欢迎访问《钢铁研究学报(英文版)》官方网站!今天是

2023年, 第30卷, 第6期 刊出日期:2023-06-25
  

  • 全选
    |
    综述
  • Zhong-qiu Liu, Jun Li, Pei-yuan Ni
    钢铁研究学报(英文版). 2023, 30(6): 1057-1058.
    https://doi.org/10.1007/s42243-023-00978-6
    摘要 ( )   可视化   收藏
  • Yu-chao Yao, Miao Liu, Zhong-qiu Liu, Bao-kuan Li, Yong Gan
    钢铁研究学报(英文版). 2023, 30(6): 1059-1072.
    https://doi.org/10.1007/s42243-023-00979-5
    摘要 ( )   可视化   收藏
    Advancements in metallurgical technology have led to the emergence of high-performance requirements for metal materials, like high uniformity, high purity, and superfine crystallinity. This has resulted in the development and application of internal cooling source (ICS), vibrational, and vibrational internal cooling source methods in metal solidification processes to afford products with refined crystal grains and large proportions of equiaxed crystals. These methods have gradually been introduced into laboratories and some steel mills over the past few decades. However, there are few successful industrial applications of these methods, as there is no comprehensive understanding of their control theories and principles. Accordingly, the development, basic principles, and classifications of the three types of methods are summarized, and their impact on the solidification of molten metals and the morphology of solid products is discussed. In addition, experimental and numerical simulation-based researches on each type of method are reviewed and their prospects for applications are briefly discussed to control metal solidification. Finally, detailed future perspectives are provided on vibratory strip feeding, ICS, and pulsed magneto-oscillation methods. Hopefully, it will serve as a reference for future studies of the application of these and related methods in metal solidification processes.
  • 论著
  • Yong-kun Yang, Jia-yu Zhu, Wei-an Wang, Yang Wang, Jian-li Wang, Guan-jie Wang, Xiao-ming Li1
    钢铁研究学报(英文版). 2023, 30(6): 1073-1089.
    https://doi.org/10.1007/s42243-023-00923-7
    摘要 ( )   可视化   收藏
    Central crack is a common quality defect in continuous casting strand, which is difficult to fully weld in the rolling and forging processes, and has become a key technical problem that restricts the stable production of high-end alloy rod/forging/pipe. In recent years, the central crack control has been one of the main focuses in high quality steel research. In order to fully understand the central crack, the research status of central crack characteristics, formation mechanism, influencing factors, and control methods in the world was reviewed. The deficiencies in the research of the central crack and the key research directions in the future were pointed out, which will provide references for other scholars in this field of research. It is found that alloying elements segregation during solidification and inclusions precipitated at grain boundaries are the main reasons for the central crack formation, while the unreasonable application of production processes can also induce the initiation of central crack. The optimization of alloying element composition and production process is helpful to reduce the initiation of central cracks. In addition, the quantitative characterization mechanism based on steel grades, temperature, stress, and other factors induced central crack should be established in the further study, forming a systematic quantitative determination criterion and control strategy for coupling the composition, process and thermal/ mechanical characteristic.
  • Cong-lin Yao, Hong-chun Zhu, Zhou-hua Jiang, Hua-bing Li, Hong-bin Lu, Shu-cai Zhang, Hao Feng
    钢铁研究学报(英文版). 2023, 30(6): 1090-1100.
    https://doi.org/10.1007/s42243-022-00864-7
    摘要 ( )   可视化   收藏
    Herein, a numerical simulation with simultaneous heat and mass transfers is carried out to investigate the scrap melting characteristics in molten steel after model verification by published experimental data. The numerical results show that the scrap melting stages consist of the frozen shell formation stage, the frozen shell remelting stage and the parent scrap melting stage. The heat transfer coefficient and the carbon mass transfer coefficient between the scrap and the molten steel are, respectively, in the range of 4209–6249 W m-2 K-1 and 6.4 × 10–5 m s-1. Meanwhile, the effects of process parameters on scrap melting time were studied. An increase in the scrap preheating temperature (Tscrap ), the molten steel temperature (Tsteel )and the carbon content of molten steel (Csteel) , and a decrease in the scrap thickness dscrap , can reduce the frozen shell existence time, as well as the scrap melting time. On this basis, a quantitative relationship between the aforementioned process parameters and the scrap melting time is obtained to predict the formation of frozen shell (W), which provides process guidance for shortening the scrap melting time. The quantitative relationship is expressed as: lnΨ=311.32-2.34lnTscrap -39.99lnTsteel -0.08lndscrap-0.57lnCsteel.
