1 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081,Hubei, China 2 School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
Effect of vanadium on modification of inclusions in Mn- and Si-deoxidized steel during heat treatment at 1473 K
1 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081,Hubei, China 2 School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China
ժҪ The effect of vanadium (V) on the modification of oxide inclusions in steels with different concentrations of Mn, Si, and V was determined before and after heat treatment at 1473 K. Changes in the morphology, size, and composition of these inclusions were analyzed. Equilibrium relations between the inclusions and steels at 1873 K and 1473 K were calculated using available thermodynamic data to roughly approximate the stable oxide inclusions in the steels. The results revealed that the concentrations of V and Si in the steel are critical for controlling the modification of the inclusions during heat treatment at 1473 K. MnO-SiO2-type oxide inclusions gradually transformed into MnO-V2O3-type or Mn-SiO2- and MnO-V2O3-type inclusions in low-Si high-V steels heat-treated for 60 min. In addition, the morphology of the inclusions changed from spherical to irregular. A Si-accumulated zone and a V-depleted zone formed close to the interface in the steel matrix. The experimental and calculation results indicated that, during the heat treatment, an interface chemical reaction occurred between the Fe-Mn-Si-V steel and the MnO-SiO2-type oxide inclusion.
Abstract��The effect of vanadium (V) on the modification of oxide inclusions in steels with different concentrations of Mn, Si, and V was determined before and after heat treatment at 1473 K. Changes in the morphology, size, and composition of these inclusions were analyzed. Equilibrium relations between the inclusions and steels at 1873 K and 1473 K were calculated using available thermodynamic data to roughly approximate the stable oxide inclusions in the steels. The results revealed that the concentrations of V and Si in the steel are critical for controlling the modification of the inclusions during heat treatment at 1473 K. MnO-SiO2-type oxide inclusions gradually transformed into MnO-V2O3-type or Mn-SiO2- and MnO-V2O3-type inclusions in low-Si high-V steels heat-treated for 60 min. In addition, the morphology of the inclusions changed from spherical to irregular. A Si-accumulated zone and a V-depleted zone formed close to the interface in the steel matrix. The experimental and calculation results indicated that, during the heat treatment, an interface chemical reaction occurred between the Fe-Mn-Si-V steel and the MnO-SiO2-type oxide inclusion.
��������:Chinese National Natural Science Foundation;Chinese National Natural Science Foundation
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E-mail: chengsongliu@126.com
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Cheng-song Liu,Xiao-qin Liu,*,Hong-wei Ni,Shu-feng Yang,Jing-she Li,Fei Ye. Effect of vanadium on modification of inclusions in Mn- and Si-deoxidized steel during heat treatment at 1473 K[J]. �й������ڿ���, 2017, 24(5): 520-528.
Cheng-song Liu,Xiao-qin Liu,*,Hong-wei Ni,Shu-feng Yang,Jing-she Li,Fei Ye. Effect of vanadium on modification of inclusions in Mn- and Si-deoxidized steel during heat treatment at 1473 K. Chinese Journal of Iron and Steel, 2017, 24(5): 520-528.
2017, Vol. 24 
