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2026年, 第33卷, 第9期 刊出日期:2026-09-25
  

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    ORIGINAL PAPERS
  • Hong-Man He, Ting-Le Li, Ming-Xin Wu, Qi Wang, Chang-Yu Sun, Jun-Chen Huang, Liang-Ping Xu, Yong-Qiang Jiang, Guang-Hui Li
    钢铁研究学报(英文版). 2026, 33(9): 249.
    https://doi.org/10.1007/s42243-026-01887-0
    摘要 ( ) PDF全文 ( )   可视化   收藏
    During the blast furnace iron smelting process, the properties of acidic slags are critical to maintaining stable furnace operation. Viscosity, a key slag property, directly influences this stability. However, there is an extreme lack of research on the viscosity behavior and structural characteristics of acidic slag. The effects of w(MgO)/w(Al2O3) (M/A, 0.41-0.86) and FeO content (30-45 wt.%) on the viscosity and structural properties of CaO-MgO-Al2O3-SiO2-FeO slag with a basicity of 0.06 were investigated. The results indicated that both the breaking temperature (Tb) and the flow activation energy (Eg) decreased initially and then increased with rising M/A, reaching minima at M/A of 0.71, with values of 1523 K and 45 kJ mol-1, respectively. When FeO content was increased from 30 to 45 wt.%, Tb decreased from 1696 to 1552 K, and Eg decreased from 65.24 to 35.94 kJ mol-1. Raman spectroscopic analysis revealed that the primary cause of viscosity reduction was depolymerization of the silicate network. Increasing M/A or FeO content promoted the breakdown of Q3 units into lower-order Qn species (Q0-Q2), with a pronounced increase in the Q1 fraction from 27 to 42 mol% at M/A of 0.71. This structural evolution elevated the non-bridging oxygen per silicon, thereby reducing melt viscosity. However, when M/A exceeded 0.71, re-polymerization of Q3 units occurred, leading to a subsequent increase in viscosity.
  • Zhong-Lin Wu, Guang-Ming Cao, Yang Sun, Yi-Fan Ji, Wei-Na Zhang, Cheng-Gang Li, Peng-Jie Wang, Biao Deng, Zhao-Xia Liu, Zhen-Yu Liu
    钢铁研究学报(英文版). 2026, 33(9): 250.
    https://doi.org/10.1007/s42243-026-01791-7
    摘要 ( ) PDF全文 ( )   可视化   收藏
    5.5Ni cryogenic steel was developed through a microalloying design. A lamellar treatment, added between traditional quenching and tempering (QT) processes, is referred to as QLT process. By adjusting the reversed transformation austenite/ferrite phase content in the lamellar microstructure, a fibrous texture was achieved in 5.5Ni cryogenic steel. This adjustment promotes the redistribution of C, Mn, and Ni elements within the microstructure during the subsequent tempering process. This reduces the resistance to deformation of the microstructure by external forces and produces a higher number of high-angle grain boundaries. As the lamellarization temperature decreases, the formation of fiber structures reduces the tendency for martensite variants to form in the microstructure, encouraging the formation of reversed transformation austenite. The self-regulation of martensite variant stress, the blocking of cracks by high-angle grain boundaries, and the deflection effect of reversed transformation austenite on cracks enhance the impact toughness of 5.5Ni cryogenic steel. Additionally, during uniaxial tensile testing, when shear stress is parallel to the habit plane of the slip system, the material exhibits easier sliding and greater plastic deformation. Furthermore, the special textures (Brass, Goss, E-type and copper) in the microstructure promote uniform plastic deformation. Therefore, when shear stress aligns with both the slip plane and the special texture, the plasticity of the material is maximized. Using this process, 5.5Ni cryogenic steel with a yield strength of 658 MPa, elongation of 23.90%, and impact energy of 178 J at 77 K was successfully produced.
  • Xiao-Ming Li, Zhi-Bin Geng, Bao-Rong Wang, Xin-Hua Zhang, Yong-Kun Yang, Wei-An Wang
    钢铁研究学报(英文版). 2026, 33(9): 251.
    https://doi.org/10.1007/s42243-026-01863-8
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Quantitatively determining the effect of volume shrinkage during the peritectic reaction on hot cracking formation is crucial. P91 high-alloy steel was taken as the research object. The solidification process was observed in-situ using a high-temperature confocal laser scanning microscope, and the liquid phase feeding capacity and solidification shrinkage behavior during the phase precipitation and transformation stages of the peritectic reaction were analyzed. A hot cracking susceptibility criterion related to solid-liquid density changes and mushy zone permeability during the peritectic reaction was established to quantitatively calculate the solidification shrinkage volume (Vs) and liquid phase feeding volume (Vf). Theoretical calculations show that Vs reaches the maximum value of 0.601 mm3 when the solid fraction (fs) is 0.839, with the difference between Vf and Vs being approximately 2.52 mm3. Experimental results indicate that Vs peaks at 0.764 mm3 when fs is 0.828, and the difference between Vf and Vs is about 2.69 mm3. The maximum theoretical Vs is 0.163 mm3 lower than the experimental result. The probability of hot cracking is the highest when fs is about 0.99, where Vf is approximately 0.366 mm3, Vs is about 0.118 mm3, and the difference is around 0.248 mm3. Under the experimental cooling rate (10 °C/min), Vf is always greater than Vs, which is consistent with the in-situ observation result of no cracks.
  • Feng Chen, Meng Zhang, Dong-Yue Li, Yu-Feng Guo, Yue-Kai Wen, Hao Li, Shuai Wang, Ling-Zhi Yang
    钢铁研究学报(英文版). 2026, 33(9): 252.
    https://doi.org/10.1007/s42243-026-01877-2
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    The addition of MgO is widely used to improve the high-temperature metallurgical performance of iron ore pellets, including vanadium-titanium magnetite pellets. However, the effects of MgO addition on the oxidation consolidation and low-temperature reduction disintegration behavior of vanadium-titanium magnetite pellets remain unclear. Therefore, magnesium-containing vanadium-titanium magnetite pellets were prepared to systematically investigate their oxidation and reduction behaviors, especially on the reduction disintegration mechanism. The pellets strength initially increased and then decreased as the addition of MgO increased. When the MgO addition increased from 0 to 2.0 wt.%, the compressive strength of roasted pellets rose from 2024 to 2560 N/pellet, and the low-temperature reduction disintegration index showed slight variation. The increase in MgO addition promoted the transformation of (Fe, Ti)2O3 to (Fe, Ti)3O4 especially when it was beyond 3.0 wt.%, accompanying larger unit-cell volume expansion and higher internal stresses. In the above MgO addition range, the reduction disintegration index RDI-3.15 mm exceeded 28%, indicating a marked deterioration in reduction disintegration behavior of magnesium-containing vanadium-titanium magnetite pellets.