  • Yi-peng Sun, Hao-jian Duan, Li-feng Zhang
    钢铁研究学报(英文版). 2023, 30(6): 1101-1108.
    https://doi.org/10.1007/s42243-023-00957-x
    摘要 ( )   可视化   收藏
    A boundary layer model was developed to predict the capture of inclusions by steel–slag interface in a turbulent fluid flow, which is based on the detailed analysis of inclusion trajectories. The effective boundary layer for inclusion removal was proposed by a statistical method. It is noticed that the capture of inclusions by steel–slag interface is not only dependent on the diameter of inclusions but also related to the local turbulent conditions. In high turbulent flow fields, the transport of inclusions is mainly dominated by the turbulent flow, and thus, the effective boundary layer thickness is mainly affected by the level of turbulent kinetic energy and is almost independent of the inclusion diameter. The inertia of inclusions gradually takes over the stochastic effect of turbulent flow, and the effect of inclusion diameter on effective boundary layer thickness becomes more noticeable with the decrease in the level of turbulent kinetic energy. Besides, the effective boundary layer thickness is more susceptible to the inclusion diameter for larger inclusions due to its greater inertia under the same turbulent condition while it principally depends on the level of turbulent kinetic energy for smaller inclusions. As the characteristic velocity increases, the time for inclusions transport and interaction with steel–slag interface decreases, and thus, the effective boundary layer thickness decreases. Moreover, the graphical user interface was developed by using the cubic spline interpolation for ease of coupling the current boundary layer model with the macro-scale model of a turbulent fluid flow in the metallurgical vessel.
  • Ming-ming Li, Zhen-qiang Wu, Lin Li, Zong-shu Zou
    钢铁研究学报(英文版). 2023, 30(6): 1109-1116.
    https://doi.org/10.1007/s42243-023-00977-7
    摘要 ( )   可视化   收藏
    A mathematical model accounting for unsteady mass transfer across interface of a stationary iron droplet immersed into molten slag was established through the volume of fluid coupled with level set method. The Marangoni effect induced by mass transfer was reproduced successfully, and the hydrodynamic instability phenomena at the interface, such as the Marangoni convection flow, the evolution of the interfacial tension during the mass transfer, and the influence of Marangoni effect on the mass transfer rate, were revealed. The results show that the Marangoni convection flow develops quickly and behaves as an ordered structure in the forms of four pairs of the convection cell at the edge of the droplet once the oxygen transfer across the interface starts. The average convection flow velocity along the interface is high, even more than 0.025 m/s, depending on the droplet diameter, which facilitates the mass transfer. The Marangoni convection flow of the large droplet develops more easily than that of the small droplet, and the larger the droplet diameter is, the higher the convection flow velocity and the mass transfer rate are. Moreover, it is shown that the droplet diameter influences the impacting region of the Marangoni convection flow and its duration period.
  • Chao Lv, Xu-xin Chen, Zhao-xiang Ji, Hong-liang Zhao, Tao Yang, Lin-hui Yu
    钢铁研究学报(英文版). 2023, 30(6): 1117-1127.
    https://doi.org/10.1007/s42243-023-00984-8
    摘要 ( )   可视化   收藏
    The gas–liquid flow behavior of the stirred flow field, the different positions of a single bubble, the initial velocity, the surface tension and the agglomeration of multiple bubbles were studied by CFD numerical simulation. The results show that the pressure distribution and velocity distribution inside the fluid during agitation indicate that the velocity difference between the liquid and the gas phase and the collision between the bubbles caused by the turbulent behavior of the liquid are the important conditions leading to the bubble breakage. Different initial bubble positions and initial bubble velocities have important effects on single bubble breakage. The surface tension is an important condition that affects the bubble breakage. When the surface tension coefficient is 0.7, the bubble will be stretched to the smallest degree; when the surface tension coefficient is 0.1, the bubble will be stretched to the largest degree and it will be easily broken into smaller bubbles. The multi-bubble results show the states and trajectories of coalescence between bubbles. The research results can provide data support for the engineering application of desulfurization process and theoretical guidance for the research of bubble breaking mechanism.
