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Design and heat treatment of large-scale casting and forging materials for coal-fired power stations |
WANG Jing-zhong1, YAO Hui-qin1, ZHAO Ji-qing2, YANG Xi-rong1, YANG Gang2, DING Kai-lun2 |
1. School of Metalllurgy and Engineering, Xi′an University of Architecture and Technoloy, Xi′an 710055, Shaanxi, China; 2. Institute for Special Steels, Central Iron and Steel Research Institute Co., Ltd., Beijing 100081, China |
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Abstract The research status of material design and heat treatment of steel and alloy used for large castings and forgings of coal-fired power station is reviewed from the aspects of development background,development history,alloying characteristics,heat treatment process,microstructure and evolution. Advanced industries such as Europe,America and Japan have made remarkable achievements in the research,development and production of large castings and forgings for coal-fired power stations after decades of continuous investment and efforts. Our country also made large investment in this aspect,since 1980,pay attention to the study of subcritical,supercritical rotor material,to the ultra supercritical materials after 2000,2015 to present advanced supercritical materials research,on the basis of the introduction of digestion-absorption,has obtained certain achievements,began to create new steel and alloy with independent intellectual property rights,And realized the stable supply of some products. With the increase of coal steam parameters,the chemical composition of steel used for large forgings tends to be complicated,and the 105h extrapolation endurance strength of steel increases continuously. In the composition design of new martensitic heat resistant steel castings,more attention is paid to the application of trace elements B and N,and the compound addition of W,Mo and Co. Domestic scholars have reported many researches on the microstructure and mechanical properties of steel for large forgings,and the researches are more in-depth and systematic. It is necessary to strengthen the creation of prototype steel grade or alloy by using the new material design method combined with the existing strong plastic processing ability in China. Sufficient attention should be paid to the research and development of generator rotor protection ring materials,which should be strengthened. The key physical properties of several typical steels for rotor,turbine cylinder and valve were compared and analyzed. The future development direction of steel or alloy materials for large castings and forgings used in ultra-supercritical power plants with high parameters is discussed based on experience.
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Received: 26 July 2022
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[1] 王敬忠,刘正东,包汉生,等. 中国超超临界电站锅炉关键材料用钢及合金的研究现状[J]. 钢铁,2015,50(8):1. (WANG Jing-zhong,LIU Zheng-dong,BAO Han-sheng,et al. Study of steel and alloys for ultra-supercritical power plant in china[J]. Iron and Steel,2018,50(8):1.) [2] A Di Gianfrancesco. The fossil power plants technology[J]. Materials for Ultra-Supercritical and Advanced Ultra-Supercritical Power Plants,2017,104:1. [3] Mayer K H,Bakker W T. New ferritic steels increase the thermal efficiency of steam turbines[C]//4th International Colloquium on Ageing of Materials and Methods for the Assessment of Lifetimes of Engineering Plant. Houston,USA:American Society of Mechanical Engineers,1996:333. [4] Hald J. Metallurgy and creep properties of new 9-12% Cr steels[J]. Steel Research,1996,67(9):369. [5] Masuyama F. Alloy development and material issues with increasing steam temperature[C]//4th International Conference on Advances in Materials Technology for Fossil Power Plants. South Carolina,USA:Electric Power Research Institute,2004:35. [6] Zeiler G. Martensitic steels for rotors in ultra-supercritical power plants[J]. Materials for Ultra-Supercritical and Advanced Ultra-Supercritical Power Plants,2017,104:143. [7] 赵吉庆,杨钢,赵林,等. 