Research progress and prospect of dezincing process of iron and steel dust and mud
ZHANG Yuzhu1,2, KOU Xinlin1,2, TIAN Tielei1,2, LONG Yue1,2, JIN Xinyu1,2, YANG Jiayi1,2
1. College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063210, Hebei, China; 2. Hebei Key Laboratory of Modern Metallurgical Technology, Tangshan 063009, Hebei, China
Abstract:With the aggravation of environmental pollution and the shortage of zinc resources, the iron and steel industry pays more and more attention to the treatment of dust and mud. In order to efficiently utilize resources and reduce environmental pollution, researchers have developed a variety of processes to recover zinc metal from iron and steel dust and mud. The source and chemical composition of iron and steel dust and mud are explored, the process flow and characteristics of physical method, wet method, fire method, microwave method, chloride method and plasma method are described, and their advantages and disadvantages are analyzed from the reduction efficiency, energy consumption and other aspects. The results show that the physical method is simple and suitable for the pretreatment of fire and wet dezinc process. The selective leaching ability of wet process is strong, but the solvent corrodes the equipment seriously and it is difficult to remove impurities later. Pyrotechnics are widely used, but energy consumption and pollution are the main limiting factors. Microwave, chloride and plasma methods, as emerging technologies, have superior dezincing performance compared with traditional processes, but there are also some problems in practical application that need to be further improved. Finally, in order to respond to the policy of "carbon peak, carbon neutral", this paper proposes the hydrocarbon-coupled reduction dezinc process according to the excellent environmental performance of the hydrogen metallurgy process and the mature and stable rotary hearth furnace process, which can effectively reduce carbon dioxide emissions in the steel industry, reduce energy consumption, and improve the metallization rate of rotary hearth furnace process. It is hoped that the above work can provide valuable reference for the development of the process of removing zinc from iron and steel dust and mud.
张玉柱, 寇鑫林, 田铁磊, 龙跃, 靳鑫玉, 杨佳毅. 钢铁尘泥脱锌工艺的研究进展与展望[J]. 钢铁, 2023, 58(6): 1-11.
ZHANG Yuzhu, KOU Xinlin, TIAN Tielei, LONG Yue, JIN Xinyu, YANG Jiayi. Research progress and prospect of dezincing process of iron and steel dust and mud[J]. Iron and Steel, 2023, 58(6): 1-11.
[1] National Bureau of Statistics of China. China statistical yearbook[EB/OL].[2022-09-27].https://data.stats.gov.cn/easyquery.htm. [2] 刘超,张玉柱,王峰,等. 多源冶金粉尘资源化研究现状及展望[J]. 中国冶金,2022,32(10):38.(LIU C, ZHANG Y Z, WANG F, et al. Research status and prospect of multi-source metallurgical dust recycling[J]. China Metallurgy,2022,32(10):38.) [3] 臧永港,黄润,杨婧飘,等. 含锌电炉粉尘水浸处理-真空碳热还原工艺[J]. 中国冶金,2022,32(9):134.(ZANG Y G,HUANG R,YANG J P,et al. Water leaching treatment-vacuum carbothermic reduction process of zinc-bearing electric furnace dust[J]. China Metallurgy,2022, 32(9):134.) [4] 薛洋,郝先生,刘晓明,等. 从钢厂粉尘中回收锌和铁:可用技术概述[J]. 材料,2022,15(12):4127.(XUE Y,HAO X S,LIU X M,et al. Recovery of zinc and iron from steel mill dust: An overview of available technologies[J]. Materials,2022,15(12):4127.) [5] 田玮,岳昌盛,彭犇. 钢铁冶金尘泥的产生及处置利用技术分析[J]. 矿产保护与利用,2019,39(3):105.(TIAN W,YUE C S,PENG B. Analysis of the characteristics and disposal technology of metallurgical dust[J]. Conservation and Utilization of Mineral Resources,2019,39(3):105.) [6] 魏秀泉,马腾飞,佘雪峰.