|
|
Effect of high-silicon iron ore on sintered on ore sintering process and metallurgical properties |
WU Ying, GAO Lihua |
Ironmaking Plant, Baosteel Co., Ltd., Shanghai 201900, China |
|
|
Abstract At present, the global iron ore price index continues to rise, the issue of low-quality iron ore resources and rising steel production demand that iron and steel companies are currently dealing with had a significant influence to maintain their stable development. The Baoshan sintering base of Baosteel steadily increased the usage of high silicon iron ore powder to achieve the strategy of blast furnace ironmaking resources, extend the procurement channels of ore resources, and strengthen the right to speak of Baowu ore resources procurement. Nevertheless, the effect of increasing the proportion of high-silica iron ore powder on the sintering mechanism and the formation mechanism of compound calcium ferrate (SFCA) is not clear, so based on a high proportion of high-silica iron ore sintering test to research. The effect of high silica-type iron ore on the generation mechanism and solidification mechanism of SFCA as well as the metallurgical performance of sintered ore was researched using the micro sintering experiment, sintering cup test and the Baosteel sintering machine industrial test. The findings demonstrate that when the replacement ratio of high silica-type iron ore powder is raised to 12%, the assimilative temperature and liquid phase fluidity index increase gradually, but the decrease of the crystalline strength is more pronounced and decreases rapidly from 1 080.72 N to 745.79 N, which is primarily related to the formation of the silicate phase. The detrimental impact of silica on the formation of the binder phase was lessened with an increase in reaction time and temperature. The mass percent of ferrous iron increases from 8.7% to 9.1% as the proportion of high silica iron ore powder replacing Tubarang powder rises. This is due to an increase in calcium ferrate, which reduces the production of calcium silicate and iron olivine and improves the fluidity of the liquid phase binder phase. Consideration of the ideal high silica iron ore powder replacement ratio should be less than 12%. The results can provide theoretical guidance and a reference basis for the sintering of high silica iron ore and benefit the economical material strategy.
|
Received: 31 May 2023
|
|
|
|
[1] 张招崇,李厚民,李建威,等. 我国铁矿成矿背景与富铁矿成矿机制[J]. 中国科学:地球科学,2021,51(6):827.(ZHANG Z C,LI H M,LI J W,et al. Geological settings and metallogenesis of high-grade iron deposits in China[J]. Scientia Sinica(Terrae),2021,51(6):827.) [2] 陈景明.梅钢烧结绿色低碳技术实践[J].冶金能源,2023,42(5):17.(CHEN J M. Practice of green and low carbon sintering technology in Meigang[J]. Energy for Metallurgical Industry,2023,42(5):17.) [3] 张琦,沈佳林,许立松. 中国钢铁工业碳达峰及低碳转型路径[J]. 钢铁,2021,56(10):152.(ZHANG Q,SHEN J L,XU L S. Carbon peak and low-carbon transition path of China's iron and steel industry[J]. Iron and Steel,2021,56(10):152.) [4] 赵沛,董鹏莉. 碳排放是中国钢铁业未来不容忽视的问题[J]. 钢铁,2018,53(8):1.(ZHAO P,DONG P L. Carbon emission cannot be ignored in future of Chinese steel industry[J]. Iron and Steel,2018,53(8):1.) [5] 刘丽娜. 碱度对石钢烧结矿矿相结构及冶金性能的影响[J]. 钢铁钒钛,2021,42(3):125.(LIU L N. Influence of basicity on mineralogical microstructure and metallurgical property of sinter in Shijiazhuang Iron and Steel[J]. Iron Steel Vanadium Titanium,2021,42(3):125.) [6] 林恩玉. 高配比褐铁矿烧结工艺优化试验研究[J]. 烧结球团,2020,45(2):15.(LIN E Y. Experimental study on sintering process optimization of high ratio limonites[J]. Sintering and Pelletizing,2020,45(2):15.) [7] 妥建德,侯名强,付光军.