25 October 2025, Volume 37 Issue 10
    

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    Reviews
  • BAO Jiwei, CHU Mansheng, DENG Yong, WANG Yuqi, TIAN Chen, LI Haoyu, WANG Jiacheng
    Journal of Iron and Steel Research. 2025, 37(10): 1257-1272. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250053
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    Iron coke as a new type of low-carbon ironmaking raw material, has a good reactivity. The use of appropriate amount of iron coke in blast furnaces (BF) can improve gas utilization efficiency and strengthen energy conservation and carbon emission reduction. Iron coke needs to have high mechanical strength and high reactivity to meet the requirements of production, transportation, and low-carbon blast furnace smelting of iron coke. Carbonization treatment is a key process for the transformation of iron ore-coal mixture into iron coke, which has a significant impact on the metallurgical properties of iron coke, such as mechanical strength and reactivity. The study of pyrolysis behavior and carbonization consolidation mechanism of iron coke is crucial for optimizing the metallurgical properties of iron coke. The research progress of pyrolysis behavior and carbonization consolidation mechanism of composite iron coke was reviewed. The current research results, the contents that need to be further studied and the prospect of theoretical research on iron coke carbonization consolidation were analyzed and summarized. To a certain extent, the key theoretical basis for the pyrolysis behavior and carbonization consolidation mechanism of iron coke has been summarized, which will theoretically clarify the carbonization process of iron ore-coal mixture into iron coke, promote the optimization of carbonization process technology path of iron coke, and advance the technology of iron coke preparation and its use in BF smelting.
  • Smelting and Working
  • CHEN Xuling, ZHANG Yujun, HUANG Xiaoxian, FENG Zhenxiang, PENG Zitang, FAN Xiaohui
    Journal of Iron and Steel Research. 2025, 37(10): 1273-1280. https://doi.org/10.13228/j.boyuan.issn1001-0963.20240337
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    The sinter yield is an important technical and economic index in sintering production, and its prediction in advance can provide important references for production operations. Based on feature selection and JITL-Optuna-KPLS, a prediction model of sinter yield was proposed for the high-dimensional, nonlinear and time-varying characteristics of sintering process. Firstly, the process knowledge and recursive feature elimination method were used for feature selection to obtain the optimal subset of sinter yield prediction features. Then, a JITL method using composite similarity measurement was proposed to extract small-scale prediction samples from historical data samples. The Optuna algorithm was used to optimize hyperparameters and establish a local model using kernel partial least squares method to predict the sinter yield. The experimental results show that the mean square error of the proposed model for sinter yield prediction is 0.18,coefficient of determination is 0.98, and the average relative error is 0.13%, which can meet the prediction accuracy of actual production.
  • HUANG Xu, ZHANG Jianliang, XU Runsheng, ZHANG Kaijun, WANG Yanmin, ZHU Jinfeng, YE Lian, YU Yang
    Journal of Iron and Steel Research. 2025, 37(10): 1281-1289. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250063
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    In order to study the influence of decarburization rate of circulating gas on the smelting process, a mathematical model was established based on the process of gas circulating oxygen blast furnace. The effects of different decarburization rates such as 100%, 98%, 96%, 94%, 92% and 90% of circulating gas on theoretical combustion temperature, coke ratio, direct reduction degree, gas distribution and carbon emission were analyzed. The results show that the theoretical combustion temperature increases by about 14-15 ℃, the coke ratio increases by about 1.46 kg/t, and the direct reduction degree increases with the decrease of 1% decarburization rate. The amount of gas in the hearth increased by about 2.47 m3/t, the amount of gas in the bosh and just entering the furnace body increased by about 2.60 m3/t, and the amount of gas in the top of the furnace increased by about 0.18 m3/t. As the decarbonization rate decreases, carbon emissions gradually increase. For every 1% reduction in decarburization rate, the total carbon emissions increase by about 1.01 m3/t. The carbon consumption in the internal area of the blast furnace, including the total carbon consumption per ton of iron into the furnace, direct reduction carbon consumption, desulfurization carbon consumption, and melting loss reaction carbon consumption, all showed an increasing trend. The carbon content of combustion in front of the tuyere showed a decreasing trend, and the carbon content of molten iron remained unchanged.