  • Yi Wang, Yi-chen Dang, Xiao-qing Chen, Bao Wang, Zhong-qiu Liu, Jian-an Zhou, Chang-yong Chen
    钢铁研究学报(英文版). 2023, 30(6): 1128-1141.
    https://doi.org/10.1007/s42243-023-00943-3
    摘要 ( )   可视化   收藏
    As the width–thickness ratio of the discrete nozzle atomizer’s discrete hole greatly influences the loss of atomizing gas flow rate, the discrete nozzle atomizer was transformed into an annular slit atomizer with the same total nozzle outlet area. A numerical simulation study on the effect of various parameters on the atomization in the annular slit atomizer was carried out by coupling both the large eddy simulation (LES) and volume of fluid (VOF) model, which is based on the applicability of LES in capturing the breakup behavior of transient liquid droplets and the advantage of VOF method in directly capturing the phase interface. The simulation results showed that the increase in the atomization pressure makes the gas gain higher momentum, while the increase in the nozzle intersection angle decreases the distance between the nozzle exit and the computational domain axis. The increase in these two variables results in enhancing the gas–liquid interaction in the primary atomization zone and the formation of more aluminum droplets simultaneously. It is considered that the atomization effect becomes better when atomization pressure is 2.5 MPa, and the nozzle intersection angle is 60°. Industrial tests showed that the aluminum powder prepared by the optimized annular slit atomizer has a finer mean particle size and a higher yield of fine powder. The numerical simulation results agree well with the industrial test data of the powder particle size.
  • Jia-qi Liu, Yan-nan Dong, Pu Wang, Huan Zhao, Jing Pang, Xiao-yu Li, Jia-quan Zhang
    钢铁研究学报(英文版). 2023, 30(6): 1142-1155.
    https://doi.org/10.1007/s42243-022-00855-8
    摘要 ( )   可视化   收藏
    Based on computational fluid dynamics method, the effect of atomization gas pressure on the atomization efficiency of Laval nozzle was studied, and then a discrete phase model was established and combined with industrial trials to study the effect of a new type of assisted gas nozzles (AGNs) on powder size distribution and amorphous powder yield. The results show that increasing the atomization pressure can effectively improve the gas velocity for the Laval nozzle; however, it will decrease the aspiration pressure, and the optimal atomization pressure is 2.0 MPa. Compared with this, after the application of AGNs with the inlet velocity of 200 m s-1, assisted gas jet can increase the velocity of overall droplets in the break-up and solidification area by 40 m s-1 and the maximum cooling rate is increased from 1.9×104 to 2.3 ×104 K s-1. The predicted particle behavior is demonstrated by the industrial trails, that is, after the application of AGNs, the median diameter of powders d50 is decreased from 28.42 to 25.56 lm, the sphericity is increased from 0.874 to 0.927, the fraction of amorphous powders is increased from 90.4% to 99.4%, and only the coercivity is increased slightly due to the accumulation of internal stress. It is illustrated that the AGNs can improve the yield of fine amorphous powders, which is beneficial to providing high-performance raw powders for additive manufacturing technology.
