|
|
Kinetic analysis and prediction of FeO eutectoid transformation in hot-rolled strip steel |
WANG Hao, CAO Guangming, SHAN Wenchao, CUI Chunyuan, LIU Zhenyu |
The State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819, Liaoning, China |
|
|
Abstract The oxide scales will be formed on the surface of the hot-rolled strip,in which FeO will undergo eutectoid phase transformation during the cooling process after coiling,forming a eutectoid organization consisting of Fe and Fe3O4. Traditionally,studies on the eutectoid phase transformation have focused on the qualitative analysis of the eutectoid phase transformation,such as chemical composition,phase transformation environment and other factors,but there are few modeling analyses and calculations for the phase transformation process. Besides,since the phase transformation process of FeO in actual production mostly occurs during continuous cooling,it is affected by the superposition of temperature changes at different moments,which increases the degree of difficulty in the study. For this reason,the isothermal structural transformation experiments of FeO at different temperatures and times were first conducted using a simultaneous thermal analyzer for common plain carbon steel. The volume percent of eutectoid structures in FeO at 30 experimental nodes was counted. Afterwards,an isothermal phase transition kinetic model of FeO was established based on Johnson-Mehl-Avrami-Kolmogorov(JMAK) equation,and the key parameters were solved by the experimental data to obtain the volume percent of eutectoid structure versus time under isothermal transition conditions,and the Time-Temperature-Transformation(TTT) curves can be directly plotted to describe the eutectoid transition of FeO.On the basis of this isothermal phase transition,a model for the FeO eutectoid phase transformation during continuous cooling was established by combining Scheil′s additivity law,and the volume percent of FeO eutectoid organization during continuous cooling transformation was predicted by calculating the model constant. With the experimental validation,the predicted volume percent of FeO eutectoid phase transformation remains basically consistent with the experimental values,which proves the usability of the model. This method can be used to describe the phase transformation process of FeO more concretely and provide a new solution for the study of the phase transformation behavior of FeO.
|
Received: 26 May 2023
|
|
|
|
[1] 刘振宇,李志峰. 新一代热轧板带材表面氧化铁皮控制技术的现状与进展[J]. 轧钢,2020,37(1):1. (LIU Z Y,LI Z F. State of the art development on technology for new generation to controlling oxide scale of hot rolled plate and strip[J]. Steel Rolling,2020,37(1):1.) [2] CHEN R Y,YUEN W Y D. Review of the high-temperature oxidation of iron and carbon steels in air or oxygen[J]. Oxidation of Metals,2003,59(5/6):433. [3] 刘振宇,曹光明. 热轧钢材高温氧化行为及氧化铁皮控制技术开发与应用[M]. 北京:冶金工业出版社,2021. (LIU Z Y,CAO G M. Studies on Oxidation Behavior of Steels During Hot Rolling and Development and Application of the Scale Control Technologies[M]. Beijing:Metallurgical Industry Press,2021.) [4] GLEESON B,HADAVI S M M,YOUNG D J. Isothermal transformation behavior of thermally-grown wüstite[J]. Materials at High Temperatures,2000,17(2):311. [5] 曹光明,刘怡私,高欣宇,等. 700 MPa级别热轧高强钢氧化铁皮结构转变规律[J]. 工程科学学报,2019,41(12):1591.(CAO G M,LIU Y S,GAO X Y,et al. Structural transformation of oxide scale of 700 MPa grade hot rolled high strength steel[J]. Chinese Journal of Engineering,2019,41(12):1591.) [6] LIU S,TANG D,WU H B,et al. Isothermal transformation of wustite for low carbon micro-alloyed steel[C]//Advanced Materials Research. Switzerland:Trans Tech Publications Ltd,2013:457. [7] WANG H,CAO G M,LI S L,et al. Eutectoid transformation kinetics of FeO under N2and air atmospheres[J]. Metals,2023,13(2):220. [8] 曹光明,何永全,刘小江,等. 热轧低碳钢卷取后冷却过程中三次氧化铁皮结构转变行为[J]. 中南大学学报(自然科学版),2014,45(6):1790.(CAO G M,HE Y Q,LIU X J,et al. Tertiary oxide scale structure transition of low carbon steel during continuous cooling after coiling process[J]. Journal of Central South University(Science and Technology),2014,45(6):1790.) [9] 吴迪青,王耀,廖砚林,等. 热轧SPHC带钢酸洗行为及其高效酸洗工艺研究[J]. 轧钢,2022,39(2):44.