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2026年, 第33卷, 第4期 刊出日期:2026-04-25
  

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  • Wen-Peng Li, Guang-Lei Wang, Hua Zhang, Jing-Long Qu, Jin-Hui Du
    钢铁研究学报(英文版). 2026, 33(4): 99.
    https://doi.org/10.1007/s42243-025-01711-1
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Uniaxial compression tests and microstructural analyses were performed on a Ni-based wrought superalloy across a temperature range spanning the γ+γ’ duplex-phase region (below the γ’ solvus) and the γ single-phase region (above the γ’ solvus). Analysis of the fiow stress curves using an Arrhenius constitutive equation revealed that the activation energy for dynamic recrystallization (DRX) is significantly higher in the duplex-phase region than in the single-phase region. A three-dimensional hot processing map was developed to delineate the infiuence of temperature, strain rate, and strain on the alloy’s workability. The results also indicated that rapid fiow softening at low temperatures (950-980 ℃) and a high strain rate (1 s-1) is attributable to processing instability. During deformation in the γ+γ’ duplex region, both discontinuous dynamic recrystallization (DDRX) and continuous dynamic recrystallization (CDRX) mechanisms were active, with DDRX becoming the dominant mechanism at higher temperatures. Initially, the dispersed γ’ precipitates retard DRX. However, these precipitates subsequently dissolve and re-precipitate along DRX grain boundaries as nano- to micro-scale particles, which effectively pin the boundaries and inhibit grain growth.
  • Bin-Yu Lyu, Ju-Jin Wang, Wei Chen, Ying Ren, Li-Feng Zhang
    钢铁研究学报(英文版). 2026, 33(4): 100.
    https://doi.org/10.1007/s42243-025-01625-y
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    A three-dimensional numerical model was established based on a 210 t industrial ladle to simulate the multiphase fiow behavior during the entire teeming process. The volume of fiuid method was used to capture the gas-slag-steel interface, and large eddy simulation was employed to resolve the turbulent fiow. A discrete phase model was applied to simulate the entrainment of dispersed inclusions, and the simulation results were validated by industrial sampling under different retained steel conditions. In addition, a user-defined function was developed to calculate the slag detection system, and the predicted critical slag carryover moments matched well with online recorded results. Parametric studies showed that with the increase of the interfacial tension from 0.4 to 1.8 N/m the critical steel mass was decreased by 3.53 t, while increasing the slag viscosity from 0.1 to 0.6 Pa s resulted in a gain of 0.57 t. The clogging layer around the ladle nozzle significantly advanced the slag carryover. A 100 mm clogging layer increased the retained steel by 3.89 t. Relative infiuence weights of the interfacial tension, slag viscosity, and clogging layer height were calculated to be 44.2%, 7.1%, and 48.7%, respec-tively. Industrial trials confirmed that retaining 25 t of steel reduced 40% of the slag-type inclusions, comparing to the condition without the retained steel.
  • Wen-Jie Rong, Yan Jiang, Xin-Yi Li, Zhong-Qiu Liu, Bao-Kuan Li, Cheng-Jun Liu
    钢铁研究学报(英文版). 2026, 33(4): 101.
    https://doi.org/10.1007/s42243-025-01670-7
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    The fiow of molten steel at the solidification front in a continuous casting mold has a significant impact on slab quality. However, due to the high temperature and opacity of the mold, direct velocity measurements are extremely challenging. The functional relationship between fiow speed at the solidification front and the temperature of the outer surface of the solidified shell is derived heat conduction equations. Subsequently, a coupled fiow-heat transfer-solidification model for the mold is developed to numerically determine the fiow speed and temperature distribution. Based on thermocouple instal-lation positions and the impingement point location of the molten steel jet on the narrow face of the mold, 33 sampling points are selected along both the narrow/wide face centerline and corresponding heights at the solidification front. Finally, the fiow speed at the solidification front is fitted as a function of the outer surface temperature of solidified shell and the distance from the meniscus, with detailed analysis of its distribution characteristics.
  • Xu Zhang, Jian-Liang Sun, Yan Peng, Qiao-Gao Huang, Guang Pan
    钢铁研究学报(英文版). 2026, 33(4): 102.
    https://doi.org/10.1007/s42243-025-01633-y
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    As critical structural components in large-scale deep-sea equipment such as submarines and submersibles, cylindrical pressure shells require advanced manufacturing solutions to address the limitations of conventional methods characterized by prolonged production cycles and elevated costs. This study proposes an innovative corrugated rolling process (CRP) for high-performance, efficient fabrication of corrugated pressure shells. The theoretical foundations and critical parameters governing stable CRP operations were systematically established. Through comprehensive finite element simulations, systematic investigations were conducted on material fiow patterns during corrugation formation, revealing three distinct processing stages classified into clamping, local forming, and global forming. Analytical results revealed that clamping-induced indentations progressively dissi-pated during subsequent forming stages. Distinct deformation zones within the billet were identified, consisting of active and passive deformation zones characterized by differential thickness reduction rates that synergistically ensured complete corrugation development. Given the complexity of metal fiow in CRP, indicators such as corrugation saturation, uniformity of corrugation height, rib back depression rate, average spread and fishtail coefficient were defined to quantitatively assess the forming quality of corrugated pressure shells. The process rationality and technical feasibility of CRP were verified by the corrugated rolling test. This research establishes a theoretical foundation and provides practical technical guidance for manufacturing load-bearing structural components in large-scale deep-sea applications.
