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25 May 2025, Volume 32 Issue 5
    

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    PREFACE
  • Huan Zhao, Chuan-bo Hu, Bin-bin Zhang, Yue Yin, Bei-yue Ma
    Journal of Iron and Steel Research International. 2025, 32(5): 1125-1126.
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  • ORIGINAL PAPERS
  • Zhang-yan Zhou, Bei-yue Ma, Xin Zhang, Yue Yin, Hong-tao Shen, Yu-xiang Wang, Chuan-bo Hu, Guang-ming Li, Cheng-cheng Zhang, Yong-li Liu, Guang-yi Zhao
    Journal of Iron and Steel Research International. 2025, 32(5): 1127-1138.
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    To improve the practical application of carbon steel, developing a superhydrophobic coating with outstanding mechanical properties is essential for effective corrosion resistance protection. Here, we obtained a robust superhy-drophobic anti-corrosion coating with a cauliflower structure by co-depositing the lauric acid with Ni ions and Mn ions onto a carbon steel through electrodeposition method. As demonstrated by the results, superhydrophobic Ni/Mn alloy (SNMAmit) displays a multi-hierarchical micro/nano cauliflower structure under the synergy of optimal parameters, exhibiting superb superhydrophobicity with contact angle of 161.9° and sliding angle of 6.2°. Surprisingly, the Tafel polarization curves in 3.5% NaCl showed that the corrosion potential of SNMAmit coating was 476 mV, and the corrosion current density was reduced from 1.39 9 10-5 to 5.89 9 10-7 A/cm2. The reduced corrosion current density of superhydrophobic Ni/Mn alloy (SNMA) indicates that SNMA coating can significantly enhance the anti-corrosion properties of carbon steel. In addition, after being subjected to various damages such as blade scraping, tape cyclic peeling, acid and alkalis, sandpaper cyclic abrasion, high temperatures, ultrasound, and graphite contaminant, SNMA showed good mechanical stability, interference resistance, heat resistance, and self-cleaning properties, which made it suitable for hostile conditions.
  • Hao Xie, Yu-nong Lei, Guo-jun Tang, Lin Hu, Ao Huang, Hua-zhi Gu, Lu Gan
    Journal of Iron and Steel Research International. 2025, 32(5): 1139-1150.
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    In order to simultaneously improve the oxidation resistance and the electrical conductivity of solid oxide fuel cell (SOFC) interconnectors, a composite coating of Co-W/NiO was fabricated on ferritic stainless steel by composite deposition and pre-oxidation. Based on phase identification and microstructural analysis, the novel coating was confirmed to effectively suppress Cr diffusion to form a compact Cr-rich layer. Thus, the oxidation rate has been reduced to 9.46 9 10-15 g2 cm-4 s-1, which showed a imporvement of 56.4% in oxidation resistance. The area specific resistance value of Co-W/NiO coated steel was evaluated as 27.6 m Ω cm2, much lower than that of Co-W coating as 53.38 m Ω cm2, which is adequate for SOFC application. Furthermore, the mechanism of the improvement has been investigated that the addition of NiO led to the formation of Ni-Co spinels and Ni-W composites, which affected the surface microstructure of the coating. Thus, the composite Co-W/NiO coated ferritic stainless steel exhibited the optimal combination for oxidation resistance and electrical conductivity.
  • Ye-sen Zhu, Shi-jie Yu, Si Chen, Bao-wen Hu, Chuan-min Wang, Yun-ze Xu, Yi Huang, Ming-yu Wang
    Journal of Iron and Steel Research International. 2025, 32(5): 1151-1162.
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    The corrosion behaviors of an as-cast FeCoNiAl0.75Cr1.25 high-entropy alloy (HEA) in acidic Na2SO4 solution with different pH values were investigated. The results indicate that the as-cast FeCoNiAl0.75Cr1.25 HEA is mainly composed of face-centered cubic phase, body-centered cubic (BCC1) phase (Co-Cr-Fe) and ordered BCC (B2) phase (Ni-Al), in which BCC1 phase and B2 phase have a eutectic microstructure. Moreover, the corrosion of B2 phase occurs preferentially in a 0.05 mol/L SO42- acidic solution. The electrochemical measurement results show that the corrosion resistance of the investigated HEA significantly changes as the solution pH increases from 2 to 2.5. This indicates that there is a critical pH in the range of 2-2.5 that affects the corrosion of HEA. In addition, the results of X-ray photoelectron spectroscopy prove that the surface film of FeCoNiAl0.75Cr1.25 in SO42- solution is formed with Al2O3 and Cr2O3 as the main components, and The content of Al2O3 and Cr2O3 increases with increasing solution pH.