  • ZHANG Chengbo, ZHANG Dandan, SONG Yancheng, JI Yuzhong, SHAO Lei, ZOU Zongshu
    Journal of Iron and Steel Research. 2025, 37(10): 1290-1298. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250073
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    The carburization of hot metal by deadman coke in the blast furnace hearth is decisive for the hot metal carbon content. The influence of the different voidage ratios of the deadman on the flow and carburization behaviors in the hearth is of great significance to the study of the uneven erosion of the hearth lining and fluctuation of the hot metal carbon content. The flow and carbonization behavior of hot metal in the hearth were studied by using CFD numerical simulation technology under the conditions of voidage ratios. The results show that the flow rate and carbon content of hot metal in the peripheral region under different voidage ratios are relatively different. With the decrease of the voidage ratio of the deadman, the carbon content of the hot metal deteriorates, and the carbon dissolution erosions of the hearth lining become more severe. Under the voidage ratio of 0.4, 0.5, 0.6 and 0.7, the tapped hot metal carbon mass fraction is 4.15%, 4.23%, 4.32% and 4.43%, respectively.
  • MA Suwei, LI Qiang
    Journal of Iron and Steel Research. 2025, 37(10): 1299-1309. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250089
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    To addressneeds of cost reduction and efficiency improvement in hot metal desulfurization steel enterprises for optimizing the energy efficiency characteristics of the KR(Kanbara Reactor) pretreatment of hot metal process holds significant value.The multiphase flow behavior during KR desulfurization through both water modeling and numerical simulation isinvestigated.The dynamic behavior of slag dispersion and the energy consumption characteristics during KR stirring areexamined, proposing two key evaluation metrics: stirring power density and desulfurization energy efficiency index. These metrics enable comprehensive assessment of both energy consumption patterns and efficiency indicators in KR hot metal desulfurization. Effects of impeller type, rotation speed, immersion depth and density of desulfurization flux on the power density and desulfurization efficiency index were investigated, which reflect the power consumption and efficiency features at different agitation parameters.The results show that increasing rotation speed or aspect ratio of impeller causes significant increase in power consumption, while changing impeller immersion depth or desulfurization flux has almost no effect.When investigating the desulfurization efficiency characteristics, it is found that the desulfurization efficiency index is closely related to the impeller rotation speed.The desulfurization efficiency index increases first and then decreases with impeller rotation speed increasing from 50 to 80 r/min.The maximum efficiency index occurs at the rotation speed of 60 r/min.The desulfurization efficiency of KR significantly decreases with the increase in impeller aspect ratio, which means that improving the desulfurization performance of KR by increasing the aspect ratio of impeller blades is achieved at the cost ofmore stirring energy.The desulfurization efficiency of desulfurization flux increases first and then decreases with the immersion depth increasing and the maximum efficiency index occurs at the immersion depth of 1 815 mm.Increasing density of desulfurization flux can promote the dispersion of desulfurization flux and enhance the refining efficiency.
  • ZHU Qingtong, DING Wei, LI Yan
    Journal of Iron and Steel Research. 2025, 37(10): 1310-1321. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250068
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    Medium-high manganese steel has become the preferred material for automobile steel due to its high strength-plasticity synergistic effect and lightweight characteristics. However, it faces severe challenges in industrial smelting.The redox reaction between slag SiO2 and Mn in molten steel during refining process significantly leads to the failure of composition control such as [Si] and (MnO). In order to solve this problem, the thermodynamic equilibrium model of CaO-SiO2-Al2O3-MgO quaternary slag system and Fe-xMn (x=5%,10%,20%,30%) system was constructed based on FactSage thermodynamic software. Under the condition of 1 600 ℃ and steel slag ratio of 10∶1, the interaction mechanism of basicity (R=CaO/SiO2=1—6) and Al2O3 content (20%-50%) on slag-metal reaction was systematically investigated. The key parameters such as SiO2 activity (aSiO2), MnO content and desulfurization efficiency in the slag were analyzed. The regulation of refined slag composition on slag-metal reaction was clarified, and the optimal design scheme of slag system was proposed. The results show that increasing the basicity can significantly reduces the activity of SiO2, inhibits the reaction 2[Mn]+(SiO2)=[Si]+2(MnO), and reduces the MnO content in the slag from 19.7% when R=1 to 2.3% when R=6. In order to maintain the stability of the refined slag component, the basicity should be controlled to be greater than 4. Al2O3 exhibits significant amphoteric behavior. When Al2O3 is acidic, its acidic characteristics will weaken the effective basicity, resulting in an increase in SiO2 activity and a sharp increase in MnO content. The MnO content can be controlled at the lowest value by synergistic regulation of basicity and Al2O3 content. When refined slag(R=6, w(Al2O3)=30%) reacts with 30%Mn steel, the MnO content is 2.1%. For 0.03S steel, when the basicity of refined slag is 5-6 and Al2O3 content is 27%-30%, the desulfurization efficiency is the best, but it is necessary to control w(MnO)≤2% to avoid the significant deterioration of desulfurization effect. Under the condition of satisfying the control of MnO content and the best desulfurization efficiency, the optimized slag system is suitable for the smelting of medium and high manganese steel with w(Mn)≤28%.