  • Bo-Ning Zhang, Xiao-Hui Wang, Zhen-Bao Liu, Yong-Qiang Li, Huan-Huan Bai, Jian-Xiong Liang, Yong Mao, Lei Zheng
    钢铁研究学报(英文版). 2026, 33(4): 103.
    https://doi.org/10.1007/s42243-025-01687-y
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    Through integrated experimental and first-principles approaches, the pivotal role of high-content Co in governing phase constituents and martensite is elucidated. Experimental observations reveal that the high Co content facilitates carbide dissolution and reduces the martensitic transformation temperature. First-principles calculations distinguish that the high-content Co intrinsically elevates the stacking fault energy and enhances the austenite thermodynamic stability. This together with Co-induced escalated shear moduli imposes a resistance to strain relief during martensitic transformation, kinetically promoting the burst transformation to refined martensitic microstructures enriched with high-angle twin-like V1-V2 variant boundaries. An optimal Co content of 9.7 wt.% featuring a balanced strength, toughness and alloying cost is unveiled, and novel opportunities to rationally engineer mechanical properties of multi-phase steels are provided through current control of phase fraction, morphological refinement, and martensite variant selection.
  • Li Zhang, Kai-Xiang Ma, Jing-Chong Yan, Zhi-Ping Lei, Zhan-Ku Li, Wei-Dong Zhang, Shi-Biao Ren, Zhi-Cai Wang, Xiao-Biao Yan, Heng-Fu Shui
    钢铁研究学报(英文版). 2026, 33(4): 104.
    https://doi.org/10.1007/s42243-025-01713-z
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    The synergistic effects of thermal dissolution soluble fraction (TDSF) and hydrogen-rich atmospheres on quality and solution loss kinetics of cokes were investigated. By integrating crucible coking tests, structural characterizations (optical microscopy, Raman spectrometer, scanning electron microscopy, nitrogen physisorption), and shrinking core modeling, it is demonstrated that 5 wt.% TDSF incorporation reduces coke reactivity index (CRI) by 3.3% and enhances coke strength after reaction by 6.0% with the introduction of 10% H2 into the gasifying atmosphere. TDSF-induced anisotropic graphitization fosters fibrous/leafiet microstructures, elevating optical texture index and reducing defect density. Hydrogen addition further suppresses CRI by lowering CO2 partial pressure and blocking active sites via competitive adsorption, thus stabilizing pore structure. Kinetic analysis reveals dual gasification regimes: interfacial reaction dominates below 1323 K, transitioning to ash-layer diffusion limitation above 1373 K. Steam addition reduces activation energy by 41% via enhanced carbon-H2O interactions, accelerating gasification rates compared to CO2. Conversely, H2 elevates interfacial resistance by 25% through reversed water-gas shift reaction. TDSF increases pore tortuosity, raising diffusion activation energy by 6.8% and extending reaction layer thickness for stabilized conversion. Optimal performance is achieved at 1323-1373 K with 5 wt.% TDSF blending, balancing structural integrity and gasification efficiency. These findings establish a microstructure-mediated strategy for coke enhancement in hydrogen-enriched blast furnaces, advancing low-carbon ironmaking technologies.
  • Qi-Lin Ma, Xiao-Dan Zhu, Pei-Yu Zhao, Rui Hong, Ba Li, Qing-You Liu, Cheng-Jia Shang, Shu-Jun Jia
    钢铁研究学报(英文版). 2026, 33(4): 105.
    https://doi.org/10.1007/s42243-025-01618-x
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    In order to understand and improve the corrosion resistance of high-strength low-alloy (HSLA) steels under supercritical CO2 (s-CO2) environment, the effects of microstructure and chromium content of experimental steels on the corrosion of pipeline steels transporting s-CO2 were investigated by rotating cage method and electrochemical techniques. The complex microstructure of HSLA steels is identified and quantified and it is related to s-CO2 corrosion rate. It was shown that the corrosion resistance of the experimental steels in s-CO2 environment was significantly reduced with the increase in coarse granular bainite (GB) and martensite-austenite (MA) in the microstructure. Electrochemical tests showed that the corrosion mechanisms of the steels were the same, but the electrochemical impedance of the higher-Cr test steel was lower in both the bare and the rusted samples, which was due to its internal coarse GB and rough MA constituents. However, the impedance of 0.6Cr steel is reduced due to its GB and coarse MA components. Kelvin probe force microscopy characterization tests confirm that there is a large potential difference between the coarse MA components and the substrate, which reduces the local corrosion resistance of the material. However, MA tends to be a companion microstructure of coarse GB, which plays an important role in promoting the occurrence of localized corrosion on the surface of experimental steels in s-CO2 environ-ments, and tends to lead to a serious deterioration of the corrosion performance of HSLA steels in s-CO2 environments.
  • Tian-Long Liu, Yi-Chu Wang, Xin-Yue Zhang, Kai-Hong Zheng, Fu-Xing Yin, Zhi-Chao Luo, Li-Ying Sun
    钢铁研究学报(英文版). 2026, 33(4): 106.
    https://doi.org/10.1007/s42243-026-01738-y
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    The infiuence of V addition on the hot corrosion behaviour of a high-Mn nickel-saving austenitic (HMA) heat-resistant steel is investigated. Advanced high-resolution microscopy techniques are performed to examine the corrosion behaviours and mechanisms of V-containing and V-free HMA steels in the molten Na2SO4 at 1173 K in air. It reveals that V addition unexpectedly improves the hot corrosion resistance of this steel against molten Na2SO4. It suggests that the rapid formation of a dense corrosion scale acts as a barrier to suppress the initial internal sulphidation. Furthermore, the subsequently generated inner mixed (Cr, Mn, V)-rich corrosion layer can effectively impede the outward diffusion of Cr and Mn from the matrix and the ingress of oxygen and sulphur. A critical role of V in enhancing the resistance against sodium sulphate-induced hot corrosion environment is established, challenging the conventional view that V-alloying exacerbates hot corrosion performance of heat-resistant alloys in molten salts.