含锌尘泥中锌铅及碱金属脱除研究[J].冶金能源,2019,38(1):54.(WEI X Q,MA T F,SHE X F.Removal of zinc,lead and alkali metals from zinc-bearing dust[J]. Energy for Metallurgical Industry,2019,38(1):54.) [7] 高春群,郝素菊,蒋武锋,等.熔融钢渣显热处理含锌粉尘的热力学研究[J].冶金能源,2015,34(3):14.(GAO C Q,HAO S J,JIANG W F,et al. Thermodynamic study on sensible heat of molten steel slag dealingwith dust containing zinc[J]. Energy for Metallurgical Industry, 2015,34(3):14.) [8] 金永龙,刘思远,秦国旗,等.典型的处置钢铁企业含锌固废工艺的能效分析[J].冶金能源,2022,41(3):18.(JIN Y L,LIU S Y,QIN G Q,et al. Energy efficiency analysis of typical technologies for disposal ferrous solid waste combined with Zn in steel plants[J]. Energy for Metallurgical Industry, 2022,41(3):18.) [9] 佘雪峰,王静松,王光,等. 直接还原过程中冶金粉尘中锌、铅和碱的去除机理[J]. 钢铁研究学报(英文版),2014,21(5):488.(SHE X F,WANG J S,WANG G,et al. Removal mechanism of Zn,Pb and alkalis from metallurgical dusts in direct reduction process[J]. Journal of Iron and Steel Research Internationa,2014,21(5):488.) [10] MA N. Recycling of basic oxygen furnace steelmaking dust by in-process separation of zinc from the dust[J]. Journal of Cleaner Production,2015,112:4497. [11] 林晓龙,彭志伟,闫家兴,等. 电弧炉粉尘的火法冶金回收[J]. 清洁生产杂志,2017,149:1079.(LIN X L,PENG Z W,YAN J X,et al. Pyrometallurgical recycling of electric arc furnace dust[J]. Journal of Cleaner Production,2017,149:1079.) [12] 石磊,陈荣欢,王如意. 钢铁工业含锌尘泥的资源化利用现状与发展方向[J]. 中国资源综合利用,2009,27(2):19.(SHI L,CHEN R H,WANG R Y. Present utilization state and development trend of zinc-borne sludge and dust in iron and steel industry[J]. China Resources Comprehensive Utilization,2009,27(2):19.) [13] 许海川,杨娟,齐渊洪,等. 钢厂尘泥的整体优化处理[J]. 中国冶金,2009,19(12):33.(XU H C,YANG J,QI Y H,et al. Overall optimization of steel mill sludge[J]. China Metallurgy,2009,19(12):33.) [14] 彭开玉,周云,李辽沙,等. 冶金含锌尘泥资源化的现状与展望[J]. 中国资源综合利用,2005(6):8.(PENG K Y,ZHOU Y,LI L S,et al. Current situation and prospect of metallurgical zinc-containing sludge resource utilization[J]. China Resources Comprehensive Utilization,2005(6):8.) [15] 郭玉华,张春霞,樊波,等. 钢铁企业含锌尘泥资源化利用途径分析评价[J]. 环境工程,2010,28(4):83.(GUO Y H,ZHANG C X,FAN B,et al. Analysis and evaluation of the resource utilization path of zinc-containing dust sludge in iron and steel enterprises[J]. Environmental Engineering,2010,28(4):83.) [16] 徐继润,刘正宁,邢军,等. 水力旋流器中的涡流机理[J]. 中国有色金属学报(英文版),2001,11(4):591.(XU J R,LIU Z N,XING J,et al. Vortex mechanism in hydrocyclones[J]. Transactions of Nonferrous Metals Society of China,2001,11(4):591.) [17] 佘雪峰,薛庆国,王静松,等. 钢铁厂含锌粉尘综合利用及相关处理工艺比较[J]. 炼铁,2010,29(4):56.(SHE X F,XUE Q G,WANG J S,et al. Comprehensive utilization of zinc-containing dust in iron and steel plant and comparison of related treatment processes[J]. Ironmaking,2010,29(4):56.) [18] CANTARINO M V,FILHO C,MANSUR M B. Selective removal of zinc from basic oxygen furnace sludges[J]. Hydrometallurgy,2012,111:124. [19] TAKAHIRO M,ROMCHAT C F,KATSUYA M,et al. Hydrometallurgical extraction of zinc from CaO treated EAF dust in ammonium chloride solution[J]. Journal of Hazardous Materials,2016,302:90. [20] HOLTZER M,KMITA A,ROCZNIAK A. The recycling of materials containing iron and zinc in the oxycup process[J]. Archives of Foundry Engineering,2015,15(1):126. [21] HARA Y,ISHIWATA N,ITAYA H. Smelting reduction process with a coke packed bed for steelmaking dust recycling[J]. ISIJ International,2000,40(3):231. [22] 张建良,李洋,袁骧,等. 中国钢铁企业尘泥处理现状及展望[J]. 钢铁,2018,53(6):1.