  • ZHANG Di, WEI Zijian, WANG Zhihao, WANG Xudong, YAO Man
    Journal of Iron and Steel Research. 2025, 37(10): 1322-1333. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250070
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    The size and distribution of non-metallic inclusions all affect slab quality, making it crucial to accurately predict the capture of inclusions at the advancing solidification front. The prediction model of inclusions in the whole process of slab continuous casting was established, and the movement, removal and capture process of inclusions were simulated.On the basis of summarizing the capture rules proposed by the predecessors, the dynamic behavior that a part of the inclusions will break away from the dendrite and then return to the molten steel after entering the solidification front was considered. An improved capture rule was proposed, which combines the four criteria of velocity distribution of molten steel at the solidification front, residence time and velocity direction of inclusions, and the solidified shell growth speed. Comparing the calculation results of the improved rule and the current rule with higher acceptance, both capture distributions show a ‘W’-shaped hollow band structure. Under this rule, the proportion of the number of inclusions captured in the mold to the total number of inclusions captured in the slab is reduced from 87.53% to 79.48%, which is due to the consideration of the residence time of inclusions in the solidification front and the high-speed flow of molten steel within 0-0.4 m below the meniscus. There are obvious inclusion aggregation bands at 3-5 mm from the narrow surface and the wide surface of the slab, which is consistent with the actual observation of the factory. The improved inclusion trapping rules and numerical calculation model accurately show the inclusion aggregation of the actual continuous casting billet, which is a useful advance in accurately predicting the inclusion distribution of the continuous casting billet.
  • FENG Kongfang, LI Hualong, WANG Bo
    Journal of Iron and Steel Research. 2025, 37(10): 1334-1344. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250088
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    Twin-roll strip casting is one of the important development directions of near-net-shape casting technology. The flow and heat transfer behavior of molten steel in molten pool are affected by the structure of delivery system and process parameters in the process of twin-roll strip casting. ProCAST finite element software was used to study the influence of delivery system structure and process parameters on the flow and heat transfer of medium/low carbon steel. The result shows that the molten steel temperature near the side dam in the pool is too low, which will seriously affect the strip product quality. Adding a side hole structure in the delivery system can increase the temperature of the molten steel near the side dam in the molten pool, and increase the molten steel flow velocity in this area. For the improved delivery system, when the side hole outlet angle is 40°, Case 1 (side hole inlet velocity: 4.82 m/s, other hole inlet velocity: 1.03 m/s) can increase the temperature of molten steel near the side dam and reduce the extreme difference of the melt pool outlet temperature.
  • Materials Researc
  • MA Junjie, ZHANG Jihong, WANG Qiang, LIU Wenguang, WU Zhenkui
    Journal of Iron and Steel Research. 2025, 37(10): 1345-1358. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250120
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    Iron and steel is a pillar industry in China, and the production quality of steel products is key to the performance andprice. In order to solve the problems of poor accuracy, low efficiency and complex model structure in strip surface defect detection, we proposed a lightweight strip surface defect detection algorithm based on YOLOv11 (PSN-YOLO). Firstly, the P-GELAN_CAA feature extraction-fusion module was designed, and PSConv was introduced based on GELAN to process multi-scale information, optimize parameter utilization, and integrate CAA to enhance feature representation. Secondly, the lightweight and efficient SCDown downsampling was selected to expand the receptive field, reduce the information loss, and reduce the complexity of the model. Finally, NWD is used to improve the loss function of the bounding box, focusing on irregular and complex micro-texture features, so as to better measure the distribution similarity between the bounding boxes and improve the detection accuracy. Experimental results on the NEU-DET dataset show that compared with the benchmark model, the mAP of the proposed model is increased by 3.1%, and the number of parameters and computation are reduced by 20.3% and 19.0%, respectively, which better balances the detection accuracy and lightweight requirements. In addition, the model shows good generalization ability on the Severstal dataset, which meets the practical engineering needs and has important application value.
  • LIU Zhi, WANG Hui, WANG Cunyu, LI Changhao, ZHANG Xiaofeng, CAO Wenquan
    Journal of Iron and Steel Research. 2025, 37(10): 1359-1369. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250069
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    Fe-Mn-Al-C low-density steel exhibits structural characteristics suitable for military and automotive applications, where microstructural stability of welded joints is critical for large-scale application. Gas tungsten arc welding (GTAW/TIG welding) was employed to join 12 mm thick Fe-Mn-Al-C steel plates using a proprietary Fe-Mn-Al-C filler wire. Five welding currents (140, 170, 210, 240, 270 A) were systematically investigated to evaluate the effects of heat input parameters on the microstructure-property relationships of the joints. Microstructural characterization was performed via optical microscopy (OM)and scanning electron microscopy (SEM), while mechanical properties were assessed through microhardness profiling,tensile testing (per GB/T 228), and charpy V-notch impact testing. Macroscopic analysis revealed that defect-free joints with smooth surface morphology were achieved at currents exceeding 210 A. These joints demonstrated room-temperature tensile strength (Rm) not less than 616 MPa and exhibited ductile fracture mode,with low-temperature impact energy (KV2) not less than 62 J at -84 ℃. A quantitative correlationwas established among heat input, microstructure, and properties, providing a theoretical foundation for optimizing welding processes in low-density steels.