  • Hao-jie Zhu, Jian-yang Han, Ke-wei Fang, Zhi-bin Zheng, Hui-ling Zhou, Lan-lan Yang, Yan-xin Qiao, Jian Chen, Jie Cui, Qiang Wang
    Journal of Iron and Steel Research International. 2025, 32(5): 1163-1175.
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    The corrosion behavior of CoCrCu0.1FeMoNi high entropy alloy (HEA) in 0.5 mol/L NaOH solution was investigated using X-ray photoelectron spectroscopy, X-ray diffraction, scanning electron microscopy, potentiodynamic polarization measurement, and electrochemical impedance spectroscopy. The results showed that the microstructure of this HEA displayed a dendritic morphology along with inter-dendritic regions. At the applied potential of -0.3, 0, and 0.1 V vs. saturated calomel electrode (SCE), no significant damage to the surface of the alloy was observed. At the applied potentials of 0.15 and 0.2 V vs. SCE, selective detachment and tearing of the microstructure on the alloy surface were observed, attributed to micro-galvanic corrosion. HEA demonstrates typical spontaneous passivation behavior and exhibits capaci-tance at all five applied potentials. The energy dispersive spectroscopy results indicate significant elemental segregation within HEA, with a decrease in the content of Cr2O3 in the passive film as the applied potential increases. Consequently, the protective efficacy of the passive film over the substrate in 0.5 mol/L NaOH solution was compromised.
  • Xin Li, Jie Chen, Jian-xin Bi, Dong-xia Huo, Jun Liu, Jun-hui Dong, Ding Nan
    Journal of Iron and Steel Research International. 2025, 32(5): 1176-1185.
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    Paraphenylenediamine (PPDA)-grafted maleic anhydride (MAH)-modified graphene oxide (PGO) was synthesized through a dual modification process. Initially, MAH was employed to modify graphene oxide (GO) to enhance its reactive sites. Subsequently, PPDA was utilized for further modification of MAH-modified GO (MGO). Through a comprehensive analysis, the successful grafting of MAH and PPDA onto GO was confirmed. It was concurrently established that the optimal ratio of PPDA to MGO is 1:1. This approach yielded PGO characterized by outstanding dispersibility and barrier properties in epoxy resin (EP) coaings for Q235 steel. The corrosion resistance of EP coatings containing varying amounts of PGO was assessed using electrochemical workstation and salt spray testing. After immersing in a 3.5 wt.% NaCl solution for 300 h, the composite coating containing 0.1 wt.% PGO exhibited superior performance in terms of low-frequency impedance modulus, measuring at 1.1 9 108 Ω cm2. The lowest corrosion current density was 2.32 9 10-10 A cm-2, and the self-corrosion voltage was -0.301 V. Additionally, polarization testing indicated that this coating also displayed the lowest corrosion rate, specifically 1.383 9 10-7 mm/a.
  • Mariel Amparo Fernandez Aramayo, Idalina Vieira Aoki
    Journal of Iron and Steel Research International. 2025, 32(5): 1186-1198.
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    The self-healing properties of dual-component epoxy microcapsules are evaluated when incorporated into an epoxy coating. The performance of the coating was assessed under immersion in a saline solution, simulating seawater conditions. Initially, synthesized microcapsules are incorporated into the epoxy coating. Then, the self-healing capabilities of the coating are studied under immersion using scanning vibrating electrode technique (SVET), open circuit potential (OCP), electrochemical impedance spectroscopy (EIS) and immersion corrosion test on coated samples with intentionally created artificial defects. The last three tests were conducted in a 3.5% NaCl solution. The adhesion of the coating is also studied by pull-off adhesion test. SVET analyses reveal lower ionic current densities in coated samples containing microcapsules during 24 h of immersion. EIS results demonstrate self-healing at the defect site for up to 12 h of immersion. After this time, the corrosion protection diminishes with prolonged immersion in the saline solution. Despite this, the coating with the microcapsules exhibits decrease in the corrosion process compared to the coating without the microcapsules. These results are consistent and complement the outcomes of the immersion tests conducted over 360 and 1056 h, which indicate that coated samples without microcapsules exhibit double the corrodedareas around the scribes compared to coated samples containing the microcapsules. These findings offer a promising outlook for applying this coating on offshore carbon steel structures under immersion aiming for a longer lifetime with less maintenance intervention.