  • Yu-Shi Yang, Ze-Ran Hou, Zhou Wang, Jian-Feng Wang, Jun-Ying Min
    钢铁研究学报(英文版). 2026, 33(4): 107.
    https://doi.org/10.1007/s42243-026-01730-6
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    A novel quantitative framework for comprehensive toughness assessment across heterogeneous regions in laser-welded press hardening steel was established. Three-point bending tests integrated with through-thickness digital image correlation (DIC) were conducted to capture full-field strain distributions in both base material and welded zones. An artificial neural network (ANN) was subsequently developed and trained to predict localized strain extremes and failure behavior at experimentally inaccessible regions. Results revealed approximately 20% reduction in maximum bending angle at the weld compared to base material, significantly dependent on loading direction relative to the weld. Contrary to conventional understanding, specimens achieving larger bending angles exhibited lower maximum tensile strains at fracture (0.132 vs. 0.143), attributed to decreased strain gradients in the outermost layer and more uniform microcrack distribution. The DIC-ANN framework quantitatively demonstrated that pressure head positioning relative to the weld pool significantly impacts strain distribution patterns and ultimate bending performance in VDA 238-100 testing.
  • Ran Liu, Huan Jin, Song Liu, Xiao-Jie Liu, Jian-Hai Hao, Jun Zhao, Qing Lv
    钢铁研究学报(英文版). 2026, 33(4): 108.
    https://doi.org/10.1007/s42243-026-01725-3
    摘要 ( ) PDF全文 ( )   可视化   收藏
    To ensure the uniformity of the gas fiow in the sintering material layer, improve the sintering efficiency, and reduce the production energy consumption, it is of great significance to predict the permeability index of the original material layer in advance. However, how to achieve accurate prediction in line with the actual production environment has always been a challenge. Based on this, deep learning was combined with finite element numerical simulation, and an integrated pre-diction method with high interpretability and controllability was proposed. This method used the wavelet threshold denoising technology jointly improved based on complete ensemble empirical mode decomposition with adaptive noise (CEEN) to process the original data, so as to improve the data quality. Subsequently, a temporal convolutional network-long short-term memory (TCN-LSTM) model was constructed and trained for permeability prediction. Comparative analysis showed that the proposed model has a higher prediction accuracy than other comparative models, with the coefficient of determination R2 as high as 95%. In the experimental simulation stage, taking a 360 m2 sintering machine of a certain steel plant as the research object, the COMSOL finite element software was used to establish a physical model for process simulation. The results showed that the variation curve of the permeability of the material layer along the depth direction is highly consistent with the measured results, with a relative error of approximately 3.90 and the R2 of 92.38%. In addition, based on the results of finite element numerical simulation, when using the TCN-LSTM model for prediction, the difference between the predicted value and the simulated value is small, with an average relative error of only 4.92%and the R2 of 97.29%, showing a high degree of fitting and matching. Therefore, the method of combining finite element numerical simulation with CEEN-TCN-LSTM can accurately predict the permeability index of the material layer, effectively meeting the dual needs of predicting the permeability in advance and monitoring the change process of the material layer in actual production and providing technical support for the optimization of the sintering process and the production of high-quality sinter.
  • Yue-Feng Jiang, Yang Xu, Rui Liang, Qin Zhang, Wen-Chen Xu, Tian Liang, Ying-Che Ma
    钢铁研究学报(英文版). 2026, 33(4): 109.
    https://doi.org/10.1007/s42243-026-01761-z
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    The stress corrosion cracking (SCC) behavior of the cold-deformed twisted tubing (TT) fabricated from nuclear grade austenitic stainless steel is investigated. Finite element simulations combined with hardness tests identified localized strain concentration in the convex regions of cold-deformed TTs. These areas exhibited dense deformation twins with high kernel average misorientation values, whose spatial distribution matched the predicted strain concentration zones. Slow strain rate tensile tests conducted in high-temperature pressurized water and argon environments show that cold-deformed TTs demonstrated SCC characteristics, displaying typical quasi-cleavage crack features with river patterns on fracture surfaces. While the original material showed minimal SCC susceptibility, further analysis using focused ion beam-transmission electron microscopy and transmission Kikuchi diffraction on longitudinal fracture sections revealed that severe plastic deformation induced refinement of deformation twins. During the initial stage of SCC, hydrogen-assisted SCC nucleation and propagation occurred preferentially along dynamically recrystallized nanocrystalline grain boundaries. In the rapid propagation stage, strain localization and reduced hydrogen effects redirected crack paths to incoherent interfaces between nanocrystals and deformation twins. Notably, the deformation twins exhibited inherent resistance to SCC, attributable to the coherent structural arrangement and minimal stress concentration characteristics.
  • Xu Wang, Jing-Yu He, Li-Qian Zhao, Ji-Guo Li, Fei Deng, Xu He, Guo-Hui Li, Guan-Zhong Gao, Xiang Chen
    钢铁研究学报(英文版). 2026, 33(4): 110.
    https://doi.org/10.1007/s42243-025-01715-x
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    The mechanical properties and microstructure of decommissioned L245NS pipeline steel are investigated after 8 years of service in a 4 MPa pure hydrogen environment. It utilized China’s first samples of long-serviced hydrogen pipelines, which are valuable for evaluating the long-term performance of hydrogen pipeline steels. A key scientific regularity was revealed: In long-term high-pressure gaseous hydrogen, hydrogen in low-strength pipeline steels preferentially segregate at MnS/AlN precipitates, dislocations, grain boundaries, and micropores. This segregation reduces local cohesive energy (e.g., MnS lattice) and induces stress concentration, synergistically initiating and propagating secondary cracks—the core mechanism of hydrogen embrittlement (HE). Notably, MnS precipitates exhibit intrinsic HE susceptibility (hydrogen causes internal cracking), a previously unreported phenomenon. Slow strain tensile tests (significant cross-sectional shrinkage decrease, HE sensitivity index up to 17.79%) quantitatively validated this mechanism.