  • Xue-Ying Gao, Xin Lin, Yi Ding, Jian-Wei Wei, Ren-Hu Song
    钢铁研究学报(英文版). 2026, 33(9): 253.
    https://doi.org/10.1007/s42243-026-01769-5
    摘要 ( ) PDF全文 ( )   可视化   收藏
    With increasingly stringent environmental regulations, perfluoroisobutyronitrile (C4F7N/CO2) mixed gas has gained considerable attention as a substitute for sulfur hexafluoride (SF6) in gas circuit breakers. However, the mechanisms underlying its influence on the corrosion behavior of copper-tungsten (CuW) contact materials remain unclear. The corrosion behavior and interfacial reaction mechanisms of CuW contacts in SF6 and 9%C4F7N/91%CO2 environments are systematically compared. Corrosion morphology analysis revealed that, compared to SF6, contacts exposed to the mixed gas exhibited significantly increased surface defects including micro-pores and cracks, enlarged cross-sectional voids, and increased remelted tungsten layer thickness from approximately 69 to 94.6 lm. Interfacial reaction analysis indicated that complex chemical reactions occurred between the decomposition products of the mixed gas and the contact materials, generating multiple corrosion products including CuO, Cu2O, CuF2, and WO3. To elucidate the physical nature of enhanced corrosion, a temperature field simulation model was established to simulate the phase transformation behaviors of the contact materials, including melting and vaporization processes. Simulation results demonstrated that the mixed gas environment resulted in higher peak surface temperatures and broader high-temperature regions on the contacts, leading to intensified phase transformations, which corroborated the experimentally observed enhanced corrosion phenomena. The coupled mechanisms of enhanced corrosion of CuW contacts in C4F7N/CO2 mixed gas were elucidated, providing theoretical foundation and data support for the optimized design of contact materials, development of surface protection technologies, and reliability assessment in next-generation environmentally friendly gas circuit breakers.
  • Xiao-Hang Liu, Chang Liu, Ai-Da Xiao, Wen Yan, Guang-Qiang Li, Zhu He, Qiang Wang
    钢铁研究学报(英文版). 2026, 33(9): 254.
    https://doi.org/10.1007/s42243-026-01878-1
    摘要 ( ) PDF全文 ( )   可视化   收藏
    An improved model (MF-GWO-RF) combines the modified formula (MF) with the gray wolf optimization (GWO) and random forest (RF) algorithms to achieve precise prediction of the slag eye area during the ladle refining process. Seven hundred oil eye photographs of the ladle water model water-oil simulation experiment were taken by a high-definition camera. The oil eye area was obtained by binarization, and the training database was established according to a training-to-validation ratio of 8:2. Taking the bottom-blown gas flow rate, the oil layer thickness, and the purging plug position as input variables to predict the oil eye area, the prediction evaluation indices of the gradient boosting decision tree (GBDT), RF, and the deep neural network (DNN) were compared; it was found that the correlation coefficients of GBDT, RF, and DNN were 94.065%, 98.485%, and 91.286%, respectively, while that of the proposed MF-GWO-RF model reached 99.399%. In 140 testing sets, the MF-GWO-RF model had two testing data relative errors of about 20% and 40%, respectively, while those of other testing groups were below 15%. This proved the MF-GWO-RF model’s superiority over the other models in predicting the oil eye area data. The GWO algorithm is utilized to perform global optimization of the RF model, thereby overcoming the limitation of the RF algorithm that relies on grid search for hyperparameter tuning.
  • Yu Ji, Chao Yang, Ting-Ting Xu, Chun-Dong Hu, Han Dong
    钢铁研究学报(英文版). 2026, 33(9): 255.
    https://doi.org/10.1007/s42243-026-01867-4
    摘要 ( ) PDF全文 ( )   可视化   收藏
    The mechanisms governing the high-temperature strengthening of the novel medium-alloy steel 30Cr2Ni3Mo3V are investigated, and tensile tests are conducted in the temperature range of 500-700 °C. Comprehensive characterization was carried out using scanning electron microscopy, high-temperature X-ray diffraction, electron backscatter diffraction, and transmission electron microscopy. Results indicate a progressive decrease in tensile strength with rising temperatures. Notably, at 600 °C, rapid material softening is observed, where the grain boundary strength drops below the intragranular strength, resulting exclusively in transgranular fracture. The degradation of mechanical properties at elevated temperatures is primarily attributed to the dynamic recovery of tempered martensite, recrystallization phenomena, and a reduction in dislocation density. Within the steel matrix, spherical MC carbides are uniformly dispersed, while fine, rod-shaped M23C6 carbides anchor the lath boundaries, effectively retarding grain boundary migration and subsequent grain coarsening. Upon tensile deformation at 700 °C, finer-sized (approximately 3-5 nm) thermally stable MC precipitates form, further contributing to high-temperature strength. Both theoretical analysis and transmission electron microscopy characterization confirm that the dispersion of nanoscale MC carbides and dislocation strengthening synergistically improve the elevated-temperature strength of 30Cr2Ni3Mo3V steel.
  • Ji-Sen Yan, Ming-Hui Wang, Zhi-He Dou, Ting-An Zhang, Fang Xie
    钢铁研究学报(英文版). 2026, 33(9): 256.
    https://doi.org/10.1007/s42243-026-01826-z
    摘要 ( ) PDF全文 ( )   可视化   收藏
    The process of preparing Ti6Al4V via a multistage deep reduction method was systematically investigated. The process, which encompasses magnesiothermic self-propagation and deep reduction, was studied using X-ray diraction, scaning electon microscope-energy dispersivespectroscopy, a laser particle size analyser, inductively coupled plasma spec- tiometere, and an oxygen-nitrogen-hydrogen analyser. The magnesiothermic self-propagation process revealed that the TiO2-V2O5-Al-Mg system starts at a reaction temperature of 908 K. The reaction was initiated by a solid-solid interaction with a reaction order of n = 0.043 and an apparent activation energy of E = 1159.34 kJ/mol. The use of monomeric Al as an aluminium source in the magnesiothermic self-propagation process, along with briquetting of the feedstock and reaction in an Ar atmosphere at 0.6 MPa using local ignition, can yield porous-like precursors with an O content of 15.6 wt.% and a Mg content of 2.80 wt.%. The results of the deep reduction process indicated that the particle size of the precursor affects the O content of the Ti6Al4V alloy powder product. After holding the precursor at 1173 K for 3.5 h, the O content decreased to 0.253 wt.% and the Mg content to 0.01 wt.%. Coral-like Ti6Al4V alloy powders with a specific surface area of 0.45 m2/g were thus obtained.