  • Zhao-hui Zhou, Lan-lan Yang, Yuan-fang Wang, Shao-yu Feng, Jie Li, Jin-long Wang, Sheng-long Zhu, Fu-hui Wang
    Journal of Iron and Steel Research International. 2025, 32(5): 1199-1211.
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    Oxidation behavior of NiCrAlY nanocrystalline coatings with different Cr contents at 1050 and 1150 ℃ is investigated. The results indicate that Al2O3 scales can be formed on NiCrAlY nanocrystalline coatings after oxidation at high tem-perature. And their formation and thickening cannot be affected by the change of Cr contents in NiCrAlY coatings. During service, Cr in the coating can affect the microstructure of Ni-based single crystal superalloy. At 1050 ℃, Cr in the coating can diffuse into the superalloy, destroy its microstructure, and lead to the formation of interdiffusion zone and the precipitation of needle-like topologically closed-packed phase. The higher the Cr content in NiCrAlY the coating is, the more obvious the phenomenon is. However, after oxidation at 1150 ℃ for 100 h, no obvious changes were observed in the microstructure of CMSX-4 single crystal superalloy beneath the three kinds of NiCrAlY nanocrystalline coatings.
  • Zun-shuo Li, Zhong-shan Wang, Ming-ming Liu, Yong-ling Wu, Hong-yu Zheng
    Journal of Iron and Steel Research International. 2025, 32(5): 1212-1225.
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    Metal wear and corrosion require a protective coating with good corrosion and wear resistance. The inorganic adhesive of methyltriethoxysilane modified silica sol (SMP) was first synthesized by the dehydration condensation of silica sol (S30) with methyltriethoxysilane in propyl alcohol. Then, SMP was used to modify the organic polyurethane (PU) by adjusting the volume ratio. The optimal ratio of the organic-inorganic hybrid adhesive PU-SMP was obtained by measuring its film-forming, mechanical, and corrosion-resistant properties. Then, PU-SMP and zirconia nanoparticles (ZrO2) were used as an adhesive and functional filler to prepare the organic-inorganic composite coating of PU-SMP@ZrO2 via spraying on various substrates. The fabricated PU-SMP@ZrO2 performed superior mechanical strength, good wear performance, and excellent anti-corrosion property. The pencil hardness of the coating PU-SMP@2.5ZrO2 is 7H, the wear mass is reduced from 0.7 to 0.2 mg, and the impedance modulus reached 10; 7 Ω cm2. The synthesized organic-inorganic hybrid adhesive and its composite coatings provide a promising approach for constructing functional protective coatings on mechanical engineering material.
  • Hai-nan Zhang, Jian-bo Yu, Zhi-gang Yang, Jin-tao Jiang, Ying Dong, Xiao-xin Zhang, Jiang Wang, Zhong-ming Ren
    Journal of Iron and Steel Research International. 2025, 32(5): 1226-1244.
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    A novel plasma torch nitriding technology was applied for the first time to improve the surface properties of M2 high-speed steel by adjusting different experimental parameters. The nitrogen content, precipitate, microstructure, mechanical prop-erty, and corrosion resistance of the nitrided layer were comprehensively analyzed using an ONH analyzer, scanning electron microscope (SEM), micro-area X-ray diffractometer, transmission electron microscope (TEM), Vickers micro-hardness tester, high-temperature wear tester, 3D profilometer, tensile testing machine, and electrochemical workstation. The research results show that the novel plasma torch nitriding technology can achieve synergistic strengthening of nitrogen, carbon, and alloying element solid solution, precipitation strengthening, and martensitic structure on the surface of M2 high-speed steel. The nitrogen content on the specimen surface increased up to 0.17%, while the size and area of carbides were reduced by 89% and 86%, respectively, indicating a transformation towards fine nitrogen-rich precipitates. Compared to the original M2 steel, the nitrided specimens exhibited significant improvements in overall performance. The hardness increased from 228 HV0.2 to a maximum of 795 HV0.2, the wear coefficient decreased from a maximum of 0.8 to 0.49, the tensile strength increased from 753 MPa to a maximum of 934 MPa, and the corrosion current density decreased from 1.2 9 10-5 to a minimum of 1.9 9 10-6A/cm2.