  • Yue Li, Sha Ji, Hou-Kai Xia, Zi-Ming Wang, Qiang Yue
    钢铁研究学报(英文版). 2026, 33(4): 111.
    https://doi.org/10.1007/s42243-025-01641-y
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Manganese sulfide (MnS) inclusions have a significant impact on the mechanical properties, machinability, and service life of steel. Therefore, the formation and evolution of MnS inclusions are controlled to enhance the overall performance of steel. By regulating the quantity, morphology, and distribution of MnS inclusions, it is possible to optimize steel’s machinability, improve fatigue resistance, and mitigate the negative effects of stress concentration on steel toughness. Moreover, appropriate control of MnS inclusions can significantly enhance the electromagnetic properties and corrosion resistance of steel. Therefore, the formation mechanism of MnS inclusions, the factors affecting their precipitation, and their effects on the steel properties were analyzed. Through a systematic analysis of recent researches, the main mor-phological classifications of MnS inclusions and their evolution under various processing conditions were summarized. Additionally, strategies for effective control of MnS inclusions through the addition of chemical elements and process adjustments were discussed. The goal of regulating MnS inclusions is to improve the mechanical and machinability properties of steel, providing theoretical and practical guidance for the optimization of future steelmaking processes.
  • Yan-Li Wang, Ying-Xiong Bai, Ze-Feng Wu, You-Zhao Zhang, Chao-Liu Zeng, Xiang-Wei Li, Shu-Yan Zhang
    钢铁研究学报(英文版). 2026, 33(4): 112.
    https://doi.org/10.1007/s42243-026-01743-1
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    A systematic investigation was conducted into the infiuence of thermal treatment on the microstructure evolution and mechanical properties of additively manufactured Ni-based GH4099 superalloy, with specific focus on the selective laser melting (SLM) fabrication process. The as-fabricated GH4099 alloy demonstrated characteristic columnar grain structures with pronounced residual stresses, predominantly attributed to the steep thermal gradients inherent in the SLM process. Through solution treatment at 1110 ℃, a significant microstructural transformation was observed, characterized by recrystallization that converted the columnar grains into equiaxed structures while effectively mitigating residual stresses. Concurrently, this treatment facilitated the precipitation of fine γ’ phases, thereby enhancing the material’s strength. Subsequent aging treatments at 800 and 900 ℃, however, led to γ’ phase coarsening, which diminished the precipitation strengthening effect, but concurrently improved the alloy’s plasticity. These findings highlight the pivotal role of thermal processing in optimizing the strength-ductility balance for SLM-manufactured superalloys under high-temperature service conditions. This work contributes to a comprehensive understanding of the microstructure-property relationships in thermally processed SLM GH4099 superalloy, providing critical insights for the development of advanced Ni-based superalloys and contributing to the refinement of SLM manufacturing protocols for high-performance applications.
  • Xiao-Feng Chi, Ming-Yuan Chen, Ming-Yin Kou, Sheng-Li Wu, Xin-Dong Wang, Heng Zhou
    钢铁研究学报(英文版). 2026, 33(4): 113.
    https://doi.org/10.1007/s42243-026-01744-0
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    Oxygen-enriched blast technology for blast furnaces is widely used for its significant energy-saving and carbon-reduction potential. By injecting oxygen-enriched air and coal powder into blast furnaces, it raises the theoretical combustion temperature at the tuyere. This boosts coal injection rates, cuts coke consumption, and reduces the coke ratio while increasing output. However, its actual impact on fuel ratios and CO2 emissions needs further study. A life cycle assessment model was built for blast furnace hot metal to explore the environmental and carbon footprint impacts of oxygen-enriched coal injection. The characterization results of different impact categories show diverse trends. Greenhouse gas emissions slightly increase, while toxic pollutant emissions decrease. When the oxygen-enrichment rate rises from 5.58% to 8.10%, the life cycle CO2 emissions of hot metal increase from 1656.2 to 1698.1 kg/t (a 2.52% rise). In the production phase, CO2 emissions from the blast furnace process rise from 749.1 to 798.6 kg/t, while those from the coking process fall from 172.7 to 168.3 kg/t. Sintering emissions also decrease. During the upstream stages and transportation process, indirect emissions from coal combustion rise, while the benefits derived from by-products diminish.
  • Jing-Song Wu, Jing-Wen Zhang, Chen-Xi Liu, Qiu-Zhi Gao, Shu-Ran Chu, Jia-Cheng Yu, Ran Ding
    钢铁研究学报(英文版). 2026, 33(4): 114.
    https://doi.org/10.1007/s42243-026-01737-z
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    A double aging strategy is proposed to resolve the strength-toughness dilemma in maraging stainless steels under cryo-genic conditions. The process integrates a high-temperature pre-aging to create chemically heterogeneous martensite, followed by low-temperature aging to generate nanoscale Laves precipitates with rapidly reversed austenite. A yield strength of 1642 MPa and an impact toughness of 38 J at 77 K are achieved, preserving near-complete strength while boosting toughness over fourfold versus single-aged counterparts (1648 MPa/7.4 J). Microstructural analysis demonstrates that Ni heterogeneity from primary aging is responsible for the acceleration of austenite reversion during secondary aging. The final structure combines refined Laves phases (B 20 nm) and high-density reversed austenite, enabling synergistic strengthening-toughening. A new phase transformation guided paradigm for cryogenic steel design was established.
  • Wang Zeng, Ye-Han Fang, Zuo-Bang Chen, De-Sheng Zou, Guang-Liang Wang, Yun-Peng Si, Heng Zhou, Tian-Xiang Zhang, Ming-Yin Kou
    钢铁研究学报(英文版). 2026, 33(4): 115.
    https://doi.org/10.1007/s42243-026-01735-1
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    As the key equipment connecting the feeding belt to the top of blast furnace, the structure of the hoppers directly affects the burden distribution in blast furnace throat. Therefore, it is of great significance to explore the suitable structure of the hoppers to optimize the burden and gas distribution of the blast furnace and improve the gas utilization rate. A three-dimensional model of a 1:1 bell-less top blast furnace with serial-type hoppers was established based on the discrete element method, which simulates the entire movement process of the burden from the belt to each hopper and then to the throat. The effects of internal components, such as the distributor, guiding cone, and buffer platform, on particle size segregation in the upper hopper, the weighing hopper, and the throat of the blast furnace were investigated. The results indicate that removing the distributor can reduce the burden segregation during the discharge from the weighing hopper. The guiding cone significantly infiuences the radial particle size distribution within the weighing hopper and its discharge. Eliminating the buffer platform promotes a more uniform burden distribution both in the weighing hopper and the throat of the blast furnace. Among the conditions investigated, removing the distributor and the buffer platform yields the best distribution, with the segregation index improved by 92% compared to the base model, which is recommended for practical operations.