高性能9%~12%Cr转子钢发展现状及锻件国产化概况[J]. 汽轮机技术,2021,63(1):71. (ZHAO Ji-qing,YANG Gang,ZHAO Lin,et al. Developing of high-performance 9%-12%Cr rotor steels and localization overview of forging used for steam turbine rotors[J]. Turbine Technology,2021,63(1):71.) [8] Walsh,M A,Price. Structure and properties of large 10% CrMoVNbN forgings developed for long term high temperature steam turbine applications[J]. Micro High Temp Mat,1998(2):291. [9] John Hald,Hilmar K Danielsen. Prospects for 12Cr martensitic creep resistant steels for 650 ℃ steam power plant[J]. Baosteel Technical Research,2010,4(s1):69. [10] Vanstone R,Chilton I,Jaworski P. Manufacturing experience in an advanced 9%CrMoCoVNbNB alloy for ultra-supercritical steam turbine rotor forgings and castings[J]. Journal of Engineering for Gas Turbines and Power,2013,135:1. [11] Viswanathan R,Bakker W. Materials for ultrasupercritical coal power plants—Turbine materials:Part II[J]. Journal of Materials Engineering and Performance,2001,10(1):96. [12] Scarlin R B,Berger C,Mayer K H,et al. Steam turbine materials:High temperature castings[C]//COST Conference,Part I. Netherlands:Kluwer Academic Publishers Group,1994:73. [13] Kern,T U,Staubli M,Mayer K H. et al. The European effort in development of new high temperature rotor materials up to 650 C-COST 522 [C]//7th Liege Conference,Part 2. Liege,France:Liege Materials for Advanced Power Engineering,2002:1049. [14] Satubli M,Mayer K H,Giselbrecht W,et al. Development of creep resistant cast steels within the european collaboration in advanced steam turbine materials for ultra efficient,low emission steam power plant/COST 501-522[C]//7th Liege Conference,Part 2. Liege,Belgium:Liege Materials for Advanced Power Engineering,2002:1065. [15] Kasl J,Jandová D. Metallography of CB2 steel used for cast turbine components[J]. Materials Science Forum,2014,782:179. [16] Songfeng L,Hongwei S,Guoqing J,et al. The Application of 9% Cr Casting Steel with Co and B Addition for 620 ℃ Steam Turbine[M]. Energy Materials 2014. New York:John Wiley and Sons,2015. [17] Fujimitsu M. History of power plants and progress in heat resistant steels[J]. ISIJ International,2001,41(6):612. [18] 许冀鑫,林红,魏建博,等. X12CrMoWVNbN10-1-1钢超超临界蒸汽阀体铸件热处理工艺试验[J]. 铸造技术,2013,34(5):563. (XU Ji-xin,LIN Hong,WEI Jian-bo,etal. Study on heat treatment process for steam valve body castings of ultra supercritical steel X12Cr Mo WVNb N10[J]. Foundry Technology,2013,34(5):563.) [19] 马煜林,刘越,古金涛,等. 冷却方式对CB2钢中 BN 相形态及力学性能的影响[J]. 东北大学学报(自然科学版),2017,38(7):955. (MA Yu-lin,LIU Yue,GU Jin-tao,et al. Effect of cooling mode on BN phase morphology and mechanical properties of CB2 steel[J]. Journal of Northeastern University(Natural Science),2017,38(7):955.) [20] 杨雪,孙兰,范洪远. 700 ℃高温短时时效对ZG12Cr9Mo1 Co1NiVNbNB铁素体耐热钢显微组织的影响[J]. 工程科学与技术,2015(s1):158. (YANG Xue,SUN Lan,FAN Hong-yuan. Effect of short time aging at high temperature on the microstructure of ZG12Cr9Mo1Co1 NiVNbNB ferritic heat resistant steel[J]. Jounal of Sichuan University(Engineering Science Edition),2015(s1):158.) [21] 麻晓峰,王玉棉,曹登云. 超临界汽轮机用9Cr钢材料开发[J]. 机械研究与应用,2008,21(6):4. (MA Xiao-feng,WANG Yu-mian,CAO Deng-yun. Development of supercritical steam turbine with 9Cr steel materials[J]. Echanical Research and Application,2008,21(6):4.) [22] Viswanathan R,张明芳,译. 发电机护环用材料[J]. 大型铸锻件,1983(2):83. (Viswanathan R,Translated by ZHANG Ming-fang. Materials for protection rings of generators[J]. Eavy Casting and Forging,1983(2):83.) [23] 郭会光. 汽轮发电机护环生产技术的发展[J]. 大型铸锻件,1990(4):10.(GUO Hui-guang. Development of protection ring production technology for turbo generator[J]. Eavy Casting and Forging,1990(4):10.) [24] 郭会光,蔡琼尔,韩行霖. 建立发电机护环钢(Mn18-Cr4型)动态再结晶图的试验研究[J]. 