钢铁工业烧结过程VOCs减排研究进展

doi:10.13228/j.boyuan.issn0449-749x.20170278

摘要
图/表
参考文献
相关文章 (15)

全文: PDF (981 KB) HTML (1 KB)
输出: BibTeX | EndNote (RIS)

摘要铁矿石烧结是挥发性有机化合物（VOCs）的产生源之一。目前中国钢铁工业烧结过程VOCs排放基本处于“无标准、无监测、无检测”的阶段，对VOCs排放量尚不清楚。总结了国内外钢铁工业烧结过程VOCs排放现状及标准，分析了烧结过程VOCs的生成机理。结果表明，VOCs主要由焦炭、含油氧化铁皮等原燃料中的挥发性物质形成，并以气体形式排放。将VOCs减排方法分为源头削减、过程控制及末端治理3种。源头削减是减少粉尘和轧屑的油类带入，是烧结过程抑制VOCs产生的最佳选择；过程控制是将烧结台车的部分热废气再次引入烧结料层循环利用，热废气所含的VOCs在通过1 300 ℃以上的烧结带时被分解；末端治理主要有活性炭法和MEROS法。上述技术在中国部分钢铁企业都有应用实践。随着VOCs标准的制定，中国钢铁工业烧结过程VOCs有望在现有技术基础上达标排放。

	服务

	把本文推荐给朋友
	加入我的书架
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	王海风
	张春霞

关键词 ：铁矿烧结, 挥发性有机化合物, 形成机理, 减排方法

Abstract：A source of volatile organic compounds （VOCs） is iron ore sintering process. At present，the status of the VOCs emissions in Chinese steel industry is no standard，unmonitored and undetected. The amount of VOCs emissions is not clear. The VOCs emissions status and standards of steel industry in China and abroad were summarized. The VOCs formation in iron ore sintering process was analyzed. They were formed from volatile material in the coke breeze，oily mill scale，etc. and discharged as the form of gas. There are three ways to reduce VOCs emissions： source reduction，process control and treatment in the end. Source reduction is to reduce the oil content in the dust and mill scale. It is the best choice for the VOCs inhibition. Process control is that the parts of the sintering waste gas are introduced into the sintering layer. The VOCs in the hot waste gas are decomposed through the sintering zone with more than 1 300 ℃. Treatment in the end is active carbon method and MEROS method. These technologies have been used in some Chinese steel plants. With the VOCs standard to be formulated，the VOCs emissions of iron ore sintering in Chinese steel industry is expected to meet the standard with the existing technologies.

Key words： iron ore sintering volatile organic compounds formation mechanism emission reduction

收稿日期: 2017-06-01 出版日期: 2018-02-05

引用本文:

王海风，秦松，姜曦，张春霞. 钢铁工业烧结过程VOCs减排研究进展[J]. , 2018, 53(1): 1-7. WANG Hai-feng，QIN Song，JIANG Xi，ZHANG Chun-xia. Research development of VOCs emission reduction during iron ore sintering in steel industry. Iron and Steel, 2018, 53(1): 1-7.

链接本文:

http://www.chinamet.cn/Jweb_gt/CN/10.13228/j.boyuan.issn0449-749x.20170278 或 http://www.chinamet.cn/Jweb_gt/CN/Y2018/V53/I1/1

