Abstract:Aiming at microstructure refinement problems in steel plates, tubes and profiles under hot-rolling or welding conditions, a systematic study of theory-technology-product was carried out. Through the development of existing technology and innovation, a new type intrinsically fine-grained steel technology based on precipitation control was proposed. Through the whole process control of smelting-casting-rolling-cooling-welding, distribution of thermostable micro-nano particles in steel was regulated. In combination with optimized process, the matrix and welding microstructure was uniformly refined. It broke through the limitation in microstructure control methods and process conditions, improved the comprehensive performance, and promoted green manufacturing of advanced steels. The precipitation laws of some nitride and oxide were analyzed using thermodynamics calculation software. Typical precipitation particles were characterized with an electron probe micro-analyzer (EPMA) and a scanning electron microscope (SEM). The design concept of composite precipitates was explained from the perspective of thermal stability and their interaction with the matrix. Mn-depletion zone and coherent interface mechanism for particle-induced ferrite nucleation was discussed. Transformation behavior of intragranular ferrite was studied using high-temperature in-situ characterization technology. The multiple microstructure refinement mechanism based on multi-type and multi-scale precipitation system was elaborated. The technology has been applied to high heat input welding steel, efficient hot-rolling of structural steel, hot-rolled seamless steel tubes and low-cost hot-rolled ribbed bars. The technology has achieved good results and demonstrates a broad application prospect in more product fields.
王超, 袁国, 王国栋. 基于析出相控制的热轧本质细晶钢技术及应用[J]. 钢铁, 2023, 58(9): 167-177.
WANG Chao, YUAN Guo, WANG Guodong. Hot-rolled intrinsically fine-grained steel technology based on precipitation control and its application[J]. Iron and Steel, 2023, 58(9): 167-177.
[1] 王国栋. 高质量中厚板生产关键共性技术研发现状和前景[J]. 轧钢,2019,36(1):1. (WANG G D. Status and prospects of research and development of key common technologies for high-quality heavy and medium plate production[J]. Steel Rolling,2019,36(1):1.) [2] 刘庆波,许少普,陈熙,等. 水电用大厚度钢板Q500DZ35的开发[J]. 中国冶金,2019,29(8):64. (LIU Q B,XU S P,CHEN X,et al. Development of large thickness steel plate with Q500DZ35 hydropower[J]. China Metallurgy,2019,29(8):64.) [3] 礼宾,王泽彬,兰亮云. TMCP工艺下Q390钢板厚度、温度场与组织演变的关系[J/OL]. 热加工工艺[2023-08-03].https://doi.org/10.14158/j.cnki.1001-3814.20221647. (LI B, WANG Z B, LAN L Y. Relationship between thickness, temperature field and microstructure evolution of Q390 steel plate under TMCP process[J/OL]. Hot Working Technology[2023-08-03].https://doi.org/10.14158/j.cnki.1001-3814.20221647.) [4] 李铮,刘耀恒. 基于控制冷却技术的Q620级别高强度热轧无缝钢管开发[J]. 钢管,2020,49(2):9.(LI Z, LIU Y H. Development of Q620 high-strength hot-rolled seamless steel tube on the basis of TMCP[J]. Steel Pipe,2020,49(2):9.) [5] 陈辉,夏勐,吴保桥,等. 控轧温度对含Nb热轧H型钢组织性能的影响[J]. 轧钢,2020,37(3):44. (CHEN H,XIA M,WU B Q,et al. Study on influence of controlled rolling temperatures on microstructure and mechanical properties of H-beam containing Nb[J]. Steel Rolling,2020,37(3):44.) [6] 冷菊. 大线能量焊接对原油储罐用钢焊接接头机械性能影响研究[J]. 工程与试验,2022,62(4):78.(LENG J. Study on the effect of high heat input welding on the mechanical property of welded joint of the steel plate of crude oil storage tank[J]. Engineering and Test,2022,62(4):78.) [7] 崔忠圻. 金属学与热处理[M]. 北京:机械工业出版社,2000.(CUI Z Q. Metallography and Heat Treatment[M] Beijing:Mechanical Industry Press,2000.) [8] WANG C,HAO J,KANG J,et al. Tailoring the microstructure of coarse-grained HAZ in steel for large heat input welding:Effect of Ti-Mg-Ce-V inclusion/precipitation particles[J]. Metallurgical and Materials Transactions A,2021,52(8):3191. [9] WANG C,WANG X,KANG J,et al. Effect of austenitization conditions on the transformation behavior of low carbon steel containing Ti-Ca oxide particles[J]. Materials,2019,12(7):1070. [10] LIU F,WANG Q,LI J,et al. Systematic study on orientation relationships between acicular ferrite and Ti-Mg oxide at different cooling rates in low-carbon steel[J].Materials Characterization,2021,181:111503. [11] WANG X,WANG C,KANG J,et al. An in-situ microscopy study on nucleation and growth of acicular ferrite in Ti-Ca-Zr deoxidized low-carbon steel[J]. Materials Characterization,2020,165:110381. [12] 鲍亮亮,王勇,韩涛,等. 