Abstract：Seconclary refining is an important turning point in the control of nonmetallic inclusions in steel during the steelmaking process. The ladle-lining refractory are always confronted with severe physiochemical reactions during the whole secondary refining process, which leads to the introduction of inclusions in the molten steel and resulting in less than expected refining results. The interface reaction between ladle-lining refractories and the molten steel and introduce the resulting influences on the formation of inclusions was focused, and it was found that the ladle lining refractory material will affect the morphology, composition and physical and chemical properties of the inclusions in the steel. It is possible not only to introduce inclusions into the steel, but also to absorb and remove them. It is proposed that the future refractory materials for ladle lining should be given more development direction for the purification of molten steel and other functional indicators.
侯新梅, 刘云松, 王恩会. 钢包内衬用耐火材料对钢中非金属夹杂物的影响[J]. 钢铁, 2020, 55(6): 15-24.
HOU Xin-mei, LIU Yun-song, WANG En-hui. Effect of ladle-lining refractory on non-metallic inclusions in steel. Iron and Steel, 2020, 55(6): 15-24.
[1] Moghaddam S M, Sadeghi F, Paulson K, et al. Effect of non-metallic inclusions on butterfly wing initiation, crack formation, and spall geometry in bearing steels[J]. International Journal of Fatigue,2015, 80: 203. [2] Liu H, Liu J, Michelic S K, et al. Characterization and analysis of non-metallic inclusions in low-carbon Fe-Mn-Si-Al twip steels[J]. Steel Research International, 2016, 87(12): 1723. [3] GUAN J, WANG L, ZHANG C, et al. Effects of non-metallic inclusions on the crack propagation in bearing steel[J]. Tribology International, 2017, 106: 123. [4] Lund T B. Sub-surface initiated rolling contact fatigue—influence of non-metallic inclusions, processing history,and operating conditions[J]. Journal of ASTM International, 2010, 7(5): 1. [5] Shibaeva T V, Laurinavichyute V K, Tsirlina G A, et al. The effect of microstructure and non-metallic inclusions on corrosion behavior of low carbon steel in chloride containing solutions[J]. Corrosion Science, 2014, 80: 299. [6] 韩少伟,郭靖,陈兴润,等.低碱度渣冶炼304不锈钢脱硫热力学和工业试验[J].钢铁, 2018, 53(6): 47.(HAN Shao-wei,GUO Jing,CHEN Xing-run ,et al. Thermodynamics of desulfurization and industrial trials for refining of 304 stainless steel with low basicity slag[J]. Iron and Steel, 2018, 53(6): 47. ) [7] 罗衍昭,田志红,李向奎,等. 超低碳IF钢中夹杂物来源的示踪分析[J]. 中国冶金, 2019, 29(9): 56. (LUO Yan-zhao,TIAN Zhi-hong,LI Xiang-kui,et al. Analysis of inclusions source in ultra-low carbon IF steel by tracer method[J]. China Metallurgy, 2019, 29(9): 56.) [8] Shim J H, Cho Y W, Chung S H, et al. Nucleation of intragranular ferrite at Ti2O3 particle in low carbon steel[J]. Acta Materialia,1999, 47(9): 2751. [9] Madariaga I, Gutierrez I. Role of the particle-matrix interface on the nucleation of acicular ferrite in a medium carbon microalloyed steel[J]. Acta Materialia, 1999, 47(3): 951. [10] 杨俊,杜江,陈波涛,等.超低氧精炼时钙处理对氧化物夹杂的影响[J].