[1]	张云,李彦锋. 环境中VOCs的污染现状及处理技术研究进展[J]. 化工环保,2009,29(5): 411-415.
[1]	张云,李彦锋. 环境中VOCs的污染现状及处理技术研究进展[J]. 化工环保,2009,29(5): 411-415.
[2]	Shao M, Zhang Y H, Zeng L M, et al. Ground-level ozone in the Pearl River Delta and the roles of VOC and NOx in its production[J]. Journal of Environmental Management,2009,90(1): 512-518.
[2]	Shao M, Zhang Y H, Zeng L M, et al. Ground-level ozone in the Pearl River Delta and the roles of VOC and NOx in its production[J]. Journal of Environmental Management,2009,90(1): 512-518.
[3]	吴祖良,谢德援,陆豪,等. 挥发性有机物处理新技术的研究[J]. 环境工程,2012,30(3): 76-80.
[3]	吴祖良,谢德援,陆豪,等. 挥发性有机物处理新技术的研究[J]. 环境工程,2012,30(3): 76-80.
[4]	栾志强,郝郑平,王喜芹．工业固定源VOCs治理技术分析评估[J]．环境科学,2011,32( 12) : 3476-3486．
[4]	栾志强,郝郑平,王喜芹．工业固定源VOCs治理技术分析评估[J]．环境科学,2011,32( 12) : 3476-3486．
[5]	杨一鸣,崔积山,童莉,等. 美国VOCs定义演变历程对我国VOCs环境管控的启示[J].环境科学研究. 2017, 30(3):368-379.
[5]	杨一鸣,崔积山,童莉,等. 美国VOCs定义演变历程对我国VOCs环境管控的启示[J].环境科学研究. 2017, 30(3):368-379.
[6]	王海林,张国宁,聂磊,等. 我国工业VOCs减排控制与管理对策[J].环境科学,2011,32(12): 3462-3468.
[6]	王海林,张国宁,聂磊,等. 我国工业VOCs减排控制与管理对策[J].环境科学,2011,32(12): 3462-3468.
[7]	Hunter P,Oyama S T． Control of volatile organic compound emissions: conventional and emerging[M]. New York: John Wiley & Sons,Inc.,2000.
[7]	Hunter P,Oyama S T． Control of volatile organic compound emissions: conventional and emerging[M]. New York: John Wiley & Sons,Inc.,2000.
[8]	Department of the Environment, Water, Heritage and the Arts. NPI volatile organic compound definition and information. Version 2.7[M]. Austria: Australian Government, 2009:1-5
[8]	Department of the Environment, Water, Heritage and the Arts. NPI volatile organic compound definition and information. Version 2.7[M]. Austria: Australian Government, 2009:1-5
[9]	The European Paliament and the Council of the European Union. 2008/50/EC ambient air quality and cleaner air for Europe[S]. England: Official Journal of the European Union, 2008
[9]	The European Paliament and the Council of the European Union. 2008/50/EC ambient air quality and cleaner air for Europe[S]. England: Official Journal of the European Union, 2008
[10]	Chemicals Sector Directorate. Environment Canada s proposal to add compounds to the exclusion list of the volatile organic compound(VOCs) definition under schedule 1 of the Canadian Environmental Protection Act[R]. Gatineau, Canada: Environment Canada, 2013:1-10
[10]	Chemicals Sector Directorate. Environment Canada s proposal to add compounds to the exclusion list of the volatile organic compound(VOCs) definition under schedule 1 of the Canadian Environmental Protection Act[R]. Gatineau, Canada: Environment Canada, 2013:1-10
[11]	Environmental Protection Department. A guide to the air pollution control VOCs regulation[M]. HongKong:HKSAR Government, 2010:1-77
[11]	Environmental Protection Department. A guide to the air pollution control VOCs regulation[M]. HongKong:HKSAR Government, 2010:1-77
[12]	江梅,邹兰,李晓倩,等. 我国挥发性有机物定义和控制指标的探讨[J]. 环境科学,2015,36(9):3522-3532
[12]	江梅,邹兰,李晓倩,等. 我国挥发性有机物定义和控制指标的探讨[J]. 环境科学,2015,36(9):3522-3532
[13]	张卿川,夏邦寿,杨正宁,等. 国内外对挥发性有机物定义与表征的问题研究[J]. 污染防治技术,2014,27(5):3-7
[14]	Nippon Steel & Sumitomo Metal, Sustainability Report 2013, 2016-10-21. http://www.nssmc.com/en/csr/report/nssmc/pdf/report2013_all.pdf