  • Tong-Ze Xin, Min Wang, Xin-Gang Ai
    钢铁研究学报(英文版). 2026, 33(9): 257.
    https://doi.org/10.1007/s42243-026-01848-7
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Splash dynamics of molten droplets play a critical role in achieving efficient decarbonization and smelting during converter blowing, yet the process mechanisms remain underexplored due to monitoring limitations. A computational model was systematically established for droplet initial conditions through mechanism analysis, employing finite difference methods to simulate droplet trajectories and residence time. The influence of smelting parameters on droplet generation and motion behavior was discussed. Results indicate that as the lance position decreases and oxygen pressure increases, the blowing number, droplet generation rate, characteristic droplet size, and initial droplet angle all increase. Initial droplet velocity displays a U-shaped trend relative to lance position, reaching minimum values at specific positions that shift upward with higher oxygen pressure. Droplet behavior shows strong sensitivity to droplet carbon content, droplet size, slag FeO content, slag height, gas phase fraction, and slag viscosity, while initial angle and velocity demonstrate a weaker influence. Comparative analysis of three 300 t converters reveals inverse correlations between lance position and droplet initial conditions (blowing number, droplet generation rate, diameter, and angle). The difference between initial velocity and angle is small.
  • SHORT COMMUNICATION
  • Jia-Sheng Wang, Yong Zhang
    钢铁研究学报(英文版). 2026, 33(9): 258.
    https://doi.org/10.1007/s42243-026-01932-y
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Partial/local high-entropy (PLHE) design is proposed as an entropy-efficient framework in which configurational complexity is assigned only to selected functional units that govern degradation or performance. Rather than requiring a whole alloy to be high entropy, PLHE design retains a conventional matrix with established processing, cost and service advantages, while entropy is introduced into precipitates, interfaces, sublattices, binders, dispersoids or local environments. Local high entropy confines complexity in space, whereas partial high entropy confines it chemically to selected phases or mixing sites. The operational boundary of PLHE design is defined by the requirement that the entropy-bearing unit be compositionally identifiable, intentionally designed, and mechanistically linked to the targeted response. Configurational entropy should be evaluated at the scale of the designed unit rather than from bulk nominal composition, and long-term stability requires thermodynamic and kinetic verification. By linking entropy-bearing units to mechanism-controlling bottlenecks, including coarsening, defect accumulation, passivation failure and functional coupling, PLHE design offers a selective route for applying high-entropy concepts to steels and related metallic materials.
  • ORIGINAL PAPERS
  • Hong-Ya Li, Yue-Feng Jiang, Yu-Jun Han, Qin Zhang, Li-Jun Ai, Zhen Zhang, Bao-Sen Zhang, Xia Zhao, Qing-Zhong Song, Mei-Qiong Ou, Shu-Bing Hu
    钢铁研究学报(英文版). 2026, 33(9): 259.
    https://doi.org/10.1007/s42243-026-01882-5
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Refractory high-entropy alloys (RHEAs) for extreme service environments require targeted mechanical property optimization. For this purpose, four NbMoTaWV-based RHEA/ceramic composites (undoped N, C-doped NC, 1 wt.% Al2O3-reinforced NCA-1, 5 wt.% Al2O3-reinforced NCA-5) were fabricated via mechanical alloying combined with rapid vacuum hot pressing. The effects of carbon doping and Al2O3 addition on phase composition, microstructure, and hardness were systematically investigated via multi-scale characterization and hardness testing, focusing on the synergy of multiple strengthening mechanisms. Results show that all samples possess ultrafine-grained structures in the nano- to submicron-scale. Carbon doping forms high-hardness W2C and Mo2C carbides, introducing significant precipitation strengthening. 1 wt.% Al2O3 refines and homogenizes grains, promotes the formation of a single (Ta,V)2O5 high-entropy ceramic phase, and achieves highly efficient strengthening synergy. Excessive Al2O3 causes local grain coarsening, breaking the synergistic balance and weakening the strengthening effect. Multi-scale hardness tests confirm the base N sample reaches 1473.19 HV; the NC sample achieves a 5.83% hardness increase; the optimal NCA-1 sample obtains a nearly 10% hardness improvement with a peak nanohardness of 24.558 GPa. The composition-microstructure-property correlation of the four RHEAs was revealed, and the addition of 1 wt.% Al2O3 was identified as the optimal parameter, and a reasonable design guidance for high-performance RHEA fabrication was introduced.
  • Di Zhang, Gang-Sheng Xie, Meng-Xiao Li, Li-Ya Guo, Yu-Lin Xia, Zhou-Yan Cai, Teng-Shi Liu, Han Dong
    钢铁研究学报(英文版). 2026, 33(9): 260.
    https://doi.org/10.1007/s42243-026-01883-4
    摘要 ( ) PDF全文 ( )   可视化   收藏
    The microstructure, inclusion morphology, corrosion resistance and evolutionary mechanisms of electrolytic pure iron are studied at different purity levels under salt-spray corrosion conditions. Electrochemical impedance spectroscopy is conducted, and potentiodynamic polarization curves are plotted and used to assess the corrosion resistance capacity of electrolytic pure iron. The results indicate that the inclusions in electrolytic pure iron primarily contain Fe-Al-O type mixed inclusions. These inclusions generally range in size from 2 to 5 lm. As the purity increases to 4N1, the number of inclusions decreases to 20, and the average ferrite grain size reduces to 4.83 lm. The distribution of columnar crystals is finer and more uniform. The corrosion rate is minimized to its lowest value (1.35 g mm-2 h-1). The enhancement in purity reduces the pit depth from 173 to 71 lm. Moreover, the rust layer thickness decreases from 111.68 to 54.62 lm. Meanwhile, the self-corrosion potential increases and the self-corrosion current decreases. At 4N1 purity, the self-corrosion potential and current are -0.5307 mV and 8.59 lA cm-2, respectively. The primary corrosion products are a-FeOOH, b-FeOOH, c-FeOOH and Fe3O4.