高硅烧结矿适宜碱度及经济性[J]. 钢铁,2018,53(3):16.(SUI J D,HOU M Q,FU G J. Optimum basicity and economy of high silicon sinter[J]. Iron and Steel,2018,53(3):16.) [8] 杜亮,韩秀丽,张全胜,等. 外矿型烧结矿矿相结构与冶金性能的定量关系[J]. 钢铁,2020,55(6):38.(DU L,HAN X L,ZHANG Q S,et al. Quantitative relation between mineralogical structure and metallurgical properties of sinter of import iron ore[J]. Iron and Steel,2020,55(6):38.) [9] 秦洋洋,王涛,刘正勇,等. 优化进口矿粉与钒钛精粉比例提高烧结矿冶金性能的研究[J]. 四川冶金,2021,43(5):4.(QIN Y Y,WANG T,LIU Z Y,et al. Study on optimizing the ratio of imported ore powder and vanadium-titanium powder to improve the metallurgical properties of sinter[J]. Sichuan Metallurgy,2021,43(5):4.) [10] 牛乐乐,刘征建,张建良,等. 铁矿粉矿物组成对烧结矿冶金性能的影响[J]. 钢铁,2019,54(9):27.(NIU L L,LIU Z J,ZHANG J L,et al. Effect of mineral composition of iron ore on metallurgical properties of sinter[J]. Iron and Steel,2019,54(9):27.) [11] 张国柱,杨锦涛,闫龙飞,等. 铁酸钙及其复合体系的研究进展[J]. 铸造技术,2017,38(3):497.(ZHANG G Z,YANG J T,YAN L F, et al. Research progress of calcium ferrite and its composite system[J]. Foundry Technology,2017,38(3):497.) [12] 孟凡俭,孙长余,李廷乐,等. 烧结矿中复合铁酸钙形成影响因素[J]. 钢铁,2018,53(7):16.(MENG F J,SUN C Y,LI Y L,et al. Formation and influencing factors of silico-ferrite of calcium and aluminum in sinter[J]. Iron and Steel,2018,53(7):16.) [13] 陈小龙,高立华.富氢还原对烧结矿低温还原粉化的影响[J].冶金能源,2022,41(4):27. (CHEN X L,GAO L H.Effect of rich hydrogen reduction on low temperature reduction disintegration of sinters[J].Energy for Metallurgical Industry,2022,41(4):27.) [14] 胡长庆,韩涛,师学峰. 含铝铁酸钙CFA的生成行为[J]. 钢铁,2020,55(8):70.(HU C Q,HAN T,SHI X F. Formation behavior of calcium ferrite containing aluminum[J]. Iron and Steel,2020,55(8):70.) [15] YANG S P,LIU H J,SUN H X,et al. Study on influencing factors of high-temperature basic characteristics of iron ore powder and optimization of ore blending[J]. Materials, 2022,15(9):3329. [16] 杨涛,龙红明,丁成义,等. 铝硅比对烧结成矿特性及冶金性能的影响[J]. 钢铁,2022,57(4):43.(YANG T,LONG H M,DING C Y,et al. Effect of w(Al2O3)/w(SiO2) on sintered ore mineralization characteristics and metallurgical properties[J]. Iron and Steel,2022,57(4):43.) [17] MENG F J, SUN C Y, LI T L, et al. Primary slag formation behavior during reduction process of SFCA-I and SFCA[J]. Journal of Iron and Steel Research International, 2022,29(11):1748. [18] 陈子罗,张建良,张亚鹏,等. 烧结矿适宜的SiO2质量分数和碱度[J]. 钢铁,2016,51(12):8.(CHNE Z L, ZHANG J L, ZHANG Y P, et al. Influence of basicity and w(SiO2) on sinter mineral quality[J]. Iron and Steel,2016,51(12):8.) [19] 范晓慧,孟君,陈许玲,等. 铁矿烧结中铁酸钙形成的影响因素[J]. 中南大学学报(自然科学版),2008,39(6):1125.(FAN X H,MENG J,CHEN X L,et al. Influence factors of calcium ferrite formation in iron ore sintering[J]. Journal of Central South University(Natural Science),2008,39(6):1125.) [20] 张芳,李荣,罗果萍,等. 包钢低硅烧结矿的冶金性能[J]. 钢铁研究学报,2013,25(2):4.(ZHANG F, LI R,LUO G P,et al. Metallurgical property of low silicon sinter in Baotou Ion and Steel[J]. Journal of Iron and Steel Research,2013,25(2):4.) [21] 傅菊英,王荣成. 高铁低硅烧结技术研究[J]. 钢铁,2007,42(6):17.(FU J Y,WANG R C. Study on production of high Fe and low SiO2 sinter[J]. Iron and Steel,2007,42(6):17.) [22] 李光森,金明芳,姜鑫,等. 烧结矿粘结相流动性的研究[J]. 中国冶金,2008,18(5):20.(LI G S,JIN M F,JIANG X,et al. Study on fluidity of binging phase sinter[J]. China Metallurgy,2008,18(5):20.) [23] 杨聪聪,朱德庆,潘建,等. 铁矿石高温烧结基础特性评价方法的国外研究进展[J]. 钢铁,2022,57(5):11.(YANG C C,ZHU D Q,PAN J,et al. Overseas research advances in evaluation methods of high-temperature fundamental sintering characteristics of iron ores[J]. Iron and Steel,2022,57(5):11.) [24] GAO L H, LIU P X, ZHAN W, et al. New understanding on formation mechanism of CaFe2O4 in Fe2O3-Fe3O4-CaO-SiO2 system during sintering process: Phase transformation and morphologies evolution[J]. Advanced Powder Technology,2022,33(10):103712. [25] 王永红,孙立伟,于原浩,等. 