(ZHANG J L,LI Y,YUAN X,et al. Current situation and prospect of dust sludge treatment in chinese iron and steel enterprises[J]. Iron and Steel,2018,53(6):1.) [23] YAMADA S,ITAYA H,HARA Y. Simultaneous recovery of zinc and iron from electric arc furnace dust with a coke packed bed smelting-reduction process[J]. Iron and Steel Engineer,1998,75(8):64. [24] MAGDZIARZ A,KUNIA M,BEMBENEK M,et al. Briquetting of EAF dust for its utilisation in metallurgical processes[J]. Chemical and Process Engineering,2015,36(2):263. [25] KURUNOV I F. Environmental aspects of industrial technologies for recycling sludge and dust that contain iron and zinc[J]. Metallurgist,2012,55(9/10):634. [26] 邸久海,潘聪超,庞建明,等. 直接还原回转窑协同处理含锌固废技术及应用[J]. 中国冶金,2019, 29(10):71.(DI J H,PAN C C,PANG J M,et al. Technology and application of cooperative disposal of zinc solid waste by direct reduction rotary kiln[J]. China Metallurgy, 2019, 29(10): 71.) [27] YAKORNOV S A,PANSHIN A M,KOZLOV P A,et al. Current state of electrical arc furnace dusts processing in russia and abroad[J]. Tsvetnye Metally,2017(4):23. [28] Zinc Recovery from EAF Dust Brochure. ILZSG EAF dust report brochure[EB/OL].[2015-02-23].https://ilzsg.org/pages/document/p2/list.aspx [29] 巨建涛,党要均. 钢铁厂含锌粉尘处理工艺的现状及发展[J]. 材料导报,2014,28(9):109.(JU J T,DANG Y J. Present state and development of zinc-bearing dust treatment process in iron and steel plants[J]. Materials Reports,2014,28(9):109.) [30] 王东彦,王文忠,陈伟庆,等. 含锌铅钢铁厂粉尘处理技术现状和发展趋势分析[J]. 钢铁,1998(1):67.(WANG D Y,WANG W Z,CHEN W Q,et al. Present state and development trend of disposal technique of in-plant Zn-Pb-bearing dust[J]. Iron and Steel,1998(1):67.) [31] TSUTSUMI H,YOSHIDA S,TETSUMOTO M. Features of FASTMET®process[J]. Kobelco Technology Review,2010,60:85. [32] SUETENS T,KLAASEN B,VANACKER K,et al. Comparison of electric arc furnace dust treatment technologies using exergy efficiency[J]. Journal of Cleaner Production,2014(65):152. [33] 周渝生,张友平. 转底炉直接还原炼铁工艺的发展[C]//2006年中国非高炉炼铁会议论文集. 沈阳:中国金属学会非高炉炼铁学术委员会,2006:179.(ZHOU Y S,ZHANG Y P. Development of rotary hearth furnace direct reduction ironmaking process[C]//Proceedings of the 2006 China Non-blast Furnace Ironmaking Conference. Shenyang: Non-blast Furnace Ironmaking Academic Committee of the Chinese Society for Metals,2006:179.) [34] GEORGE H L,LONGBOTTOM R J,CHEW S J,et al. Flow of molten slag through a coke packed bed[J]. ISIJ International,2014,54(4):820. [35] 王梦凡,刘晓明. 赤泥作为环境修复材料的应用研究进展[J]. 有害物质学报,2020,408(1):124420.(WANG M F,LIU X M. Applications of red mud as an environmental remediation material:A review[J]. Journal of Hazardous Materials,2020,408(1):124420.) [36] ITAYA H,HARA Y,TAGUCHI S,et al. Development of a smelting-reduction process for steelmaking dust recycling[J]. Metallurgical Research and Technology,1997,94(1):63. [37] HILLMANN C,SASSEN K J. Processing of zinc-bearing BOF dusts in a blast furnace[J]. World Iron and Steel,2013,5:8. [38] ROUSSY G,PEARCE J A. Foundations and industrial applications of microwave and radio frequency fields: Physical and chemical processes[C]//Proceedings of the 6th International Conference on Optimization of Electrical and Electronic Equipments. West Sussex,Chichester: John Wiley and Sons Ltd.,1998:115. [39] HAQUE K E. Microwave energy for mineral treatment processes: A brief review[J]. International Journal of Mineral Processing,1999,57(1):1. [40] OMRAN M,FABRITIUS T,MATTILA R. Thermally assisted liberation of high phosphorus oolitic iron ore: A comparison between microwave and conventional furnaces[J]. Powder Technology,2015,269:7. [41] OMRAN M,FABRITIUS T,ELMANDY A M,et al. XPS and FTIR spectroscopic study on microwave treated high phosphorus iron ore[J]. Applied Surface Science,2015,345(1):127. [42] KINGMAN S W,ROWSON N A. Microwave treatment of minerals a review[J]. Minerals Engineering,1998,11(11):1081. [43] 王鑫,杨大金,鞠少华,等. 