[15]	Nippon Steel & Sumitomo Metal, Sustainability Report 2016, 2017-5-14. http://www.nssmc.com/en/csr/report/nssmc/pdf/report2016_all.pdf
[13]	张卿川,夏邦寿,杨正宁,等. 国内外对挥发性有机物定义与表征的问题研究[J]. 污染防治技术,2014,27(5):3-7
[14]	Nippon Steel & Sumitomo Metal, Sustainability Report 2013, 2016-10-21. http://www.nssmc.com/en/csr/report/nssmc/pdf/report2013_all.pdf
[15]	Nippon Steel & Sumitomo Metal, Sustainability Report 2016, 2017-5-14. http://www.nssmc.com/en/csr/report/nssmc/pdf/report2016_all.pdf
[16]	中钢公司. 企业社会责任报告书[M]. 2015
[16]	中钢公司. 企业社会责任报告书[M]. 2015
[17]	Joint Research Center, European Communities. Best availiable techniques(BAT) reference document for iron and steel productions[M], 2010
[17]	Joint Research Center, European Communities. Best availiable techniques(BAT) reference document for iron and steel productions[M], 2010
[18]	Netherlands, Contribution from the Netherlands to the revision of the I&S BREF[M],2007:8
[18]	Netherlands, Contribution from the Netherlands to the revision of the I&S BREF[M],2007:8
[19]	WANG Haifeng,ZHANG Chunxia,QIE Junmao, et al.. Development trends of environmental protection technologies for Chinese steel industry[J]. Journal of Iron and Steel Research International. 2017,24(3):235-242
[19]	WANG Haifeng,ZHANG Chunxia,QIE Junmao, et al.. Development trends of environmental protection technologies for Chinese steel industry[J]. Journal of Iron and Steel Research International. 2017,24(3):235-242
[20]	Environment Canada. 2001. Environmental Code of Practice for Integrated Steel Mills: CEPA 1999 Code of Practice. Public Works and Government Services, Canada.
[20]	Environment Canada. 2001. Environmental Code of Practice for Integrated Steel Mills: CEPA 1999 Code of Practice. Public Works and Government Services, Canada.
[21]	European Commission 2001.
[21]	European Commission 2001.
[22]	邹明,关克静,王策军.论限定烧结燃料挥发分含量对污染减排的重要意义[J].浙江冶金,2015,(3):6-8.
[22]	邹明,关克静,王策军.论限定烧结燃料挥发分含量对污染减排的重要意义[J].浙江冶金,2015,(3):6-8.
[23]	Gebert, Abgasreinigungssysteme fuer Sinteranlagen (Off Gas Purification Systems for Sinter Plants) [M],1995
[23]	Gebert, Abgasreinigungssysteme fuer Sinteranlagen (Off Gas Purification Systems for Sinter Plants) [M],1995
[24]	Infomil, Dutch Notes on BAT for the Production of Primary Iron and Steel, Spatial Planning and the Environment, Directorate for Air and Energy[M], Department of Industry, 1997
[24]	Infomil, Dutch Notes on BAT for the Production of Primary Iron and Steel, Spatial Planning and the Environment, Directorate for Air and Energy[M], Department of Industry, 1997
[25]	UBA Comments, Comments on the draft ‘Dutch Notes on Best Available Techniques for Pollution Prevention and Control in the Production of Primary Iron and Steel’ Environmental Protection Agency of Germany(UBA) [M], Berlin, 1997
[25]	UBA Comments, Comments on the draft ‘Dutch Notes on Best Available Techniques for Pollution Prevention and Control in the Production of Primary Iron and Steel’ Environmental Protection Agency of Germany(UBA) [M], Berlin, 1997
[26]	Caughlin, UK comments to the I&S BREF[M], UK Environmental Agency, 2007:8
[26]	Caughlin, UK comments to the I&S BREF[M], UK Environmental Agency, 2007:8