  • Qiang Li, Qian-Qian Xu, Ya-Xiang Zhao
    钢铁研究学报(英文版). 2026, 33(9): 261.
    https://doi.org/10.1007/s42243-026-01875-4
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Amid growing global demand for ultra-high-purity steel, the Ruhrstahl-Heraeus (RH) vacuum refining furnace has emerged as a pivotal technology for the impurity removal in advanced steel production. However, enhancing the efficiency of conventional RH degassers faces two fundamental limitations: constrained snorkel diameter due to ladle mouth size restrictions in traditional twin-circular snorkel configurations, and significant energy dissipation caused by intermixing of ascending and descending flows in single-snorkel systems. An innovative solution is proposed to overcome these limitations through the development of an arched snorkel design featuring bottom tuyere gas injection. The proposed design demonstrates three key advantages: full utilization of the ladle’s mouth area, prolonged bubble retention time achieved through bottom gas injection, and significant improvements in refining efficiency. To rigorously justify the proposed design, a systematic comparative analysis of three RH configurations coupled with bottom gas injection was conducted using Eulerian-Eulerian multiphase simulations: twin-circular snorkels (RH-CB), single large circular snorkel (RH-SB), and twin arched snorkels (RH-AB). Performance was evaluated based on multiple metallurgical parameters, including flow field characteristics, gas injection efficiency, recirculation flow rate, and mixing time. The results demonstrate that the novel RH-AB improves gas injection efficiency by 56.84% and recirculation flow rate by 36.74%, while reducing mixing time by 9.41%, compared to the RH-CB. These improvements are indicative of enhanced refining efficiency and potential reductions in production costs.
  • Ming-Rui Gong, Zhi-Chao Zhao, Xiao-Guang Yang, Sheng-Li Jiang, De-Li Duan
    钢铁研究学报(英文版). 2026, 33(9): 262.
    https://doi.org/10.1007/s42243-026-01886-1
    摘要 ( ) PDF全文 ( )   可视化   收藏
    The sliding friction and wear behavior of cold-rolled austenitic stainless steel paired with two austenitic stainless steels of similar chemical composition is investigated. The results indicate that under low loads, Z5CND17-12 steel (cold-rolled austenitic stainless steel) exhibits strong resistance to abrasive wear due to the strengthening and hardening effects induced by work hardening. The wear mechanisms are primarily abrasive wear and brittle spalling of the hardened surface layer. As the load increases, pronounced plastic deformation and delamination occur on the worn surface, accompanied by intensified adhesive wear. The X-ray diffraction (XRD) analysis confirms that no martensitic phase transformation takes place during sliding. XRD calculation results indicate that increasing the applied load leads to an increase in dislocation density and lattice strain, accompanied by a reduction in grain size. Microcracks are observed in the subsurface region, especially under high-load conditions, indicating inferior resistance to fatigue wear when subjected to high cyclic stresses.
  • Ya-Di Zhao, Chang-Hao Li, Song Liu, Xiao-Jie Liu, Fu-Min Li, Dian-Yu E, Shi-Bo Kuang
    钢铁研究学报(英文版). 2026, 33(9): 263.
    https://doi.org/10.1007/s42243-026-01901-5
    摘要 ( ) PDF全文 ( )   可视化   收藏
    A stable and reasonable gas flow distribution is critical to ensure the stable and efficient operation of blast furnaces, which directly impacts gas utilisation rate and overall smelting performance. However, owing to the harsh internal environment of blast furnaces and the limitations of current sensing technologies, real-time recognition of gas flow distribution patterns is still a major challenge. To address this issue, a central gas flow distribution pattern recognition model was established based on machine learning, which employed multimodal data fusion to integrate infrared images with cross temperature measurements. Specifically, three key feature parameters of the central gas flow, namely, area, temperature, and offset degree, were extracted using entropy and neighbourhood valley-enhanced Otsu method, heat transfer principles, and dual-point tilt correction method, respectively. The convolutional neural network-long short-term memory model was used to forecast the temporal dynamics of these parameters. Through the feature parameters, the proposed Euclidean-weighted fuzzy C-means algorithm was applied to recognise the central gas flow distribution patterns. The results show that the model achieves high accuracy over 95% in parameters prediction and exceeds 90% in pattern recognition, highlighting its potential for intelligent monitoring and control of central gas flow behaviour in blast furnaces.
  • Jue Tang, Ming-Hui Ma, Quan Shi, Man-Sheng Chu, Zhen Zhang, Qi-Chen Hu
    钢铁研究学报(英文版). 2026, 33(9): 264.
    https://doi.org/10.1007/s42243-026-01850-z
    摘要 ( ) PDF全文 ( )   可视化   收藏
    Maintaining stable pressure difference within an appropriate range was a critical approach to ensuring high-quality production, high yield, and low consumption in blast furnaces. A pressure difference prediction model was established based on blast furnace big data, enabling operational staff to proactively manage blast furnaces. Data preprocessing techniques were employed to enhance blast furnace industrial data governance, thereby improving data quality. Feature engineering (FE) was utilized to construct a feature set for pressure difference characterization, incorporating 58 blast furnace parameters selected through recursive feature elimination and 32 derived features generated via variational mode decomposition. These features exhibited strong correlations with pressure difference. Gradient boosting decision tree, light gradient boosting machine, and categorical boosting (CatBoost) were implemented to establish the pressure difference prediction model. The application of FE reduced the mean squared error of prediction models by an average of 14.32%. The hit rate within the ± 2.5 kPa error margin increased by 9.26%. After hyperparameter optimization was performed using the grey wolf optimizer (GWO), the GWO-FE-CatBoost framework achieved optimal predictive performance, yielding a mean absolute percentage error of 0.78%, a mean squared error of 3.07, and a hit rate of 88.62%. Additionally, a periodic optimization mechanism was proposed, which enhanced the hit rate by 7.88% during the testing period. This approach effectively maintained stable high-precision predictive performance. The robust pressure difference prediction results gained unanimous recognition from field engineers. This reliable predictive trend proved essential for facilitating proactive blast furnace control.
