Microstructure and properties of 09MnNiDR steel for -70 ℃ ultra low temperature environment
FENG Lu-lu1,2,3, HU Feng1,3, QIAO Wen-wei4, LU Xiu-yu5
1. The State Key Laboratory for Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, Hubei, China; 2. School of Mechanical Engineering, Jing Chu University of Technology,Jingmen 448000, Hubei, China; 3. Collaborative Innovation Center for Advanced Steels, Wuhan Universityof Science and Technology, Wuhan 430081, China; 4. Jiangsu Huaneng Cable Co., Ltd., Gaoyou 225613,Jiangsu, China; 5. Longwood Research Institute, Research Institute of Wuhan Iron and Steel Group, Wuhan 430080, Hubei, China
Abstract:As a -70 ℃ ultra-low temperature steel,09MnNiDR has attracted a lot of attention due to its low cost and low Ni content. Refining ferrite grains and spheroidizing cementite are the main methods to improve its low temperature impact toughness. In order to investigate the effect of microstructure on its comprehensive mechanical properties,three different heat treatment processes were used. The microstructure of the test steel were observed by optical microscope,scanning microscope,and the mechanical properties of the test steel were test by tensile testing machine and low temperature impact toughness testing machine. The results showed that the ferrite grain size of the test steel was refined after normalizing,the grain size is grade 13,the -70 ℃ low temperature impact toughness no less than 180 J,and the ductile-brittle transition temperature is between -70 ℃ and -80 ℃. The grain size of test steel is further refined after normalizing+accelerated cooling by wind,the grain size is grade 14,both the strength and toughness are improved,and the ductile-brittle transition temperature is between -80 ℃ and -90 ℃. Test steel after normalizing + tempering,the lamellar or short rod cementite formed by normalizing degenerates into granular cementite,the strength is decreased and the low temperature impact toughness is improved,and the ductile-brittle transition temperature is decreased to -100 ℃. Different production enterprises can choose the appropriate heat treatment process to improve the low temperature impact toughness of 09MnNiDR,to meet the special needs of users.
冯路路, 胡锋, 乔文玮, 鲁修宇. -70 ℃超低温环境用钢09MnNiDR的组织性能[J]. 钢铁, 2020, 55(10): 89-95.
FENG Lu-lu, HU Feng, QIAO Wen-wei, LU Xiu-yu. Microstructure and properties of 09MnNiDR steel for -70 ℃ ultra low temperature environment[J]. Iron and Steel, 2020, 55(10): 89-95.