[27]	Eurofer, Update technique lowering the content of volatile hydrocarbons in the sinter feed[M], Eurofer, 2007:3
[27]	Eurofer, Update technique lowering the content of volatile hydrocarbons in the sinter feed[M], Eurofer, 2007:3
[28]	Fisher, et al., Influence of sinter mix materials on the environmental impact of high productivity iron ore sintering, 2005:89
[28]	Fisher, et al., Influence of sinter mix materials on the environmental impact of high productivity iron ore sintering, 2005:89
[29]	韩星北,彭晓兰. 执行烧结行业污染物排放新标准的解决方案探讨[J]. 冶金管理. 2014,6:13-17
[29]	韩星北,彭晓兰. 执行烧结行业污染物排放新标准的解决方案探讨[J]. 冶金管理. 2014,6:13-17
[30]	迟俊峰.我国钢铁工业技术进步研究[D].南京:河海大学硕士学位论文,2007.
[30]	迟俊峰.我国钢铁工业技术进步研究[D].南京:河海大学硕士学位论文,2007.
[31]	池永淳一郎,桜木準一,大山浩一.戸畑第３焼結機における主排ガス循環技術の適用[J]. 鉄と鋼,1995,81(11):49-52.
[31]	池永淳一郎,桜木準一,大山浩一.戸畑第３焼結機における主排ガス循環技術の適用[J]. 鉄と鋼,1995,81(11):49-52.
[32]	毛艳丽,张东丽,曲余玲.烧结主排烟气减排与余热高效回收技术[J].冶金能源,2011,30(5):49-54.
[32]	毛艳丽,张东丽,曲余玲.烧结主排烟气减排与余热高效回收技术[J].冶金能源,2011,30(5):49-54.
[33]	Cappel F, Schwinning G M, Skroch R. Waste gas treatment in sinter plants[C]. Ironmaking Conference Proceedings, Dallas: The United States Iron and Steel Society, 1993:471-481.
[33]	Cappel F, Schwinning G M, Skroch R. Waste gas treatment in sinter plants[C]. Ironmaking Conference Proceedings, Dallas: The United States Iron and Steel Society, 1993:471-481.
[34]	Werz H J, Otto J, Rengersom J. Environmental protection in iron ore sintering by waste gas recirculation[J]. MPT International, 1995(4):120-126.
[34]	Werz H J, Otto J, Rengersom J. Environmental protection in iron ore sintering by waste gas recirculation[J]. MPT International, 1995(4):120-126.
[35]	Werz H J, Otto J, Rengersom J. Pollution control at iron ore sintering plants through waste gas recycling[J].Stahl und Eisen,1995, 115(11):37-40.
[35]	Werz H J, Otto J, Rengersom J. Pollution control at iron ore sintering plants through waste gas recycling[J].Stahl und Eisen,1995, 115(11):37-40.
[36]	周渝生,钱晖,张友平.有主要炼铁工艺的优缺点和研发方向[J].钢铁,2009,44(2):1-10.
[36]	周渝生,钱晖,张友平.有主要炼铁工艺的优缺点和研发方向[J].钢铁,2009,44(2):1-10.
[37]	王玲.烧结机使用部分废气循环的初步工业经验[J].武钢技术,1996(4):9-13.
[37]	王玲.烧结机使用部分废气循环的初步工业经验[J].武钢技术,1996(4):9-13.
[38]	杨红博,李咸伟,俞勇梅,等.烧结烟气二恶英减排控制技术研究进展[J].世界钢铁,2011(1):6-11.
[38]	杨红博,李咸伟,俞勇梅,等.烧结烟气二恶英减排控制技术研究进展[J].世界钢铁,2011(1):6-11.
[39]	Menad N, Tayibi H, Carcedo F G, et al.. Minimization methods for emissions generated from sinter strands: a review[J].Journal of Cleaner Production, 2006(14):740-747.
[39]	Menad N, Tayibi H, Carcedo F G, et al.. Minimization methods for emissions generated from sinter strands: a review[J].Journal of Cleaner Production, 2006(14):740-747.
[40]	Luengen H B, Endemann G, Schmoele P. Measures to reduce CO2 and other emissions in the steel industry in Germany and Europe[C]. The 3rd China-German symposium on Science and Technology of Iron and Steel. Beijing: CSM-VDEh Metallurgical Seminar,2011: 75-88.
[40]	Luengen H B, Endemann G, Schmoele P. Measures to reduce CO2 and other emissions in the steel industry in Germany and Europe[C]. The 3rd China-German symposium on Science and Technology of Iron and Steel. Beijing: CSM-VDEh Metallurgical Seminar,2011: 75-88.