(WU D Q,WANG Y,LIAO Y L,et al. Research on pickling behavior of hot rolled SPHC strip and a high efficiency pickling process[J]. Steel Rolling,2022,39(2):44.) [10] CHEN R Y,YUEN W Y D.A study of the scale structure of hot-rolled steel strip by simulated coiling and cooling[J]. Oxidation of Metals,2020,53(5/6):539. [11] HAYASHI S,YAMANOUCHI Y,HAYASHI K,et al. Stress measurement in the iron oxide scale formed on pure Fe during isothermal transformation by in situ high-temperature X-ray diffraction[J]. Corrosion Science,2021,187:109482. [12] HAYASHI S,MIZUMOTO K,YONEDA S,et al. The mechanism of phase transformation in thermally-grown FeO scale formed on pure-Fe in air[J]. Oxidation of Metals,2014,81(3/4):357. [13] YONEDA S,HAYASHI S,KONDO Y,et al. Effect of Mn on isothermal transformation of thermally grown FeO scale formed on Fe-Mn alloys[J]. Oxidation of Metals,2017,87(1/2):125. [14] HAYASHI S,YONEDA S,KONDO Y,et al. Phase transformation of thermally grown FeO formed on high-purity Fe at low oxygen potential[J]. Oxidation of Metals,2020,94(1/2):81. [15] PAIDASSI J. The precipitation of Fe3O4 in scales formed by oxidation of iron at elevated temperatures[J]. Acta Metallurgica,1955,3(5):447. [16] ZHOU C H,MA H T,LI Y,et al. Eutectoid magnetite in wüstite under conditions of compressive stress and cooling[J]. Oxidation of Metals,2012,78(1):145. [17] LI Z F,CAO G M,LIN F,et al. Phase transformation behavior of oxide scale on plain carbon steel containing 0.4wt.% Cr during continuous cooling[J]. ISIJ International,2018,58(12):2338. [18] LI Z F,CAO G M,LIN F,et al. Characterization of oxide scales formed on plain carbon steels in dry and wet atmospheres and their eutectoid transformation from FeO in inert atmosphere[J]. Oxidation of Metals,2018,90(3/4):337. [19] LIN S N,HUANG C C,WU M T,et al. Crucial mechanism to the eutectoid transformation of wüstite scale on low carbon steel[J]. Steel Research International,2017,88(11):1700045. [20] SUN W,TIEU A K,JIANG Z,et al. High temperature oxide scale characteristics of low carbon steel in hot rolling[J]. Journal of Materials Processing Technology,2004,155:1307. [21] 韩斌,刘振宇,杨奕,等. 轧制过程表面氧化层控制技术的研发应用[J]. 轧钢,2016,33(3):49.(HAN B,LIU Z Y,YANG Y,et al. Research and application of oxide scale control technology in rolling process[J]. Steel Rolling,2016,33(3):49.) [22] CAO G M,WU T Z,XU R,et al. Effects of coiling temperature and cooling condition on transformation behavior of tertiary oxide scale[J]. Journal of Iron and Steel Research International,2015,22(10):892. [23] YU X L,JIANG Z Y,ZHAO J W,et al. Effect of cooling rate on oxidation behavior of micro-alloyed steel[C]//Applied Mechanics and Materials. Switzerland:Trans Tech Publications Ltd,2013:273. [24] 李美栓. 金属的高温腐蚀[M]. 北京:冶金工业出版社,2001.(LI M S. High Temperature Corrosion of Metals[M]. Beijing:Metallurgical Industry Press,2001.) [25] WILLIAM J,MEHL R. Reaction kinetics in processes of nucleation and growth[J]. AIME,1939,135(8):416. [26] AVRAMI M. Kinetics of phase change. II transformation-time relations for random distribution of nuclei[J]. The Journal of Chemical Physics,1940,8(2):212. [27] MAISURADZE M V,YUDIN Y V,RYZHKOV M A. Numerical simulation of pearlitic transformation in steel 45Kh5MF[J]. Metal Science and Heat Treatment,2015,56(9):512. [28] BOK H H,KIM S N,SUH D W,et al. Non-isothermal kinetics model to predict accurate phase transformation and hardness of 22MnB5 boron steel[J]. Materials Science and Engineering A,2015,626:67. [29] LIU F,YANG C,YANG G,et al. Additivity rule,isothermal and non-isothermal transformations on the basis of an analytical transformation model[J]. Acta Materialia,2007,55(15):5255. [30] XU J,LIU Y,ZHOU S. Computer simulation on the controlled cooling of 82B high-speed rod[J]. Journal of University of Science and Technology Beijing,2008,15(3):330. [31] KIRKALDY J S,BAGANIS E A. Thermodynamic prediction of the Ae3 temperature of steels with additions of Mn,Si,Ni,Cr,Mo,Cu[J]. Metallurgical Transactions A,1978,9(4):495. |
[1] |
XIA Wen1,JIA Juan1,LIU Jing1,CHAI Xiyang2. Oxidation behavior of 590MPa high strength ship plate steel at high temperature[J]. JOURNAL OF IRON AND STEEL RESEARCH , 2023, 35(9): 1142-1151. |
[2] |
ZHANG Zhen, TANG Jue, CHU Mansheng, LIU Zhenggen, LI Fumin, LÜ Qing. Long short term comprehensive prediction of sinter FeO components based on EEMD and machine learning[J]. Iron and Steel, 2023, 58(8): 32-40. |
[3] |
ZHANG Jie, KONG Ning, WANG Yi-bo, SONG Yu-wei. Quantitative evaluation and analysis on spalling of powdered iron oxide scale for automobile beam steel[J]. Iron and Steel, 2023, 58(1): 125-132. |
[4] |
ZHANG Qi, MI Zhenli, ZHU Rong, WANG Mai, WU Yanxin, LI Lei. EBSD sample preparation and characterization method of oxide scale on the surface of hot-rolled steel strip[J]. PHYSICS EXAMINATION AND TESTING, 2023, 41(1): 21-24. |
[5] |
CAO Guang-ming, SHAN Wen-chao, LIU Xiao-jiang, WANG Chen-yang. High temperature oxidation behavior of Fe-2.2%Si steel in different atmosphere[J]. Iron and Steel, 2022, 57(8): 132-142. |
[6] |
SHI Xuexing,JU Xinhua,YAN Chunlian,WEN Juan. Effect of holding time at 850 ℃ on intergranular oxidation layer of 15CrMo steel[J]. PHYSICS EXAMINATION AND TESTING, 2022, 40(6): 1-. |
|
|
|
|