大型铸锻件,1980(5):55. (GUO Hui-guang,CAI Qiong-er,HAN Xing-lin. Experimental study on dynamic recrystallization chart of generator guard ring steel(Mn18-Cr4 type)[J]. Eavy Casting and Forging,1980(5):55.) [25] 孙茂才,郭成海,刘玉明. Mnl8Cr18新型200 MW汽轮发电机护环材料高温性能[J]. 大电机技术,1990(3):21. (SUN Mao-cai,GUO Cheng-hai,LIU Yu-ming. Tensile stenrgth at high temperature of now material Mn18Cr18 for the retaining ring of 200 MW turbogenenrator[J]. Large Electric Machine and Hydraulic Turbine,1990(3):21.) [26] 马洪香. 发电机护环钢推荐选用81Mn-18Cr[J]. 华北电力技术,1993(6):45.(MA Hong-xiang. 18Mn-18Cr steel is recommended for the generator guard ring[J]. North China Electric Power,1993(6):45.) [27] 向大林,王克武,朱孝渭. Cr18Mn18 N护环用钢电渣重熔技术的开发研究[J]. 上海金属,1996,18(4):7.(XIANG Da-lin,WANG Ke-wu,ZHU Xiao-wei. Development and application of ESR process for Cr18Mn18 N steel used for retaining rings[J]. Shanghai Metals,1996,18(4):7.) [28] 郑文,吴奇,刘建平. 发电机护环变形强化工艺研究[J]. 大连工业大学学报,1998,17(1):31. (ZHENG Wen,WU Qi,LIU Jian-ping. Hydroforming of turbogenerator's protective-ring[J]. Journal of Dalian Institute of Light Industry,1998,17(1):31.) [29] Eggeler G. The effect of long-term creep on particle coarsening in tempered martensite ferritic steels[J]. Acta Metallurgica,1989,37(12):3225. [30] Abe F,Horiuchi T,Taneike M,et al. Stabilization of martensitic microstructure in advanced 9Cr steel during creep at high temperature[J]. Materials Science and Engineering A,2004,378(1/2):299. [31] Kaibyshev R O,Skorobogatykh V N,Shchenkova I A. Formation of the Z-phase and prospects of martensitic steels with 11% Cr for operation above 590 ℃[J]. Metal Science and Heat Treatment,2010,52(3/4):90. [32] Yoshizawa M,Igarashi M,Moriguchi K,et al. Effect of precipitates on long-term creep deformation properties of P92 and P122 type advanced ferritic steels for USC power plants[J]. Materials Science and Engineering A,2009,510(10):162. [33] Hald J. Microstructure and long-term creep properties of 9-12% Cr steels[J]. International Journal of Pressure Vessels and Piping,2008,85(1):30. [34] Danielsen H K,Hald J. Behaviour of Z phase in 9-12%Cr steels[J]. Energy Materials,2006,1(1):49. [35] Kim M Y,Hong S M,Lee K H,et al. Mechanism for Z-phase formation in 11CrMoVNbN martensitic heat-resistant steel[J]. Materials Characterization,2017,129:40. [36] Danielsen H K,Hald J. A thermodynamic model of the Z-phase Cr(V,Nb)N[J]. Calphad:Computer Coupling of Phase Diagrams and Thermochemistry,2007,31(4):505. [37] Rashidi M,Odqvist J,Johansson L,et al. Experimental and theoretical investigation of precipitate coarsening rate in Z-phase strengthened steels[J]. Materialia,2018(4):247. [38] Taneike M,Abe F,Sawada K. Creep-strengthening of steel at high temperatures using nano-sized carbonitride dispersions[J]. Nature,2003,424(6946):294. [39] 石如星. 超超临界火电机组用P92钢组织性能优化研究[D]. 北京:钢铁研究总院,2011. (SHI Ru-xing. Investigation on Optimization of Microstructure and Mechanical Properties of P92 in Ultra-Supercritica Units[D]. Beijing:Central Iron and Steel Research Institute,2011.) [40] 王敬忠,刘正东,程世长,等. 固溶态S31042钢高温塑性波动大的原因分析[J]. 钢铁,2012,47(1):60. (WANG Jing-zhong,LIU Zheng-dong,CHENG Shi-chang,et al. Analysis on big fluctuation in elevated temperature ductility of solution S31042 steel[J]. Iron and steel,2012,47(1):60.) [41] Fujio Abe. Bainitic and martensitic creep-resistant steels[J]. Current Opinion in Solid State and Materials Science,2004,8(3/4):305. [42] Httestrand M,Andrén H O. Boron distribution in 9-12% chromium steels[J]. Materials Science and Engineering A,1999,270(1):33. [43] Liu F,Fors D H R,Golpayegani A,et al. Effect of boron on carbide coarsening at 873 K (600 ℃) in 9 to 12 pct chromium steels[J]. Metallurgical and Materials Transactions A,2012,43(11):4053. [44] 马煜林,刘越,张莉萍,等. B含量对马氏体耐热钢中BN相形态及性能的影响[J]. 材料研究学报,2017(5):27.(MA Yu-lin,LIU Yue,ZHANG Li-ping,et al. Effect of B content on morphology and properties of BN phase in martensite heat resistant steel[J]. Chinese Journal of Materials Research,2017(5):27.) [45] 包汉生,傅万堂,程世长,等. T122耐热钢中氮化硼(BN)化合物的探讨[J]. 