  • Sha-Sha Zhang, Liang Sun, Tian-Qi Chen, Bing-Qin Wang, Zhi-Chao Che, Hui Xue, Xue-Qun Cheng, Xiao-Gang Li, Chao Liu
    钢铁研究学报(英文版). 2026, 33(4): 116.
    https://doi.org/10.1007/s42243-026-01727-1
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    The corrosion protection mechanism of a Cr-Ni-Cu-Mo multi-alloyed weathering steel (Q500qENH) is systematically investigated by coupling experimental characterization with dissolution-diffusion-deposition modeling. Compared with conventional Q500q steel, Q500qENH steel exhibits one order of magnitude lower metal-ion concentration in the elec-trolyte, effectively alleviating acidification caused by hydrolysis and retarding substrate dissolution. The rust layer evolves through sequential deposition of Fe3O4, MoO2,Cr2O3, and CuO, forming a dense and defect-minimized microstructure. Thermodynamic and kinetic analyses reveal that the nucleation rates of Fe3O4 and CuO in Q500qENH steel are two orders of magnitude higher than in Q500q steel, accelerating the establishment of a compact barrier film. The multi-alloy synergy enhances α-FeOOH and FeCr2O4 formation, increasing charge-transfer resistance (Rct) and polarization resistance (Rp) over exposure time. These results demonstrate that Cr, Mo, and Cu collectively improve ion equilibrium and oxide nucleation behavior, offering a quantitative understanding of rust layer evolution and superior long-term corrosion pro-tection in multi-alloyed weathering steels.
  • Kang Huang, Min Gan, Xiao-Hui Fan, Zhi-Yun Ji, Gai-Ge Zhao, Yi Liu, Jia-Fa Xiang, Jin-Hua Li, Xiao-Long Wang
    钢铁研究学报(英文版). 2026, 33(4): 117.
    https://doi.org/10.1007/s42243-026-01758-8
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    Low-temperature reduction degradation (LTRD) has long been regarded as a key metallurgical property of iron ore sinter, which exhibits a significant infiuence on the stability and efficiency of blast furnace operation. However, the reduction behavior of sinter under low-temperature conditions is not yet fully understood. The low-temperature reduction behavior of sinter was investigated. The reduction mechanism of sinter under low-temperature conditions was clarified through characterization methods, including X-ray diffraction, microstructural analysis and energy-dispersive X-ray spectroscopy. An interesting phenomenon was found that the reduction degradation index RDI+3.15 of sinter sharply decreased from 86.05% after reducing for 30 min and to 58.6% for 45 min. The reduction behavior of sinter was further investigated using a thermogravimetric furnace. The results showed that the reduction rate initially reached a peak, followed by a sharp decline to a minimum at approximately 10 min. This decrease occurred as a result of the formation of a reaction product layer, which hindered the diffusion of the reducing gas into the interior of the sinter. Subsequently, the reduction rate increased again, reaching a second peak at approximately 40 min. The increase in reduction rate was attributed to the formation of cracks rather than gas diffusion. It was further determined that the primary cause of LTRD is the volumetric expansion induced by the reduction of surface hematite. Moreover, the low-temperature reduction of sinter involved only the transformation of hematite to magnetite, with the overall reduction degree remaining low at only 6.31%.
  • Xi-Han Zheng, Jun-Ying Wan, Tie-Jun Chen, Hao-Ran Zhang, Jia-Wen Liu, Yu Deng, Xian-Lin Zhou, Jun Zhuang
    钢铁研究学报(英文版). 2026, 33(4): 118.
    https://doi.org/10.1007/s42243-026-01765-9
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    In pursuit of more efficient low-carbon ironmaking, fulfilling the requirements of blast furnace materials, four types of low-carbon cold-bound pellets were prepared from blended iron ore, which were dually strengthened through sintered return fines and binder. The strengthening mechanism of low-carbon cold-bound pellets was discussed based on the analysis of the characterization results including optical microscopy, scanning electron microscopy-energy dispersive spectroscopy, X-ray diffraction and Fourier transform infrared spectroscopy and the reduction performance detection results. The results demonstrate that, when subjected to external forces, the interlocking of returned fines with blended iron ores leads to the formation of a load-bearing skeleton. During the drying process, the binder is dehydrated and condensed to yield a gel network structure, with which the bonding effect is imposed. In contrast to the organic binder PR, the inorganic binder SS ensures a stabler thermal structure and reduction performance for the cold-bound pellets. The comparison of energy consumption and carbon emissions was estimated before and after introducing cold-bound pellets in the process, and it was ascertained that low-carbon cold-bound pellets are able to foster the low-carbon sustainable ironmaking.