  • Zhuang Liu, Wen-tao Lou, Miao-yong Zhu
    钢铁研究学报(英文版). 2023, 30(6): 1156-1170.
    https://doi.org/10.1007/s42243-023-00973-x
    摘要 ( )   可视化   收藏
    A transient numerical model was established to predict the dispersion, distribution, and circulation behavior of the powder injected through the up snorkel in a Ruhrstahl–Heraeus (RH) degasser. The effects of the powder diameter, the lifting gas flow rate, and the powder injection rate on the powder transport were investigated. Local powder concentration was measured by a cold model. The results showed that the predicted powder concentration agreed well with the measured. The powder injection process is divided into three periods, named dispersion period, aggregation and circulation period, and dynamically stable period according to the powder transport behavior. The powder diameter has a great effect on the particle dispersion. When the particles size changes from 30 to 500 μm, the powder dispersion characteristic index changes from 0.110 to 0.741, and the ladle top zone powder mass ratio changes from 0.118 to 0.685. The powder circulation mass flow rate increases to 101.0 kg min-1 (150 μm) and then decreases to 46.6 kg min-1 (500 μm). Powders with a diameter of more than 220 μm can change the steel flow mode in the RH degasser. Increasing the lifting gas flow could slightly improve the powder dispersion. Variation in the powder injection rate has almost no effect on the powder dispersion.
  • Jiang-shan Zhang, Bang-ming Qin, Yu-hong Liu, Quan-hui Li, Xiao-tan Zuo, Chao Wang, Shu-feng Yang, Qing Liu
    钢铁研究学报(英文版). 2023, 30(6): 1171-1181.
    https://doi.org/10.1007/s42243-023-00982-w
    摘要 ( )   可视化   收藏
    Numerical and physical models have been built and validated to study the multiphase flow inside three ladle shrouds and a four-strand tundish. A conventional straight ladle shroud and two types of trumpet-shaped ladle shroud (TLS) have been comparatively investigated. The maximum velocity at ladle shroud outlet reduces from 1.3 to 0.5 m/s, which indicates a quieter tundish pool. It is demonstrated that the use of a TLS can also decrease the maximum surface velocity from 0.16 to 0.13 m/s, which reduces the tendency of forming tundish open eye. The flow pattern and mixing behavior are improved inside the tundish, especially in enlarging the plug volume from 6.61% to 9.04%. The difference between the near and far outlets is narrowed when the TLS is applied. A computational program was developed to calculate characteristic parameters of different ladle shroud designs, and a dimensionless index was proposed to evaluate their mass and inner volume. Plant trials have been carried out, and the results showed that TLS can reduce level fluctuation in the pouring zone, which is beneficial to promoting better protective performance from secondary contamination and heat loss during continuous casting.
  • Qi Quan, Zhi-xiao Zhang, Tian-peng Qu, Xiang-long Li, Jun Tian, De-yong Wang
    钢铁研究学报(英文版). 2023, 30(6): 1182-1198.
    https://doi.org/10.1007/s42243-022-00884-3
    摘要 ( )   可视化   收藏
    Aiming at the problem that the existence of inclusions in the tundish continuous casting process can easily lead to quality defects of the slab, the stainless steel continuous casting tundish was taken as the research object. The effects of flow control device, inclusion density and inclusion size on the mixing characteristics of molten steel and inclusion behavior in tundish were studied. The results showed that compared with the tundish without flow control device, the average residence time of molten steel was prolonged by about 49 s, the dead zone volume fraction was reduced by 8.93%, and the piston fluid integral rate was increased by 12.68%. In the turbulence inhibitor (TI) tundish with weir–dam combination, the removal rate of inclusions with a density of 2700 kg m-3 and a particle size of 5 lm is 63.32%, while the removal rate of large inclusions with a density of 150 μm could reach 89.04%. When the inclusion particle size was 10–50 μm and the density was 2700–4500 kg m-3, the effect of inclusion density on inclusion removal rate was small. At the same time, when weir–dam combination TI tundish was set, the inclusions were mainly limited to the slag–metal interface of the first and second chambers of the tundish. The removal rate of inclusions in the first chamber was generally improved, with 10 μm inclusions accounting for 47.67% and 150 μm inclusions accounting for 60.69%. Furthermore, it has the best effect on the removal of small-size inclusions, especially those less than 70 μm.
