球性能的交互影响[J]. 工程科学学报,2017,39(6):830.(PAN J,TIAN H Y,ZHU D Q,et al. Particle size and wettability effect of ultrafine magnetite concentrate on ballability[J]. Chinese Journal of Engineering,2017,39(6):830.) [20] 朱德庆,周冰致,王召元,等. 西澳超细粒磁铁精矿特性及其对球团焙烧性能的影响[J]. 烧结球团,2016,41(6):38.(ZHU D Q,ZHOU B Z,WANG Z Y,et al. Characteristics of Western Australia Ultrafine(WAU) magnetite concentrates and their influence on pellet roasting performance[J]. Sintering and Pelletizing,2016,41(6):38.) [21] FAN X,ZHOU Z,WANG S,et al. Mineralization characteristics of pellets prepared by ultrafine magnetite concentrate: influence on metallurgical property and improving method[J]. Journal of Iron and Steel Research International,2023,30(3):446. [22] 范建军,张文平,刘慈光,等. 磁铁矿粉粒度对球团矿预热焙烧性能的影响[J]. 钢铁,2014,49(11):20.(FAN J J,ZHANG W P,LIU C G,et al. Effect of particle size distribution of magnetite concentrate on preheating and roasting parameters of pellet[J]. Iron and Steel,2014,49(11):20.) [23] 朱德庆,虎训,潘建,等. 优化配矿强化西澳超细粒磁铁精矿球团焙烧研究[J]. 工程科学学报,2017,39(5):683.(ZHU D Q,HU X,PAN J,et al. Optimization of feed blends to enhance the roasting performance of pellets made from Western Australian ultrafine magnetite concentrate[J]. Chinese Journal of Engineering,2017,39(5):683.) [24] 李亚飞, 杨涛, 刘在春, 等. 高压辊磨对含硫酸渣超细铁精粉生球性能的影响[J]. 钢铁研究学报,2022,34(7):683.(LI Y F, YANG T, LIU Z C,et al. Effect of high pressure roller grinding on the green pellets properties of ultra-fine iron concentrate containing pyrite cinder[J]. Journal of Iron and Steel Research,2022,34(7):683.) [25] WONG G,FAN X,GAN M, et al. Improvement on the thermal cracking performance of pellets prepared from ultrafine iron ore[J]. Powder Technology, 2019,342:873. [26] 朱德庆,周文涛,潘建,等. 含硼磁铁矿强化巴西赤铁矿球团的制备[J]. 中南大学学报(自然科学版),2014,45(2):348.(ZHU D Q,ZHOU W T,PAN J, et al. Improving pelletization of Brazilian hematite by adding boron-containing magnetite[J] Journal of Central South University(Natural Science), 2014,45(2):348.) [27] 从俊强,温宝良,李家新,等. 消石灰对细粒级铁精矿球团性能的影响[J]. 钢铁,2023,58(5):1(CONG J Q, WEN B L, LI J X,et al. Effect of lime hydrate on the pellet properties of fine-grained iron ore concentrates[J]. Iron and Steel,2023,58(5):1) [28] 朱德庆,刘震,杨聪聪,等. MgO含量和来源对球团焙烧特性及冶金性能的影响[J]. 工程科学学报,2021,43(8):1116.(ZHU D Q,LIU Z,YANG C C,et al. Effect of magnesium oxide and its occurrence on the roasting and metallurgical performance of magnetite pellets[J]. Chinese Journal of Engineering,2021,43(8):1116) [29] KAWATRA S K,CLAREMBOUX V. Iron ore pelletization: Part I. Fundamentals[J]. Mineral Processing and Extractive Metallurgy Review,2022,43(4):529. [30] EISELE T C,KAWATRA S K.A review of binders in iron ore pelletization[J]. Mineral Processing and Extractive Metallurgy Review,2003,24(1):1. [31] ATHAYDE M,COTA M,COVCEVICH M. Iron ore pellet drying assisted by microwave: A kinetic evaluation[J]. Mineral Processing and Extractive Metallurgy Review,2018,39(4):266. [32] KAWATRA S K,CLAREMBOUX V. Iron ore pelletization: Part II. Inorganic binders[J]. Mineral Processing and Extractive Metallurgy Review,2022,43(7):813. [33] FAN X,GAN M,JIANG T,et al. Influence of flux additives on iron ore oxidized pellets[J]. Journal of Central South University of Technology,2010,17(4):732. [34] FIRTH A R,GARDEN J F,DOUGLAS J D. Phase equilibria and slag formation in the magnetite core of fluxed iron ore pellets[J]. ISIJ International,2008,48(11):1485. [35] 路明,陈小燕,王兴锋,等. 钙质添加剂对碱性球团性能的影响[J]. 冶金能源,2022,41(2):19.(LU M, CHEN X Y,WANG X F,et al. Effect of calcium additives on the performance of calcium fluxed iron ore pellets[J]. Energy for Metallurgical Industry,2022,41(2):19.) |
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