Energy Saving and Environmental Protection
WANG Guangwei, WEI Kang, XU Yingtie, TAO Xuan, ZHAN Xiaoting, LIU Jiangbin, NING Xiaojun, WANG Chuan
Foamed slag technology is the core process of ultra-high-power electric furnace steelmaking, which is crucial for enhancing thermal efficiency, protecting furnace lining and optimizing molten steel quality. It takes biomass charcoal as the research object, systematically analyzed its performance and influencing factors as a blowing agent, and compares it with traditional fossil-based blowing agents (coke, graphite, anthracite). Waste wood block charcoal, corn stover charcoal, waste bamboo charcoal and industrial wood charcoal were used in the experiment, combined with chemically formulated electric furnace slag, and their foaming ability was evaluated by high-temperature foaming experiments with comprehensive foaming index (K). The results showed that the waste wood charcoal showed the best overall performance due to its high fixed carbon and low ash. The corn stover charcoal significantly reduced the viscosity of the slag due to its high ash content and high alkali metal content, resulting in the worst foaming area and duration. The waste bamboo charcoal, although with the highest fixed carbon, had a high potassium content in the ash content that exacerbated the deterioration of the foam stability, and had a second best overall performance than that of the waste wood charcoal. Compared with fossil blowing agents, graphite showed the highest maximum foaming area and comprehensive foaming index, but industrial wood charcoal showed substitution potential by virtue of its longer foaming time and low-carbon environmental protection characteristics. The synergistic effects of slag alkalinity, viscosity and surface tension on foaming performance were further revealed. It was pointed out that alkali metals (e.g., K, Na) in the ash fraction of biomass char reduced the viscosity by disrupting the silica-oxygen network, but an excessive amount shortened the foam life. This study meets the development needs of green metallurgy under the "double carbon" strategy, and provides a theoretical basis for the large-scale application of biomass carbon in electric furnace steelmaking.