钢铁, 2015, 50(1): 19. (YANG Jun, DU Jiang, CHEN Bo-tao, et al.Influence of calcium treatment on oxide inclusions in ultra-low oxygen refining process[J]. Iron and Steel, 2015, 50(1): 19. ) [11] WANG L, YANG S, LI J, et al. Effect of Mg addition on the refinement and homogenized distribution of inclusions in steel with different Al contents[J]. Metallurgical and Materials Transactions B, 2017, 48(2): 805. [12] 王新华,姜敏,于会香,等. 超低氧特殊钢中非金属夹杂物研究[J]. 炼钢,2015, 31(6): 1. (WANG Xin-hua, JIANG Min, YU Hui-xiang, et al. Investigation on non-metallic inclusions in ultra-low oxygen special steels[J]. Steelmaking, 2015, 31(6): 1.) [13] 刘彭, 隋亚飞, 徐刚军,等. 低碳钢夹杂物产生原因及控制[J].钢铁,2020,55(2):67.(LIU Peng, SUI Ya-fei, XU Gang-jun, et al.Inclusion generation and control of low carbon steel[J].Iron and Steel,2020,55(2): 67.) [14] LI J Z, JIANG M, HE X F, et al. Investigation on nonmetallic inclusions in ultra-low-oxygen special steels[J]. Metallurgical and Materials Transactions B, 2016, 47(4): 2386. [15] 杨虎林,何平,翟玉春.高品质轴承钢超低氧含量和非金属夹杂物控制的进展[J]. 特殊钢,2013, 34(2): 16. (YANG Hu-lin, HE Ping, ZHAI Yu-chun. Progress on control of ultra-low-oxygen content and non-metallic inclusions in high quality bearing steel[J]. Special Steel,2013, 34(2): 16.) [16] Park J S,Park J H.Effect of slag composition on the concentration of Al2O3 in the inclusions in Si-Mn-killed steel[J].Metallurgical and Materials Transactions B,2014,45(3): 953.) [17] Sawai T, Wakoh M, Ueshima Y, et al. Analysis of oxide dispersion during solidification in Ti, Zr-deoxidized steels[J]. ISIJ International, 1992, 32(1):169. [18] 王恩会, 陈俊红, 侯新梅. 钢包工作衬用耐火材料的研究现状及最新进展[J]. 工程科学学报, 2019, 41(6): 695. (WANG En-hui, CHEN Jun-hong, HOU Xin-mei. Current research and latest developments on refractories used as ladle linings[J]. Chinese Journal of Engineering,2019, 41(6):695.) [19] 俞海明. 转炉钢水的炉外精炼技术[M]. 北京:冶金工业出版社, 2011. (YU Hai-ming. External Refining Technology of Converter Molten Steel[M]. Beijing: Metallurgical Industry Press, 2011.) [20] Yusasa G, Sugiura S, Fujine M. Oxygen content in refractories[J]. Transaction ISIJ, 1983, 23: 289. [21] Bannenberg N. Demands on refractory material for clean steel production[C]//In UNITECR'95 Congress.[S.l.]:Unified International Technology Conference on Refractories,1995:4.) [22] 戴文斌,于景坤.纯净钢冶炼用耐火材料[J]. 材料与冶金学报, 2003(1): 3. (DAI Wen-bin, YU Jing-kun. Refractory for clean steel making[J]. Journal of Materials and Metallurgy, 2003(1): 3.) [23] 陈肇友,田守信.耐火材料与洁净钢的关系[J]. 耐火材料, 2004, 38(4): 219.(CHEN Zhao-you, TIAN Shou-xin. Relationship between clean steel and refractories[J]. Refractories, 2004, 38(4): 219.) [24] 钟香崇. 展望新一代优质高效耐火材料[J]. 耐火材料, 2003(1): 1. (ZHONG Xiang-chong. Looking ahead-A new generation of high performance refractory ceramics[J]. Refractories,2003 (1): 1.) [25] Chang-ming K, Nan L, Ji-ning M. Contribution of lime based tundish working lining to clean steel making[C]// Proceedings of 38th Annual Conference of Metallurgists of CIM-Advances in Refractories for the Metallurgical Industries Ⅲ. Canada:[s.n.], 1999:177. [26] Yao-wu W, Nan L. Refractories for clean steelmaking[J]. American Ceramic Society Bulletin, 2002, 81(5): 32. [27] Chan C F, Ko Y C. Effect of CaO content on the hot strength of alumina-spinel castables in the temperature range of 1 000 to 1 500 ℃[J]. Journal of the American Ceramic Society, 1998, 81(11): 2957. [28] 李乃动,谢宜才,燕宿祥,等.添加物对高铝砖结构和性能的影响[J]. 耐火材料, 1999, 33(3), 158.