  • Pu Wang, Hong Xiao, Xi-qing Chen, Hai-yan Tang, Jia-quan Zhang
    钢铁研究学报(英文版). 2023, 30(6): 1199-1210.
    https://doi.org/10.1007/s42243-023-00911-x
    摘要 ( )   可视化   收藏
    The electromagnetic, flow, heat transfer and inclusions motion model of the channel-type induction heating (IH) tundish was established, and the effect of the channel diameter on the metallurgical behavior of the tundish was studied. The results show that the magnetic field in the channel of the IH tundish tends to concentrate on the surface layer and the side near the coil. As the channel diameter is increased from 100 to 180 mm, the maximum value of magnetic flux density in the channel decreases by 0.125 T, and the maximum value of electromagnetic force decreases by 11.83 9 105 N m-3; however, the off-center distance of magnetic field increases by 9.4 mm, and the Joule heat in the channel decreases by 1004 kW, which leads to the reduction in temperature rising rate of the tundish from 1.41 to 0.59 K min-1. When the channel diameter is 100, 140 and 180 mm, the maximum velocity at the channel exit before heating is 0.59, 0.29 and 0.18 m s-1, and after heating for 1800 s, it is 1.52, 1.12 and 0.92 m s-1, respectively. In addition, the total inclusions escape ratio after heating for 1800 s with a channel diameter of 140 mm can be reduced by 12.39% compared to that before heating, and the maximum difference of escape ratios for each strand is only 4.51% and 5.32% before heating and after heating for 1800 s, respectively. Compared with the channel diameters of 100 and 180 mm, the channel diameter of 140 mm is more favorable to improve the metallurgical effect of the IH tundish.
  • Qing-hua Xie, Pei-yuan Ni, Toshihiro Tanaka, Mikael Ersson, Ying Li
    钢铁研究学报(英文版). 2023, 30(6): 1211-1221.
    https://doi.org/10.1007/s42243-023-00975-9
    摘要 ( )   可视化   收藏
    Flow field, heat transfer and inclusion behavior in a 700 mm round bloom mold under the effect of a swirling flow submerged entry nozzle (SEN) were investigated with the aim to enhance the casting process. The results indicate that the impinging flow phenomenon, which is commonly observed in conventional single-port SEN casting, was completely suppressed by the swirling flow SEN coming from a novel swirling flow generator design in tundish. Steel from the SEN port moved towards the mold wall in 360 direction, leading to a uniform temperature distribution in the mold. Compared to a conventional single-port SEN casting, the steel super-heat was decreased by about 5 K at the mold center, and the temperature was increased by around 3.5 K near the meniscus. In addition, the removal ratio of inclusions to the mold top surface in the swirling flow SEN casting was found to be increased. Specifically, the removal ratio of spherical inclusions with diameters of 1, 10, 50 and 100 μm was increased by 18.2%, 18.5%, 22.6% and 42.7%, respectively. Furthermore, the ratio was raised by 18.2%, 20.8%, 21.5% and 44.1% for non-spherical inclusions, respectively.
  • Rui-song Tan, Wei Liu, Bo Song, Shu-feng Yang, Yong-feng Chen, Xiao-tan Zuo, Yan Huang
    钢铁研究学报(英文版). 2023, 30(6): 1222-1233.
    https://doi.org/10.1007/s42243-023-00972-y
    摘要 ( )   可视化   收藏
    A coupled cellular automaton-finite element model was developed to simulate the solidification behavior and structure of 38CrMoAl large round bloom, in which mold electromagnetic stirring + final electromagnetic stirring was taken into consideration, under different superheat, casting speeds, and secondary cooling water flow. Industrial trials for infrared temperature measurement and macro etch experiments of the post-test round bloom samples were used to verify the simulated solidification structure and temperature field. The simulation results show that superheat and secondary cooling water flow have little influence on the surface temperature, center temperature, and center solid fraction while casting speed has a more obvious influence on solidification behavior. With the increase in the casting speed of 0.02 m min-1, the solidification position is prolonged by about 1.64 m. With the increasing specific water ratio by 0.02 L kg-1 each, the surface temperature of the secondary cooling zones decreases by about 18 °C, and the solidification position shortens by about 0.11 m. As the superheat increases from 10 to 40 °C, the ratio of the equiaxed crystal zone decreases from 35.98% to 23.98%. The casting speed and secondary cooling water flow increase the equiaxed crystal ratios of the large round bloom, but neither is significant, both being about 2%.