  • Shu-fan Zhou, Liang-yu Chen, Wei-gang Lv, Jun-jie Gu, Fei Ye, Dubovyy Oleksandr, Sheng Lu, Ze-xin Wang
    Journal of Iron and Steel Research International. 2025, 32(5): 1245-1262.
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    A custom micro-arc oxidation (MAO) apparatus is employed to produce coatings under optimized constant voltage-current two-step power supply mode. Various analytical techniques, including scanning electron microscopy, confocal laser microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, and electrochemical analysis, are employed to characterize MAO coatings at different stages of preparation. MAO has MgO, hydroxyapatite, Ca3(PO4)2, and Mg2SiO4 phases. Its microstructure of the coating is characterized by ‘‘multiple breakdowns, pores within pores’’, and ‘‘repaired blind pores’’. The porosity and the uniformity of MAO coating first declines in the constant voltage mode, then augments while the discharge phenomenon takes place, and finally decreases in the repair stage. These analyses reveal a four-stage growth pattern for MAO coatings: anodic oxidation stage, micro-arc oxidation stage, breakdown stage, and repairing stage. During anodic oxidation and MAO stages, inward growth prevails, while the breakdown stage sees outward and accelerated growth. Simultaneous inward and outward growth in the repair stage results in a denser, more uniform coating with increased thickness and improved corrosion resistance.
  • Yang Ni, Hua-wei Yin, Yin-qiu Luo, Xin-yue Li, Hao Tan, Ting-zhen Li, Chuan-bo Hu
    Journal of Iron and Steel Research International. 2025, 32(5): 1263-1274.
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    Building a superhydrophobic coating on a carbon steel substrate is an effective strategy for enhancing metal protection. A practical approach to producing a series of superhydrophobic Ni/SiO2 composite coatings (SSN) using one-step elec-trodeposition method is shown. The effect of processing parameters on surface structure and wettability was thoroughly explored, resulting in the identification of three typical surface morphologies. The prepared coating with petal-like structure (SSN-3) obtained under the optimum parameters exhibited the best water repellency, achieving a contact angle of 162.7° and a sliding angle of 4.1°. The droplet bouncing behavior on SSN coatings surface was studied, and the delayed icing time was recorded. Meanwhile, the mechanical stability and chemical corrosion resistance of SSN coatings were focused. The superhydrophobic SSN-3 coating with unique surface structure exhibited excellent reliability. The anticor-rosion mechanism of SSN-3 coating was discussed, and its corrosion protection efficiency was up to 98.5%. The superior properties of the superhydrophobic SSN-3 coating make it suitable for diverse applications.
  • Xin-long Wei, Wei-feng Xin, Hu-shui Hong, Chao Zhang, Sergi Dosta
    Journal of Iron and Steel Research International. 2025, 32(5): 1275-1285.
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    The mathematical model between laser cladding parameters and coating properties was established by the response surface method (RSM). Ni-WC-reinforced CoCrNiFeAl high-entropy alloy (HEA) composite coatings were prepared on the surface of 0Cr13Ni5Mo steel by laser cladding to study the addition of Ni-WC on slurry erosion resistance of coatings. The optimal parameters obtained by RSM are laser power of 1450 W, scanning speed of 4.3 mm/s, powder feeding speed of 1.3 r/min and overlap rate of 60%, respectively. The grains of CoCrNiFeAl composite coatings are refined by adding Ni-WC-reinforced powder. 15 wt.% Ni-WC composite coating presents the maximum microhardness with the value of 655 HV0.3. The cumulative mass loss of the composite coatings at different erosion angles is lower than that of the pure CoCrNiFeAl coating. In addition, at low erosion angles, the cumulative mass loss of the composite coatings gradually decreases with the increase in the mass fraction of Ni-WC. Ploughing and microcutting are the primary erosion mechanisms of CoCrNiFeAl composite coatings at low erosion angles. When erosion damage occurs at high erosion angle, the erosion mechanisms of composite coating material loss are dominated by lip formation and craters. The proposed high-entropy alloy composite coatings can be applied to improve the erosion resistance of components in contact with high-speed fluids, such as ship propellers and centrifugal pump blades.