  • Qian Dang, Shan-Shan Wang, Yun-Fei Zhang, Chi Zhang, Wan Zhang, Guo-Huai Liu, Zhao-Dong Wang
    钢铁研究学报(英文版). 2026, 33(4): 119.
    https://doi.org/10.1007/s42243-025-01628-9
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    To improve the melt purity of DD6 single-crystal superalloy and mitigate interfacial reactions with Al2O3-SiO2 ceramics during casting, an anti-erosion enhancement strategy that combines sintering parameter optimization with surface coating modification is proposed. By systematically tailoring the sintering temperature and impregnation-coating process, Al2O3-SiO2 ceramics with both superior mechanical properties and refined surface quality were fabricated. On this basis, the high-temperature wetting behavior and interfacial reaction mechanisms between ceramics with different surface conditions and DD6 alloy melt were investigated. Results show that sintering at 1260 ℃yields a dense and homogeneous microstructure with a porosity of 30.5% and a fiexural strength of 12.75 MPa, ensuring thermal stability and structural integrity. The introduction of a dense Al2O3 surface coating further reduced surface porosity, suppressed melt infiltration, and retarded interfacial reactions. High-temperature melting tests revealed that the erosion layer thickness decreased from 150 to 200 μm for the uncoated ceramics to ~100 μm for the coated one. Wetting measurements showed that the contact angle between the melt and the ceramic surface increased from 126.15° to 129.77° after coating treatment, indicating weakened wettability. Interfacial characterization confirmed the formation of HfO2 as a reaction product, evidencing a reactive wetting mechanism. Overall, the synergistic optimization of sintering parameters and surface densification significantly enhances the high-temperature corrosion resistance and service stability of Al2O3-SiO2 ceramics, offering robust engi-neering support for their application in clean melting of advanced superalloys.
  • Xiang-Yu Xu, Zhan-Jiang Gao, Jian-Xun Fu, Wen-Jun Wang, Xue-Min Wang, Nian-Fu Liu
    钢铁研究学报(英文版). 2026, 33(4): 120.
    https://doi.org/10.1007/s42243-026-01724-4
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    Through the addition of Ce for inclusion modification, a systematic investigation was conducted to examine the effects of Ce on inclusion characteristics in Nb-microalloyed medium-carbon alloy structural steels. The distribution and morphology of inclusions in both as-cast and hot-rolled specimens were characterized using optical microscopy, scanning electron microscopy, and electron probe microanalysis, while the equilibrium phase transformation pathways of inclusions were simulated through thermodynamic software. With increasing Ce content, progressive modification of Al2O3 and MnS inclusions into CeAlO3,Ce2O2S, and Ce2O3 was observed, accompanied by a reduction in average inclusion size from 3.9 to 3.0 μm. Concurrently, Ce inhibited the coupled precipitation of primary NbC and MnS through MnS modification, thereby promoting the independent refinement of primary NbC precipitates. When excessive Ce (e.g., 0.029 wt.%) is added to steel, Ce2O3 inclusions precipitate extensively. Owing to the substantial capillary forces of the Ce2O3 inclusions, aggregation occurs, thereby forming large-sized inclusions. Following hot rolling, the aspect ratio of sulfide inclusions exhibited a significant decrease with increasing Ce content, while oxide inclusions showed minimal variation in aspect ratio. Based on integrated experimental and thermodynamic analyses, for niobium-microalloyed medium-carbon alloy structural steels in industrial production, the optimal Ce modification strategy should prioritize maximum sulfide modi-fication while suppressing Ce2O3 formation or minimizing its content to prevent inclusion aggregation.
  • Hai-Tao Lu, Da-Zhao Li, Zhi-Jie Yan, Shao-Bin Bai, Yong-An Chen, Peng-Fei Cao, Teng-Fei Xu, He-Jia Zhu
    钢铁研究学报(英文版). 2026, 33(4): 121.
    https://doi.org/10.1007/s42243-026-01721-7
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    Lightweight steel with low density and superior mechanical properties is highly desirable for transportation equipment applications. An Fe-27Mn-10Al-1C (wt.%) lightweight steel with tensile strength of 917 MPa and ductility of 56.6% was prepared via short-time solution treatment. The microstructural evolution during heat treatment and the deformation mechanisms closely associated with strain hardening response were mainly discussed. The coarse intergranular j-carbides detrimental to ductility gradually dissolved with increasing the solution temperature. Meanwhile, the intragranular j-carbides and B2 were precipitated in austenite and ferrite, respectively. Quantitative analysis revealed that the intragranular precipitates contributed approximately ~ 195 MPa to the yield strength. Investigation of deformation behavior revealed that the trans-interface strain transfer by dislocation evolution and pile-up serves as the dominant mediator enabling coordinated deformation between austenite and ferrite. Additionally, it was revealed that the ferrite with deformation ability could dynamically regulate the strain partitioning to inhibit cracks initiation. Such multiscale coordinated defor-mation mechanisms effectively enhanced the strain hardening capacity and the plastic stability.
  • Qi Jia, Zi-Wen Zhao, Chang Liu, Zhu He, Guang-Qiang Li, Wen Yan, Qiang Wang
    钢铁研究学报(英文版). 2026, 33(4): 122.
    https://doi.org/10.1007/s42243-026-01750-2
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    A reduced-order model (ROM) based on proper orthogonal decomposition (POD) is proposed, integrating POD methodology with regression techniques to predict velocity magnitude fiow field morphology in continuous casting electromagnetic stirring processes under varying operational parameters. Computational fiuid dynamics (CFD) simulations were performed to calculate fiow fields at various casting speeds and applied currents, resulting in a comprehensive sample database. The velocity matrix was decomposed via POD, and regression models were subsequently trained to correlate operational parameters with mode coefficients. Validation against CFD simulations proved the ROM’s effectiveness in predicting velocity magnitude fiow fields under electromagnetic stirring, with maximum relative errors of 6.5% in the mold region and 8.4% in the turbulent stirring zone. Notably, the POD-based ROM achieved a computational efficiency three orders of magnitude higher than conventional CFD simulations (prediction time of about 1/1000 of CFD).