  • Dan-qing Jiang, Shu-jian Sun, Han Wu, Yang-jian Xu, Fu-hai Zhu, Zhen-qiang Zhang, Jiang Wang, Zhong-ming Ren
    钢铁研究学报(英文版). 2023, 30(6): 1234-1243.
    https://doi.org/10.1007/s42243-023-00971-z
    摘要 ( )   可视化   收藏
    With establishment of thermal and numerical simulation models, the influence of reduction amount on solidification structure, segregation and shrinkage porosity of continuous casting (CC) billets was investigated. The thermal–mechanical coupled simulation results indicated that with an increase in reduction amount, the temperature in the central area decreases, and the reduction efficiency firstly increases and then decreases, reaching the maximum value at reduction amount of 6 mm. Metallographic analysis showed that increasing the reduction amount is beneficial for the refinement of central solidification structure. Moreover, the internal cracks are more likely to appear at higher reduction efficiency. The X-ray computerized tomography results revealed that a higher reduction amount can significantly reduce the volume fraction and equivalent diameter of the central shrinkage porosities of CC billets and increase the sphericity of them. Simultaneously, the macrosegregation of carbon along the central line is improved as the reduction amount increases; while the reduction amount exceeds 8 mm, the segregation degree will not change any more.
  • Yang Liu, Jian-hua Liu, Yang He
    钢铁研究学报(英文版). 2023, 30(6): 1244-1257.
    https://doi.org/10.1007/s42243-022-00868-3
    摘要 ( )   可视化   收藏
    The reduction pretreatment process has been proposed to improve the center quality of large billet and reduce the rolling ratio. The microstructure evolution during the reduction pretreatment was further understood. The austenite grains were refined after the reduction pretreatment experiment, especially those at the center of the billet. The effects of strain and strain rate on the average grain size were dependent on the deformation temperature. At a strain rate of 0.01 s-1 and 1200 °C, the newly formed strain-free austenite grains grew very fast as the strain continued to increase, which resulted in the coarsening of austenite grains. The calculation results of the microstructure evolution model showed that at the same deformation temperature, the evolution curves of average grain size with different strain rates had the intersection points. With the increase in temperature, the position of intersection point moved to the downward direction of strain. The simulation results showed that when the reduction amount increased to 20%, the average grain size at the center was smaller than that near the surface. It could be inferred that when the reduction amount greatly exceeded 20%, the dynamic recrystallization at the center was mostly completed, and the austenite grain growth would become the main mechanism.
  • Fu-bin Liu, Xin-hao Yu, Hua-bing Li, Zhou-hua Jiang, Hong-chun Zhu, Xin Geng
    钢铁研究学报(英文版). 2023, 30(6): 1258-1267.
    https://doi.org/10.1007/s42243-023-00976-8
    摘要 ( )   可视化   收藏
    A numerical model coupled with a multi-physical field based on dynamic formation of slag skin is established. After validation by comparing the experimental and simulation results of depth of metal pool, slag skin thickness and melt rate, it is utilized to investigate the effect of melt current on the coupled multi-physical field, slag skin thickness, metal pool depth and the heat flow distribution during electroslag remelting (ESR) Inconel 625 solidification process. The results showed that with the increase in the melt current, the velocities of ESR system and the temperature of metal pool increased, whereas the highest temperature of slag bath firstly decreased and then increased. With the increase in the melt current, the slag skin thickness, metal pool depth and melt rate increased. Furthermore, the characteristics of the heat flow distribution and the effect of melt current on the heat flow distribution were analysed.
