JIN Yaxuan, PIAO Zhanlong, WANG Xingjuan, ZHANG Caijun, ZHU Liguang, GONG Penghui
The novel fluorine-free CaO-Al2O3-TiO2-based mold flux is designed to suppress interfacial reactions between high-titanium steel and the flux, ensuring stable flux performance during continuous casting. The physicochemical properties of the mold flux directly influence the surface quality of the cast strand and the smooth operation of the casting process, with lubrication behavior being a critical aspect of its metallurgical function. Key indicators such as melting temperature, viscosity, and breaking temperature are essential in characterizing lubrication performance; however, their experimental determination is often time-consuming and costly. To address this, the melting temperature, viscosity, and breaking temperature of the mold flux were systematically measured and analyzed. Based on a comprehensive dataset, predictive models for these parameters were developed. The findings reveal that Na2O and B2O3 lower the melting temperature, while the w(CaO)/w(Al2O3) ratio and SiO2 raise it. In contrast, TiO2, BaO, Li2O, and MgO exhibit dual effects. The w(CaO)/w(Al2O3) ratio, BaO, Na2O, B2O3, Li2O, and MgO reduce viscosity, whereas SiO2 increases it. TiO2 again shows a dual influence on viscosity. BaO, Na2O, B2O3, and SiO2 decrease the breaking temperature, while the w(CaO)/w(Al2O3) ratio, TiO2, and MgO increase it; Li2O presents a dual effect. The predictive models for melting temperature, viscosity, and breaking temperature exhibit mean absolute percentage errors of 1.60%, 8.43%, and 0.63%, respectively, demonstrating their strong predictive capability for the lubrication behavior of CaO-Al2O3-TiO2-based mold fluxes. These models offer an intuitive reference and technical support for the development of mold fluxes used in high-titanium steel continuous casting.