  • Li-Hua Zhao, Xue-Ming Li, Shuai Yang, Yan-Ping Bao
    钢铁研究学报(英文版). 2026, 33(4): 123.
    https://doi.org/10.1007/s42243-026-01726-2
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    The application of fiow control devices in continuous casting tundishes is a common strategy to extend molten steel residence time and optimize fiow and temperature fields. However, rational expansion of tundish capacity offers an alternative means to achieve comparable metallurgical benefits. To systematically investigate the effect of tundish capacity on molten steel transport characteristics, based on the adjustment of tundish longitudinal width, a novel stepwise expansion method was proposed. A six-strand T-type tundish was used as the research subject. Four geometrically scaled configu-rations with capacities ranging from 22 to 34 t were created through proportional width expansion. Computational fiuid dynamics simulations were employed to track the evolution of molten steel fiow patterns. The results demonstrated that expanding the capacity from 22 to 30 t increased the mean residence time of the molten steel from 349.14 to 626.91 s, corresponding to a 79.6% increase. The dead zone volume fraction decreased from 30.16% to 24.18%, while the surface velocity declined from 0.06399 to 0.05814 m/s. Additionally, the maximum temperature difference across strands was reduced from 2.52 to 1.39 K, representing a 45% decrease. However, the 34 t tundish exhibited reduced metallurgical performance compared with that of the 30 t design. Furthermore, when the casting speed of the 30 t tundish increased to 3.2 m/min, the mean residence time decreased by 58.26 s. However, it remained 219.51 s longer than that of the prototype tundish, and the dead zone volume fraction achieved a 5.98% reduction.
  • Wen-Hao Li, Yue Zheng, Wan-Qi Chen, Qi-Qian Chen, Lian-Min Zhang, Ai-Li Ma, Zhan Sun, Xia Liu, Yu-Gui Zheng
    钢铁研究学报(英文版). 2026, 33(4): 124.
    https://doi.org/10.1007/s42243-026-01759-7
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    The effects of nitrate ion (NO3-) concentration on corrosion behavior of 304L and C25 stainless steels in 6 mol/L boiling nitric acid (simulating spent nuclear fuel reprocessing) were explored. Increasing NO3- to 5 mol/L accelerate the corrosion of both 304L and C25 steels by enhancing the cathodic reduction reaction drastically, as evidenced by the increased corrosion current density and mass loss rate, positive shifts in corrosion potential, and a decrease in cathodic Tafel slope. These observations suggest a transition from activation-controlled to diffusion- or mixed-controlled corrosion mechanisms. Meanwhile, passive films degraded significantly with the reduced Cr(OH)3/Cr2O3 content. 304L stainless steel undergoes intergranular corrosion at low NO3- concentrations (0.5 mol/L) and transitions to uniform corrosion at 5 mol/L NO3-.In contrast, C25 stainless steel exhibits pitting corrosion at NO3- concentrations of 3 mol/L or higher, with the formation of Mo-oxide precipitates observed at 5 mol/L.
  • Wei-Yang Zha, Hua Zhang, Jian-Hao Wang, Peng-Sheng Lu, Zheng-Chao Huang, Zhi-Hui Ji, Qing Fang
    钢铁研究学报(英文版). 2026, 33(4): 125.
    https://doi.org/10.1007/s42243-026-01742-2
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    A combined approach of numerical simulation and water model experiments was employed to investigate the steel-slag-air multiphase fiow behavior and initial solidification characteristics in a 200 mm 9 1248 mm slab mold with varying submerged entry nozzle (SEN) inclination angles and argon-blowing rates. The results demonstrated that as the argon-blowing rate increases from 0 to 15 L/min, the fiuctuation amplitude at the steel-slag interface expands from 6.4 to 14.3 mm. When the argon-blowing rate ranges between 0 and 10 L/min, the shell thickness at both narrow and wide faces increases from 6.68 and 23.1 to 12.38 and 27.11 mm, respectively, but excessive blowing rates lead to shell thinning. The steel exposure behavior is eliminated as the SEN is inclined downward. As the SEN inclination angle decreases from upward 12° to downward 15°, the relationship between the SEN inclination angle and shell thickness growth exhibits nonlinear characteristics. The shell thickness at mold out ranges from 9.71 to 20 mm at the narrow face and 12.49 to 27 mm at the wide face. The superior parameters are with 10 L/min argon fiow and 12° downward nozzle inclination, delivering no slay layer while achieving mold exit shell thicknesses of 11.63 mm at the narrow face and 26.5 mm at the wide face.
  • Jian Pan, Bing Han, Yue Shi, De-Qing Zhu, Yi-Jun Cao, Zheng-Qi Guo, Yi-Xing Liao
    钢铁研究学报(英文版). 2026, 33(4): 126.
    https://doi.org/10.1007/s42243-026-01734-2
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    To address the issues of low process efficiency, high energy consumption, and significant pollution in the traditional Hoganas method for producing reduced iron powder, reduced iron powder for powder metallurgy was prepared using ultrapure magnetite pellets with various compressive strengths by coal-based reduction-hydrogen reduction method. The results show that pellets with compressive strength of 2500 N/pellet ultimately produce a powder metallurgy iron powder with iron grade of 98.24%, hydrogen loss of only 0.5%, bulk density of 2.38 g cm-3, fiow rate of 35.97 s (50 g)-1, and compressibility of 6.41 g cm-3 after reduction for 12 h at a C/Fe mass ratio of 2 and a temperature of 105 C, followed by crushing, fine grinding, and secondary hydrogen reduction at 800 ℃ for 2 h, meeting the standard for FHY100·240. As the compressive strength of ultrapure magnetite pellets increases, the aggregation of metallic iron grains in the reduced pellets intensifies, the porosity of the pellets decreases, and the structure densifies, resulting in a significant increase in the bulk density of reduced iron powder.