  • Xiao-qing Zhang, Shu-han Qiang, Jia-xing Fan, Hui-ling Zhou, Lan-lan Yang, Yan-bing Tang, Zhi-hong Liu, Dao-hua Lu
    Journal of Iron and Steel Research International. 2025, 32(5): 1286-1301.
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    The effects of the annealing temperatures (800, 1000, 1200 °C) on the microstructure evolution and corrosion behavior of laser powder bed fusion (LPBF) 316L stainless steel (SS) were investigated by optical microscopy, scanning electron microscopy, X-ray diffraction, energy dispersive spectroscopy, electron backscattered diffraction, X-ray photoelectron spectroscopy, and electrochemical testing. The findings indicated that the corrosion resistance of LPBF 316L SS deteri-orated after annealing treatment. The sub-cellular structure disappeared, the grain size increased, (111) orientation and the dislocation density decreased after the annealing treatment. The corrosion resistance deteriorated after the annealing treatment. In addition, the passive film was loose and unstable after the annealing treatment. Meanwhile, O2-/OH- ratio and Cr2O3 content in the passive film decreased after the annealing treatment. The stability and protection of the passive film were weakened, especially at 800 and 1000 °C, leading to a further reduction in the corrosion resistance of the annealed samples.
  • Qiang Da, Jia-jie Kang, Guo-zheng Ma, Yong-kuan Zhou, Zhi-qiang Fu, Li-na Zhu, Ding-shun She, Jian Liang, Hai-dou Wang
    Journal of Iron and Steel Research International. 2025, 32(5): 1302-1319.
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    AlCoCrFeNi and AlCoCrFeNiSi high entropy alloy (HEA) coatings have been prepared by high velocity oxygen fuel spraying, and the microstructure, mechanical properties as well as wear behaviors of the two HEA coatings were studied. With Si element addition, the surface and cross-sectional microstructure of HEA coating are reÞned, and it was found that both HEA coatings have a body-centered cubic structure, and the X-ray diffraction peaks of AlCoCrFeNiSi HEA coating deviate to the right. The microhardness, bonding strength nanohardness and elastic modulus of AlCoCrFeNi HEA coating increased with addition of Si element due to the fact that Si promotes uniformly distribution of other elements. In terms of wear properties, coefÞcient of friction and the wear rate were reduced with Si element addition, and the two HEA coatings have similar wear mechanism at the same loads. And at lower loads, the wear mechanism is abrasive wear, adhesive and slight oxidative wear, it is turn to oxidative wear and severe abrasive wear while the load is increased. The AlCoCrFeNiSi HEA coating has a higher corrosion potential and a lower corrosion current density, indicating improved corrosion resistance. This enhancement is attributed to the presence of Si, which reduces interatomic spacing and results in a more compact atomic arrangement. Consequently, element migration and chemical reactions are reduced, leading to the for-mation of a denser and more uniform passivation Þlm.
  • Wen-bin Liu, Feng Huang, Feng-jun Lang, Qian Hu, Yun-feng Xu, Wei Yuan, Shi-qi Zhang, Jing Liu
    Journal of Iron and Steel Research International. 2025, 32(5): 1320-1340.
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    A low-carbon, low-cost, and high-efficient method was reported for remarkably improving corrosion resistance of C-Mn structural steel by weak deoxidation. The results showed that, with the total oxygen content (wOT) increasing in the tested steel from 41 9 10-6 to 195 9 10-6, both the degree of element segregation and the level of banded microstructure weakened, presenting the lower potential difference between pearlite (P) and ferrite (F), and then smaller galvanic corrosion driving force, and thus effectively improving general corrosion properties. In addition, with wOT growing up, the number and size of inclusions increased, and the shape also changed from long chain or small particle to large particle ball with typical mosaic structure, which could effectively inhibit the preferential dissolution of local component due to multiple complex interfaces, and correspondingly suppress the pitting susceptibility. However, the impact toughness at low temperature of the tested steel reduced with wOT increasing, and then, taking the mechanical properties and corrosion resistance all into account, 160 9 10-6 was the optimal oxygen content within the present scope.
  • Yu-cheng Xing, Zhen-bang Sun, Yong-quan Han, Da-xing Zhang
    Journal of Iron and Steel Research International. 2025, 32(5): 1341-1355.