  • SHU Yuxin, CHEN Nana, LI Bo, XIAO Kui
    Journal of Iron and Steel Research. 2025, 37(10): 1370-1381. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250107
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    To investigate the corrosion behavior of hot-dip galvanized steel under the combined influence of chloride ions (Cl-) and sulfur dioxide (SO2), an accelerated corrosion test simulating a coastal industrial atmosphere was conducted. Mass loss measurements, electrochemical analysis, SEM, EDS, and XRD were employed to examine corrosion kinetics and product evolution. Results indicate that the corrosion products show a distinct layered structure, with a dense inner layer of Zn5(OH)8Cl2·H2O and a porous outer layer of NaZn4(SO4)Cl(OH)6·6H2O. Cl- promotes pitting initiation, while SO2 enhances acidity and drives the transformation of carbonate phases into sulfate/chloride composite salts. Cyclic wet-dry conditions accelerate cracking and spalling of the corrosion layer. Electrochemical results showthat the corrosion current density decreases and polarization resistance increases, indicating a temporary protective effect of the corrosion products.
  • WANG Yangbo, LI Wei, LI Jie
    Journal of Iron and Steel Research. 2025, 37(10): 1382-1394. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250113
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    To clarify the corrosive abrasive wear (CAW) mechanism of wear-resistant steels, the corrosion behavior,abrasive wear (AW) behavior, and CAW behavior of quenched-partitioned (Q-P) steels, quenched-tempered (Q-T) steels and high-manganese (Mn13Cr2) steels were studied. The results indicate that the wear weight loss of tested steels is mainly caused by the abrasive’s micro-cutting. However, as for the transformation of the matrix, their micro-cutting resistance depends on the hardness of the deformed layer formed in the worn subsurface. The nano-hardness of the deformed layers of Q-P, Q-T and Mn13Cr2 steels was 8.17/7.76, 8.23/7.88, and 8.11/6.61 GPa under the conditions of AW and CAW, respectively. Therefore, the ordering of the wear resistance of the three tested steels is consistent under both AW and CAW conditions:Q-T steel > Q-P steel > Mn13Cr2 steel. However, the corrosive solution accelerates the corrosion of the deformed layers, thereby inhibiting their formation and reducing their hardness. The CAW-induced weight loss for Q-T, Q-P, and Mn13Cr2 steels increased by 143.6, 173.8, and 304.1 mg, respectively, compared to AW conditions. The significant increase in corrosion-abrasive wear weight loss for Mn13Cr2 steel can be attributed to following reusons:(1) γ-Fe is more susceptible to forming lattice defects compared to the α-Fe. The lattice defect within the deformed layer could enhance its hardness, but also accelerate its corrosion. (2) The austenite content in Mn13Cr2 steel is 100%, significantly higher than the 2.7% in Q-T steel and 9.2% in Q-P steel.
  • Energy and Environmental Protection
  • LIN Xianghai, WANG Guangwei, ZHANG Nan, LI Renguo, NING Xiaojun
    Journal of Iron and Steel Research. 2025, 37(10): 1395-1404. https://doi.org/10.13228/j.boyuan.issn1001-0963.20250052
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    The efficient recycling of waste plastics, a widely existing waste, is one of the issues that need to be focused on. The hydrothermal carbonization method was used to co-hydrothermally treat two common waste plastics, and the product performance was studied in detail. The results show that the co-hydrothermal carbonization of PVC and PET will increase the high calorific value and energy recovery rate. Increasing the carbonization temperature and the proportion of PVC can effectively increase the effective element content of hydrochar, reduce the volatile content and oxygen element content, and improve the quality of hydrochar. Increasing the carbonization temperature and the proportion of PET can reduce the Cl element content in hydrochar and increase the dechlorination rate. More Cl elements migrate to the liquid phase and gas phase. The addition of PET does not significantly promote the dechlorination reaction of PVC.With increasing the carbonization temperature and PVC ratio, the oxygen-containing functional groups in hydrochar decrease, the carbon-containing functional groups increase, and the order of the carbonaceous structure of hydrochar increases. The research results show that co-hydrothermal carbonization has a good effect in removing harmful elements.