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Shear thinning properties of calcium-aluminum-based mold flux containing B2O3 |
LIU Hao1,2, QI Jie1,2, LIU Cheng-jun1,2, JIANG Mao-fa1,2 |
1. Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry Education), Northeastern University, Shenyang 110819, Liaoning, China; 2. School of Metallurgy, Northeastern University, Shenyang 110819, Liaoning, China |
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Abstract To take into account the performance of the calcium-aluminum-based mold flux in regions of the mold with different shear rates, the shear-thinning properties of the CaO-Al2O3-Li2O-B2O3 mold flux were studied from the perspective of non-Newtonian fluid characteristics. The results show that in the shear-thinning temperature range, as the temperature decreased, the shear-thinning properties of the mold flux become stronger. In the calcium-aluminum-based mold flux, B2O3 had a significant inhibitory effect on the shear-thinning properties, which was opposite to its role in the silica-based mold flux. At 1 300 ℃, when the mass fraction of B2O3 increased from 4% to 6%, the shear-thinning properties gradually become weaker. When the mass fraction of B2O3 increased to 8%, the molten slag was transformed into a Newtonian fluid, showing no shear thinning properties.
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Received: 29 December 2020
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