[41]	Luengen H B, Peters M, Schmoele P. Iron making in western Europe[C]. The 3rd China-German symposium on Science and Technology of Iron and Steel. Beijing: CSM-VDEh Metallurgical Seminar, 2011: 33-50.
[41]	Luengen H B, Peters M, Schmoele P. Iron making in western Europe[C]. The 3rd China-German symposium on Science and Technology of Iron and Steel. Beijing: CSM-VDEh Metallurgical Seminar, 2011: 33-50.
[42]	Eisen H P, rüdiger K, K?fler A. Construction of the exhaust recycling facilities at a sintering plant[J]. Stahl und eisen, 2004, 124(5): 37-40.
[42]	Eisen H P, rüdiger K, K?fler A. Construction of the exhaust recycling facilities at a sintering plant[J]. Stahl und eisen, 2004, 124(5): 37-40.
[43]	Bastürk S, Delwig C, Ehler W, et al.. Technologies and trends for waste gas cleaning at sinter plants[J]. Stahl und eisen, 2009, 129(5): 51-59.
[43]	Bastürk S, Delwig C, Ehler W, et al.. Technologies and trends for waste gas cleaning at sinter plants[J]. Stahl und eisen, 2009, 129(5): 51-59.
[44]	Reidetschlager J, Stiasny H, Hotzinger S, et al..Siemens VAI sintering selective waste gas recirculation system: meet the future's environmental requirements today[C].AISTech 2009 Proceedings. Saint Louis: The American Institute of Mining, Metallurgical, and Petroleum Engineers, 2009:47-54.
[44]	Reidetschlager J, Stiasny H, Hotzinger S, et al..Siemens VAI sintering selective waste gas recirculation system: meet the future's environmental requirements today[C].AISTech 2009 Proceedings. Saint Louis: The American Institute of Mining, Metallurgical, and Petroleum Engineers, 2009:47-54.
[45]	Brunnbauer G, Ehler W, Zwittag E, et al.. Eposint-a new waste gas recirculation system concept for sinter plant[J]. Stahl und eisen, 2006, 126(9): 41-46.
[45]	Brunnbauer G, Ehler W, Zwittag E, et al.. Eposint-a new waste gas recirculation system concept for sinter plant[J]. Stahl und eisen, 2006, 126(9): 41-46.
[46]	Fleischanderl A,Aichinger C,Zwittag E.环保型烧结生产新技术——Eposint and MEROS[J].中国冶金,2008,18(11):41-46.
[46]	Fleischanderl A,Aichinger C,Zwittag E.环保型烧结生产新技术——Eposint and MEROS[J].中国冶金,2008,18(11):41-46.
[47]	吴天月.宁钢烧结机烟气循环新技术的应用[J].矿业工程,2013(3):51-52.
[47]	吴天月.宁钢烧结机烟气循环新技术的应用[J].矿业工程,2013(3):51-52.
[48]	肖文德,吴志泉. 二氧化硫脱除与回收[M]. 北京:化学工业出版社. 2001年5月:255
[48]	肖文德,吴志泉. 二氧化硫脱除与回收[M]. 北京:化学工业出版社. 2001年5月:255
[49]	李博. 南钢360m2烧结机烟气脱硫方式的选择[A]. 烧结工序节能减排技术研讨会文集[C]. 中国金属学会. 福建. 2009年10月:195-201
[49]	李博. 南钢360m2烧结机烟气脱硫方式的选择[A]. 烧结工序节能减排技术研讨会文集[C]. 中国金属学会. 福建. 2009年10月:195-201
[50]	周末. 活性炭吸附法在烧结烟气治理领域的进展及前景[A]. 烧结工序节能减排技术研讨会文集[C]. 中国金属学会. 福建. 2009年10月:65-67,74
[50]	周末. 活性炭吸附法在烧结烟气治理领域的进展及前景[A]. 烧结工序节能减排技术研讨会文集[C]. 中国金属学会. 福建. 2009年10月:65-67,74
[51]	Alexander Fleischanderl,Wilhelm Fingerhut. MEROS-烧结厂废气干法净化新技术[A]. 2007中国钢铁年会论文集[C]. 中国金属学会. 成都. 2007年11月
[51]	Alexander Fleischanderl,Wilhelm Fingerhut. MEROS-烧结厂废气干法净化新技术[A]. 2007中国钢铁年会论文集[C]. 中国金属学会. 成都. 2007年11月
[52]	Alexander Fleischanderl.Improved dry-type gas-cleaning process for the treatment of sinter offgas[J]. Metallurgical Plant & Technology International, 2006, (3): 36-40
[52]	Alexander Fleischanderl.Improved dry-type gas-cleaning process for the treatment of sinter offgas[J]. Metallurgical Plant & Technology International, 2006, (3): 36-40