  • Zhi-Yong Liu, Xin Ren, Rong Zhu, Xiao-Fang Jia, Kang-Lin Zuo, Rui-Zhi Wang, Guang-Sheng Wei, Chao Feng, Kai Dong
    钢铁研究学报(英文版). 2026, 33(9): 265.
    https://doi.org/10.1007/s42243-026-01870-9
    摘要 ( ) PDF全文 ( )   可视化   收藏
    To overcome the 25%-30% scrap ratio limitation in conventional basic oxygen furnace smelting, a pioneering 500 kg-scale pilot platform was established utilizing bottom-injected carbonaceous materials for high-scrap-ratio smelting. Graphite and sawdust-derived biochar were employed as the carbonaceous materials to provide supplementary heating. Key operational parameters for 25%-40% scrap ratios were determined via a comprehensive mass-energy balance model. Using a batched scrap-charging strategy, stable smelting was achieved at 40% scrap. Comparative analysis demonstrated that graphite offered superior thermal compensation: each kilogram of graphite can melt 7.56 kg of scrap steel, whereas biochar, when used as a heat-supplementing agent, melts an average of 5.16 kg of scrap steel per kilogram. At a 40% scrap ratio, graphite maintained a thermal efficiency of 65%, whereas that of biochar decreased to 48% owing to its high ash content and low fixed-carbon content, inducing slag foaming. Metallurgical indicator improvements included reduced slag oxidation (slag FeO content of 7.8-18.2 wt.% vs. the conventional more than 20 wt.%), a derived quantitative relationship (coefficient of determination, R2 = 0.912), increased metal yield (88%-91%), and minimized hot-metal consumption (659 kg/t). For industrial applications, further work is needed to reduce the cycle length (graphite of 34 min, biochar of 39 min) and endpoint sulfur levels (average of 0.038 wt.%) to reduce the need for secondary refining.
  • Jin-Yue Li, Chao-Gang Zhou, Wei Gong, Shu-Huan Wang, Da-Chao Qi, Xu Gao, Bing Deng, Qing Zhao, Pei-Wei Han
    钢铁研究学报(英文版). 2026, 33(9): 266.
    https://doi.org/10.1007/s42243-026-01889-y
    摘要 ( ) PDF全文 ( )   可视化   收藏
    As metallurgical solid wastes, red mud and converter slag require substantial storage space and pose serious environmental risks. Owing to their abundant Fe and Al contents, red mud can serve as a modifier for converter slag. The phase evolution and degree of polymerisation of the slag before and after modification and leaching were characterised by X-ray diffraction, scanning electron microscopy-energy dispersive spectroscopy, Raman spectroscopy, and Fourier transform infrared spectroscopy. Increasing the red mud addition from 0 to 8 wt.% raised the P content of the P-rich phase from 3.62 to 4.58 wt.% and maximised the polymerisation degree of the slag. Post-modification, the P-rich phase transformed from Ca2P2O7 to a C2S-C3P (2CaO·SiO2-3CaO·P2O5) solid solution, with its domain size enlarged and sharp, well-defined phase boundaries formed. While the unleached slag remained chemically inert during leaching, leaching the modified slag selectively dissolved the C2S-C3P phase, achieving a P extraction efficiency of 66.13%. X-ray diffraction patterns revealed a pronounced decrease in the intensity of C2S-C3P diffraction peaks, whereas the Fe-bearing matrix phase showed negligible changes, confirming the selective leaching of P. The resulting low-P residue can be recycled back to the steel plant for hot-metal pretreatment or converter dephosphorisation processes, whereas the P-bearing precipitate is a potential feedstock for phosphate fertiliser production.
  • Yi Duan, Guang Chen, Xiang-Jun Bao, Lu Zhang, Xiao-Jing Yang
    钢铁研究学报(英文版). 2026, 33(9): 267.
    https://doi.org/10.1007/s42243-026-01856-7
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    As a core high-energy-consuming unit in the steel industry, the steel rolling reheating furnace (SRRF) presents a critical technical challenge in achieving energy savings and carbon emission reduction through accurate energy consumption prediction. The multivariable coupling and high-dimensional nonlinear characteristics of SRRF operational data were addressed by systematically evaluating four feature selection methods: principal component analysis (PCA), process-driven feature engineering, Spearman correlation filtering, and random forest (RF) feature importance. These methods were integrated with two machine learning algorithms, RF and gradient boosting regression tree (GBRT), to develop predictive models for specific energy consumption. Based on 2000 real production data samples collected from a steel plant, a high-quality dataset of 1251 samples was constructed using a combined boxplot-process threshold filtering strategy. To eliminate dimensional inconsistencies, all features were normalized using the min-max scaling method. Experimental results show that using the top nine features identified by RF importance ranking (accounting for approximately 50% of total features), the GBRT model achieved optimal prediction performance, with a test set root mean square error (RMSE) of 0.1032 GJ/t and a coefficient of determination (R2) of 0.8830, while reducing the training time by 33.1% compared to the model trained on the full feature set. In contrast, while PCA improved computational efficiency by 42.3%, it also increased the RMSE by 25.8%. The correlation-based method and process-driven feature construction exhibited context sensitivity and local optimization effects, respectively. The findings demonstrate that the model-driven feature selection strategy based on RF importance, combined with ensemble learning GBRT, effectively balances dimensionality reduction and information retention, offering an interpretable and efficient solution for intelligent prediction and control of the SRRF.