  • Dong-bin Jiang, Fu-zhong Yang, Jian Zhang, Yang Zhou, Li-feng Zhang
    钢铁研究学报(英文版). 2023, 30(6): 1268-1278.
    https://doi.org/10.1007/s42243-022-00862-9
    摘要 ( )   可视化   收藏
    The feeding parameters in the final stage of vacuum arc remelting process obviously affect the solute segregation and shrinkage pore depth. Coupled with the electromagnetic field, fluid flow, and solute transport, a numerical model was built to investigate the effect of feeding parameters on the ingot solidification phenomena. The Nb segregation and shrinkage pore depth in the solidified ingot were measured. The results show that the liquid moves along the solidification front and the vertex flow is formed in the liquid pool, which promotes solute transport. In the solidified ingot, the Nb segregation in the lower part is negative, while that in the upper part is positive. With the differential electrode applied, the positive segregation is slightly reduced but the segregation distribution remains unchanged. As the feeding current decreases, the positive segregation zone moves toward the ingot top surface, due to the final solidification position moving upward. With the feeding time extended, the positive segregation moves to the top surface and the shrinkage pore depth is reduced. As the feeding time is set at 12 min, the shrinkage pore depth can be reduced to 21 mm.
  • Yun-he Yu, Zheng-dong Liu, Zhen Liu, Zheng-zong Chen, Han-sheng Bao, Chi Zhang, Zhi-gang Yang
    钢铁研究学报(英文版). 2023, 30(6): 1279-1290.
    https://doi.org/10.1007/s42243-022-00854-9
    摘要 ( )   可视化   收藏
    The service performance of heat resistance steels is largely determined by the precipitation kinetics. The nucleation– growth–coarsening behaviors of precipitates in G115 martensitic heat resistance steel during long-term aging at 650 °C have been systemically investigated. The microstructural characteristics, precipitate morphology and alloying element distribution were studied by scanning electron microscopy, transmission electron microscopy and scanning transmission electron microscopy. The lognormal distribution fitting combined with the multiple regression analysis was adopted to evaluate the precipitate size distributions. Laves phase has longer incubation time, and its coarsening rate is almost one order of magnitude higher in comparison with that of M23C6 carbide. Furthermore, the nucleation rate, number density, average radius, and volume fraction of two precipitates are simulated based on the classical nucleation theory and the modified Langer-Schwartz model. The precipitation behavior of Laves phase can be well explained with the Fe–W system as the interfacial energy takes 0.10 J/m2. In contrast, the simulation results of M23C6 carbide in the Fe–Cr–C system are significantly overestimated, which results from the inhibitory effect of boron on coarsening.
  • Hai-hui Zhang, Hui-hui Xiong, Jing Qin, Jian-bo Zhang
    钢铁研究学报(英文版). 2023, 30(6): 1291-1299.
    https://doi.org/10.1007/s42243-023-00986-6
    摘要 ( )   可视化   收藏
    To reveal the mechanism of ferrite nucleation induced by Y2O2S inclusion in steel, the work of adhesion, interfacial energy, structure stability and electronic properties of Fe(111)/YY2O2S(001) interfaces with various terminations were first investigated using the first-principles calculations. Secondly, the steels with and without yttrium were prepared, while the rare earth yttrium-based inclusions in low carbon steel were characterized using an electron probe micro-analyzer, and the grain size of steel was analyzed using a scanning electron microscope with electron backscattered diffraction. The results show that the bonding strength of Fe/Y2O2S interfaces with S- and Y-terminations is stronger than that of the interface with O-terminations. The Fe–hcp–S interfaces with S-termination have the highest work of adhesion (4.01 J/m2) and the lowest interface distance (1.323 Å ). The Fe–hcp–S interface exhibits the highest stability, and its interfacial bonding force is mainly attributed to the strong hybridization of Fe-3d and S-2p orbitals in the energy range of - 7.5–0 eV. Moreover, the interfacial energy of Fe–hcp–S is substantially lower than those of the ferrite(s)/Fe(L) interface and the ferrite–austenite interface, suggesting that Y2O2S inclusions in steel can efficiently promote ferrite nucleation. The experimental observations demonstrate that the ferrite grain size of steel containing 0.03 wt.% Y is much more refined than that of the steel without yttrium, and the average grain size of steel with and without Y is 102 and 258 μm, respectively. This indicates that the results of our calculations match with experimental findings.