(LI Nai-dong, XIE Yi-cai, YAN Su-xiang et al. Effect of additives on the structure and properties of high alumina bricks[J]. Refractories, 1999, 33(3), 158.) [29] 赵伟. 炉外精炼及铁水预处理实用技术手册[M]. 北京:冶金工业出版社,2004.(ZHAO Wei. Practical Technical Manual for Furnace Refining and Hot Metal Pretreatment[M]. Beijing: Metallurgical Industry Press,2004.) [30] 姚华柏,姚苏哲,骆昶,等. 镁碳砖的研究现状与发展趋势[J]. 工程科学学报, 2018, 40(3): 253.(YAO Hua-bo, YAO Su-zhe, LUO Chang, et al. Current research and developing trend of MgO-C bricks[J]. Chinese Journal of Engineering,2018, 40(3): 253.) [31] 王德永. 洁净钢与清洁辅助原料[M]. 北京:冶金工业出版社, 2017. (WANG De-yong. Clean Steel and Cleaning Auxiliary Materials[M]. Beijing: Metallurgical Industry Press,2017.) [32] 北村.タアグネツアの水化特性[J].Taikabutsu, 1996, 48(3): 112. [33] Park J H, Todoroki H. Control of MgO·Al2O3 spinel inclusions in stainless steels[J]. ISIJ International, 2010, 50(10): 1333. [34] YANG Z G, YAO G, LI G Y, et al. The effect of inclusions on the fatigue behavior of fine-grained high strength 42CrMoVNb steel[J]. International Journal of Fatigue. 2004, 26(9): 959. [35] Itoh H, Hino M, Ban-ya S. Thermodynamics on the formation of non-metallic inclusion of spinel (MgO·Al2O3) in liquid steel[J]. Tetsu-to-Hagané, 1998, 84(2): 85. [36] Okuyama G, Yamaguchi K, Takeuchi S, et al. Effect of slag composition on the kinetics of formation of Al2O3-MgO inclusions in aluminum killed ferritic stainless steel[J]. ISIJ International, 2000, 40(2): 121. [37] Harada A, Miyano G, Maruoka N, et al. Dissolution behavior of Mg from MgO into molten steel deoxidized by Al[J]. ISIJ International, 2014, 54(10): 2230. [38] Harada A, Maruoka N, Shibata H, et al. Kinetic analysis of compositional changes in inclusions during ladle refining[J]. ISIJ International, 2014, 54(11): 2569. [39] Brabie V. Mechanism of reaction between refractory materials and aluminum deoxidised molten steel[J]. ISIJ International, 1996, 36(s): S109. [40] Jansson S, Brabie V, Jönsson P. Magnesia-carbon refractory dissolution in Al killed low carbon steel[J]. Ironmaking and Steelmaking,2006, 33(5): 389. [41] LIU C, HUANG F, SUO J, et al. Effect of magnesia-carbon refractory on the kinetics of MgO·Al2O3 spinel inclusion generation in extra-low oxygen steels[J]. Metallurgical and Materials Transactions B,2016, 47(2): 989. [42] Liu C, Gao X, Kim S, et al. Dissolution behavior of Mg from MgO-C refractory in Al-killed molten steel[J]. ISIJ International, 2018, 58(3): 488. [43] CHI Y G, DENG Z Y, ZHU M Y. Effects of refractory and ladle glaze on evolution of non-metallic inclusions in Al-killed steel[J]. Steel Research International, 2017, 88(9):1600470. [44] Deng Z, Zhu M, Sichen D. Effect of refractory on nonmetallic inclusions in Al-killed steel[J]. Metallurgical and Materials Transactions B,2016, 47(5): 3158. [45] LIU C, HUANG F, WANG X. The effect of refining slag and refractory on inclusion transformation in extra low oxygen steels[J]. Metallurgical and Materials Transactions B, 2016, 47(2): 999. [46] HE X F, WANG X H, CHEN S H, et al. Inclusion composition control in tyre cord steel by top slag refining[J]. Ironmaking and Steelmaking, 2014, 41(9): 676. [47] 王立峰 , 卓晓军, 张炯明, 等. 冶金过程中帘线钢夹杂物成分控制[J]. 北京科技大学学报, 2003, 22(4): 308.