不同SiO2质量分数精粉对烧结指标的影响[J]. 中国冶金,2019,29(5):10.(WANG Y H,SUN L W,YU Y H,et al. Influence of different SiO2 mass fraction of fine powder on sinter index[J]. China Metallurgy,2019,29(5):10.) [26] 苏立新,吴胜利,翟晓波,等. 巴西某高硅铁矿粉对烧结黏结相流动性及劣质矿物的影响[J]. 中国冶金,2020,30(1):18.(SU L X,WU S L,ZHAI X B,et al. Effect of high-silica iron ore from Brazil on fluidity and inferior minerals of sintered binding phase[J]. China Metallurgy,2020,30(1):18.) [27] 宋鹤锴,吴胜利,周恒. 铁矿烧结黏结相气孔率影响因素分析[J]. 中国冶金,2019,29(5):15.(SONG H K,WU S L,ZHOU H,et al. Analysis of influence factors of porosity of sintered bonding phase in iron ore[J]. China Metallurgy,2019,29(5):15.) [28] 赵长奕,白晓光,付国伟. 包钢烧结配加高硅熔剂性褐铁矿的试验研究[J]. 包钢科技,2022,48(1):22.(ZHAO C Y,BAI X G,FU G W. Experimental study on adding high silicon fluxed limonite into sintering of Baotou Steel[J]. Science and Technology of Baotou Steel,2022,48(1):22.) [29] 张国成,罗果萍,宋巍,等. MgO对烧结矿液相形成性能和微观结构特性的影响[J]. 中国冶金,2021,31(10):8.(ZHANG G C,LUO G P,SONG W,et al. Effect of MgO on liquid phase formation properties and microstructure of sinter[J]. China Metallurgy,2021,31(10):8.) [30] 肖志新. 低质铁矿烧结成矿机理及配料结构研究[D]. 武汉:武汉科技大学,2018.(XIAO Z X. Research on the Mineralization Mechanism and Sinter Proportioning with Inferior Iron Ores[D]. Wuhan:Wuhan University of Science and Technology,2018.) [31] 田硕. 巴西卡矿粉和杨迪矿粉的烧结基础特性及优化配矿研究[D]. 包头:内蒙古科技大学,2020.(TIAN S. Study on the Basic Sintering Characteristics and Optimized Ore Blending of Brazilian Card Orepowder and Yangdi Ore Powder[D]. Baotou:Inner Mongolia University of Science and Technology,2020.) [32] 罗果萍,贾晓斌,吴胜利,等. K和Na对白云鄂博铁精矿烧结连晶特性的影响[J]. 钢铁研究学报,2014,26(3):32.(LUO G P,JIA X B,WU S L,et al. Effect of K and Na on sinter crystal-intensity of baiyunebo iron ore concentrates[J]. Journal of Iron and Steel Research,2014,26(3):32.) [33] 史先菊,王强,李光强,等. 熔剂颗粒在烧结过程中的特征演变及影响[J]. 钢铁,2021,56(12):28.(SHI X J,WANG Q,LI G Q,et al. Characteristic evolution and corresponding influence of flux particles in sintering process[J]. Iron and Steel,2021,56(12):28.) |
[1] |
SHEN Fengman, AN Haiwei, JIANG Xin, NI Jingfeng, ZHENG Haiyan, GAO Qiangjian. Research progress on sillico-ferrite of calcium and aluminum (SFCA) bonding phase in sintering process[J]. Iron and Steel, 2024, 59(2): 1-12. |
[2] |
FENG Junsheng1,CHENG Xinni1,WANG Huanhuan1,ZHAO Liang2,WANG Haitao1,DONG Hui2. Working medium selection and thermal economic analysis of low temperature flue gas waste heat ORC system[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2023, 35(9): 1174-1183. |
[3] |
ZHANG Zhen, TANG Jue, CHU Mansheng, LIU Zhenggen, LI Fumin, LÜ Qing. Long short term comprehensive prediction of sinter FeO components based on EEMD and machine learning[J]. Iron and Steel, 2023, 58(8): 32-40. |
[4] |
BAO Guoying, LIU Lei, HAN Xiuli, DUAN Bowen, QIN Liwen, LIU Yingying. Optimization of sintering ore blending by response surface-satisfaction function method[J]. Iron and Steel, 2023, 58(8): 41-50. |
[5] |
WEI Xin1,2,GUO Xingmin1,2. Effect of basicity on composition and microstructure of reaction products in Fe2O3-CaO-SiO2 system[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2023, 35(7): 832-839. |
[6] |
HOU Jian, BAI Chenguang, HU Meilong, LIU Xiaoming, HUANG Xiaobo, GUO Lanfen. Optimization on ore-blending of PMC concentrate and two typical limonite ores[J]. Iron and Steel, 2023, 58(6): 45-52. |
|
|
|
|