钢铁,2005,40(10):68. (BAO Han-sheng,FU Wan-tang,CHENG Shi-chang,et al. An investigation on boron-nitride(BN)compound in T122 heat resistant steel[J]. Iron and Steel,2005,40(10):68.) [46] 石如星,刘正东. P92耐热钢δ-铁素体内的析出相[J]. 材料热处理学报,2011,32(11):64. (SHI Ru-xing,LIU Zheng-dong. Precipitated phase in δ-ferrite of P92 heat-resistant steel [J]. Transactions of Materials and Heat Treatment,2011,32(11):64.) [47] Zeiler G,Meyer W,Spiradek-Hahn K,et al. 9-12% chromium steel forgings for power generation plants-experiences in manufacturing and long-term mechanical and microstructural testing[C]//15th International Forgemasters Meeting. Kobe,Japan:Japan Institute of Metal Materials,2003:248. [48] Zeiler G,Meyer W,Spiradek-Hahn K,et al. Experiences in manufacturing and long-term mechanical and microstructural testing on 9-12% chromium steel forgings for power generation plants[C]//4th International Conference on Advances in Materials Technology for Fossil Power Plants. Hilton Head Island,South Carolina,USA:Electric Power Research Institute,2004:222. [49] Tanaka Y,Azuma T,Yaegashi N. Isothermal aging test results(up to 100 000 h) of NiCrMoV steels for low-pressure steam turbine[J]. International Journal of Pressure Vessels and Piping,1994,59(1/2/3):71. [50] 陈睿恺. 30Cr2 Ni4MoV钢低压转子热处理工艺的研究[D]. 上海:上海交通大学,2012. (CHEN Rui-kai. Study on Heat Treatment for Low Pressure Rotors of 30Cr2 Ni4Mo V Steel[D]. Shanghai:Shanghai Jiao Tong University,2012.) [51] 韩利战. X12CrMoWVNbN1011钢超超临界转子热处理工艺的研究[D]. 上海:上海交通大学,2009. (HAN Li-zhan. Studies on Heat Treatment Process for Ultra—Supercritical Rotors of X12CrMoWVNbNl011 Steel[D]. Shanghai:Shanghai Jiao Tong University,2009.) [52] 康大滔,叶国斌. 大型锻件材料及热处理[M]. 北京:龙门书局,1998. (KANG Da-tao,YE Guo-bin. Large Forging Materials and Heat Treatment[M]. Beijing:Longmen Publishing Company,1998.) [53] Roberts S. Martensitic steels for cast components in ultra-supercritical power plants[J]. Materials for Ultra-Supercritical and Advanced Ultra-Supercritical Power Plants,2017,104:121. [54] 王晓芳. 620 ℃汽轮机转子锻件用钢晶粒细化热处理工艺研究[J]. 大型铸锻件,2016(2):6.(WANG Xiao-fang. Research on grain refining heat treatment process of steel used for 620 ℃ steam turbine rotor forgings[J]. Heavy Casting and Forging,2016(2):6.) [55] 张思清,刘凯泉,刘时雨. 1Cr12Mo钢晶粒细化热处理工艺的研究[J]. 大型铸锻件,2007(6):11. (ZHANG Si-qing,LIU Kai-quan,LIU Shi-yu. The research on grain refinement heat treatment process for 1Cr12Mo steel[J]. Eavy Casting and Forging,2007(6):11.) [56] Kondo M,Tabuchi M,Tsukamoto S,et al. Suppressing type IV failure via modification of heat affected zone microstructures using high boron content in 9Cr heat resistant steel welded joints[J]. Science and Technology of Welding and Joining,2006,11(2):216. [57] 严鹏. 新型马氏体耐热钢G115的组织与性能研究[D]. 北京:清华大学,2014. (YAN Peng. Microstructure and Properties of a Novel Martensitic Heat Resistant Steel G115[D]. Beijing:Tsinghua University,2014.) [58] XIAO Bo,XU Lian-yong,TANG Zheng-xin,et al. A physical-based yield strength model for the microstructural degradation of G115 steel during long-term creep[J]. Materials Science and Engineering A,2019,747:161. [59] LIU Zhen,LIU Zheng-dong,WANG X-itao,et al. Investigation of the microstructure and strength in G115 steel with the different concentration of tungsten during creep test[J]. Materials Characterization,2019,149:95. [60] Benaarbia A,Xu X,Sun W,et al. Investigation of short-term creep deformation mechanisms in marbn steel at elevated temperatures[J]. Materials Science and Engineering A,2018,734:491. [61] Abstossa K G,Schmigallab S,Schultzeb S,et al. Microstructural changes during creep and aging of a heat resistant MARBN steel and their effect on the electrochemical behaviour[J]. Materials Science and Engineering A,2019,743:233. [62] Matsunaga T,Hongo H,Tabuchi M,et al. Suppression of grain refinement in heat-affected zone of 9Cr-3W-3Co-VNb steels[J]. Materials Science and Engineering A,2016,655:168. |
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