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    An alternating magnetic field (AMF) was introduced into the narrow gap laser-arc hybrid welding process for 2205 duplex stainless steel thick plates. The corrosion performance of the welded joints was evaluated through electrochemical studies. The results revealed that joints welded with the application of AMF had a lower corrosion current density compared to those welded without an external AMF. Additionally, these joints showed higher pitting potential and polarization resistance. Microscopic electrochemical analysis indicated that joints subjected to AMF exhibited minimal cathodic current in simulated seawater, with only slight fluctuations in the anodic current peak. Overall, the corrosion levels on the joint surfaces were relatively low. After 4 h of immersion in the corrosive medium, the average impedance of joints exposed to AMF increased by 60.7% compared to those not influenced by a magnetic field. These findings suggest that applying AMF during the narrow gap laser-arc hybrid welding process can significantly improve the corrosion resistance of duplex stainless steel welded joints, reducing their susceptibility to stress corrosion in seawater-like environments.
  • Xing-xing Li, Li-yi Chen, Wen-bin Hu, Shan Wan, Long-fei Song, Yi-peng Wang, Bo-kai Liao, Xing-peng Guo
    Journal of Iron and Steel Research International. 2025, 32(5): 1356-1370.
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    The corrosion behavior of Ti-6Al-2Zr-1Mo-1V (TA15) alloy fabricated through selective laser melting (SLM) tech-nology and traditional wrought technology in hydrochloric acid solutions was investigated using electrochemical testing and surface characterizations, including electron backscattered diffraction, scanning electron microscopy, and X-ray photoelectron spectroscopy analyses. The results showed that both types of TA15 alloy underwent spontaneous passivation reactions in HCl solution, and with the increase in HCl concentration, the surface of SLM-TA15 sample exhibited larger and deeper pits. In comparison to SLM-TA15 sample, the pits on the wrought-TA15 sample were shallower and the surface was more uniform. Analysis of the passive current density, breakdown potential, and electrochemical impedance revealed that the corrosion resistance of both alloys decreased as the concentration of HCl increased, and SLM sample exhibited poorer corrosion resistance compared with the wrought sample. Analysis of Mott-Schottky test curves and calculation of passive film thickness indicated that the passive film of wrought-TA15 sample was superior to that of SLM-TA15 sample.
  • Bao-jie Wang, Dao-kui Xu, Tian-qi Xu, Shuo Wang
    Journal of Iron and Steel Research International. 2025, 32(5): 1371-1381.
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    Combined with the hydrogen pre-charging and tensile testing methods, the effect of charged hydrogen content on the microstructure and mechanical behavior of an as-forged Ti-6Al-4V alloy was investigated. After performing hydrogen charging for 2, 4, 6, 8 and 10 h at a constant cathodic current density value of 75 mA/cm2 in a corrosion medium of 3.5 wt.% NaCl solution, the hydrogen contents in the charged samples increased gradually from 73 9 10-4 to 230 9 10-4 wt.%. When the hydrogen content was less than 190 9 10-4 wt.%, the charged hydrogen atoms were present as the solute atoms in the matrix, resulting in the enhanced tensile strength due to the solid solution strengthening of hydrogen atoms. Moreover, the reduced axial ratio c/a for a-Ti matrix due to the hydrogen dissolution was beneficial to improving the ductility of the hydrogenated samples. The critical hydrogen content for simultaneously improving the ductility and strength is determined to be 99 9 10-4 wt.%. When the hydrogen content was 230 9 10-4 wt.%, a small number of d-TiHx hydrides and micro cracks formed in the localized areas of a-Ti matrix, resulting in the simultaneous decrease of ductility and strength.
  • Chao-qun Xia, Hong-pu Zhou, Tian-shuo Song, Shu-guang Liu, Tai Yang, Qiang Li
    Journal of Iron and Steel Research International. 2025, 32(5): 1382-1395.