  • Wei-Gang Lv, Jin-Hua Peng, Ze-Xin Wang, Zi-Meng Xiao, Jun Ma, Liang-Yu Chen, Sheng Lu, Dubovyy Oleksandr
    钢铁研究学报(英文版). 2026, 33(9): 268.
    https://doi.org/10.1007/s42243-026-01885-2
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    To address the excessively rapid degradation issue of magnesium (Mg) alloys, ZK60/hydroxyapatite (HA) composites were fabricated via multi-pass friction stir processing (FSP). The effects of rotational speeds (1300, 1500, 1700 r/min) and FSP passes (1, 3, 5) on the microstructure and comprehensive performance of the composites were investigated through microstructure observation, mechanical property test, electrochemical measurements and antimicrobial assays. Microstructural analysis revealed that grain refinement and uniform HA dispersion are achieved due to the severe plastic deformation and dynamic recrystallization. S1500-3 composite (1500 r/min, 3 FSP passes) exhibits optimal comprehensive properties with the average grain size of 1.53 μm, ultimate tensile strength of 226.3 MPa and microhardness of 65.9 HV0.1. Micro-area electrochemical analysis indicates uniform current density distribution in Hank’s solution while polarization curves reveal a maximum corrosion potential of -1.3397 V, confirming the excellent corrosion resistance of S1500-3 composite. Antimicrobial assays demonstrated that S1500-3 composite exhibited an 87.27% antibacterial rate against Escherichia coli (E. coli) due to the uniformly dispersed HA particles. This work verifies that optimized multi-pass FSP enables ZK60/HA composites with integrated mechanical properties, corrosion resistance and antibacterial performance, laying a solid foundation for their application as bone implant materials.
  • Xu-Yang Wang, Ya-Qiang Li, Guang-Qian Zhu, Bao-Chen Han, Jian-Hua Liu, Yang He, Xue-Wu Hu, Hao Liu, Yao-Li Ji, Yan Zhang, Yu-Xi Liu
    钢铁研究学报(英文版). 2026, 33(9): 269.
    https://doi.org/10.1007/s42243-026-01900-6
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    High-manganese twinning-induced plasticity (TWIP) steels exhibit an outstanding combination of strength and ductility; however, their industrial application is limited by pronounced elemental segregation and coarse columnar grains that develop during solidification. Fe-23Mn-0.45C-1Al-1Cu TWIP steels were fabricated through copper-mold injection rapid solidification to systematically examine the effects of rare-earth lanthanum (La) additions (0-0.20 wt.%) on solidification microstructure, elemental segregation, and inclusion behavior. The results showed that a moderate La addition (0.05 wt.%) promoted the columnar-to-equiaxed transition, increased the fraction of equiaxed grains, refined the secondary dendrite arm spacing, and effectively suppressed Mn, Cu, and C segregation between dendrites. La forms fine, dispersed inclusions such as La2O3, LaAlO3, and La2O2S, which possess a lattice misfit below 6% with c-Fe, acting as potent heterogeneous nucleation cores that work together to refine the solidification structure through enhanced constitutional undercooling. However, excessive La additions (≥ 0.10 wt.%) lead to inclusion to being coarsen and cluster, thus weakening the nucleation potency and aggravating segregation. The dual role of La in refining solidification microstructure and regulating solute segregation under non-equilibrium solidification is revealed.
  • Zhen-Yu Cai, Hui Li, Hu-Yuan Sun, Qing-Yuan Yang, Li-Juan Sun, Hong-Bin Sun, Ji-Zhou Duan, Ting-Ting Zhang
    钢铁研究学报(英文版). 2026, 33(9): 270.
    https://doi.org/10.1007/s42243-026-01763-x
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    The corrosion of oxide scale on Q370qENH weathering steel and Q355C low-carbon steel within a simulated tropical marine environment was investigated. The results demonstrate that the oxide scales of both steels afforded protective effects to steel substrates at the initial corrosion stage but gradually deteriorated and ultimately failed with prolonged exposure. X-ray diffraction analysis (XRD) revealed the oxide scale composition of both steels to be magnetite (Fe3O4), hematite (a-Fe2O3), and wustite (Fe0.9O), with Q370qENH steel exhibiting a relatively lower mass fraction of Fe3O4 and a relatively higher mass fraction of Fe0.9O. The (Fe7.6Ni0.4)O6.44(OH)9.56Cl1.16 and Fe8O8(OH)8Cl1.35 were detected by XRD within the rust layers of Q370qENH and Q355C steels, respectively, with both compositions classified as akaganeite (b- FeOOH). The rust layer of Q370qENH steel contained NiO, NiFe2O4, Cr(III) oxide, FeCr2O4, and NiCr2O4. Under cyclic wet-dry conditions, the oxide scale failure time was approximately 80 d. Q370qENH steel exhibited lower corrosion mass loss, but it exhibited relatively more severe and wider-spread pitting compared to Q355C steel.
  • Xi Chen, Wei-Yao Liang, Yan-Wu Dong, Ao Wang, Zhou-Hua Jiang, Yu-Xiao Liu
    钢铁研究学报(英文版). 2026, 33(9): 271.
    https://doi.org/10.1007/s42243-026-01880-7
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    A collaborative framework integrating phase diagram digitization, sparse region identification, molecular dynamics simulations, modified Arrhenius equation fitting, and adaptive multi-source ensemble learning is developed for viscosity prediction of CaF2-CaO-Al2O3/SiO2 slag systems in electroslag remelting. The methodology overcomes challenges posed by high-temperature measurement limitations and sparse compositional coverage by expanding experimental data through systematic phase diagram analysis and supplementing missing values via molecular dynamics simulations in the liquid phase region and empirical extrapolation. An adaptive ensemble strategy combining categorical boosting, eXtreme gradient boosting, and support vector regression achieves test-set performance metrics: 0.0413 for mean squared error, 0.0886 for mean absolute error, and 0.857 for R2 (coefficient of determination), representing a 5.8-fold increase in compositional-temperature space coverage with minimal experimental cost. Microstructural analysis reveals that Al2O3 functions as a ‘‘weak network former’’ with a critical threshold at 20%, while SiO2 acts as a ‘‘strong network former’’ with a polymerization transition at 4 wt.%. The quantitative mapping of bridging oxygen ratios, Qn distribution, and network density to viscosity evolution establishes the composition-structure-property relationship at the atomic scale. A low-viscosity operational window (20% Al2O3-4% SiO2) is proposed for slag system optimization.
  • Yi-Hui Lv, Yue Zhao, Lin Cai, Ting-Ting Zhang, Chao Zhang
    钢铁研究学报(英文版). 2026, 33(9): 272.
    https://doi.org/10.1007/s42243-026-01881-6
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    WTaNbMo/Inconel 718 composite coatings were successfully fabricated using magnetic field-assisted laser cladding. Numerical simulations of the magnetic field-assisted laser cladding process were conducted to elucidate the influence of the magnetic field on the temperature and flow fields of the molten pool. The applied magnetic field enhanced melt convection, which promoted heat exchange with the laser beam and led to a more uniform energy distribution, thereby improving both the macroscopic forming quality and the microstructure of the coating. Furthermore, the influence of Inconel 718 content on the microstructure, hardness, and corrosion resistance was systematically investigated. Experimental results demonstrated that increasing the Inconel 718 content effectively eliminated micro-defects and significantly improved the corrosion resistance, albeit with a concomitant reduction in coating hardness. An optimal balance between hardness and corrosion resistance was achieved at 30 wt.% Inconel 718 content, with a hardness of 849.48 HV and a corrosion rate of 0.112 mm a-1. The superior corrosion resistance is primarily attributed to the formation of a protective passive film enriched with Cr2O3, NiO, and Ni(OH)2, which acts as an effective barrier against chloride ion penetration and suppresses anodic dissolution.