  • Li-Long Zhu, Yu-Ting Jin, Nuo Chen, Xiao-Bo Yan, Bing-Zhi Ren, Sheng-Ping He, Hong-Dan Wang, Qian Wang
    钢铁研究学报(英文版). 2026, 33(4): 127.
    https://doi.org/10.1007/s42243-026-01748-w
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    In the continuous casting of medium-carbon steel, highly crystalline mold fiuxes are employed to suppress surface longitudinal cracks; however, the lubrication performance of such mold fiuxes is generally poor. One hypothesis is that the composition segregation of the remaining liquid slag after crystallization in the mold fiuxes leads to the deterioration of lubrication performance, but no direct experimental data currently confirm this hypothesis. Thus, remaining liquid slag in the glassy state after crystallization was obtained by rapidly cooling samples. The composition of original slag, crystals, and remaining liquid slag was analyzed using an electron probe microanalysis system. The performance changes caused by the compositional changes in the remaining liquid slag at 200 lm away from the crystals were calculated using FactSage. The results indicated that the crystalline phase of all mold fiuxes is cuspidine (3CaO·2SiO2·CaF2). After the mold fiuxes precipitate crystals, the content of non-cuspidine components in the remaining slag increases. As for the cuspidine component, the CaO content has significantly decreased. Overall, the content of SiO2 in the remaining slag decreases, while the content of F increases. The experimental results confirmed that there is obvious segregation in the remaining liquid slag after the mold fiux selectively crystallizes. Compared with the original slag, the liquidus temperature of the remaining liquid slag is significantly reduced, and the maximum crystallization ratio of cuspidine also decreases. The poor lubricity of the mold fiuxes for medium-carbon steel is its nature, rather than caused by segregation.
  • Ming-Xia Liu, Hui-Min Zhang, Tie-Jun Chen, Han-Quan Zhang, Fan Yang, Zhao-Hui Yao, Man-Man Lu
    钢铁研究学报(英文版). 2026, 33(4): 128.
    https://doi.org/10.1007/s42243-026-01753-z
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    A comparative study was conducted on the kinetics of coal- and gas-based magnetization roasting processes and the reduction-separation behavior for an oolitic hematite ore. The magnetization reduction rate of roasted ore reached 46.86%when roasting for 45 min under 750 ℃with coal-to-ore ratio of 8% for coal-based system, an optimized concentrate with iron grade and recovery rate of 61.51% and 91.43% could be obtained; for gas-based system, the magnetization rate was 44.34%, and the iron grade and recovery rate reached 58.09% and 94.30% under the optimized roasting temperature of 650 ℃ for 60 min with CO proportion of 30%. Microscopic morphology analyses indicated that the transformation process for both systems was in accordance with the unreacted-core shrinking model. Artificial magnetite was generated layer-by-layer, and the inside oolitic cores were difficult to fully magnetize. Kinetic studies showed that the magnetization reduction process mainly fitted the internal-diffusion-control and chemical-reaction-control model, respectively, for coal- and gas-based systems, with activation energy of 127.80 and 36.68 kJ/mol, indicating that the gas-based system was significantly lower than that of the coal-based system.
  • Zhi-Xiang Liu, De-Ming Xu, Si-Qian Bao, Geng-Wei Yang, Qing-Ming Chang
    钢铁研究学报(英文版). 2026, 33(4): 129.
    https://doi.org/10.1007/s42243-026-01755-x
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    Sulfur segregation at grain boundaries induces hot brittleness in steel, necessitating strict control of sulfur content in conventional non-oriented silicon steel. The ultra-rapid solidification characteristics of the planar fiow casting process can effectively inhibit sulfur segregation, therefore avoiding hot brittleness of silicon steel ribbons caused by sulfur. The effect of sulfur segregation/precipitation on surface quality, microstructure and magnetic properties of Fe-3%Si ultra-thin ribbons prepared with planar fiow casting process is systematically investigated. Results indicate that extensive precipitation of FeS at grain boundaries and internal stresses induced by non-uniform solidification shrinkage leads to crack formation in 0.1%S ribbons. At 0.03%S, nanoscale precipitates (primarily FeS and MnS) distribute uniformly, when sulfur content exceeds 0.06%, and diffuse sulfur aggregation zones emerge. {001} \ 100 [ texture strength and magnetic induction of 0.03%S ribbons increase due to the optimized texture. Compared to 0%S ribbons, the magnetic induction of 0.03%S ribbons increases from 1.598 to 1.608 T. Higher sulfur raises iron loss due to increased grain boundaries and impeded magnetic domain motion. After annealing, 0.03%S ribbons achieve a magnetic induction of 1.625 T, attributed to sulfur inhibiting undesirable {110} and {111} grain growth. However, excessive sulfur restricts grain growth and texture evolution. Fe-3%Si-0.03%S ribbons possess the best magnetic properties after annealing at 1075 ℃, with a magnetic induction of 1.625 T, higher than 1.603 T of Fe-3%Si ribbons as well as a greater iron loss (17.51 W/kg vs. 12.33 W/kg).
  • Hao-Jie Wang, Yu-Fei Chen, Jun-Yu Tian, Fang-Qin Dai, Guang-Qiang Li, Qiang Wang
    钢铁研究学报(英文版). 2026, 33(4): 130.
    https://doi.org/10.1007/s42243-026-01760-0
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    Inclusions and carbides in die steels reduce ladle/mold service life. To mitigate this, La-Ce mixed rare earth (RE) microalloying elements were added to H13 hot-work die steel via the mold-casting suspension method in an industrial test conducted via a 2.5-t three-step process (electric arc furnace-ladle furnace-vacuum refining) combined with ingot casting technology. The results show that RE elements primarily affect the distribution of O and S elements, slightly increasing O content at the steel pouring gate and insignificantly affecting C and N distributions. RE addition modified the inclusion types, converting typical CaAl2O4-CaS composite inclusions into (Ce, La)2O2S-CaS RE-containing ones, reducing the diversity of inclusions in the steel central region, and improving the overall internal quality. The average carbides size dropped by 46.2%, and their distribution became more uniform. After forging, the recovery rate of rare earth elements in the ingot reached 90.72%. The addition of rare earths led to a grain size reduction of up to 13.46% and an improvement in impact toughness by 82.26%. Based on the observed trends in grain size and impact toughness with varying RE contents, the optimal addition range was determined to be 200 9 10-4-260 9 10-4 wt.%.