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    The microstructure, mechanical properties, and corrosion resistance of as-cast Zr-Sn-Co ternary alloys have been investigated in this experiment. The properties of as-cast Zr-1.5Sn-xCo (x = 0, 2.5, 5, 7.5, and 10 at.%) ternary alloys were investigated, and the alloy composition exhibiting the best comprehensive performance was identified. Subsequently, the chosen alloys were subjected to hot rolling treatment. The microstructure of the alloys in the rolled state was analyzed using the optical microscope, X-ray diffractometer, and scanning electron microscope. The mechanical properties of the alloys were analyzed using room temperature compression tests and microhardness tests, while the corrosion properties of the alloy were investigated through electrochemical testing. The results show that the strength of as-cast Zr-1.5Sn-Co ternary alloy increases significantly with the increase in Co content. The incorporation of Co element makes the corrosion resistance of as-cast Zr-1.5Sn-Co alloy increase significantly. The hot rolling treatment has minimal effect on enhancing the corrosion resistance of Zr-1.5Sn-2.5Co alloy. However, the mechanical properties of Zr-1.5Sn-2.5Co alloy after rolling treatment are significantly enhanced. The alloy exhibits the highest strength and hardness at a rolling temperature of 600 °C and exhibits the best plasticity at a rolling temperature of 800 °C.
  • Liu Yang, Xue-qun Cheng, Hong-wei Cao, Xiao-gang Li
    Journal of Iron and Steel Research International. 2025, 32(5): 1396-1412.
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    A series of Sn microalloying high-strength low-alloy (HSLA) steels were prepared through vacuum melting and hot rolling. Their stress corrosion cracking (SCC) behavior under high Cl- environments was investigated using U-bend immersion, slow strain rate testing, electrochemical methods, and novel SCC sensor. Results revealed that HSLA steel microalloying with 0.1 wt.% Sn demonstrated superior SCC resistance, primarily attributed to the effective inhibition of the anodic dissolution mechanism. Fracture morphology revealed a transformation in fracture mode from brittle to a mixture of brittle-ductile characteristics, accompanied by the formation of a protective SnO2 oxide film on the steel surface. However, excessive Sn content exacerbated SCC susceptibility due to the increased hydrolysis of Sn2+, leading to localized pitting and crack initiation. The critical role of optimal Sn content was highlighted in balancing mechanical properties and corrosion resistance, suggesting potential applications in industries where materials face harsh chloride environments.
  • Li-yun Wu, Zhong Zheng, Zhang-fu Yuan, Liang Liao, Yan-gang Zhang, Lin-fei Zhao
    Journal of Iron and Steel Research International. 2025, 32(5): 1413-1426.
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    A hydrophobic composite coating was obtained on the carbon steel surface through electrochemical deposition of a copper coating in a sulfate solution and chemical vapor deposition of a carbon fiber film. It alleviated the serious corrosion problem of carbon steel on the evaporator of hot film coupled seawater desalination system in harsh marine environment. The morphologies and compositions of the coatings were analyzed, revealing the influence of electrodeposition time on their performance. The micro-nano copper structure formed by electrodeposition significantly improved the deposition effect of carbon layer. Additionally, experiments with seawater solution contact angle tests indicated that electrodeposition transformed the surface properties from hydrophilic to hydrophobic, effectively inhibiting the diffusion of corrosive medium into the interior of the substrate. Through polarization curves, electrochemical impedance spectroscopy, and other analyses, it was demonstrated that the hydrophobic coating significantly improves the corrosion resistance of carbon steel substrates in seawater environments, surpassing the performance of traditional duplex steel.
  • Ze-yun Zeng, Shang-jun Gu, Jie Wang, Fu-long Wei, Xiang Xie, Zhi-ying Li, Hui Yang, Chang-rong Li
    Journal of Iron and Steel Research International. 2025, 32(5): 1427-1453.
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    The influence mechanism of trace Nb on the corrosion resistance of surface corrosion products of high-strength anti-seismic rebar in the simulated marine environment was studied by combining first-principles calculations with corrosion mass loss method, surface analysis, cross-sectional analysis, quantitative analysis, and electrochemical test. The results demonstrated that the addition of trace Nb effectively improved the compactness and stability of surface corrosion layer of rebar, and the corrosion resistance of corrosion layer increased with the increase in Nb content. The beneficial effect of Nb content on the corrosion layer summarized two important key points. Firstly, the addition of Nb was beneficial to promoting the improvement in the structural stability of α-FeOOH, and α-FeOOH structure of solid solution Nb atoms was beneficial to strengthening the fixation of Cl atoms, thus increasing α/(β + γ) ratio, total impedance value, and corrosion potential. Secondly, the formation of Nb oxides can not only repair the corrosion layer, but also play a role in the fixation Cl atoms, resulting in the improvement in corrosion resistance of corrosion layer.