  • Xiao-Dong Zhang, Jia-Yin Wang, Zhi-Xuan Wang, Wen-Qi Wang, Jin-Chi Zhang, Zhen-Hua Bai
    钢铁研究学报(英文版). 2026, 33(9): 273.
    https://doi.org/10.1007/s42243-026-01858-5
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    Aiming at the problems of insufficient accuracy of traditional theoretical models and weak physical interpretability of artificial neural networks, a rolling force prediction method combining finite element data enhancement and physical information neural network (PINN) was proposed. A finite element model of a six-high cold rolling mill was constructed, and the scaled expansion of sample data was achieved by simulating multi-parameter coupling working conditions (the error between simulation values and real values was not above 5%). Two types of PINN frameworks were constructed, which incorporated process-sensitive physical features (such as the partial differential relationships of reduction and tension difference) and the Hill formula, respectively, realizing the in-depth integration of data-driven approaches and physical mechanisms. The Bayesian optimization algorithm was used for global optimization of model hyperparameters (such as the number of hidden layers, learning rate, and weight of physical loss), ensuring that each model achieved the optimal configuration. Combined with Spearman correlation coefficient and SHapley Additive exPlanations value analysis, quantitative research was conducted on the monotonicity and influence degree of each feature. The research showed that the determination coefficient of the process-sensitive physical feature model was 0.9711, and the root mean square error was 0.0159. Additionally, this model exhibited the fewest data points exceeding the 5% error threshold in the test set, showcasing the best prediction accuracy.
  • Nan-Lv Liu, Guang-Zhou Lu, Ke-Qing Cai, Bei-Ping Xu, Li-Wen Huang, Ling-Zhi Yang, Kai Feng
    钢铁研究学报(英文版). 2026, 33(9): 274.
    https://doi.org/10.1007/s42243-026-01904-2
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    Traditional basic oxygen furnace (BOF) decarburization kinetic models often neglect material transport between zones and therefore fail to capture the dynamic evolution of carbon. To overcome these limitations, a modified kinetic model is proposed based on a multi-field coupled diffusion mechanism. First, candidate kinetic models for the BOF blowing process are reviewed. A three-zone framework that explicitly incorporates process control parameters is then selected based on industrial applicability and predictive accuracy. Within this framework, inter-zone diffusion flux terms are introduced to formulate carbon mass-transfer equations between the jet impact, emulsion, and slag-metal reaction zones. Diffusion driven by carbon concentration gradients is used to represent mass-transfer processes induced by intense convection and emulsification in the melt pool. The key diffusion coefficients, which cannot be measured directly, are identified by parameter inversion using industrial smelting data, and a ‘‘primary-to-secondary, stepwise optimization’’ calibration strategy is proposed. Using 9199 heats for training and 2300 heats for independent validation, the calibrated model accurately reproduces the nonlinear decrease in carbon content during the middle and final stages of blowing. Compared with the baseline kinetic model, the hit rate of end-blowing temperature-sampling-oxygen carbon predictions within the ± 0.025% error band increases from 37.54% to 58.84% after integrating process control parameters and further to 90.71% after adding the coupled diffusion term; the mid-blowing temperature-sampling-carbon hit rate within ± 0.3% simultaneously rises from 52.48% to 82.58% and 85.57%, respectively. These quantitative results confirm the effectiveness and engineering applicability of the proposed model and calibration strategy.
  • Xu-Yuan Zhang, Xiao-Guang Zhou, Si-Qiao Wang, Xin-Yao Zhang, Si-Wei Wu, Guang-Ming Cao, Hong-Bing Wang, Chun-Yang Shu, Zhen-Yu Liu
    钢铁研究学报(英文版). 2026, 33(9): 275.
    https://doi.org/10.1007/s42243-026-01866-5
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    Accurate determination of the relationship among composition, process, and properties is crucial for predicting the yield strength of HRB400E rebar and enhancing the stability of its yield strength. Four yield strength prediction models of HRB400E rebar built using the random forest (RF) algorithm are compared, and a reverse process design is conducted based on the optimal model. The first model is an RF model driven solely by industrial big data, the second is an RF model with optimized hyperparameters (optimized RF model), the third combines physical metallurgy (PM) with industrial big data (PM-RF model), and the fourth is a dual-driven model of optimized PM and industrial big data (optimized PM-RF model). In the establishment of the optimized RF and optimized PM-RF models, a dynamic hyperparameter optimization algorithm was introduced, employing the Optuna optimization framework to optimize the curve parameters of an improved particle swarm optimization (PSO) algorithm with sigmoid-like inertial weight (Optuna-S-PSO). During the establishment of the PM-RF and optimized PM-RF models, the newly introduced input parameters, including ferrite grain size (da) and the fraction of precipitated phases in ferrite (f pa), were calculated using the PM model. The results demonstrate that the application of the Optuna-S-PSO algorithm, along with the inclusion of PM parameters, significantly improves the models’ prediction accuracy. Among these, the optimized PM-RF model exhibited the highest yield strength prediction accuracy, with the coefficient of determination, root mean square error, and mean absolute error values of 0.856, 4.00 MPa, and 3.31 MPa, respectively. Based on this model, the SHapley Additive exPlanation (SHAP) method was used to comprehensively analyze the effects of composition, rolling parameters, and microstructure on the material’s yield strength. Ultimately, the yield strength fluctuation range of multi-specification HRB400E rebar is effectively reduced by reversely designing the rolling speed based on the optimized PM-RF model.