海洋平台焊接技术及发展趋势[J].焊接,2019,63(1):21. (BAO L L,WANG Y,HAN T,et al. Welding technology and development trend of offshore platform[J]. Welding and Joining,2019,63(1):21.) [13] 赵立苏,蔡莼,徐飞. 船用大厚度钢板FCB法与单丝埋弧焊混合焊工艺研究[J]. 金属加工(热加工),2020,71(9):16. (ZHAO L S,CAI C,XU F. Research on hybrid welding process of FCB and single wire SAW for marine large thickness steel plate[J]. MW Metal Forming,2020,71(9):16.) [14] SATOSHI I,MASARU M. Development of thermo-mechanical control process (TMCP) and high performance steels in JFE steel[J]. JFE Technical Report,2021,26(1):86. [15] SHIGESATO G. Progress of high performance steel plates with excellent HAZ toughness[J]. Nippon Steel and Sumitomo Metal Technical Report,2018,119(1):22. [16] 尹士科,王畅畅,王存. 日本两公司开发的大热输入焊接用高强度钢[J]. 材料开发与应用,2021,36(3):78. (YIN S K,WANG C C,WANG C. High strength steel for welding with high heat input developed in Japan[J]. Development and Application of Materials,2021,36(3):78.) [17] 赵沛. 氧化物冶金之探析[J]. 中国冶金,2022,32(10):1.(ZHAO P. Analysis and discussion on oxides metallurgy[J]. China Metallurgy,2022,32(10):1.) [18] 程鼎,杨俊. 关于大规格H型钢生产难点的探讨[J]. 中国冶金,2008,18(3):56. (CHENG D,YANG J. Study difficulty of big-section H-beam rolling[J]. China Metallurgy,2008,18(3):56.) [19] 高兵,赵亚娟. 厚板冷却均匀性的研究与控制[J]. 现代冶金,2012,40(3):13. (GAO B,ZHAO Y J. Research and control on cooling uniformity of thick plate[J]. Modern Metallurgy,2012,40(3):13.) [20] 张志慧,马永福,叶高旗,等. 控制轧制对海洋石油平台用H型钢热轧性能的影响[J]. 河北冶金,2020(11):58. (ZHANG Z H,MA Y F,YE G Q,et al. Effect of rolling control on hot rolling properties of H-beam used for offshore oil platform[J]. Hebei Metallurgy,2020(11):58.) [21] ALHAJERI K F,GARCIA C I,HUA M,et al. Particle-stimulated nucleation of ferrite in heavy steel sections[J]. ISIJ International,2006,46(8):1233. [22] MINTZ B,QABAN A,BENDKE P,et al. The influence of a high aluminium addition on the strength and impact behaviour of hot-rolled Nb containing steels[J]. Materials Science and Technology,2020,36(2):233. [23] 焦多田,王路兵,武会宾,等. HTP高铌钢形变奥氏体再结晶规律研究[J]. 塑性工程学报,2008,15(3):119.(JIAO D T,WANG L B,WU H B,et al. Study of austenite recrystallization of high Nb HTP steel[J]. Journal of Plasticity Engineering,2008,15(3):119.) [24] 刘晓瑾,康健,李振垒,等. 热轧无缝钢管控制冷却关键技术的开发与工业应用[J]. 轧钢,2022,39(1):9. (LIU X J,KANG J,LI Z L,et al. Development and industrial application of key technologies of controlled cooling for hot rolled seamless steel tube[J]. Steel Rolling,2022,39(1):9.) [25] ZHANG C, WANG Q, SUN Y, et al. Investigation and application of Nb microalloying technology in seamless steel tube with high performance[C]//Proceedings of the HSLA Steels 2015, Microalloying 2015 and Offshore Engineering Steels 2015. Hoboken:John Wiley and Sons,Inc.,2016:759. [26] 王晓东,郭锋,包喜荣,等. 钢管轧制热机械控制工艺的应用与研究[J]. 热加工工艺,2016,45(15):20. (WANG X D,GUO F,BAO X R,et al. Application and research of thermo-mechanical control process for steel tube rolling[J]. Hot Working Technology,2016,45(15):20.) [27] PAN T,YANG C F,YUE M A,et al. Chemistry and process optimization of V-microalloyed N80-class seamless casing tube[J]. Journal of Iron and Steel Research International,2010,17(3):72. [28] SHENG X L,GUO Q L,YONG C,et al. Comprehensive control on microstructures and properties of medium carbon V-N microalloyed steel seamless oil-well tubes of hot-rolling non-quenched/tempered[J]. Journal of Iron and Steel Research International,2011,18(s1/s2):696. [29] 杨才福,陈雪慧,王瑞珍. 高强度建筑钢筋质量分析及标准修改建议[J]. 钢铁,2017,52(10):94. (YANG C F,CHEN X H,WANG R Z. Quality assessment and suggestion of standard revision for high strength rebars in China[J]. Iron and Steel,2017,52(10):94.) [30] 郭建平,张志立,张亚飞,等. HRB400E抗震钢筋稳定性能的工艺改进[J]. 山西冶金,2023,46(4):145. (GUO J P,ZHANG Z L,ZHANG Y F,et al. Process improvement of stability performance of HRB400E seismic reinforcement[J]. Shanxi Metallurgy,2023,46(4):145.)