微波加热还原锌铁氧体的热力学和动力学[J]. 中国有色金属学报,2013,23(12):3808.(WANG X,YANG D J,JU S H,et al. Thermodynamics and kinetics of carbothermal reduction of zinc ferrite by microwave heating[J]. Transactions of Nonferrous Metals Society of China,2013,23(12):3808.) [44] SAIDI A,AZARI K. Carbothermic reduction of zinc oxide concentrate by microwave[J]. Journal of Materials Science Technology,2005,21(5):724. [45] OMRAN M,FABRITIUS T. Utilization of blast furnace sludge for the removal of zinc from steelmaking dusts using microwave heating[J]. Separation and Purification Technology,2019,210:867. [46] 彭志伟,林晓龙,闫家兴,等. 低锌电弧炉粉尘的表征[C]//矿物、金属和材料表征研讨会. 瑞士,卡姆:方色普林格国际出版公司,2017:103.(PENG Z W,LIN X L,YAN J X,et al. Characterization of low-zinc electric arc furnace dust[C]//Symposium on Characterization of Minerals,Metals,and Materials. Cham,Switzerland:Springer International Publishing,2017:103.) [47] ZHANG H N,LI J L,XU A J,et al. Carbothermic reduction of zinc and iron oxides in electric arc furnace dust[J]. Journal of Iron and Steel Research International,2014,21(4):427. [48] OMRAN M,FABRITIUS T,HEIKKINEN E P. Selective zinc removal from electric arc furnace(EAF) dust by using microwave heating[J]. Journal of Sustainable Metallurgy,2019,5:331. [49] KIM E,CHO S,LEE J. Kinetics of the reactions of carbon containing zinc oxide composites under microwave irradiation[J]. Metals and Materials International,2009,15(6):1033. [50] 叶青,李光辉,彭志伟,等. 微波辅助电弧炉粉尘生物炭复合团块自还原生产直接还原铁[J]. 粉末技术,2020,362:781.(YE Q,LI G H,PENG Z W,et al. Microwave assisted self-reduction of EAF dust biochar composite briquettes for production of direct reduced iron[J]. Powder Technology,2020,362:781.) [51] XIA D K,PICKLESI C A. Microwave caustic leaching of electric arc furnace dust[J]. Minerals Engineering,2000,13(1):79. [52] 郭婷,胡晓军,束奇峰,等. 铁酸锌选择性氯化挥发除锌的研究[C]//2008年全国冶金物理化学学术会议. 贵阳:中国稀土学报编辑委员会,2008:357.(GUO T,HU X J,SHU Q F,et al. Removal of Zn from ZnFe2O4 by selective chlorination and evaporation[C]//2008 National Conference on Metallurgical Physical Chemistry. Guiyang: Editorial Board of Chinese Journal of Rare Earths,2008:357.) [53] 郭婷,胡晓军,侯新梅,等. ZnFe2O4与CaCl2氯化反应机理[J]. 北京科技大学学报,2011,33(4):474.(GUO T,HU X J,HOU X M,et al. Chlorination reaction mechanism between ZnFe2O4 and CaCl2[J]. Chinese Journal of Engineering,2011,33(4):474.) [54] 张达,叶凯,唐政刚,等. 等离子体冶金的现状与发展[J]. 中国有色金属学报,2021,31(7):1907.(ZHANG D,YE K,TANG Z G,et al. Development and status of plasma metallurgy[J]. The Chinese Journal of Nonferrous Metals,2021,31(7):1907.) [55] STEINMETZ E,邓庆球. 铁矿石直接还原法和熔融还原法的现状和发展[J]. 烧结球团,1988(2):44.(STEINMETZ E,DENG Q Q. Status and development of iron ore direct reduction method and melt reduction method[J]. Sintering and Pelletizing,1988(2):44.) [56] 任磊,周胜,彭天铎,等. 以中国为重点的钢铁行业CO2减排技术与低碳发展综述[J]. 可再生和可持续能源评论,2021,143:110846.(REN L,ZHOU S,PENG T D,et al. A review of CO2 emissions reduction technologies and low-carbon development in the iron and steel industry focusing on china[J]. Renewable and Sustainable Energy Reviews,2021,143:110846.) [57] KIM S J,RYU K M,OH M S. Addition of cerium and yttrium to ferritic steel weld metal to improve hydrogen trapping efficiency[J]. International Journal of Minerals Metallurgy and Materials,2017,24(4):415. [58] RAZZAQ R,LI C S,ZHANG S J. Coke oven gas: Availability,properties,purification,and utilization in China[J]. Fuel,2013,113:287. [59] 白宗庆,白进,李文. 焦炉煤气综合利用及CO2减排潜力分析[J]. 洁净煤技术,2016,22:90.(BAI Z Q,BAI J,LI W. Comprehensive utilization of coke oven gas and analysis of CO2 emission reduction potential[J]. Clean Coal Technology,2016,22:90.)