  • Peng-Fei Zhang, Wan-Ming Li, Chuan-Bo Yan, Jia-Qi Fang, Yu-Xing Zhao, Song Huang
    钢铁研究学报(英文版). 2026, 33(9): 276.
    https://doi.org/10.1007/s42243-026-01897-y
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    Accurate prediction of mechanical properties during medium-heavy plate rolling is of great significance for improving rolling qualification rates and optimizing alloy composition. Based on the actual production data of steel grades A and B, a hybrid approach integrating metallurgical mechanisms, data analytics, and expert knowledge was employed for feature selection. A random forest surrogate-based Bayesian optimization of extreme gradient boosting (RF-BO-XGBoost) model was developed to predict yield strength, tensile strength, and elongation. In the Bayesian optimization (BO) procedure, the conventional Gaussian process (GP) surrogate was replaced with a random forest (RF) model. This modification improves compatibility with the high-dimensional and nonlinear characteristics of rolling data and accelerates hyperparameter-search convergence. Comparisons with extreme gradient boosting (XGBoost), light gradient boosting machine (LightGBM), Bayesian optimization-LightGBM (BO-LightGBM), and Gaussian process-based Bayesian optimization of XGBoost (GP-BO-XGBoost) showed that RF-BO-XGBoost achieved the best overall performance. Relative to GP-BO-XGBoost, the proposed model reduced the iteration count and convergence time by 14.6% and 32.4%, respectively. SHapley Additive exPlanations analysis identified final rolling thickness and composition-related variables, including Ceq, Ti, Nb, and V, as important factors affecting mechanical properties, supporting the physical interpretability of the model. After implementation in the plant control system, the model increased the qualification rate of steel grade A by 2.2 percentage points, reduced its Nb content by 1.4%, and increased the elongation of steel grade B by 6.5%.
  • Qian-Qian Dong, Xiang-Yu Li, Jiang-Wen Li, Hong-Lian Wang
    钢铁研究学报(英文版). 2026, 33(9): 277.
    https://doi.org/10.1007/s42243-026-01922-0
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    Accurate prediction of oxygen consumption in the basic oxygen furnace (BOF) steelmaking process is essential for precise process control, high-quality steel production, and energy efficiency. However, the intrinsic complexity of physicochemical reactions, fluctuations in raw materials, and the frequent occurrence of missing and abnormal values in industrial data hinder the effectiveness of existing models, which often suffer from high computational cost, limited adaptability, and poor robustness. To address these challenges, a unified anomaly detection, missing data imputation, and prediction framework are proposed, which integrate neighborhood-enhanced representation learning and physics-informed constraints to enable robust oxygen consumption prediction in BOF steelmaking under abnormal and incomplete data conditions. Specifically, the isolation forest is first employed for anomaly detection, replacing outliers with missing values. Then, a neighborhood-enhanced and physics-informed variational autoencoder is developed to perform structure-aware missing data imputation and oxygen consumption prediction in an end-to-end manner by combining latent representation learning with oxygen balance-based physical guidance. Experimental results on real BOF production data from Ansteel Group demonstrate that the proposed method achieves a mean absolute error of 91.40 m3, a mean relative error of 0.69%, a root-mean-square error of 118.20 m3, and a coefficient of determination of 0.78. In addition, a hit rate of 90.8% within a ± 200 m3 tolerance range is obtained on the test set, significantly outperforming conventional ensemble learning and deep learning approaches.
  • Xiao-Dong Ping, Ling-Bing Kong, Pei-Min Guo, Lei Wang, Mu Zhou, Yu-Chuan Yan
    钢铁研究学报(英文版). 2026, 33(9): 278.
    https://doi.org/10.1007/s42243-026-01862-9
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    The efficient comprehensive utilization of vanadium-titanium magnetite is still a major challenge. In the context of low-carbon development, the low-temperature reduction separation is an appropriate process path. Sodium-based additives can significantly lower the reduction temperature. However, the high addition ratios reported in existing studies tend to exacerbate equipment corrosion and environmental concerns. The high-temperature characteristics of different sodium-based additives and the reduction thermodynamics, kinetics, and reduction separation effects assisted by these additives were thus examined to provide a reference for the application of the low-temperature reduction process utilizing low-proportion sodium-based additives. The results showed that Na2CO3 had the best reduction effect. The low melting point of NaOH exacerbated material adhesion to the reduction equipment. NaCl did not promote the reduction of FeTiO3, and the introduced Cl element would affect the composition of the flue gas. The S element introduced by Na2SO4 would enter the solid reduced product and form Fe1-xS. Under low-temperature and low-proportion additives conditions, the water leaching-magnetic separation effect was poor. Melting separation proved to be the preferred option, as it also circumvented the environmental issues associated with water leaching. After reduction (Na2CO3 content of 9 wt.%, temperature of 1000 °C, time of 60 min, C/O ratio of 1.0), the metallization rate reached 94.82%. After further melting (temperature of 1500 °C, time of 60 min), the Fe recovery rate in the iron nugget was 97.83%, and the Ti and V recovery rates in the slag were 100% and 99.34%, respectively. Slag could be subjected to vanadium-titanium extraction treatment.
  • Ji-Jie Ding, Xiao-Chen Wang, Hai-Nan He, Quan Yang, Dong Xu
    钢铁研究学报(英文版). 2026, 33(9): 279.
    https://doi.org/10.1007/s42243-026-01959-1
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    Head-end deviation at the finishing entry is strongly influenced by asymmetric roughing transfer-bar geometry, whereas direct measurements of strip posture and head-end shape are generally unavailable before biting at the first finishing stand (F1). To characterize this incoming asymmetry, the exit centerline curve of the second roughing stand (R2) is used as an upstream measurable descriptor and converted into a transfer-bar state representation. The centerline curve is classified into L-, C-, and S-type dominant camber patterns and parameterized by the signed head-end camber amplitude, camber length, global offset, and global deflection angle. These descriptors are introduced into a three-dimensional finite element model of the entry edger roll-strip-mill roll system. A representative industrial case is used for load-level validation, and the average relative error of the F1 total rolling force is 8.39%. The results show that local head-end camber and global offset affect head-end deviation more strongly than entry posture. Local head-end camber changes the strip-head contact sequence and promotes sustained lateral displacement development, whereas global offset redistributes the entry constraint and produces a larger peak deviation. The effect of edger-roll displacement is state dependent, acting through local strip-head contact under camber-dominated conditions and through body-entry position adjustment under offset-dominated conditions. The proposed representation links roughing-side centerline morphology with finishing-entry contact response.