[1] 李恒坤,孙新军,赵柏杰,等. 新型锰镍系低温钢应变时效行为研究[J]. 钢铁,2018,53(4):74. (LI Heng-kun,SUN Xin-jun,ZHAO Bo-jie,et al. Strain aging of new-type Mn-Ni low temperature steel[J]. Iron and Steel,2018,53(4):74. ) [2] 肖大恒,汤伟,罗登,等. 超大型液化石油气船用低温钢组织性能[J]. 钢铁,2020,55(4):82. (XIAO Da-heng,TANG Wei,LUO Deng,et al. Microstructure and properties of low temperature steel for ultra large liquefied petroleum gas carrier)[J]. Iron and Steel,2020,55(4):82. ) [3] 梁鹏跃,董汉雄,陈宇,等. 0.5Ni低温用钢的研制[J]. 压力容器,1992,9(5):12.(LIANG Peng-yue,DONG Han-xiong,CHEN Yu,et al. The development of 09MnNiDR(0.5 Ni) steel used at low temperature[J]. Pressure Vessel Technology,1992,9(5):12.) [4] HUO S B,FANG L,HUANG Y X. Research on the low temperature pressure vessel steel of nisco[C]//Energy Materials 2014. Beijing:The Chinese Society for Metals(CSM),The Minerais, Metals and Materials Society(TMS),2014:855. [5] 胡昕明,王储,李新玲,等. 09MnNiDR钢的热变形行为[J].金属热处理,2013,38(7):62.(HU Xin-ming,WANG Chu,LI Xin-ling,et al. Hot deformation behavior of 09MnNiDR steel[J]. Heat Treatment of Metals,2013,38(7): 62.) [6] 胡昕明,高强,赵宝纯,等. 09MnNiDR低温容器钢奥氏体的静态再结晶行为[J].金属热处理,2011,36(9):18.(HU Xin-ming,GAO Qiang,ZHAO Bao-chun,et al. Static recrystallization behavior of austenite in 09MnNiDR steel during hot rolling[J]. Heat Treatment of Metals,2011,36(9):18.) [7] 胡昕明,高强,乔馨,等. 正火温度对09MnNiDR钢组织性能的影响[J]. 钢铁,2011,46(3):71.(HU Xin-ming,GAO Qiang,QIAO Xin,et al. Effect of normalization temperature on microstructure and mechanical properties of 09MnNiDR plate steel [J]. Iron and Steel,2011,46(3):71.) [8] 李建华,吴开明,邱金鳌,等. 预应变对Nb微合金化09Mn-NiDR低温钢高温塑性的影响[J]. 材料工程,2012,40(11):82.(LI Jian-hua,WU Kai-ming,QIU Jin-ao,et al. Effect of normalization temperature on microstructure and mechanical properties of 09MnNiDR plate steel[J]. Journal of Materials Engineering,2012,40(11):82.) [9] 高照海,唐郑磊,许少普,等. 09MnNiDR高韧性低温钢板的试制[J]. 轧钢,2017,34(1):73.(GAO Zhao-hai,TANG Zheng-lei,XU Shao-pu,et al. Development of high toughness and loe temperature 09MnNiDR steel plate[J]. Steel Rolling,2017,34(1):73.) [10] 王西霞,曲锦波,杨汉,等. 09MnNiDR钢焊接临界粗晶区冲击脆断行为及焊后热处理工艺[J]. 钢铁研究学报,2014,26(4):46.(WANG Xi-xia,QU Jin-bo,YANG Han,et al. Impact fracture behavior and post-welding heat treatment process of the Intercritically reheated coarse-grained heat-affected zone of 09MnNiDR steel[J]. Journal of Iron and Steel Research,2014,26(4):46.) [11] 于雄. 09MnNiDR钢板正火工艺的研究[J]. 宽厚板,2015,21(4):6.(YU Xiong. Study on normalizing process of 09MnNiDR steel plate[J]. Wide and Heavy Plate,2015,21(4):6.) [12] 黄煜博,张琪,文艺贝,等. Ni元素对高碳纳米结构贝氏体钢组织和性能的影响[J]. 钢铁研究学报,2018,30(9):735.(HUANG Yu-bo,ZHANG Qi,WEN Yi-bei,et al. Effects of Ni on microstructures and properties of high carbon nano-structured bainite steels[J]. Journal of Iron and Steel Research,2018,30(9):735.) [13] MAO G J,CAO R,CHEN J H,et al. In-situ observation of microstructural evolution in reheated low carbon bainite weld metals with various Ni contents[J]. Journal of Iron and Steel Research,International,2017,24(12):1206. [14] 张熹,陈延清,章军,等. 合金元素对09MnNiDR钢焊接热影响区韧性的影响[J]. 钢铁,2013,48(12):68.(ZHANG Xi,CHEN Yan-qing,ZHANG Jun,et al. Effect of alloying agent on the heat affected zone toughness of 09MnNiDR[J]. Iron and Steel,2013,48(12):68.) [15] 张文锋. 不同热处理工艺对09MnNiDR钢显微组织和力学性能的影响[D].上海:上海交通大学,2015.