(WANG Li-feng, ZHUO Xiao-jun, ZHANG Jiong-ming, et al. Controlling inclusion composition in steelmaking process for tire cord steel[J]. Journal of University of Science and Technology Beijing, 2003, 22(4): 308.) [48] DENG Z, CHENG L, CHEN L, et al. Effect of refractory on nonmetallic inclusions in Si-Mn-killed steel[J]. Steel Research International, 2019, 90(12): 1900268. [49] Fujii K, Nagasaka T, Hino M. Activities of the constituents in spinel solid solution and free energies of formation of MgO, MgO·Al2O3[J]. ISIJ International, 2000, 40(11): 1059. [50] KONG L, DENG Z, ZHU M. Reaction behaviors of Al-killed medium-manganese steel with different refractories[J]. Metallurgical and Materials Transactions B, 2018, 49(3): 1444. [51] 孔令种. 铝镇静中锰钢非金属夹杂物的演变行为[C]//中国钢铁年会. 北京: 中国金属学会, 2017: 855.(KONG Ling-zhong. Evolution behaviors of non-metallic inclusions in Al-killed medium manganese steel[C]// China Iron and Steel Annual Conference. Beijing: The Chinese Society for Metals, 2017: 855. [52] HUANG A, WANG Y, ZOU Y, et al. Dynamic interaction of refractory and molten steel: Corrosion mechanism of alumina-magnesia castables[J]. Ceramics International, 2018, 44(12): 14617. [53] WANG Y, HUANG A, WU M, et al. Corrosion of alumina-magnesia castable by high manganese steel with respect to steel cleanness[J]. Ceramics International, 2019, 45(8):9884. [54] HUANG A, WANG Y, GU H, et al. Dynamic interaction of refractory and molten steel: Effect of alumina-magnesia castables on alloy steel cleanness[J]. Ceramics International, 2018, 44(18): 22146. [55] 李阳,陈常勇,孙萌,等. 耐火材料对95Cr切割丝用钢中夹杂物的影响[J]. 钢铁. 2020, 55(2): 56.(LI Yang, CHEN Chang-yong, SUN Meng, et al. Effect of refractory on inclusions in 95Cr saw wire steel[J]. Iron and Steel, 2020, 55(2): 56.) [56] Tuttle R B, Smith J D, Peaslee K D. Interaction of alumina inclusions in steel with calcium-containing materials[J]. Metallurgical and Materials Transactions B,2005, 36(6): 885. [57] 谭立华. CA6耐火材料[J]. 耐火与石灰, 1992, 17(10): 58. (TAN Li-hua. CA6 Refractory[J]. Refractories and Lime, 1992, 17(10): 58. [58] Tulliani J M, Pagès G, Fantozzi G, et al. Dilatometry as a tool to study a new synthesis for calcium hexaluminate[J]. Journal of Thermal Analysis and Calorimetry, 2003, 72(3): 1135. [59] Fuhrer M, Hey A, Lee W E. Microstructural evolution in self-forming spinel/calcium aluminate-bonded castable refractories[J]. Journal of the European Ceramic Society,1998, 18(7): 813. [60] Chan C F, Ko Y C. Effect of CaO Content on the hot strength of alumina-spinel castables in the temperature range of 1 000 to 1 500 ℃[J]. Journal of the American Ceramic Society,1998, 81(11): 2957. [61] CHEN J, CHEN H, MI W, et al. Substitution of Ba for Ca in the structure of CaAl12O19[J]. Journal of the American Ceramic Society, 2017, 100(1): 413. [62] LI B, LI G, CHEN H, et al. Physical and mechanical properties of hot-press sintering ternary CM2A8 (CaMg2Al16O27) and C2M2A14 (Ca2Mg2Al28O46) ceramics[J]. Journal of Advanced Ceramics, 2018, 7(3): 229. [63] LI B, CHEN H, CHEN J, et al. Preparation, growth mechanism and slag resistance behavior of ternary Ca2Mg2Al28O46 (C2M2A14)[J]. International Journal of Applied Ceramic Technology, 2019, 16(3): 1126.
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