(ZHANG Wen-feng. Effect of Different Heat Treatment on the MICROSTRUCTUre and Mechanical Properties of 09MnNiDR Steel[D]. Shanghai:Shanghai Jiaotong University,2015.) [16] 周平,王月香,衣忠文,等. 09MnNiDR 耐低温压力容器钢的热处理工艺[J]. 金属热处理,2011,36(9):46.(ZHOU Ping,WANG Yue-xiang,YI Zhong-wen,et al. Heat treatment process of 09MnNiDR low-temperature pressure vessel steel[J]. Heat Treatment of Metals,2011,36(9):46.) [17] 王月香,周平,麻衡,等. 热处理工艺对低温压力容器用钢组织性能的影响[J]. 材料热处理学报,2012,33(增刊):77.(WANG Yue-xiang,ZHOU Ping,MA Heng,et al. Influence of heat treatment process on microstructure and properties of the low-temperature pressure vessel steel[J]. Transactions of Materials and Heat Treatment,2012,33(s):77.) [18] 郭新立,刘治国,刘俊明,等. Ni在球墨铸铁中的行为及作用[J].材料研究学报,1995,9(4):289.(GUO Xin-li,LIU Zhi-guo,LIU Jun-ming,et al. The behavior and function of Ni in ductile iron[J]. Chinese Journal of Materials Research,1995,9(4):289.) [19] 王猛. Ni系超低温用钢强韧化机理研究及生产技术开发[D]. 沈阳:东北大学,2017.(WANG Meng. Study on Strengthening and Toughening Mechanisms and Development of Industrial Manufacturing Technology for Ni-Containing Cryogenic Steels[D]. Shenyang:Northeastern University,2017.) [20] Kim S H,Lee S,Lee B S. Effects of grain size on fracture toughness in transition temperature region of Mn-Mo-Ni low-alloy steels[J]. Materials Science and Engineering A,2003,359:198. [21] 吴年春. 亚临界区淬火温度对一种新型“锰代镍”低温钢组织演变及力学性能的影响[J]. 钢铁研究学报,2014,26(10):60.(WU Nian-chun. Effects of intercritical quenching temperature on microstructural evolution mechanical properties of a new type of cryogenic steel with Ni replaced by Mn[J]. Journal of Iron and Steel Research,2014,26(10):60.) [22] 冯建英. 低温压力容器用钢09MnNiDR的研制与开发[D].沈阳:东北大学,2011.(FENG Jian-ying. Research and Development on Low Temperature Pressure Vessel Steel 09Mn-NiDR[D]. Shenyang:Northeastern University,2011.) [23] 卢伟煜. Zr-Ti复合脱氧对高强度钢力学性能与焊接性能的影响[D]. 武汉:武汉科技大学,2011.(LU Wei-yu. Effect of Zr-Ti Deoxidation on the Mechanical Properties and Weldability of High-Strength Steels[D].Whan:Wuhan University of Science and Technology,2011.) [24] CHEN X,GUO A M,DONG H X. The properties of high toughness low-temperature -70 ℃ steel 09MnNiDR[J]. International Journal of Pressure Vessels and Piping,1999,76:13. [25] 李文卿. 控冷低碳钢珠光体形貌与退化机制[J]. 钢铁,1991,26(10):30.(LI Wen-qing. Morphology and degeneration mechanism of pearlite in control-cooled low-carbon steel[J]. Iron and Steel,1991,26(10):30.) [26] 何仙灵,杨庚蔚,毛新平,等. CSP热轧50CrV4带钢普通球化退火工艺[J]. 钢铁研究学报,2017,29(10):831.(HE Xian-ling,YANG Geng-wei,MAO Xin-ping. Spheroidized annealing process of hot rolled 50CrV4 steel strip produced by CSP process[J]. Journal of Iron and Steel Research,2017,29(10):831.) [27] 章为夷. 等温球化处理过程中球状碳化物的Oswtald长大现象[J]. 材料科学与工艺,1993,4(1):45.(ZHANG Wei-yi. Microstructure evolution of medinm carbon steel during deform ation of undercooled austenite[J]. Material Science and Technology,1993,4(1):45.)
[1]
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